Issue

Vol. 14 (2022)

Oxygen Evolution Reaction in Energy Conversion and Storage: Design Strategies Under and Beyond the Energy Scaling Relationship

https://doi.org/10.1007/s40820-022-00857-x
Jiangtian Li
U.S. Army Combat Capabilities Development Command Army Research Laboratory, 2800 Powder Mill Road, Adelphi, MD 20783, USA

Corresponding Author: Jiangtian Li

jiangtian.li.ctr@army.mil

Nano-Micro Letters, Vol. 14 (2022), Article Number: 112

Abstract

The oxygen evolution reaction (OER) is the essential module in energy conversion and storage devices such as electrolyzer, rechargeable metal–air batteries and regenerative fuel cells. The adsorption energy scaling relations between the reaction intermediates, however, impose a large intrinsic overpotential and sluggish reaction kinetics on OER catalysts. Developing advanced electrocatalysts with high activity and stability based on non-noble metal materials is still a grand challenge. Central to the rational design of novel and high-efficiency catalysts is the development and understanding of quantitative structure–activity relationships, which correlate the catalytic activities with structural and electronic descriptors. This paper comprehensively reviews the benchmark descriptors for OER electrolysis, aiming to give an in-depth understanding on the origins of the electrocatalytic activity of the OER and further contribute to building the theory of electrocatalysis. Meanwhile, the cutting-edge research frontiers for proposing new OER paradigms and crucial strategies to circumvent the scaling relationship are also summarized. Challenges, opportunities and perspectives are discussed, intending to shed some light on the rational design concepts and advance the development of more efficient catalysts for enhancing OER performance.


Highlights:


1 Catalytic descriptors for oxygen evolution reaction under scaling relationship are comprehensively reviewed.
2 New oxygen evolution paradigms and design strategies aiming to circumvent the adsorption energy scaling relationship are summarized.
3 Challenges and perspectives for further improving oxygen evolution activity are discussed.

Keywords

Oxygen evolution Energy conversion and storage Scaling relationship Catalytic descriptors Lattice oxygen oxidation
Li, Jiangtian. 2022. “Oxygen Evolution Reaction in Energy Conversion and Storage: Design Strategies Under and Beyond the Energy Scaling Relationship”. Nano-Micro Letters 14 (April):112. https://doi.org/10.1007/s40820-022-00857-x.
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References
  1. A.R. Zeradjanin, J. Masa, I. Spanos, R. Schlögl, Activity and stability of oxides during oxygen evolution reaction—from mechanistic controversies toward relevant electrocatalytic descriptors. Front. Energy Res. 8, 613092 (2021). https://doi.org/10.3389/fenrg.2020.613092
  2. Y. Pan, X. Xu, Y. Zhong, L. Ge, Y. Chen et al., Direct evidence of boosted oxygen evolution over perovskite by enhanced lattice oxygen participation. Nat. Commun. 11, 2002 (2020). https://doi.org/10.1038/s41467-020-15873-x
  3. Y. Yang, Y. Yu, J. Li, Q. Chen, Y. Du et al., Engineering ruthenium-based electrocatalysts for effective hydrogen evolution reaction. Nano-Micro Lett. 13, 160 (2021). https://doi.org/10.1007/s40820-021-00679-3
  4. A. Grimaud, K.J. May, C.E. Carlton, Y. Lee, M. Risch et al., Double perovskites as a family of highly active catalysts for oxygen evolution in alkaline solution. Nat. Commun. 4, 2439 (2013). https://doi.org/10.1038/ncomms3439
  5. M. Cui, X. Ding, X. Huang, Z. Shen, T. Lee et al., Ni3+-induced hole states enhance the oxygen evolution reaction activity of nixco3−xo4 electrocatalysts. Chem. Mater. 31(18), 7618–7625 (2019). https://doi.org/10.1021/acs.chemmater.9b02453
  6. W.H. Lee, M.H. Han, Y. Ko, B.K. Min, K.H. Chae et al., Electrode reconstruction strategy for oxygen evolution reaction: maintaining Fe–CoOOH phase with intermediate-spin state during electrolysis. Nat. Commun. 13, 605 (2022). https://doi.org/10.1038/s41467-022-28260-5
  7. D.A. Cullen, K.C. Neyerlin, R.K. Ahluwalia, R. Mukundan, K.L. More et al., New roads and challenges for fuel cells in heavy-duty transportation. Nat. Energy 6, 462–474 (2021). https://doi.org/10.1038/s41560-021-00775-z
  8. X. Wan, X. Liu, Y. Li, R. Yu, L. Zheng et al., Fe–N–C electrocatalyst with dense active sites and efficient mass transport for high-performance proton exchange membrane fuel cells. Nat. Catal. 2, 259–268 (2019). https://doi.org/10.1038/s41929-019-0237-3
  9. W.H. Lee, Y. Ko, J.H. Kim, C.H. Choi, K.H. Chae et al., High crystallinity design of Ir-based catalysts drives catalytic reversibility for water electrolysis and fuel cells. Nat. Commun. 12, 4271 (2021). https://doi.org/10.1038/s41467-021-24578-8
