Thermal Evaporation Deposition of Few-layer MoS2 Films
Corresponding Author: Xiying Ma
Nano-Micro Letters,
Vol. 5 No. 2 (2013), Article Number: 135-139
Abstract
We present a study of the fabrication of monolayer MoS2 on n-Si (111) substrates by modified thermal evaporation deposition and the optoelectrical properties of the resulting film. The as-grown MoS2 ultrathin film is about 10 nm thick, or about a few atomic layers of MoS2. The film has a large optical absorption range of 300–700 nm and strong luminescence emission at 682 nm. The optical absorption range covered almost the entire ultraviolet to visible light range, which is very useful for making high-efficiency solar cells. Moreover, the MoS2/Si heterojunction exhibited good rectification characteristics and excellent photovoltaic effects. The power conversion efficiency of the heterojunction device is about 1.79% under white light illumination of 10 mW/cm2. The results show that the monolayer MoS2 film will find many applications in high-efficiency optoelectronic devices.
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- F. Schwierz, “Graphene transistors”, Nat. Nanotechnol. 5(7), 487–551 (2010). http://dx.doi.org/10.1038/nnano.2010.89
- Zhi Yang, Rungang Gao, Nantao Hu, Jing Chai, Yingwu Cheng, Liying Zhang, Hao Wei, Eric Siu-Wai Kong and Yafei Zhang, “The Prospective 2D Graphene Nanosheets: Preparation, Functionalization and Applications”, Nano-Micro Lett. 4 (1), 1–9 (2012). http://dx.doi.org/10.3786/nml.v4i1.p1-9
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- P. Joensen, R. F. Frindt and S. R. Morrison, “Single-layer MoS2”, Mater. Res. Bull. 21(4), 457–461 (1986). http://dx.doi.org/10.1016/0025-5408(86)90011-5
- A. Schumacher, L. Scandella, N. Kruse and R. Prins, “Single-layer MoS2 on mica: studies by means of scanning force microscopy”, Surf. Sci. Lett. 289(1–2), L595–L598 (1993). http://dx.doi.org/10.1016/0167-2584(93)90727-Z
- Y. H. Lee, L. Yu, H. Wang, W. Fang, X. Ling, Y. Shi, C. T. Lin, J. K. Huang, M. T. Chang, C. S. Chang, M. Dresselhaus, T. Palacios, L. J. Li and J. Kong, “Synthesis and Transfer of Single-Layer Transition Metal Disulfides on Diverse Surfaces”, Nano Lett. 13(4), 1852–1857 (2013). http://dx.doi.org/10.1021/nl400687n
- A. Castellanos-Gomez, M. Barkelid, A. M. Goossens, V. E. Calado, H. S. J. van der Zant, and G. A. Steele, “Laser-thinning of MoS2: on demand generation of a single-layer semiconductor”, Nano Lett. 12(6), 3187–3192 (2012). http://dx.doi.org/10.1021/nl301164v
- W. K. Hoffman, “Thin films of molybdenum and tungsten disulphides by metal organic chemical vapour deposition”, J. Mater. Sci. 23(11), 3981–3986 (1988). http://dx.doi.org/10.1007/BF01106824
- K. K. Liu, W. Zhang, Y. H. Lee, Y. C. Lin, M. T. Chang, C. Y. Su, C. S. Chang, H. Li, Y. Shi, H. Zhang, C. S. Lai and L. J. Li, “Growth of large-area and highly crystalline MoS2 thin layers on insulating substrates”, Nano Lett. 12(3), 1538–1544 (2012). http://dx.doi.org/10.1021/nl2043612
References
F. Schwierz, “Graphene transistors”, Nat. Nanotechnol. 5(7), 487–551 (2010). http://dx.doi.org/10.1038/nnano.2010.89
Zhi Yang, Rungang Gao, Nantao Hu, Jing Chai, Yingwu Cheng, Liying Zhang, Hao Wei, Eric Siu-Wai Kong and Yafei Zhang, “The Prospective 2D Graphene Nanosheets: Preparation, Functionalization and Applications”, Nano-Micro Lett. 4 (1), 1–9 (2012). http://dx.doi.org/10.3786/nml.v4i1.p1-9
A. Splendiani, L. Sun, Y. Zhang, T. Li, J. Kim, C. Y. Chim, G. Galli and F. Wang, “Emerging photoluminescence in monolayer MoS2”, Nano Lett. 10(4), 1271–1275 (2010). http://dx.doi.org/10.1021/nl903868w
