Multi-Responsive SEBS/MXene Janus Membranes Enabling Piezoelectric Energy Harvesting, Humidity Sensing, and Infrared Stealth
Corresponding Author: Aimin Zhang
Nano-Micro Letters,
Vol. 18 (2026), Article Number: 365
Abstract
In response to the urgent need for multifunctional integration in flexible intelligent systems, as well as the limitations of traditional multilayer integration strategies in terms of interface and mechanical performance, inspired by the intrinsic asymmetry of natural Janus structures, this study designed and prepared a novel flexible styrene–ethylene–butylene–styrene (SEBS)/MXene (SM) Janus fibrous membrane. Under mechanical pressure, the SM Janus membrane can generate a remarkable piezoelectric output of up to 28 V and 133 nA, sufficient to drive humidity sensing, thereby establishing a self-powered sensing-energy supply closed-loop system. The synergistic interaction between the hydrophilic MXene layer and the hydrophobic SEBS layer enables the humidity sensor to exhibit high sensitivity and rapid response characteristics, with response and recovery times of 0.79 and 0.35 s, respectively. This allows for effective monitoring of respiration, ambient humidity, and speech signals. Furthermore, the membrane demonstrates exceptional infrared camouflage performance, with an emissivity as low as 32%, significantly modulating the apparent temperature of targets. This study pioneers the integration of energy harvesting, self-powered sensing, and adaptive camouflage into a single material platform, showcasing broad application prospects in fields such as bionic electronic skin and environmental interactive systems.
Highlights:
1 Styrene–ethylene–butylene–styrene copolymer/MXene Janus membranes prepared via electrospinning–vacuum filtration enable synergistic integration of energy harvesting, self-powered sensing, and stealth technology.
2 Piezoelectric output (28 V/133 nA) drives self-powered humidity sensing with response recovery as fast as 0.79/0.35 s.
3 Low infrared emissivity achieves precise regulation of target apparent temperature, demonstrating outstanding stealth performance.
Keywords
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- V. Orts Mercadillo, K.C. Chan, M. Caironi, A. Athanassiou, I.A. Kinloch et al., Electrically conductive 2D material coatings for flexible and stretchable electronics: a comparative review of graphenes and MXenes. Adv. Funct. Mater. 32(38), 2204772 (2022). https://doi.org/10.1002/adfm.202204772
- B. Li, N. Wu, Y. Yang, F. Pan, C. Wang et al., Graphene oxide-assisted multiple cross-linking of MXene for large-area, high-strength, oxidation-resistant, and multifunctional films. Adv. Funct. Mater. 33(11), 2213357 (2023). https://doi.org/10.1002/adfm.202213357
- T. Bai, Y. Wang, K. Zhu, X. Zhang, Y. Mu et al., Multifunctional ultraelastic helical conductive yarn for motion detection and human-machine interaction. Chem. Eng. J. 498, 155143 (2024). https://doi.org/10.1016/j.cej.2024.155143
- Q. Gao, S. Agarwal, A. Greiner, T. Zhang, Electrospun fiber-based flexible electronics: fiber fabrication, device platform, functionality integration and applications. Prog. Mater. Sci. 137, 101139 (2023). https://doi.org/10.1016/j.pmatsci.2023.101139
- C.M. Costa, V.F. Cardoso, P. Martins, D.M. Correia, R. Gonçalves et al., Smart and multifunctional materials based on electroactive poly(vinylidene fluoride): recent advances and opportunities in sensors, actuators, energy, environmental, and biomedical applications. Chem. Rev. 123(19), 11392–11487 (2023). https://doi.org/10.1021/acs.chemrev.3c00196
- Y. Chen, T. Feng, M. Peng, F. Qin, Ultra-high filling ratio of non-percolative rapeseed-shaped liquid metal fiber mats for pressure sensors via electrospinning aided inhomogeneous dispersion. Adv. Fiber Mater. 7(2), 633–644 (2025). https://doi.org/10.1007/s42765-025-00515-y
- J. Fan, S. Xu, B. Newell, J. Garcia, W. Wu et al., Liquid-based material extrusion of flexible silver electrodes onto electrospun poly(vinylidene fluoride) microfibers for soft piezoelectric pressure sensors: towards fully three-dimensional printed functional materials. Nano Energy 137, 110820 (2025). https://doi.org/10.1016/j.nanoen.2025.110820
- Y. Liu, J. Wang, T. Liu, Z. Wei, B. Luo et al., Triboelectric tactile sensor for pressure and temperature sensing in high-temperature applications. Nat. Commun. 16(1), 383 (2025). https://doi.org/10.1038/s41467-024-55771-0