  10. J. Li, D. Chu, D.R. Baker, R. Jiang, Seamless separation of OHad and Had on a Ni–O catalyst toward exceptional alkaline hydrogen evolution. J. Mater. Chem. A 10(3), 1278–1283 (2022). https://doi.org/10.1039/D1TA07303F
  11. H. Nan, Y. Su, C. Tang, R. Cao, D. Li et al., Engineering the electronic and strained interface for high activity of PdMcore@Ptmonolayer electrocatalysts for oxygen reduction reaction. Sci. Bull. 65(16), 1396–1404 (2020). https://doi.org/10.1016/j.scib.2020.04.015
  12. P. Rao, Y. Liu, Y. Su, M. Zhong, K. Zhang et al., S, N co-doped carbon nanotube encased Co NPs as efficient bifunctional oxygen electrocatalysts for zinc–air batteries. Chem. Eng. J. 422, 130135 (2021). https://doi.org/10.1016/j.cej.2021.130135
  13. T.M. Gür, Review of electrical energy storage technologies, materials and systems: challenges and prospects for large-scale grid storage. Energy Environ. Sci. 11(10), 2696–2767 (2018). https://doi.org/10.1039/C8EE01419A
  14. Z. Seh, J. Kibsgaard, C.F. Dickens, I. Chorkendorff, J.K. Norskov et al., Combining theory and experiment in electrocatalysis: insights into materials design. Science 355(6321), eaad4998 (2017). https://doi.org/10.1126/science.aad4998
  15. L.C. Seitz, C.F. Dickens, K. Nishio, Y. Hikita, J. Montoya et al., A highly active and stable IrOx/SrIrO3 catalyst for the oxygen evolution reaction. Science 353(6303), 1011–1014 (2016). https://doi.org/10.1126/science.aaf5050
  16. H.N. Nong, T. Reier, H. Oh, M. Gliech, P. Paciok et al., A unique oxygen ligand environment facilitates water oxidation in hole-doped IrNiOx core-shell electrocatalysts. Nat. Catal. 1, 841–851 (2018). https://doi.org/10.1038/s41929-018-0153-y
  17. J. Zhang, Q. Zhou, Y. Tang, L. Zhang, Y. Li, Zinc–air batteries: are they ready for prime time? Chem. Sci. 10(39), 8924–8929 (2019). https://doi.org/10.1039/C9SC04221K
  18. W. Sun, F. Wang, B. Zhang, M. Zhang, V. Küpers et al., A rechargeable zinc–air battery based on zinc peroxide chemistry. Science 371(6524), 46–51 (2021). https://doi.org/10.1126/science.abb9554
  19. Y. Zhu, K. Yue, C. Xia, S. Zaman, H. Yang et al., Recent advances on MOF derivatives for non-noble metal oxygen electrocatalysts in zinc–air batteries. Nano-Micro Lett. 13, 137 (2021). https://doi.org/10.1007/s40820-021-00669-5
  20. W. Xia, A. Mahmood, Z. Liang, R. Zou, S. Guo, Earth-abundant nanomaterials for oxygen reduction. Angew. Chem. Int. Ed. 55(8), 2650–2676 (2016). https://doi.org/10.1002/anie.201504830
  21. Y.N. Regmi, X. Peng, J.C. Fornaciari, M. Wei, D.J. Myers et al., A low temperature unitized regenerative fuel cell realizing 60% round trip efficiency and 10,000 cycles of durability for energy storage applications. Energy Environ. Sci. 13(7), 2096–2105 (2020). https://doi.org/10.1039/C9EE03626A
  22. J.T. Mefford, A.R. Akbashev, M. Kang, C.L. Bentley, W.E. Gent et al., Correlative operando microscopy of oxygen evolution electrocatalysts. Nature 593, 67–73 (2021). https://doi.org/10.1038/s41586-021-03454-x
  23. H.N. Nong, L.J. Falling, A. Bergmann, M. Klingenhof, H.P. Tran et al., Key role of chemistry versus bias in electrocatalytic oxygen evolution. Nature 587, 408–413 (2020). https://doi.org/10.1038/s41586-020-2908-2
  24. J. Li, D. Chu, D.R. Baker, A. Leff, P. Zheng et al., Earth-abundant Fe and Ni dually doped Co2P for superior oxygen evolution reactivity and as a bifunctional electrocatalyst toward renewable energy-powered overall alkaline water splitting. ACS Appl. Energy Mater. 4(9), 9969–9981 (2021). https://doi.org/10.1021/acsaem.1c01926
  25. J. Li, D. Chu, H. Dong, D.R. Baker, R. Jiang, Boosted oxygen evolution reactivity by igniting double exchange interaction in spinel oxides. J. Am. Chem. Soc. 142(1), 50–54 (2020). https://doi.org/10.1021/jacs.9b10882
  26. R. Xie, Z. Nie, X. Hu, Y. Yu, C. Aruta et al., Pr-doped LaCoO3 toward stable and efficient oxygen evolution reaction. ACS Appl. Energy Mater. 4(9), 9057–9065 (2021). https://doi.org/10.1021/acsaem.1c01348
  27. J.S. Kim, B. Kim, H. Kim, K. Kang, Recent progress on multimetal oxide catalysts for the oxygen evolution reaction. Adv. Energy Mater. 8(11), 1702774 (2018). https://doi.org/10.1002/aenm.201702774
  28. H. Tian, L. Zeng, Y. Huang, Z. Ma, G. Meng et al., In situ electrochemical Mn(III)/Mn(IV) generation of Mn(II)O electrocatalysts for high-performance oxygen reduction. Nano-Micro Lett. 12, 161 (2020). https://doi.org/10.1007/s40820-020-00500-7
  29. G. Wu, A. Santandreu, W. Kellogg, S. Gupta, O. Ogoke et al., Carbon nanocomposite catalysts for oxygen reduction and evolution reactions: from nitrogen doping to transition-metal addition. Nano Energy 29, 83 (2016). https://doi.org/10.1016/j.nanoen.2015.12.032
