Synthesis and Luminescence Properties of (Y, Gd) (P, V)O4:Eu3+, Bi3+Red Nano-phosphors with Enhanced Photoluminescence by Bi3+, Gd3+ Doping
Corresponding Author: Da-Chuan Zhu
Nano-Micro Letters,
Vol. 5 No. 2 (2013), Article Number: 117-123
Abstract
A series of (Y1−y, Gd y )0.95−x(P y , V1−y)O4:0.05Eu3+, xBi3+ phosphors have been successfully prepared by a subsection method. The crystal structure, surface morphology and luminescence properties were investigated. It was found that the sintered samples crystallized in a tetragonal crystal system with space group I41/amd(a = b = 0.7119 nm, c = 0.6290 nm). The products presented rod-like morphology with length of 100–150 nm and width of 50–100 nm. A maximum peak at 619 nm (5D0 →7F2) was observed in emission spectrum of the phosphors. It was also found that co-doping of Bi3+, P5+ and Gd3+ions into YVO4:Eu3+ can not only made the right edge of the excitation band shift to the long-wavelength region, but also increased the emission intensity at 619 nm sharply and decreased the lifetime of fluorescence decay. These results may expand the application scope of the phosphors.
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- K. N. Shinde, S. J. Dhoble and K. Park, “Effect of synthesis method on photolumin-escence properties of Na2Sr2Al2PO4Cl9:Ce3+ nanophosphor”, Nano-Micro Lett. 4(2), 78–82 (2012). http://dx.doi.org/10.3786/nml.v4i2.p78-82
- W. S. Song, K. H. Lee, Y. S. Kim and H. Yang, “Tuning of size and luminescence of red Y(V,P)O4:Eu nanophosphors for their application to transparent panels of plasma display”, Mater. Chem. Phys. 135(1), 51–57 (2012). http://dx.doi.org/10.1016/j.matchemphys.2012.04.013
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- B. K. Grandhe, V. R. Bandi, K. Jang, S. Ramaprabhu, H. S. Lee, D. S. Shin, S. S. Yi and J. H. Jeong, “Multi wall carbon nanotubes assisted synthesis of YVO4:Eu3+ nanocomposites for display device applications”, Compos. Part B 43(1), 1192–1195 (2012). http://dx.doi.org/10.1016/j.compositesb.2011.08.011
- C. Jang, S. M. Lee and K. C. Choi, “Optical characteristics of YVO4:Eu3+ phosphor in close proximity to Ag nanofilm: emitting layer for mirror-type displays”, Opt. Express 20(3), 2143–2148 (2012). http://dx.doi.org/10.1364/OE.20.002143
- Y. S. Chang, Z. R. Shi, Y. Y. Tsai, S. Wuc and H. L. Chen, “The effect of Eu3+-activated InVO4 phosphors prepared by solgel method”, Opt. Mater. 33(3), 375–380 (2011). http://dx.doi.org/10.1016/j.optmat.2010.09.018
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- J. Wang, M. Hojamberdiev and Y. H. Xu, “CTABassisted hydrothermal synthesis of YVO4:Eu3+ powders in a wide pH range”, Solid State Sci. 14(1), 191–196 (2012). http://dx.doi.org/10.1016/j.solidstatesciences.2011.10.019
- K. Park and S. W. Nam, “VUV photoluminescence characteristics of (Y, Gd)VO4:Eu,Zn phosphors produced by ultrasonic spray pyrolysis”, Mater. Chem. Phys. 123(2–3), 601–605 (2010). http://dx.doi.org/10.1016/j.matchemphys.2010.05.021
- S. Takeshita, T. Watanabe, T. Isobe, T. Sawayama and S. Niikura, “Improvement of the photostability for YVO4:Bi3+,Eu3+ nanoparticles synthesized by the citrate route”, Opt. Mater. 33(3), 323–326 (2011). http://dx.doi.org/10.1016/j.optmat.2010.09.006
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- Y. Y. Zuo, W. J. Ling and Y. H. Wang, “Synthesis and photoluminescence properties of YVO4:Eu3+, Al3+ phosphor”, J. Lumin. 132(1), 61–63 (2012). http://dx.doi.org/10.1016/j.jlumin.2011.07.012