- P. Wang, X. Li, G. Sun, G. Wang, Q. Han et al., Natural human skin-inspired wearable and breathable nanofiber-based sensors with excellent thermal management functionality. Adv. Fiber Mater. 6(6), 1955–1968 (2024). https://doi.org/10.1007/s42765-024-00464-y
- J. Lin, X. Cai, Z. Liu, N. Liu, M. Xie et al., Anti-liquid-interfering and bacterially antiadhesive strategy for highly stretchable and ultrasensitive strain sensors based on Cassie-Baxter wetting state. Adv. Funct. Mater. 30(23), 2000398 (2020). https://doi.org/10.1002/adfm.202000398
- Y. Guo, H. Guo, Y. Han, X. Chen, J. Liu et al., Multifunctional hydrogel sensor with curved macro cracks: a strategy for high sensitivity and wide detection range. Adv. Funct. Mater. 33(47), 2370277 (2023). https://doi.org/10.1002/adfm.202370277
- J. Lee, S. Shin, S. Lee, J. Song, S. Kang et al., Highly sensitive multifilament fiber strain sensors with ultrabroad sensing range for textile electronics. ACS Nano 12(5), 4259–4268 (2018). https://doi.org/10.1021/acsnano.7b07795
- L. Gao, J. Yang, Y. Zhao, X. Zhao, K. Zhou et al., Multilayer bionic tunable strain sensor with mutually non-interfering conductive networks for machine learning-assisted gesture recognition. Adv. Funct. Mater. 35(11), 2416911 (2025). https://doi.org/10.1002/adfm.202416911
- U. Yong, D. Kim, H. Kim, D.G. Hwang, S. Cho et al., Biohybrid 3D printing of a tissue-sensor platform for wireless, real-time, and continuous monitoring of drug-induced cardiotoxicity. Adv. Mater. 35(11), 2208983 (2023). https://doi.org/10.1002/adma.202208983
- J. Gao, Y. Fan, Q. Zhang, L. Luo, X. Hu et al., Ultra-robust and extensible fibrous mechanical sensors for wearable smart healthcare. Adv. Mater. 34(20), e2107511 (2022). https://doi.org/10.1002/adma.202107511
- Z. Wang, H. Zhou, D. Liu, X. Chen, D. Wang et al., A structural gel composite enabled robust underwater mechanosensing strategy with high sensitivity. Adv. Funct. Mater. 32(25), 2201396 (2022). https://doi.org/10.1002/adfm.202201396
- O.A. Araromi, M.A. Graule, K.L. Dorsey, S. Castellanos, J.R. Foster et al., Ultra-sensitive and resilient compliant strain gauges for soft machines. Nature 587(7833), 219–224 (2020). https://doi.org/10.1038/s41586-020-2892-6
- Y. Si, S. Shi, C. Zhi, L. Lei, J. Hu et al., Janus electrospun membranes. Adv. Mater. 37(38), 2507498 (2025). https://doi.org/10.1002/adma.202507498
- Y. Si, S. Shi, J. Hu, Electrospinning and electrospraying synergism: Twins-tech collaboration across dimensions. Matter 7(4), 1373–1405 (2024). https://doi.org/10.1016/j.matt.2024.01.009
- H. Ling, W. Xin, Y. Qian, X. He, L. Yang et al., Heterogeneous electrospinning nanofiber membranes with pH-regulated ion gating for tunable osmotic power harvesting. Angew. Chem. Int. Ed. 62(1), e202212120 (2023). https://doi.org/10.1002/anie.202212120
- X. Cheng, T. Li, L. Yan, Y. Jiao, Y. Zhang et al., Biodegradable electrospinning superhydrophilic nanofiber membranes for ultrafast oil-water separation. Sci. Adv. 9(34), eadh8195 (2023). https://doi.org/10.1126/sciadv.adh8195
- Y. Chen, Y. Jiang, X. Zhang, T. Zhang, W. Feng et al., Janus nanofibrous membranes for multifunctional sensing and personal thermal-moisture management. Chem. Eng. J. 519, 165413 (2025). https://doi.org/10.1016/j.cej.2025.165413
- X. Kuang, Z. Zhang, X. Ma, L. Zhu, Y. Li et al., Advances in directional liquid transport textiles: mechanism, construction, and applications. Adv. Funct. Mater. 34(42), 2406906 (2024). https://doi.org/10.1002/adfm.202406906
- S. Shi, Y. Ming, H. Wu, C. Zhi, L. Yang et al., A bionic skin for health management: excellent breathability, in situ sensing, and big data analysis. Adv. Mater. 36(17), e2306435 (2024). https://doi.org/10.1002/adma.202306435
- C. Zhi, S. Shi, H. Wu, Y. Si, S. Zhang et al., Emerging trends of nanofibrous piezoelectric and triboelectric applications: mechanisms, electroactive materials, and designed architectures. Adv. Mater. 36(26), 2401264 (2024). https://doi.org/10.1002/adma.202401264
- W. Yang, D. Pan, S. Liu, G. Jia, Y. Wang et al., Multifunctional wearable conductive nanofiber membrane with antibacterial and breathable ability for superior sensing, electromagnetic interference shielding, and thermal management. Adv. Funct. Mater. 35(6), 2414811 (2025). https://doi.org/10.1002/adfm.202414811
- Z. Ma, Q. Huang, Q. Xu, Q. Zhuang, X. Zhao et al., Permeable superelastic liquid-metal fibre mat enables biocompatible and monolithic stretchable electronics. Nat. Mater. 20(6), 859–868 (2021). https://doi.org/10.1038/s41563-020-00902-3