  30. W.T. Hong, R.E. Welsch, Y. Shao-Horn, Descriptors of oxygen-evolution activity for oxides: a statistical evaluation. J. Phys. Chem. C 120(1), 78–86 (2016). https://doi.org/10.1021/acs.jpcc.5b10071
  31. B. Hammer, J.K. Nørskov, Theoretical surface science and catalysis-calculations and concepts. Adv. Catal. 45, 71–129 (2000). https://doi.org/10.1016/S0360-0564(02)45013-4
  32. H. Dau, C. Limberg, T. Reier, M. Risch, S. Roggan et al., The mechanism of water oxidation: from electrolysis via homogeneous to biological catalysis. ChemCatChem 2(7), 724–771 (2010). https://doi.org/10.1002/cctc.201000126
  33. H. Lv, D. Li, D. Strmcnik, A.P. Paulikas, N.M. Markovic et al., Recent advances in the design of tailored nanomaterials for efficient oxygen reduction reaction. Nano Energy 29, 149–165 (2016). https://doi.org/10.1016/j.nanoen.2016.04.008
  34. L. Gao, X. Cui, C. Sewell, J. Li, Z. Lin, Recent advances in activating surface reconstruction for the high-efficiency oxygen evolution reaction. Chem. Soc. Rev. 50(15), 8428–8569 (2021). https://doi.org/10.1039/D0CS00962H
  35. S. Yuan, X. Duan, J. Liu, Y. Ye, F. Lv et al., Recent progress on transition metal oxides as advanced materials for energy conversion and storage. Energy Storage Mater. 42, 317–369 (2021). https://doi.org/10.1016/j.ensm.2021.07.007
  36. H. Sun, X. Xu, Y. Song, W. Zhou, Z. Shao, Designing high-valence metal sites for electrochemical water splitting. Adv. Funct. Mater. 31(16), 2009779 (2021). https://doi.org/10.1002/adfm.202009779
  37. I.C. Man, H. Su, F. Calle-Vallejo, H.A. Hansen, J.I. Martínez et al., Universality in oxygen evolution electrocatalysis on oxide surfaces. ChemCatChem 3(7), 1159–1165 (2011). https://doi.org/10.1002/cctc.201000397
  38. J. Rossmeisl, A. Logadottir, J.K. Nørskov, Electrolysis of water on (oxidized) metal surfaces. Chem. Phys. 319(1–3), 178–184 (2005). https://doi.org/10.1016/j.chemphys.2005.05.038
  39. J. Rossmeisl, Z.W. Qu, H. Zhu, G.J. Kroes, J.K. Nørskov, Electrolysis of water on oxide surfaces. J. Electroanal. Chem. 607(1–2), 83–89 (2007). https://doi.org/10.1016/j.jelechem.2006.11.008
  40. J.K. Nørskov, J. Rossmeisl, A. Logadottir, L. Lindqvist, J.R. Kitchin et al., Origin of the overpotential for oxygen reduction at a fuel-cell cathode. J. Phys. Chem. B 108(46), 17886–17892 (2004). https://doi.org/10.1021/jp047349j
  41. Z. Huang, J. Song, S. Dou, X. Li, J. Wang et al., Strategies to break the scaling relationtoward enhanced oxygen electrocatalysis. Matter 1(6), 1494–1518 (2019). https://doi.org/10.1016/j.matt.2019.09.011
  42. X. Li, S. Duan, E. Sharman, Y. Zhao, L. Yang et al., Exceeding the volcano relationship in oxygen reduction/evolution reactions using single-atom-based catalysts with dual-active-sites. J. Mater. Chem. A 8(20), 10193–10198 (2020). https://doi.org/10.1039/D0TA01399D
  43. J. Liu, H. Liu, H. Chen, X. Du, B. Zhang et al., Progress and challenges toward the rational design of oxygen electrocatalysts based on a descriptor approach. Adv. Sci. 7(1), 1901614 (2020). https://doi.org/10.1002/advs.201901614
  44. J.K. Nørskov, F. Abild-Pedersen, F. Studt, T. Bligaard, Density functional theory in surface chemistry and catalysis. PNAS 108(3), 937–943 (2011). https://doi.org/10.1073/pnas.1006652108
  45. Z. Zhao, S. Liu, S. Zha, D. Cheng, F. Studt et al., Theory-guided design of catalytic materials using scaling relationships and reactivity descriptors. Nat. Rev. Mater. 4, 792–804 (2019). https://doi.org/10.1038/s41578-019-0152-x
  46. K. Zhang, R. Zou, Advanced transition metal-based OER electrocatalysts: current status, opportunities, and challenges. Small 17(37), 2100129 (2021). https://doi.org/10.1002/smll.202100129
  47. J.K. Nørskov, T. Bligaard, J. Rossmeisl, C.H. Christensen, Towards the computational design of solid catalysts. Nat. Chem. 1, 37–46 (2009). https://doi.org/10.1038/nchem.121
  48. Z. Wang, J. Huang, L. Wang, Y. Liu, W. Liu et al., Cation-tuning induced d-band center modulation on Co-based spinel oxide for oxygen reduction/evolution reaction. Angew. Chem. Int. Ed. (2022). https://doi.org/10.1002/anie.202114696
  49. K. Yang, P. Xu, Z. Lin, Y. Yang, P. Jiang et al., Ultrasmall Ru/Cu-doped RuO2 complex embedded in amorphous carbon skeleton as highly active bifunctional electrocatalysts for overall water splitting. Small 14(41), 1803009 (2018). https://doi.org/10.1002/smll.201803009
  50. S. Sun, X. Zhou, B. Cong, W. Hong, G. Chen, Tailoring the d-band centers endows (NixFe1−x)2P nanosheets with efficient oxygen evolution catalysis. ACS Catal. 10(16), 9086–9097 (2020). https://doi.org/10.1021/acscatal.0c01273
  51. W.T. Hong, M. Risch, K.A. Stoerzinger, A. Grimaud, J. Suntivich et al., Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis. Energy Environ. Sci. 8(5), 1404–1427 (2015). https://doi.org/10.1039/C4EE03869J