C. Lee, H. Yan, L. E. Brus, T. F. Heinz, J. Hone and S. Ryu, “Anomalous lattice vibrations of single- and few-layer MoS2”, ACS Nano 4(5), 2695–2700 (2010). http://dx.doi.org/10.1021/nn1003937
K. F. Mak, C. Lee, J. Hone, J. Shan and T. F. Heinz, “Atomically thin MoS2: a new direct-gap semiconductor”, Phys. Rev. Lett. 105(13), 136805–08 (2010). http://dx.doi.org/10.1103/PhysRevLett.105.136805
N. R. Pradhan, D. Rhodes, Q. Zhang, S. Talapatra, M. Terrones, P. M. Ajayan and L. Balicas, “Intrinsic carrier mobility of multi-layered MoS2 field-effect transistors on SiO2”, Appl. Phys. Lett. 102(12), 123105–08 (2013). http://dx.doi.org/10.1063/1.4799172
A. C. Gomez, M. Poot, G. A. Steele, H. S. J. van der Zant, N. Agraït and G. R. Bollinger, “Elastic properties of freely suspended MoS2 nanosheets”, Adv. Mater. 24(6), 772–775 (2012). http://dx.doi.org/10.1002/adma.201103965
W. Yu, Z. Li, H. Zhou, Y. Chen, Y. Wang, Y. Huang and X. Duan, “Vertically stacked multiheterostructures of layered materials for logic transistors and complementary inverters”, Nat. Mater. 12(3), 246–252 (2013). http://dx.doi.org/10.1038/nmat3518
H. S. Lee, S. W. Min, Y. G. Chang, M. K. Park, T. Nam, H. Kim, J. H. Kim, S. Ryu and S. Im, “MoS2 nanosheet phototransistors with thickness-modulated optical energy gap”, Nano Lett. 12(7), 3695 (2012). http://dx.doi.org/10.1021/nl301485q
M. Buscema, M. Barkelid, V. Zwiller, H. S. J. van der Zant, G. A. Steele and A. C. Gomez, “Large and tunable photothermoelectric effect in single-layer MoS2”, Nano Lett. 13(2), 358–363 (2013). http://dx.doi.org/10.1021/nl303321g
H. Shin, J. Doerr, C. V. Deshpandey, B. Dunn and R. F. Bunshah, “Effect of deposition variables on the properties of molybdenum sulfide films prepared by the activated reactive evaporation technique”, Surf. Coat. Tech. 39/40(2), 683–690 (1989). http://dx.doi.org/10.1016/S0257-8972(89)80030-1
J. J. Auborn, Y. L. Barberio, K. J. Hanson, D. M. Schleich and M. J. Martin, “Amorphous molybdenum sulfide electrodes for nonaqueous electrochemical cells”, J. Electrochem. Soc. 134(3), 580–586 (1987). http://dx.doi.org/10.1149/1.2100512
P. Joensen, R. F. Frindt and S. R. Morrison, “Single-layer MoS2”, Mater. Res. Bull. 21(4), 457–461 (1986). http://dx.doi.org/10.1016/0025-5408(86)90011-5
A. Schumacher, L. Scandella, N. Kruse and R. Prins, “Single-layer MoS2 on mica: studies by means of scanning force microscopy”, Surf. Sci. Lett. 289(1–2), L595–L598 (1993). http://dx.doi.org/10.1016/0167-2584(93)90727-Z
Y. H. Lee, L. Yu, H. Wang, W. Fang, X. Ling, Y. Shi, C. T. Lin, J. K. Huang, M. T. Chang, C. S. Chang, M. Dresselhaus, T. Palacios, L. J. Li and J. Kong, “Synthesis and Transfer of Single-Layer Transition Metal Disulfides on Diverse Surfaces”, Nano Lett. 13(4), 1852–1857 (2013). http://dx.doi.org/10.1021/nl400687n
A. Castellanos-Gomez, M. Barkelid, A. M. Goossens, V. E. Calado, H. S. J. van der Zant, and G. A. Steele, “Laser-thinning of MoS2: on demand generation of a single-layer semiconductor”, Nano Lett. 12(6), 3187–3192 (2012). http://dx.doi.org/10.1021/nl301164v
W. K. Hoffman, “Thin films of molybdenum and tungsten disulphides by metal organic chemical vapour deposition”, J. Mater. Sci. 23(11), 3981–3986 (1988). http://dx.doi.org/10.1007/BF01106824
K. K. Liu, W. Zhang, Y. H. Lee, Y. C. Lin, M. T. Chang, C. Y. Su, C. S. Chang, H. Li, Y. Shi, H. Zhang, C. S. Lai and L. J. Li, “Growth of large-area and highly crystalline MoS2 thin layers on insulating substrates”, Nano Lett. 12(3), 1538–1544 (2012). http://dx.doi.org/10.1021/nl2043612