- C. Fan, Y. Zhang, Z. Long, A. Mensah, Q. Wang et al., Dynamically tunable subambient daytime radiative cooling metafabric with Janus wettability. Adv. Funct. Mater. 33(29), 2300794 (2023). https://doi.org/10.1002/adfm.202300794
- B.-X. Li, Z. Luo, H. Sun, Q. Quan, S. Zhou et al., Spectral-selective and adjustable patterned polydimethylsiloxane/MXene/nanoporous polytetrafluoroethylene metafabric for dynamic infrared camouflage and thermal regulation. Adv. Funct. Mater. 34(45), 2407644 (2024). https://doi.org/10.1002/adfm.202407644
- L. Ye, L.-X. Liu, J. Meng, X. Zhou, Y. Guang et al., Interfacial confinement derived high-strength MXene@graphene oxide core-shell fibers for electromagnetic wave regulation, thermochromic alerts, and visible camouflage. Small 21(11), 2411735 (2025). https://doi.org/10.1002/smll.202411735
- H.E. Karahan, K. Goh, C.J. Zhang, E. Yang, C. Yıldırım et al., MXene materials for designing advanced separation membranes. Adv. Mater. 32(29), e1906697 (2020). https://doi.org/10.1002/adma.201906697
- J. Björk, J. Zhou, P.O.Å. Persson, J. Rosen, Two-dimensional materials by large-scale computations and chemical exfoliation of layered solids. Science 383(6688), 1210–1215 (2024). https://doi.org/10.1126/science.adj6556
- M. Naguib, M. Kurtoglu, V. Presser, J. Lu, J. Niu et al., Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Adv. Mater. 23(37), 4248–4253 (2011). https://doi.org/10.1002/adma.201102306
- M. Alhabeb, K. Maleski, B. Anasori, P. Lelyukh, L. Clark et al., Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti3C2Tx MXene). Chem. Mater. 29(18), 7633–7644 (2017). https://doi.org/10.1021/acs.chemmater.7b02847
- A. Lipatov, M. Alhabeb, M.R. Lukatskaya, A. Boson, Y. Gogotsi et al., Effect of synthesis on quality, electronic properties and environmental stability of individual monolayer Ti3C2 MXene flakes. Adv. Electron. Mater. 2(12), 1600255 (2016). https://doi.org/10.1002/aelm.201600255
- X. Sang, Y. Xie, M.-W. Lin, M. Alhabeb, K.L. Van Aken et al., Atomic defects in monolayer titanium carbide (Ti3C2Tx) MXene. ACS Nano 10(10), 9193–9200 (2016). https://doi.org/10.1021/acsnano.6b05240
- M. Tahir, L. He, L. Li, Y. Cao, X. Yu et al., Pushing the electrochemical performance limits of polypyrrole toward stable microelectronic devices. Nano-Micro Lett. 15(1), 49 (2023). https://doi.org/10.1007/s40820-023-01027-3
- Z. Gao, X. Xiao, A. Di Carlo, J. Yin, Y. Wang et al., Advances in wearable strain sensors based on electrospun fibers. Adv. Funct. Mater. 33(18), 2214265 (2023). https://doi.org/10.1002/adfm.202214265
- D. Wang, D. Zhang, P. Li, Z. Yang, Q. Mi et al., Electrospinning of flexible poly(vinyl alcohol)/MXene nanofiber-based humidity sensor self-powered by monolayer molybdenum diselenide piezoelectric nanogenerator. Nano-Micro Lett. 13(1), 57 (2021). https://doi.org/10.1007/s40820-020-00580-5
- M. Shi, M. Shen, X. Guo, X. Jin, Y. Cao et al., Ti3C2Tx MXene-decorated nanoporous polyethylene textile for passive and active personal precision heating. ACS Nano 15(7), 11396–11405 (2021). https://doi.org/10.1021/acsnano.1c00903
- Y. Bai, B. Zhang, J. Ma, Y. Cheng, P. Cui et al., Adhesion strategy for cross-linking AgNWs/MXene Janus membrane: stretchable and self-healing electromagnetic shielding and infrared stealth capabilities. Small 21(5), e2408950 (2025). https://doi.org/10.1002/smll.202408950
- Y. Wang, N. Pang, X. Yin, M. Yu, Z. Yao et al., Rapid preparation of stretchable, compressible and flexible nanofiber foams by one-step expansion for thermal insulation and adsorption of sound and oil. Chem. Eng. J. 506, 159916 (2025). https://doi.org/10.1016/j.cej.2025.159916
- Y. Wang, X. Yin, N. Pang, X. Yuan, Q. Han et al., Biomimetic all-fiber hierarchical multiscale composite aerogels for multifunctional thermal, acoustic, and oil absorption applications. Compos. Sci. Technol. 274, 111445 (2026). https://doi.org/10.1016/j.compscitech.2025.111445
- Y. Wang, X. Yin, N. Pang, X. Yuan, Y. Xu et al., Hydrogen bond-regulated dissociation of aramid fibers for high-strength hierarchical aerogels with superior thermal and acoustic properties. Chem. Eng. J. 524, 169598 (2025). https://doi.org/10.1016/j.cej.2025.169598
- J. Yang, Z. Pan, J. Zhong, S. Li, J. Wang et al., Electrostatic self-assembly of heterostructured black phosphorus–MXene nanocomposites for flexible microsupercapacitors with high rate performance. Energy Storage Mater. 36, 257–264 (2021). https://doi.org/10.1016/j.ensm.2020.12.025