  52. Y. Lee, J. Kleis, J. Rossmeisl, Y. Shao-Horn, D. Morgan, Prediction of solid oxidefuel cell cathode activity with first-principles descriptors. Energy Environ. Sci. 4(10), 3966–3970 (2011). https://doi.org/10.1039/C1EE02032C
  53. Y. Lee, D. Lee, X.R. Wang, H.N. Lee, D. Morgan et al., Kinetics of oxygen surface exchange on epitaxial Ruddlesden–Popper phases and correlations to first-principles descriptors. J. Phys. Chem. Lett. 7(2), 244–249 (2016). https://doi.org/10.1021/acs.jpclett.5b02423
  54. W. Xie, Y. Lee, Y. Shao-Horn, D. Morgan, Oxygen point defect chemistry in Ruddlesden–Popper oxides (La1−xSrx)2MO4±δ (M=Co, Ni, Cu). J. Phys. Chem. Lett. 7(10), 1939–1944 (2016). https://doi.org/10.1021/acs.jpclett.6b00739
  55. A. Fujimori, Electronic structure of metallic oxides: band-gap closure and valence control. J. Phys. Chem. Solids 53(12), 15951602 (1992). https://doi.org/10.1016/0022-3697(92)90149-8
  56. E. Antolini, J. Salgado, E. Gonzalez, The stability of Pt–M (M = first row transition metal) alloy catalysts and its effect on the activity in low temperature fuel cells: a literature review and tests on a Pt–Co catalyst. J. Power Sources 160(2), 957–968 (2006). https://doi.org/10.1016/j.jpowsour.2006.03.006
  57. T. Wang, Y. Sun, Y. Zhou, S. Sun, X. Hu et al., Identifying influential parameters of octahedrally coordinated cations in spinel ZnMnxCo2−xO4 oxides for the oxidation reaction. ACS Catal. 8(9), 8568–8577 (2018). https://doi.org/10.1021/acscatal.8b02376
  58. H. Ding, H. Liu, W. Chu, C. Wu, Y. Xie, Structural transformation of heterogeneous materials for electrocatalytic oxygen evolution reaction. Chem. Rev. 121(21), 13174–13212 (2021). https://doi.org/10.1021/acs.chemrev.1c00234
  59. K.J. May, C.E. Carlton, K.A. Stoerzinger, M. Risch, J. Suntivich et al., Influence of oxygen evolution during water oxidation on the surface of perovskite oxide catalysts. J. Phys. Chem. Lett. 3(22), 3264–3270 (2012). https://doi.org/10.1021/jz301414z
  60. B. Han, K.A. Stoerzinger, V. Tileli, A.D. Gamalski, E.A. Stach et al., Nanoscale structural oscillations in perovskite oxides induced by oxygen evolution. Nat. Mater. 16, 121–126 (2017). https://doi.org/10.1038/nmat4764
  61. Y. Matsumoto, H. Yoneyama, H. Tamura, Catalytic activity for electrochemical reduction of oxygen of lanthanum nickel oxide and related oxides. J. Electroanal. Chem. Interfacial Electrochem. 79(2), 319–326 (1977). https://doi.org/10.1016/S0022-0728(77)80453-1
  62. Y. Matsumoto, H. Yoneyama, H. Tamura, Influence of the nature of the conduction band of transition metal oxides on catalytic activity for oxygen reduction. J. Electroanal. Chem. Interfacial Electrochem. 83(2), 237–243 (1977). https://doi.org/10.1016/S0022-0728(77)80169-1
  63. J. Suntivich, K.J. May, H.A. Gasteiger, J.B. Goodenough, Y. Shao-Horn, A perovskite oxide optimized for oxygen evolution catalysis from molecular orbital principles. Science 334(6061), 1383–1385 (2011). https://doi.org/10.1126/science.1212858
  64. J. Suntivich, H.A. Gasteiger, N. Yabuuchi, H. Nakanishi, J.B. Goodenough et al., Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries. Nat. Chem. 3, 546–550 (2011). https://doi.org/10.1038/nchem.1069
  65. C. Wei, Z. Feng, G.G. Scherer, J. Barber, Y. Shao-Horn et al., Cations in octahedral sites: a descriptor for oxygen electrocatalysis on transition-metal spinels. Adv. Mater. 29(23), 1606800 (2017). https://doi.org/10.1002/adma.201606800
  66. J. Bockris, T. Otagawa, Mechanism of oxygen evolution on perovskites. J. Phys. Chem. 87(15), 2960–2971 (1983). https://doi.org/10.1021/j100238a048
  67. J. Bockris, T. Otagawa, The electrocatalysis of oxygen evolution on perovskites. J. Electrochem. Soc. 131, 290 (1984). https://doi.org/10.1149/1.2115565
  68. J. Suntivich, W.T. Hong, Y. Lee, J.M. Rondinell, W. Yang et al., Estimating hybridization of transition metal and oxygen states in perovskites from O K-edge X-ray absorption spectroscopy. J. Phys. Chem. C 118(4), 1856–1863 (2013). https://doi.org/10.1021/jp410644j
  69. X. Wang, X.J. Gao, L. Qin, C. Wang, L. Song et al., eg occupancy as an effective descriptor for the catalytic activity of perovskite oxide-based peroxidase mimics. Nat. Commun. 10, 704 (2019). https://doi.org/10.1038/s41467-019-08657-5
  70. M. Yu, G. Li, C. Fu, E. Liu, K. Manna et al., Tunable eg Orbital occupancy in heusler compounds for oxygen evolution reaction. Angew. Chem. Int. Ed. 60(11), 5800–5805 (2021). https://doi.org/10.1002/anie.202013610
  71. J. Song, C. Wei, Z. Huang, C. Liu, L. Zeng et al., A review on fundamentals for designing oxygen evolution electrocatalysts. Chem. Soc. Rev. 49(7), 2196–2214 (2020). https://doi.org/10.1039/C9CS00607A