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- Y. P. Fang, A. W. Xu, R. Q. Song, H. X. Zhang, L. P. You, J. C Yu and H. Q. Liu, “Systematic synthesis and characterization of single-crystal lanthanide orthophosphate nanowires”, J. Am. Chem. Soc. 125(51), 16025–16034 (2003). http://dx.doi.org/10.1021/ja037280d
- Y. C. Chen, Y. C. Wu, D. Y. Wang and T. M. Chen, “Controlled synthesis and luminescent properties of monodispersed PEI-modified YVO4:Bi3+,Eu3+ nanocrystals by a facile hydrothermal process”, J. Mater. Chem. 22(16), 7961–7969 (2012). http://dx.doi.org/10.1039/C2JM30756A
- C. C. Wu, K. B. Chen, C. S. Lee, T. M. Chen and B. M. Cheng, “Synthesis and VUV photoluminescence characterization of (Y, Gd)(V, P)O4:Eu3+ as a potential red-emitting PDP phosphor”, Chem. Mater. 19(13), 3278–3285 (2007). http://dx.doi.org/10.1021/cm061042a
- B. V. Rao and S. Buddhudu, “Emission analysis of RE3+ (Dy3+ or Tb3+):Ca3Ln(=Y, Gd)(VO4)3 powder phosphors”, Mater. Chem. Phys. 111(1), 65–68 (2008). http://dx.doi.org/10.1016/j.matchemphys.2008.03.013
References
K. N. Shinde, S. J. Dhoble and K. Park, “Effect of synthesis method on photolumin-escence properties of Na2Sr2Al2PO4Cl9:Ce3+ nanophosphor”, Nano-Micro Lett. 4(2), 78–82 (2012). http://dx.doi.org/10.3786/nml.v4i2.p78-82
W. S. Song, K. H. Lee, Y. S. Kim and H. Yang, “Tuning of size and luminescence of red Y(V,P)O4:Eu nanophosphors for their application to transparent panels of plasma display”, Mater. Chem. Phys. 135(1), 51–57 (2012). http://dx.doi.org/10.1016/j.matchemphys.2012.04.013
S. H. Dai, Y. F. Liu, Y. N. Lu and H. H. Min, “Microwave solvothermal synthesis of Eu3+-doped (Y, Gd)2O3 microsheets”, Powder Technol. 202(1–3), 178–184 (2010). http://dx.doi.org/10.1016/j.powtec.2010.04.036
B. K. Grandhe, V. R. Bandi, K. Jang, S. Ramaprabhu, H. S. Lee, D. S. Shin, S. S. Yi and J. H. Jeong, “Multi wall carbon nanotubes assisted synthesis of YVO4:Eu3+ nanocomposites for display device applications”, Compos. Part B 43(1), 1192–1195 (2012). http://dx.doi.org/10.1016/j.compositesb.2011.08.011
C. Jang, S. M. Lee and K. C. Choi, “Optical characteristics of YVO4:Eu3+ phosphor in close proximity to Ag nanofilm: emitting layer for mirror-type displays”, Opt. Express 20(3), 2143–2148 (2012). http://dx.doi.org/10.1364/OE.20.002143
Y. S. Chang, Z. R. Shi, Y. Y. Tsai, S. Wuc and H. L. Chen, “The effect of Eu3+-activated InVO4 phosphors prepared by solgel method”, Opt. Mater. 33(3), 375–380 (2011). http://dx.doi.org/10.1016/j.optmat.2010.09.018
N. Ogorodnikov, V. A. Pustovarov, V. M. Puzikov, V. I. Salo and A. P. Voronov, “A luminescence and absorption spectroscopy study of KH2PO4 crystals doped with Ti+ ions”, Opt. Mater. 34(9), 1522–1528 (2012). http://dx.doi.org/10.1016/j.optmat.2012.03.018
C. Mu and J. H. He, “Synthesis and luminescence properties of Eu3+ doped porous YVO4 nanowires by chemical precipitation in nanochannels”, Mater. Res. Bull. 47(2), 491–496 (2012). http://dx.doi.org/10.1016/j.materresbull.2011.06.008
X. Z. Xiao, G. Z. Lu, S. D. Shen, D. S. Mao, Y. Guo and Y. Q. Wang, “Synthesis and luminescence properties of YVO4:Eu3+ cobblestone-like microcrystalline phosphors obtained from the mixed solvent- thermal method”, Mater. Sci. Eng., B 176(1), 72–78 (2011). http://dx.doi.org/10.1016/j.mseb.2010.09.005
J. H Li, J. Liu and X. B. Yu, “Synthesis and luminescence properties of Bi3+-doped YVO4 phosphors”, J. Alloys Compd. 509(41), 9897–9900 (2011). http://dx.doi.org/10.1016/j.jallcom.2011.07.079
L. P. Xie, H. W. Song, Y. Wang, W. Xu, X. Bai and B. Dong, “Influence of concentration effect and Au coating on photoluminescence properties of YVO4:Eu3+ nanoparticle colloids”, J. Phys. Chem. C 114(21), 9975–9980 (2010). http://dx.doi.org/10.1021/jp100828t