- T.S.L. Grace, C.T. Gibson, J.R. Gascooke, J.G. Shapter, The use of gravity filtration of carbon nanotubes from suspension to produce films with low roughness for carbon nanotube/silicon heterojunction solar device application. Appl. Sci. 10(18), 6415 (2020). https://doi.org/10.3390/app10186415
- J. Cui, J. Wu, A. Feng, Y. Yu, L. Mi, Low infrared emissivity and oxidation stability of Ti3C2T MXene-based composite with tannic acid. Chem. Eng. J. 493, 152289 (2024). https://doi.org/10.1016/j.cej.2024.152289
- S.N. Shuvo, A.M. Ulloa Gomez, A. Mishra, W.Y. Chen, A.M. Dongare et al., Sulfur-doped titanium carbide MXenes for room-temperature gas sensing. ACS Sens. 5(9), 2915–2924 (2020). https://doi.org/10.1021/acssensors.0c01287
- A. Hermawan, B. Zhang, A. Taufik, Y. Asakura, T. Hasegawa et al., CuO nanops/Ti3C2Tx MXene hybrid nanocomposites for detection of toluene gas. ACS Appl. Nano Mater. 3(5), 4755–4766 (2020). https://doi.org/10.1021/acsanm.0c00749
- Y. Zhou, Y. Wang, Y. Wang, H. Yu, R. Zhang et al., MXene Ti3C2Tx -derived nitrogen-functionalized heterophase TiO2 homojunctions for room-temperature trace ammonia gas sensing. ACS Appl. Mater. Interfaces 13(47), 56485–56497 (2021). https://doi.org/10.1021/acsami.1c17429
- S.S. Kumar, H. Renuka, N. Hattrup, G.J. Wang, A.A. Presto et al., Polymer encapsulation via initiated chemical vapor deposition (iCVD) to enhance stability of Ti3C2Tx MXene-based formaldehyde sensors. Sci. Adv. 11(28), eadu6682 (2025). https://doi.org/10.1126/sciadv.adu6682
- M. Ding, S. Li, L. Guo, L. Jing, S.-P. Gao et al., Metal ion-induced assembly of MXene aerogels via biomimetic microtextures for electromagnetic interference shielding, capacitive deionization, and microsupercapacitors. Adv. Energy Mater. 11(35), 2101494 (2021). https://doi.org/10.1002/aenm.202101494
- W. Wang, L. Xu, L. Zhang, A. Zhang, J. Zhang, Self-powered integrated sensing system with in-plane micro-supercapacitors for wearable electronics. Small 19(29), e2207723 (2023). https://doi.org/10.1002/smll.202207723
- Y. Zhan, J. Poisson, X. Meng, Z. Wang, L. Chen et al., Electrospun lignin/ZnO nanofibrous membranes for self-powered ultrasensitive flexible airflow sensor and wearable device. Adv. Mater. 37(37), 2502211 (2025). https://doi.org/10.1002/adma.202502211
- A. Huang, Y. Zhu, S. Peng, B. Tan, X. Peng, Improved energy harvesting ability of single-layer binary fiber nanocomposite membrane for multifunctional wearable hybrid piezoelectric and triboelectric nanogenerator and self-powered sensors. ACS Nano 18(1), 691–702 (2024). https://doi.org/10.1021/acsnano.3c09043
- S. Ding, X. Jin, B. Wang, Z. Niu, J. Ma et al., Integrating Ti3C2Tx MXene nanosheets with thermoplastic polyurethane nanofibers as wearable humidity sensors for noninvasive sleep monitoring and noncontact sensing. ACS Appl. Nano Mater. 6(13), 11810–11821 (2023). https://doi.org/10.1021/acsanm.3c01732
- D. Lei, Q. Zhang, N. Liu, T. Su, L. Wang et al., Self-powered graphene oxide humidity sensor based on potentiometric humidity transduction mechanism. Adv. Funct. Mater. 32(10), 2107330 (2022). https://doi.org/10.1002/adfm.202107330
- J. Yang, L. Feng, Y. Chen, L. Feng, J. Lu et al., High-sensitivity and environmentally friendly humidity sensors deposited with recyclable green microspheres for wireless monitoring. ACS Appl. Mater. Interfaces 14(13), 15608–15622 (2022). https://doi.org/10.1021/acsami.2c00489
- T. Liu, D. Qu, L. Guo, G. Zhou, G. Zhang et al., MXene/TPU composite film for humidity sensing and human respiration monitoring. Adv. Sens. Res. 3(3), 2300014 (2024). https://doi.org/10.1002/adsr.202300014
- J. Li, X. Yuan, C. Lin, Y. Yang, L. Xu et al., Achieving high pseudocapacitance of 2D titanium carbide (MXene) by cation intercalation and surface modification. Adv. Energy Mater. 7(15), 1602725 (2017). https://doi.org/10.1002/aenm.201602725
- M. Ghidiu, J. Halim, S. Kota, D. Bish, Y. Gogotsi et al., Ion-exchange and cation solvation reactions in Ti3C2 MXene. Chem. Mater. 28(10), 3507–3514 (2016). https://doi.org/10.1021/acs.chemmater.6b01275
- E.S. Muckley, M. Naguib, H.-W. Wang, L. Vlcek, N.C. Osti et al., Multimodality of structural, electrical, and gravimetric responses of intercalated MXenes to water. ACS Nano 11(11), 11118–11126 (2017). https://doi.org/10.1021/acsnano.7b05264