  72. Y. Li, H. Jiang, Z. Cui, S. Zhu, Z. Li et al., Spin state tuning of the octahedral sites in Ni–Co-based spinel toward highly efficient urea oxidation reaction. J. Phys. Chem. C 125(17), 9190–9199 (2021). https://doi.org/10.1021/acs.jpcc.1c02116
  73. Y. Tong, Y. Guo, P. Chen, H. Liu, M. Zhang et al., Spin-state regulation of perovskite cobaltite to realize enhanced oxygen evolution activity. Chem 3(5), 812–821 (2017). https://doi.org/10.1016/j.chempr.2017.09.003
  74. H. Liu, S. Liu, Y. Zou, X. Zhang, P. Guo et al., Synergistic doping and tailoring: realizing in depth modulation on valence state of CoFe spinel oxide for high-efficiency water oxidation. Appl. Surf. Sci. 572, 151388 (2022). https://doi.org/10.1016/j.apsusc.2021.151388
  75. Y. Zhou, S. Sun, S. Xi, Y. Duan, T. Sritharan et al., Superexchange effects on oxygen reduction activity of edge-sharing [CoxMn1−xO6] octahedra in spinel oxide. Adv. Mater. 30(11), 1705407 (2018). https://doi.org/10.1002/adma.201705407
  76. A. Badreldin, A.E. Abusrafa, A. Abdel-Wahab, Oxygen-deficient cobalt-based oxides for electrocatalytic water splitting. Chemsuschem 14(1), 10–32 (2021). https://doi.org/10.1002/cssc.202002002
  77. Y. Guo, Y. Tong, P. Chen, K. Xu, J. Zhao et al., Engineering the electronic state of a perovskite electrocatalyst for synergistically enhanced oxygen evolution reaction. Adv. Mater. 27(39), 5989–5994 (2015). https://doi.org/10.1002/adma.201502024
  78. J. Hwang, R.R. Rao, L. Giordano, Y. Katayama, Y. Yu et al., Perovskites in catalysis and electrocatalysis. Science 358(6364), 751–756 (2017). https://doi.org/10.1126/science.aam7092
  79. W.T. Hong, K.A. Stoerzinger, Y. Lee, L. Giordano, A. Grimaud et al., Charge-transfer-energy-dependent oxygen evolution reaction mechanisms for perovskite oxides. Energy Environ. Sci. 10(10), 2190–2200 (2017). https://doi.org/10.1039/C7EE02052J
  80. D.A. Kuznetsov, B. Han, Y. Yu, R.R. Rao, J. Hwang et al., Tuning redox transitions via inductive effect in metal oxides and complexes, and implicationsin oxygen electrocatalysis. Joule 2(2), 225–244 (2018). https://doi.org/10.1016/j.joule.2017.11.014
  81. Y. Duan, S. Sun, S. Xi, X. Ren, Y. Zhou et al., Tailoring the Co 3d-O 2p covalency in LaCoO3 by Fe substitution to promote oxygen evolution reaction. Chem. Mater. 29(24), 10534–10541 (2017). https://doi.org/10.1021/acs.chemmater.7b04534
  82. D. Du, R. Zheng, X. Chen, W. Xiang, C. Zhao et al., Adjusting the covalency of metal–oxygen bonds in LaCoO3 by Sr and Fe cation codoping to achieve highly efficient electrocatalysts for aprotic lithium–oxygen batteries. ACS Appl. Mater. Interfaces 13(28), 33133–33146 (2021). https://doi.org/10.1021/acsami.1c08586
  83. S. Yagi, I. Yamada, H. Tsukasaki, A. Seno, M. Murakami et al., Covalency-reinforced oxygen evolution reaction catalyst. Nat. Commun. 6, 8249 (2015). https://doi.org/10.1038/ncomms9249
  84. Y. Zhou, S. Sun, J. Song, S. Xi, B. Chen et al., Enlarged Co–O covalency in octahedral sites leading to highly efficient spinel oxides for oxygen evolution reaction. Adv. Mater. 30(32), 1802912 (2018). https://doi.org/10.1002/adma.201802912
  85. F. Liu, M. Yu, X. Chen, J. Li, H. Liu et al., Defective high-entropy rocksalt oxide with enhanced metal-oxygen covalency for electrocatalytic oxygen evolution. Chin. J. Catal. 43(1), 122–129 (2022). https://doi.org/10.1016/S1872-2067(21)63794-4
  86. Y. Zhu, H.A. Tahini, Z. Hu, Y. Yin, Q. Lin et al., Boosting oxygen evolution reaction by activation of lattice-oxygen sites in layered Ruddlesden–Popper oxide. EcoMat 2(2), e12021 (2020). https://doi.org/10.1002/eom2.12021
  87. S. Sun, Y. Sun, Y. Zhou, S. Xi, X. Ren et al., Shifting oxygen charge towards octahedral metal: a way to promote water oxidation on cobalt spinel oxides. Angew. Chem. Int. Ed. 58(18), 6042–6047 (2019). https://doi.org/10.1002/anie.201902114
  88. X. Cheng, E. Fabbri, M. Nachtegaal, I.E. Castelli, M.E. Kazzi et al., Oxygen evolution reaction on L1−xSrxCoO3 perovskites: a combined experimental and theoretical study of their structural, electronic, and electrochemical properties. Chem. Mater. 27(22), 7662–7672 (2015). https://doi.org/10.1021/acs.chemmater.5b03138
  89. C. Yang, A. Grimaud, Factors controlling the redox activity of oxygen in perovskites: from theory to application for catalytic reactions. Catalysts 7(5), 149 (2017). https://doi.org/10.3390/catal7050149
  90. F. Calle-Vallejo, N.G. Inoglu, H. Su, J.I. Martínez, I.C. Man et al., Number of outer electrons as descriptor for adsorption processes on transition metals and their oxides. Chem. Sci. 4(3), 1245–1249 (2013). https://doi.org/10.1039/C2SC21601A
  91. F. Calle-Vallejo, J.I. Martínez, J.M. García-Lastra, J. Rossmeisl, M.T.M. Koper, Physical and chemical nature of the scaling relations between adsorption energies of atoms on metal surfaces. Phys. Rev. Lett. 108, 116103 (2012). https://doi.org/10.1103/PhysRevLett.108.116103