D. Hreniak, J. Doskocz, P. Gluchowski, R. Lisiecki, W. Strek, N. Vu, D. X. Loc, T. K. Anh, M. Bettinelli and A. Speghini, “Enhancement of luminescence properties of Eu3+:YVO4 in polymeric nanocomposites upon UV excitation”, J. Lumin. 131(3), 473–476 (2011). http://dx.doi.org/10.1016/j.jlumin.2010.10.028
S. H. Choi, Y. M. Moon and H. K. Jung, “Luminescent properties of PEG-added nanocrystalline YVO4:Eu3+ phosphor prepared by a hydrothermal method”, J. Lumin. 130(4), 549–553 (2010). http://dx.doi.org/10.1016/j.jlumin.2009.10.029
D. S. Jo, Y. Y. Luo, K. Senthil, T. Masaki and D. H. Yoon, “Synthesis of high efficient nanosized Y(V,P)O4:Eu3+ red phosphors by a new technique”, Opt. Mater. 33(8), 1190–1194 (2011). http://dx.doi.org/10.1016/j.optmat.2011.02.007
Q. Z. Dong, Y. H. Wang, L. L. Peng, H. J. Zhang and B. T. Liu, “Controllable morphology and high photoluminescence of (Y, Gd)(V,P) O4:Eu3+ nanophosphors synthesized by two-step reactions”, Nanotechnol. 22(21), 215604–215611 (2011). http://dx.doi.org/10.1088/0957-4484/22/21/215604
J. Wang, M. Hojamberdiev and Y. H. Xu, “CTABassisted hydrothermal synthesis of YVO4:Eu3+ powders in a wide pH range”, Solid State Sci. 14(1), 191–196 (2012). http://dx.doi.org/10.1016/j.solidstatesciences.2011.10.019
K. Park and S. W. Nam, “VUV photoluminescence characteristics of (Y, Gd)VO4:Eu,Zn phosphors produced by ultrasonic spray pyrolysis”, Mater. Chem. Phys. 123(2–3), 601–605 (2010). http://dx.doi.org/10.1016/j.matchemphys.2010.05.021
S. Takeshita, T. Watanabe, T. Isobe, T. Sawayama and S. Niikura, “Improvement of the photostability for YVO4:Bi3+,Eu3+ nanoparticles synthesized by the citrate route”, Opt. Mater. 33(3), 323–326 (2011). http://dx.doi.org/10.1016/j.optmat.2010.09.006
J. Y. Sun, J. B. Xian, Z. G. Xia and H. Y. Du, “Synthesis, structure and luminescence properties of Y(V,P)O4:Eu3+,Bi3+ phosphors”, J. Lumin. 130(10), 1818–1824 (2010). http://dx.doi.org/10.1016/j.jlumin.2010.04.016
Y. Y. Zuo, W. J. Ling and Y. H. Wang, “Synthesis and photoluminescence properties of YVO4:Eu3+, Al3+ phosphor”, J. Lumin. 132(1), 61–63 (2012). http://dx.doi.org/10.1016/j.jlumin.2011.07.012
J. H. Shin, S. W. Choi, S. H. Hong, S. J. Kwon, S. Y. Seo, H. S. Kim, Y. H. Song and D. H. Yoon, “Luminescent properties of Y(P, V)O4:Eu3+ phosphors prepared by combining liquid phase precursor method and planetary ball milling”, J. Alloys Compd. 509(11), 4331–4335 (2011). http://dx.doi.org/10.1016/j.jallcom.2011.01.060
Y. P. Fang, A. W. Xu, R. Q. Song, H. X. Zhang, L. P. You, J. C Yu and H. Q. Liu, “Systematic synthesis and characterization of single-crystal lanthanide orthophosphate nanowires”, J. Am. Chem. Soc. 125(51), 16025–16034 (2003). http://dx.doi.org/10.1021/ja037280d
Y. C. Chen, Y. C. Wu, D. Y. Wang and T. M. Chen, “Controlled synthesis and luminescent properties of monodispersed PEI-modified YVO4:Bi3+,Eu3+ nanocrystals by a facile hydrothermal process”, J. Mater. Chem. 22(16), 7961–7969 (2012). http://dx.doi.org/10.1039/C2JM30756A
C. C. Wu, K. B. Chen, C. S. Lee, T. M. Chen and B. M. Cheng, “Synthesis and VUV photoluminescence characterization of (Y, Gd)(V, P)O4:Eu3+ as a potential red-emitting PDP phosphor”, Chem. Mater. 19(13), 3278–3285 (2007). http://dx.doi.org/10.1021/cm061042a
B. V. Rao and S. Buddhudu, “Emission analysis of RE3+ (Dy3+ or Tb3+):Ca3Ln(=Y, Gd)(VO4)3 powder phosphors”, Mater. Chem. Phys. 111(1), 65–68 (2008). http://dx.doi.org/10.1016/j.matchemphys.2008.03.013