- E.S. Muckley, M. Naguib, I.N. Ivanov, Multi-modal, ultrasensitive, wide-range humidity sensing with Ti3C2 film. Nanoscale 10(46), 21689–21695 (2018). https://doi.org/10.1039/c8nr05170d
- J. Hu, Y. Hu, Y. Ye, R. Shen, Unique applications of carbon materials in infrared stealth: a review. Chem. Eng. J. 452, 139147 (2023). https://doi.org/10.1016/j.cej.2022.139147
- Z. Wu, H.-W. Cheng, C. Jin, B. Yang, C. Xu et al., Dimensional design and core–shell engineering of nanomaterials for electromagnetic wave absorption. Adv. Mater. 34(11), 2107538 (2022). https://doi.org/10.1002/adma.202107538
- N. Pang, X. Cheng, Y. Wang, X. Yin, X. Meng et al., Flexible multifunctional MXene/SWCNTs composite films with excellent infrared stealth, electromagnetic interference shielding and electrical heating properties. Carbon 238, 120303 (2025). https://doi.org/10.1016/j.carbon.2025.120303
- N. Pang, X. Cheng, X. Yin, Y. Wang, W. Liu et al., Janus-structured ion-bridged MXene@PDA@PNF flexible composite films for synergistic infrared stealth, Joule thermal management, and EMI shielding. J. Mater. Sci. Technol. 259, 292–306 (2026). https://doi.org/10.1016/j.jmst.2025.10.007
References
V. Orts Mercadillo, K.C. Chan, M. Caironi, A. Athanassiou, I.A. Kinloch et al., Electrically conductive 2D material coatings for flexible and stretchable electronics: a comparative review of graphenes and MXenes. Adv. Funct. Mater. 32(38), 2204772 (2022). https://doi.org/10.1002/adfm.202204772
B. Li, N. Wu, Y. Yang, F. Pan, C. Wang et al., Graphene oxide-assisted multiple cross-linking of MXene for large-area, high-strength, oxidation-resistant, and multifunctional films. Adv. Funct. Mater. 33(11), 2213357 (2023). https://doi.org/10.1002/adfm.202213357
T. Bai, Y. Wang, K. Zhu, X. Zhang, Y. Mu et al., Multifunctional ultraelastic helical conductive yarn for motion detection and human-machine interaction. Chem. Eng. J. 498, 155143 (2024). https://doi.org/10.1016/j.cej.2024.155143
Q. Gao, S. Agarwal, A. Greiner, T. Zhang, Electrospun fiber-based flexible electronics: fiber fabrication, device platform, functionality integration and applications. Prog. Mater. Sci. 137, 101139 (2023). https://doi.org/10.1016/j.pmatsci.2023.101139
C.M. Costa, V.F. Cardoso, P. Martins, D.M. Correia, R. Gonçalves et al., Smart and multifunctional materials based on electroactive poly(vinylidene fluoride): recent advances and opportunities in sensors, actuators, energy, environmental, and biomedical applications. Chem. Rev. 123(19), 11392–11487 (2023). https://doi.org/10.1021/acs.chemrev.3c00196
Y. Chen, T. Feng, M. Peng, F. Qin, Ultra-high filling ratio of non-percolative rapeseed-shaped liquid metal fiber mats for pressure sensors via electrospinning aided inhomogeneous dispersion. Adv. Fiber Mater. 7(2), 633–644 (2025). https://doi.org/10.1007/s42765-025-00515-y
J. Fan, S. Xu, B. Newell, J. Garcia, W. Wu et al., Liquid-based material extrusion of flexible silver electrodes onto electrospun poly(vinylidene fluoride) microfibers for soft piezoelectric pressure sensors: towards fully three-dimensional printed functional materials. Nano Energy 137, 110820 (2025). https://doi.org/10.1016/j.nanoen.2025.110820
Y. Liu, J. Wang, T. Liu, Z. Wei, B. Luo et al., Triboelectric tactile sensor for pressure and temperature sensing in high-temperature applications. Nat. Commun. 16(1), 383 (2025). https://doi.org/10.1038/s41467-024-55771-0
P. Wang, X. Li, G. Sun, G. Wang, Q. Han et al., Natural human skin-inspired wearable and breathable nanofiber-based sensors with excellent thermal management functionality. Adv. Fiber Mater. 6(6), 1955–1968 (2024). https://doi.org/10.1007/s42765-024-00464-y
J. Lin, X. Cai, Z. Liu, N. Liu, M. Xie et al., Anti-liquid-interfering and bacterially antiadhesive strategy for highly stretchable and ultrasensitive strain sensors based on Cassie-Baxter wetting state. Adv. Funct. Mater. 30(23), 2000398 (2020). https://doi.org/10.1002/adfm.202000398
Y. Guo, H. Guo, Y. Han, X. Chen, J. Liu et al., Multifunctional hydrogel sensor with curved macro cracks: a strategy for high sensitivity and wide detection range. Adv. Funct. Mater. 33(47), 2370277 (2023). https://doi.org/10.1002/adfm.202370277
J. Lee, S. Shin, S. Lee, J. Song, S. Kang et al., Highly sensitive multifilament fiber strain sensors with ultrabroad sensing range for textile electronics. ACS Nano 12(5), 4259–4268 (2018). https://doi.org/10.1021/acsnano.7b07795