  92. F. Calle-Vallejo, J.I. Martínez, J.M.G. Lastra, E. Abad, M.T.M. Koper, Oxygen reduction and evolution at single-metal active sites: comparison between functionalized graphitic materials and protoporphyrins. Surf. Sci. 607, 47–53 (2013). https://doi.org/10.1016/j.susc.2012.08.005
  93. F. Calle-Vallejo, O. Diaz-Morales, M.J. Kolb, M.T.M. Koper, Why is bulk thermochemistry a good descriptor for the electrocatalytic activity of transition metal oxides? ACS Catal. 5(2), 869–873 (2015). https://doi.org/10.1021/cs5016657
  94. C.F. Dickens, J.H. Montoya, A.R. Kulkarni, M. Bajdich, J.K. Nørskov, An electronic structure descriptor for oxygen reactivity at metal and metaloxide surfaces. Surf. Sci. 681, 122–129 (2019). https://doi.org/10.1016/j.susc.2018.11.019
  95. H.B. Tao, L. Fang, J. Chen, H.B. Yang, J. Gao et al., Identification of surface reactivity descriptor for transition metal oxides in oxygen evolution reaction. J. Am. Chem. Soc. 138(31), 9978–9985 (2016). https://doi.org/10.1021/jacs.6b05398
  96. N. Govindarajan, M.T.M. Koper, E.J. Meijer, F. Calle-Vallejo, Outlining the scaling-based and scaling-free optimization of electrocatalysts. ACS Catal. 9(5), 4218–4225 (2019). https://doi.org/10.1021/acscatal.9b00532
  97. C.F. Dickens, C. Kirk, J.K. Nørskov, Insights into the electrochemical oxygen evolution reaction with ab initio calculations and microkinetic modeling: beyond the limiting potential volcano. J. Phys. Chem. C 123(31), 18960–18977 (2019). https://doi.org/10.1021/acs.jpcc.9b03830
  98. N.B. Halck, V. Petrykin, P. Krtil, J. Rossmeisl, Beyond the volcano limitations in electrocatalysis–oxygen evolution reaction. Phys. Chem. Chem. Phys. 16(27), 13688–13688 (2014). https://doi.org/10.1039/C4CP00571F
  99. M. Kodera, Y. Kawahara, Y. Hitomi, T. Nomura, T. Ogura et al., Reversible O–O bond scission of peroxodiiron(III) to high-spin oxodiiron(IV) in dioxygen activation of a diiron center with a bis-tpa dinucleating ligand as a soluble methane monooxygenase model. J. Am. Chem. Soc. 134(32), 13236–13239 (2012). https://doi.org/10.1021/ja306089q
  100. S. Kundu, E. Matito, S. Walleck, F.F. Pfaff, F. Heims et al., O–O bond formation mediated by a hexanuclear iron complex supported on a stannoxane. Chem. Eur. J. 18(10), 2787–2791 (2012). https://doi.org/10.1002/chem.201102326
  101. M. Okamura, M. Kondo, R. Kuga, Y. Kurashige, T. Yanai et al., A pentanuclear iron catalyst designed for water oxidation. Nature 530, 465–468 (2016). https://doi.org/10.1038/nature16529
  102. Y. Umena, K. Kawakami, J. Shen, N. Kamiya, Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å. Nature 473, 55–60 (2011). https://doi.org/10.1038/nature09913
  103. G.C. Dismukes, R. Brimblecombe, G.A.N. Felton, R.S. Pryadun, J.E. Sheats et al., Development of bioinspired Mn4O4-cubane water oxidation catalysts: lessons from photosynthesis. Acc. Chem. Res. 42(12), 1935–1943 (2009). https://doi.org/10.1021/ar900249x
  104. A. Ramírez, P. Hillebrand, D. Stellmach, M.M. May, P. Bogdanoff et al., Evaluation of MnOx, Mn2O3, and Mn3O4 electrodeposited films for the oxygen evolution reaction of water. J. Phys. Chem. C 118(26), 14073–14081 (2014). https://doi.org/10.1021/jp500939d
  105. C. Lin, J. Li, X. Li, S. Yang, W. Luo et al., In-situ reconstructed Ru atom array on α-MnO2 with enhanced performance for acidic water oxidation. Nat. Catal. 4, 1012–1023 (2021). https://doi.org/10.1038/s41929-021-00703-0
  106. J.O. Bockris, Kinetics of activation controlled consecutive electrochemical reactions: anodic evolution of oxygen. J. Chem. Phys. 24, 817 (1956). https://doi.org/10.1063/1.1742616
  107. F. Song, M.M. Busch, B. Lassalle-Kaiser, C. Hsu, E. Petkucheva et al., An unconventional iron nickel catalyst for the oxygen evolution reaction. ACS Cent. Sci. 5(3), 558–568 (2019). https://doi.org/10.1021/acscentsci.9b00053
  108. P. Garrido-Barros, C. Gimbert-Suriñach, R. Matheu, X. Sala, A. Llobet, How to make an efficient and robust molecular catalyst for water oxidation. Chem. Soc. Rev. 46(20), 6088–6098 (2017). https://doi.org/10.1039/C7CS00248C
  109. Z. Gao, J. Liu, X. Chen, X. Zheng, J. Mao et al., Engineering NiO/NiFe LDH intersection to bypass scaling relationship for oxygen evolution reaction via dynamic tridimensional adsorption of intermediates. Adv. Mater. 31(11), 1804769 (2019). https://doi.org/10.1002/adma.201804769
  110. N.B. Halck, V. Petrykin, P. Krtil, J. Rossmeisl, Beyond the volcano limitations in electrocatalysis—oxygen evolution reaction. Phys. Chem. Chem. Phys. 16(27), 13682–13688 (2014). https://doi.org/10.1039/C4CP00571F