L. Gao, J. Yang, Y. Zhao, X. Zhao, K. Zhou et al., Multilayer bionic tunable strain sensor with mutually non-interfering conductive networks for machine learning-assisted gesture recognition. Adv. Funct. Mater. 35(11), 2416911 (2025). https://doi.org/10.1002/adfm.202416911
U. Yong, D. Kim, H. Kim, D.G. Hwang, S. Cho et al., Biohybrid 3D printing of a tissue-sensor platform for wireless, real-time, and continuous monitoring of drug-induced cardiotoxicity. Adv. Mater. 35(11), 2208983 (2023). https://doi.org/10.1002/adma.202208983
J. Gao, Y. Fan, Q. Zhang, L. Luo, X. Hu et al., Ultra-robust and extensible fibrous mechanical sensors for wearable smart healthcare. Adv. Mater. 34(20), e2107511 (2022). https://doi.org/10.1002/adma.202107511
Z. Wang, H. Zhou, D. Liu, X. Chen, D. Wang et al., A structural gel composite enabled robust underwater mechanosensing strategy with high sensitivity. Adv. Funct. Mater. 32(25), 2201396 (2022). https://doi.org/10.1002/adfm.202201396
O.A. Araromi, M.A. Graule, K.L. Dorsey, S. Castellanos, J.R. Foster et al., Ultra-sensitive and resilient compliant strain gauges for soft machines. Nature 587(7833), 219–224 (2020). https://doi.org/10.1038/s41586-020-2892-6
Y. Si, S. Shi, C. Zhi, L. Lei, J. Hu et al., Janus electrospun membranes. Adv. Mater. 37(38), 2507498 (2025). https://doi.org/10.1002/adma.202507498
Y. Si, S. Shi, J. Hu, Electrospinning and electrospraying synergism: Twins-tech collaboration across dimensions. Matter 7(4), 1373–1405 (2024). https://doi.org/10.1016/j.matt.2024.01.009
H. Ling, W. Xin, Y. Qian, X. He, L. Yang et al., Heterogeneous electrospinning nanofiber membranes with pH-regulated ion gating for tunable osmotic power harvesting. Angew. Chem. Int. Ed. 62(1), e202212120 (2023). https://doi.org/10.1002/anie.202212120
X. Cheng, T. Li, L. Yan, Y. Jiao, Y. Zhang et al., Biodegradable electrospinning superhydrophilic nanofiber membranes for ultrafast oil-water separation. Sci. Adv. 9(34), eadh8195 (2023). https://doi.org/10.1126/sciadv.adh8195
Y. Chen, Y. Jiang, X. Zhang, T. Zhang, W. Feng et al., Janus nanofibrous membranes for multifunctional sensing and personal thermal-moisture management. Chem. Eng. J. 519, 165413 (2025). https://doi.org/10.1016/j.cej.2025.165413
X. Kuang, Z. Zhang, X. Ma, L. Zhu, Y. Li et al., Advances in directional liquid transport textiles: mechanism, construction, and applications. Adv. Funct. Mater. 34(42), 2406906 (2024). https://doi.org/10.1002/adfm.202406906
S. Shi, Y. Ming, H. Wu, C. Zhi, L. Yang et al., A bionic skin for health management: excellent breathability, in situ sensing, and big data analysis. Adv. Mater. 36(17), e2306435 (2024). https://doi.org/10.1002/adma.202306435
C. Zhi, S. Shi, H. Wu, Y. Si, S. Zhang et al., Emerging trends of nanofibrous piezoelectric and triboelectric applications: mechanisms, electroactive materials, and designed architectures. Adv. Mater. 36(26), 2401264 (2024). https://doi.org/10.1002/adma.202401264
W. Yang, D. Pan, S. Liu, G. Jia, Y. Wang et al., Multifunctional wearable conductive nanofiber membrane with antibacterial and breathable ability for superior sensing, electromagnetic interference shielding, and thermal management. Adv. Funct. Mater. 35(6), 2414811 (2025). https://doi.org/10.1002/adfm.202414811
Z. Ma, Q. Huang, Q. Xu, Q. Zhuang, X. Zhao et al., Permeable superelastic liquid-metal fibre mat enables biocompatible and monolithic stretchable electronics. Nat. Mater. 20(6), 859–868 (2021). https://doi.org/10.1038/s41563-020-00902-3
C. Fan, Y. Zhang, Z. Long, A. Mensah, Q. Wang et al., Dynamically tunable subambient daytime radiative cooling metafabric with Janus wettability. Adv. Funct. Mater. 33(29), 2300794 (2023). https://doi.org/10.1002/adfm.202300794
B.-X. Li, Z. Luo, H. Sun, Q. Quan, S. Zhou et al., Spectral-selective and adjustable patterned polydimethylsiloxane/MXene/nanoporous polytetrafluoroethylene metafabric for dynamic infrared camouflage and thermal regulation. Adv. Funct. Mater. 34(45), 2407644 (2024). https://doi.org/10.1002/adfm.202407644
L. Ye, L.-X. Liu, J. Meng, X. Zhou, Y. Guang et al., Interfacial confinement derived high-strength MXene@graphene oxide core-shell fibers for electromagnetic wave regulation, thermochromic alerts, and visible camouflage. Small 21(11), 2411735 (2025). https://doi.org/10.1002/smll.202411735
H.E. Karahan, K. Goh, C.J. Zhang, E. Yang, C. Yıldırım et al., MXene materials for designing advanced separation membranes. Adv. Mater. 32(29), e1906697 (2020). https://doi.org/10.1002/adma.201906697
J. Björk, J. Zhou, P.O.Å. Persson, J. Rosen, Two-dimensional materials by large-scale computations and chemical exfoliation of layered solids. Science 383(6688), 1210–1215 (2024). https://doi.org/10.1126/science.adj6556
M. Naguib, M. Kurtoglu, V. Presser, J. Lu, J. Niu et al., Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Adv. Mater. 23(37), 4248–4253 (2011). https://doi.org/10.1002/adma.201102306
M. Alhabeb, K. Maleski, B. Anasori, P. Lelyukh, L. Clark et al., Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti3C2Tx MXene). Chem. Mater. 29(18), 7633–7644 (2017). https://doi.org/10.1021/acs.chemmater.7b02847
A. Lipatov, M. Alhabeb, M.R. Lukatskaya, A. Boson, Y. Gogotsi et al., Effect of synthesis on quality, electronic properties and environmental stability of individual monolayer Ti3C2 MXene flakes. Adv. Electron. Mater. 2(12), 1600255 (2016). https://doi.org/10.1002/aelm.201600255
X. Sang, Y. Xie, M.-W. Lin, M. Alhabeb, K.L. Van Aken et al., Atomic defects in monolayer titanium carbide (Ti3C2Tx) MXene. ACS Nano 10(10), 9193–9200 (2016). https://doi.org/10.1021/acsnano.6b05240
M. Tahir, L. He, L. Li, Y. Cao, X. Yu et al., Pushing the electrochemical performance limits of polypyrrole toward stable microelectronic devices. Nano-Micro Lett. 15(1), 49 (2023). https://doi.org/10.1007/s40820-023-01027-3
Z. Gao, X. Xiao, A. Di Carlo, J. Yin, Y. Wang et al., Advances in wearable strain sensors based on electrospun fibers. Adv. Funct. Mater. 33(18), 2214265 (2023). https://doi.org/10.1002/adfm.202214265
D. Wang, D. Zhang, P. Li, Z. Yang, Q. Mi et al., Electrospinning of flexible poly(vinyl alcohol)/MXene nanofiber-based humidity sensor self-powered by monolayer molybdenum diselenide piezoelectric nanogenerator. Nano-Micro Lett. 13(1), 57 (2021). https://doi.org/10.1007/s40820-020-00580-5
M. Shi, M. Shen, X. Guo, X. Jin, Y. Cao et al., Ti3C2Tx MXene-decorated nanoporous polyethylene textile for passive and active personal precision heating. ACS Nano 15(7), 11396–11405 (2021). https://doi.org/10.1021/acsnano.1c00903
Y. Bai, B. Zhang, J. Ma, Y. Cheng, P. Cui et al., Adhesion strategy for cross-linking AgNWs/MXene Janus membrane: stretchable and self-healing electromagnetic shielding and infrared stealth capabilities. Small 21(5), e2408950 (2025). https://doi.org/10.1002/smll.202408950
Y. Wang, N. Pang, X. Yin, M. Yu, Z. Yao et al., Rapid preparation of stretchable, compressible and flexible nanofiber foams by one-step expansion for thermal insulation and adsorption of sound and oil. Chem. Eng. J. 506, 159916 (2025). https://doi.org/10.1016/j.cej.2025.159916
Y. Wang, X. Yin, N. Pang, X. Yuan, Q. Han et al., Biomimetic all-fiber hierarchical multiscale composite aerogels for multifunctional thermal, acoustic, and oil absorption applications. Compos. Sci. Technol. 274, 111445 (2026). https://doi.org/10.1016/j.compscitech.2025.111445
Y. Wang, X. Yin, N. Pang, X. Yuan, Y. Xu et al., Hydrogen bond-regulated dissociation of aramid fibers for high-strength hierarchical aerogels with superior thermal and acoustic properties. Chem. Eng. J. 524, 169598 (2025). https://doi.org/10.1016/j.cej.2025.169598
J. Yang, Z. Pan, J. Zhong, S. Li, J. Wang et al., Electrostatic self-assembly of heterostructured black phosphorus–MXene nanocomposites for flexible microsupercapacitors with high rate performance. Energy Storage Mater. 36, 257–264 (2021). https://doi.org/10.1016/j.ensm.2020.12.025
T.S.L. Grace, C.T. Gibson, J.R. Gascooke, J.G. Shapter, The use of gravity filtration of carbon nanotubes from suspension to produce films with low roughness for carbon nanotube/silicon heterojunction solar device application. Appl. Sci. 10(18), 6415 (2020). https://doi.org/10.3390/app10186415
J. Cui, J. Wu, A. Feng, Y. Yu, L. Mi, Low infrared emissivity and oxidation stability of Ti3C2T MXene-based composite with tannic acid. Chem. Eng. J. 493, 152289 (2024). https://doi.org/10.1016/j.cej.2024.152289
S.N. Shuvo, A.M. Ulloa Gomez, A. Mishra, W.Y. Chen, A.M. Dongare et al., Sulfur-doped titanium carbide MXenes for room-temperature gas sensing. ACS Sens. 5(9), 2915–2924 (2020). https://doi.org/10.1021/acssensors.0c01287
A. Hermawan, B. Zhang, A. Taufik, Y. Asakura, T. Hasegawa et al., CuO nanops/Ti3C2Tx MXene hybrid nanocomposites for detection of toluene gas. ACS Appl. Nano Mater. 3(5), 4755–4766 (2020). https://doi.org/10.1021/acsanm.0c00749