  111. H. Fei, J. Dong, Y. Feng, C.S. Allen, C. Wan et al., General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities. Nat. Catal. 1, 63–72 (2018). https://doi.org/10.1038/s41929-017-0008-y
  112. J. Zhang, J. Liu, L. Xi, Y. Yu, N. Chen et al., Single-atom Au/NiFe layered double hydroxide electrocatalyst: probing the origin of activity for oxygen evolution reaction. J. Am. Chem. Soc. 140(11), 3876–3879 (2018). https://doi.org/10.1021/jacs.8b00752
  113. H. Wang, S. Xu, C. Tsai, Y. Li, C. Liu et al., Direct and continuous strain control of catalysts with tunable battery electrode materials. Science 354(6315), 1031–1036 (2016). https://doi.org/10.1126/science.aaf7680
  114. L. Bu, N. Zhang, S. Guo, X. Zhang, J. Li et al., Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis. Science 354(6318), 1410–1414 (2016). https://doi.org/10.1126/science.aah6133
  115. M. Luo, S. Guo, Strain-controlled electrocatalysis on multimetallic nanomaterials. Nat. Rev. Mater. 2, 17059 (2017). https://doi.org/10.1038/natrevmats.2017.59
  116. Y. Xie, Z. Wang, T. Zhua, D. Shu, Z. Hou et al., Breaking the scaling relations for oxygen reduction reaction on nitrogen-doped graphene by tensile strain. Carbon 139, 129–136 (2018). https://doi.org/10.1016/j.carbon.2018.06.026
  117. A. Khorshidi, J. Violet, J. Hashemi, A.A. Peterson, How strain can break the scaling relations of catalysis. Nat. Catal. 1, 263–268 (2018). https://doi.org/10.1038/s41929-018-0054-0
  118. A.D. Doyle, J.H. Montoya, A. Vojvodic, Improving oxygen electrochemistry through nanoscopic confinement. ChemCatChem 7(5), 738–742 (2015). https://doi.org/10.1002/cctc.201402864
  119. Y. Li, L. Zhang, J. Peng, W. Zhang, K. Peng, Magnetic field enhancing electrocatalysis of Co3O4/NF for oxygen evolution reaction. J. Power Sources 433, 226704 (2019). https://doi.org/10.1016/j.jpowsour.2019.226704
  120. F.A. Garcés-Pineda, M. Blasco-Ahicart, D. Nieto-Castro, N. López, J.R. Galán-Mascarós, Direct magnetic enhancement of electrocatalytic water oxidation in alkaline media. Nat. Energy 4, 519–525 (2019). https://doi.org/10.1038/s41560-019-0404-4
  121. W. Mtangi, F. Tassinari, K. Vankayala, A.V. Jentzsch, B. Adelizzi et al., Control of electrons’ spin eliminates hydrogen peroxide formation during water splitting. J. Am. Chem. Soc. 139(7), 2794–2798 (2017). https://doi.org/10.1021/jacs.6b12971
  122. X. Ren, T. Wu, Y. Sun, Y. Li, G. Xian et al., Spin-polarized oxygen evolution reaction under magnetic field. Nat. Commun. 12, 2608 (2021). https://doi.org/10.1038/s41467-021-22865-y
  123. Y. Zhang, P. Guo, S. Li, J. Sun, W. Wang et al., Magnetic field assisted electrocatalytic oxygen evolution reaction of nickel-based materials. J. Mater. Chem. A 10(4), 1760–1767 (2022). https://doi.org/10.1039/D1TA09444K
  124. G. Zhou, P. Wang, H. Li, B. Hu, Y. Sun et al., Spin-state reconfiguration induced by alternating magnetic field for efficient oxygen evolution reaction. Nat. Commun. 12, 4827 (2021). https://doi.org/10.1038/s41467-021-25095-4
  125. L. Gao, X. Cui, Z. Wang, C.D. Sewell, Z. Li et al., Operando unraveling photothermal-promoted dynamic active-sites generation in NiFe2O4 for markedly enhanced oxygen evolution. PNAS 118(7), e2023421118 (2021). https://doi.org/10.1073/pnas.2023421118
  126. J. Li, N. Wu, Semiconductor-based photocatalysts and photoelectrochemical cells for solar fuel generation: a review. Catal. Sci. Technol. 5(3), 1360–1384 (2015). https://doi.org/10.1039/C4CY00974F
  127. J. Li, S. Cushing, F. Meng, T. Senty, A.D. Bristow et al., Plasmon-induced resonance energy transfer for solar energy conversion. Nat. Photon. 9, 601–607 (2015). https://doi.org/10.1038/nphoton.2015.142
  128. J. Li, S.K. Cushing, P. Zheng, F. Meng, D. Chu et al., Plasmon-induced photonic and energy-transfer enhancement of solar water splitting by a hematite nanorod array. Nat. Commun. 4, 2651 (2013). https://doi.org/10.1038/ncomms3651
  129. G. Liu, P. Li, G. Zhao, X. Wang, J. Kong et al., Promoting active species generation by plasmon-induced hot-electron excitation for efficient electrocatalytic oxygen evolution. J. Am. Chem. Soc. 138(29), 9128–9136 (2016). https://doi.org/10.1021/jacs.6b05190
  130. N. Zhang, Y. Chai, Lattice oxygen redox chemistry in solid-state electrocatalysts for water oxidation. Energy Enviorn. Sci. 14(9), 4647–4671 (2021). https://doi.org/10.1039/D1EE01277K
  131. Y. Sun, H. Liao, J. Wang, B. Chen, S. Sun et al., Covalency competition dominates the water oxidation structure–activity relationship on spinel oxides. Nat. Catal. 3, 554–563 (2020). https://doi.org/10.1038/s41929-020-0465-6
  132. A. Grimaud, O. Diaz-Morales, B. Han, W.T. Hong, Y. Lee et al., Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution. Nat. Chem. 9, 457–465 (2017). https://doi.org/10.1038/nchem.2695
  133. G. Assat, J. Tarascon, Fundamental understanding and practical challenges of anionic redox activity in Li–ion batteries. Nat. Energy 3, 373–386 (2018). https://doi.org/10.1038/s41560-018-0097-0
  134. J.T. Mefford, X. Rong, A.M. Abakumov, W.G. Hardin, S. Dai et al., Water electrolysis on La1−xSrxCoO3−δ perovskite electrocatalysts. Nat. Commun. 7, 11053 (2016). https://doi.org/10.1038/ncomms11053
  135. X. Li, H. Wang, Z. Cui, Y. Li, S. Xin et al., Exceptional oxygen evolution reactivities on CaCoO3 and SrCoO3. Sci. Adv. 5(8), eaav6262 (2019). https://doi.org/10.1126/sciadv.aav6262
  136. T. Maiyalagan, K.A. Jarvis, S. Therese, P.J. Ferreira, A. Manthiram, Spinel-type lithium cobalt oxide as a bifunctional electrocatalyst for the oxygen evolution and oxygen reduction reactions. Nat. Commun. 5, 3949 (2014). https://doi.org/10.1038/ncomms4949
  137. X. Rong, J. Parolin, A.M. Kolpak, A fundamental relationship between reaction mechanism and stability in metal oxide catalysts for oxygen evolution. ACS Catal. 6(2), 1153–1158 (2016). https://doi.org/10.1021/acscatal.5b02432
  138. R.P. Forslund, W.G. Hardin, X. Rong, A.M. Abakumov, D. Filimonov et al., Exceptional electrocatalytic oxygen evolution via tunable charge transfer interactions in La0.5Sr1.5Ni1−xFexO4±δ Ruddlesden–Popper oxides. Nat. Commun. 9, 3150 (2018). https://doi.org/10.1038/s41467-018-05600-y
  139. Z. Huang, J. Song, Y. Du, S. Xi, S. Dou et al., Chemical and structural origin of lattice oxygen oxidation in Co–Zn oxyhydroxide oxygen evolution electrocatalysts. Nat. Energy 4, 329–338 (2019). https://doi.org/10.1038/s41560-019-0355-9
  140. D. Seo, J. Lee, A. Urban, R. Malik, S. Kang et al., The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials. Nat. Chem. 8, 692–697 (2016). https://doi.org/10.1038/nchem.2524
  141. J. Lee, D.A. Kitchaev, D. Kwon, C. Lee, J.K. Papp et al., Reversible Mn2+/Mn4+ double redox in lithium-excess cathode materials. Nature 556, 185–190 (2018). https://doi.org/10.1038/s41586-018-0015-4
  142. J. Hong, W.E. Gent, P. Xiao, K. Lim, D. Seo et al., Metal–oxygen decoordination stabilizes anion redox in Li-rich oxides. Nat. Mater. 18, 256–265 (2019). https://doi.org/10.1038/s41563-018-0276-1
  143. V.M.V.G. Nageswaran, Operando X-ray spectroscopic techniques: a focus on hydrogen and oxygen evolution reactions. Front. Chem. 8, 23 (2020). https://doi.org/10.3389/fchem.2020.00023
  144. N. Zhang, X. Feng, D. Rao, X. Deng, L. Cai et al., Lattice oxygen activation enabled by high-valence metal sites for enhanced water oxidation. Nat. Commun. 11, 4066 (2020). https://doi.org/10.1038/s41467-020-17934-7
  145. J. Shan, T. Ling, K. Davey, Y. Zheng, S. Qiao, Transition-metal-doped RuIr bifunctional nanocrystals for overall water splitting in acidic environments. Adv. Mater. 31(17), 1900510 (2019). https://doi.org/10.1002/adma.201900510
  146. A. Moysiadou, S. Lee, C. Hsu, H.M. Chen, X. Hu, Mechanism of oxygen evolution catalyzed by cobalt oxyhydroxide: cobalt superoxide species as a key intermediate and dioxygen release as a rate-determining step. J. Am. Chem. Soc. 142(27), 11901–11914 (2020). https://doi.org/10.1021/jacs.0c04867
  147. S. Lee, K. Banjac, M. Lingenfelder, X. Hu, Oxygen isotope labeling experiments reveal different reaction sites for the oxygen evolution reaction on nickel and nickel iron oxides. Angew. Chem. Int. Ed. 58(30), 10295–10299 (2019). https://doi.org/10.1002/anie.201903200
  148. M.T.M. Koper, Theory of multiple proton-electron transfer reactions and its implications for electrocatalysis. Chem. Sci. 4(7), 2710–2723 (2013). https://doi.org/10.1039/C3SC50205H
  149. L. Giordano, B. Han, M. Risch, W.T. Hong, R.R. Rao et al., pH dependence of OER activity of oxides: current and future perspectives. Catal. Today 262, 2–10 (2016). https://doi.org/10.1016/j.cattod.2015.10.006
  150. C. Roy, B. Sebok, S.B. Scott, E.M. Fiordaliso, J.E. Sørensen et al., Impact of nanop size and lattice oxygen on water oxidation on NiFeOxHy. Nat. Catal. 1, 820–829 (2018). https://doi.org/10.1038/s41929-018-0162-x
  151. B. Hua, M. Li, W. Pang, W. Tang, S. Zhao et al., Activating p-blocking centers in perovskite for efficient water splitting. Chem 4(12), 2902–2916 (2018). https://doi.org/10.1016/j.chempr.2018.09.012
  152. P. Wang, Q. Cheng, C. Mao, W. Su, L. Yang et al., Regulation of oxygen vacancy within oxide pyrochlores by F-doping to boost oxygen-evolution activity. J. Power Sources 502, 229903 (2021). https://doi.org/10.1016/j.jpowsour.2021.229903
  153. L. Bai, C. Hsu, D.T.L. Alexander, H.M. Chen, X. Hu, A cobalt–iron double-atom catalyst for the oxygen evolution reaction. J. Am. Chem. Soc. 141(36), 14190–14199 (2019). https://doi.org/10.1021/jacs.9b05268
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