Y. Zhou, Y. Wang, Y. Wang, H. Yu, R. Zhang et al., MXene Ti3C2Tx -derived nitrogen-functionalized heterophase TiO2 homojunctions for room-temperature trace ammonia gas sensing. ACS Appl. Mater. Interfaces 13(47), 56485–56497 (2021). https://doi.org/10.1021/acsami.1c17429
S.S. Kumar, H. Renuka, N. Hattrup, G.J. Wang, A.A. Presto et al., Polymer encapsulation via initiated chemical vapor deposition (iCVD) to enhance stability of Ti3C2Tx MXene-based formaldehyde sensors. Sci. Adv. 11(28), eadu6682 (2025). https://doi.org/10.1126/sciadv.adu6682
M. Ding, S. Li, L. Guo, L. Jing, S.-P. Gao et al., Metal ion-induced assembly of MXene aerogels via biomimetic microtextures for electromagnetic interference shielding, capacitive deionization, and microsupercapacitors. Adv. Energy Mater. 11(35), 2101494 (2021). https://doi.org/10.1002/aenm.202101494
W. Wang, L. Xu, L. Zhang, A. Zhang, J. Zhang, Self-powered integrated sensing system with in-plane micro-supercapacitors for wearable electronics. Small 19(29), e2207723 (2023). https://doi.org/10.1002/smll.202207723
Y. Zhan, J. Poisson, X. Meng, Z. Wang, L. Chen et al., Electrospun lignin/ZnO nanofibrous membranes for self-powered ultrasensitive flexible airflow sensor and wearable device. Adv. Mater. 37(37), 2502211 (2025). https://doi.org/10.1002/adma.202502211
A. Huang, Y. Zhu, S. Peng, B. Tan, X. Peng, Improved energy harvesting ability of single-layer binary fiber nanocomposite membrane for multifunctional wearable hybrid piezoelectric and triboelectric nanogenerator and self-powered sensors. ACS Nano 18(1), 691–702 (2024). https://doi.org/10.1021/acsnano.3c09043
S. Ding, X. Jin, B. Wang, Z. Niu, J. Ma et al., Integrating Ti3C2Tx MXene nanosheets with thermoplastic polyurethane nanofibers as wearable humidity sensors for noninvasive sleep monitoring and noncontact sensing. ACS Appl. Nano Mater. 6(13), 11810–11821 (2023). https://doi.org/10.1021/acsanm.3c01732
D. Lei, Q. Zhang, N. Liu, T. Su, L. Wang et al., Self-powered graphene oxide humidity sensor based on potentiometric humidity transduction mechanism. Adv. Funct. Mater. 32(10), 2107330 (2022). https://doi.org/10.1002/adfm.202107330
J. Yang, L. Feng, Y. Chen, L. Feng, J. Lu et al., High-sensitivity and environmentally friendly humidity sensors deposited with recyclable green microspheres for wireless monitoring. ACS Appl. Mater. Interfaces 14(13), 15608–15622 (2022). https://doi.org/10.1021/acsami.2c00489
T. Liu, D. Qu, L. Guo, G. Zhou, G. Zhang et al., MXene/TPU composite film for humidity sensing and human respiration monitoring. Adv. Sens. Res. 3(3), 2300014 (2024). https://doi.org/10.1002/adsr.202300014
J. Li, X. Yuan, C. Lin, Y. Yang, L. Xu et al., Achieving high pseudocapacitance of 2D titanium carbide (MXene) by cation intercalation and surface modification. Adv. Energy Mater. 7(15), 1602725 (2017). https://doi.org/10.1002/aenm.201602725
M. Ghidiu, J. Halim, S. Kota, D. Bish, Y. Gogotsi et al., Ion-exchange and cation solvation reactions in Ti3C2 MXene. Chem. Mater. 28(10), 3507–3514 (2016). https://doi.org/10.1021/acs.chemmater.6b01275
E.S. Muckley, M. Naguib, H.-W. Wang, L. Vlcek, N.C. Osti et al., Multimodality of structural, electrical, and gravimetric responses of intercalated MXenes to water. ACS Nano 11(11), 11118–11126 (2017). https://doi.org/10.1021/acsnano.7b05264
E.S. Muckley, M. Naguib, I.N. Ivanov, Multi-modal, ultrasensitive, wide-range humidity sensing with Ti3C2 film. Nanoscale 10(46), 21689–21695 (2018). https://doi.org/10.1039/c8nr05170d
J. Hu, Y. Hu, Y. Ye, R. Shen, Unique applications of carbon materials in infrared stealth: a review. Chem. Eng. J. 452, 139147 (2023). https://doi.org/10.1016/j.cej.2022.139147
Z. Wu, H.-W. Cheng, C. Jin, B. Yang, C. Xu et al., Dimensional design and core–shell engineering of nanomaterials for electromagnetic wave absorption. Adv. Mater. 34(11), 2107538 (2022). https://doi.org/10.1002/adma.202107538
N. Pang, X. Cheng, Y. Wang, X. Yin, X. Meng et al., Flexible multifunctional MXene/SWCNTs composite films with excellent infrared stealth, electromagnetic interference shielding and electrical heating properties. Carbon 238, 120303 (2025). https://doi.org/10.1016/j.carbon.2025.120303
N. Pang, X. Cheng, X. Yin, Y. Wang, W. Liu et al., Janus-structured ion-bridged MXene@PDA@PNF flexible composite films for synergistic infrared stealth, Joule thermal management, and EMI shielding. J. Mater. Sci. Technol. 259, 292–306 (2026). https://doi.org/10.1016/j.jmst.2025.10.007