Issue

Vol. 9 No. 4 (2017)

Recent Advances of Graphitic Carbon Nitride-Based Structures and Applications in Catalyst, Sensing, Imaging, and LEDs

https://doi.org/10.1007/s40820-017-0148-2
Aiwu Wang
School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China
Chundong Wang
School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China
Li Fu
Center of Super-Diamond and Advanced Films (COSDAF) and Department of Physics and Materials Science, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong SAR, People’s Republic of China
Winnie Wong-Ng
Materials Science Measurement Division, National Institute of Standards and Technology, Gaitherburg, MD 20899, USA
Yucheng Lan
Department of Physics and Engineering, Morgan State University, Baltimore, MD 21251, USA

Corresponding Author: Yucheng Lan

yucheng.lan@morgan.edu

Nano-Micro Letters, Vol. 9 No. 4 (2017), Article Number: 47

Abstract

The graphitic carbon nitride (g-C3N4) which is a two-dimensional conjugated polymer has drawn broad interdisciplinary attention as a low-cost, metal-free, and visible-light-responsive photocatalyst in the area of environmental remediation. The g-C3N4-based materials have excellent electronic band structures, electron-rich properties, basic surface functionalities, high physicochemical stabilities and are “earth-abundant.” This review summarizes the latest progress related to the design and construction of g-C3N4-based materials and their applications including catalysis, sensing, imaging, and white-light-emitting diodes. An outlook on possible further developments in g-C3N4-based research for emerging properties and applications is also included.


Highlights:


1 The g-C3N4-based materials have excellent electronic band structures, electron-rich properties, basic surface functionalities, high physicochemical stabilities and are “earth-abundant.”
2 Recent progress of g-C3N4-based nanostructures in catalyst, sensing, imaging and LEDs have been discussed in details.
3 An outlook on possible further developments in g-C3N4-based research for emerging properties and applications is also included.

Keywords

Graphitic carbon nitride (g-C3N4) Catalysis Sensing Imaging LED
Wang, Aiwu, Chundong Wang, Li Fu, Winnie Wong-Ng, and Yucheng Lan. 2017. “Recent Advances of Graphitic Carbon Nitride-Based Structures and Applications in Catalyst, Sensing, Imaging, and LEDs”. Nano-Micro Letters 9 (4):47. https://doi.org/10.1007/s40820-017-0148-2.
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References
  1. J. Von, Liebig, Uber einige stickstoff-verbindungen. Eur. J. Organic Chem. 10(1), 1–47 (1834). doi:10.1002/jlac.18340100102
  2. A.Y. Liu, M.L. Cohen, Prediction of new low compressibility solids. Science 245(4920), 841–842 (1989). doi:10.1126/science.245.4920.841
  3. F. Goettmann, A. Fischer, M. Antonietti, A. Thomas, Metal-free catalysis of sustainable Friedel–Crafts reactions: direct activation of benzene by carbon nitrides to avoid the use of metal chlorides and halogenated compounds. Chem. Commun. 43, 4530–4532 (2006). doi:10.1039/B608532F
  4. D.M. Teter, R.J. Hemley, Low-compressibility carbon nitrides. Science 271(5245), 53–55 (1996). doi:10.1126/science.271.5245.53
  5. X. Wang, K. Maeda, A. Thomas, K. Takanabe, G. Xin, J.M. Carlsson, K. Domen, M. Antonietti, A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nat. Mater. 8(1), 76–80 (2009). doi:10.1038/NMAT2317
  6. Y.S. Jun, W.H. Hong, M. Antonietti, A. Thomas, Mesoporous, 2D hexagonal carbon nitride and titanium nitride/carbon composites. Adv. Mater. 21(42), 4270–4274 (2009). doi:10.1002/adma.200803500
  7. E. Kroke, M. Schwarz, E. Horath-Bordon, P. Kroll, B. Noll, A.D. Norman, Tri-s-triazine derivatives. Part I. From trichloro-tri-s-triazine to graphitic C3N4 structures. New J. Chem. 26(5), 508–512 (2002). doi:10.1039/b111062b
  8. A. Fujishima, Electrochemical photolysis of water at a semiconductor electrode. Nature 238, 37–38 (1972). doi:10.1038/238037a0
  9. H. Tong, S. Ouyang, Y. Bi, N. Umezawa, M. Oshikiri, J. Ye, Nano-photocatalytic materials: possibilities and challenges. Adv. Mater. 24(2), 229–251 (2012). doi:10.1002/adma.201102752
  10. Y. Zheng, L. Fu, F. Han, A. Wang, W. Cai, J. Yu, J. Yang, F. Peng, Green biosynthesis and characterization of zinc oxide nanoparticles using Corymbia citriodora leaf extract and their photocatalytic activity. Green Chem. Lett. Rev. 8(2), 59–63 (2015). doi:10.1080/17518253.2015.1075069
  11. C. Wang, A.W. Wang, J. Feng, Z. Li, B. Chen, Q.-H. Wu, J. Jiang, J. Lu, Y.Y. Li, Hydrothermal preparation of hierarchical MoS2-reduced graphene oxide nanocomposites towards remarkable enhanced visible-light photocatalytic activity. Ceram. Int. 43(2), 2384–2388 (2017). doi:10.1016/j.matlet.2014.12.021
  12. L. Fu, W. Cai, A. Wang, Y. Zheng, Photocatalytic hydrogenation of nitrobenzene to aniline over tungsten oxide-silver nanowires. Mater. Lett. 142, 201–203 (2015). doi:10.1016/j.matlet.2014.12.021
  13. Y. Hou, Z. Wen, S. Cui, X. Feng, J. Chen, Strongly coupled ternary hybrid aerogels of N-deficient porous graphitic-C3N4 nanosheets/N-doped graphene/NiFe-layered double hydroxide for solar-driven photoelectrochemical water oxidation. Nano Lett. 16(4), 2268–2277 (2016). doi:10.1021/acs.nanolett.5b04496
  14. Z. Tong, D. Yang, Z. Li, Y. Nan, F. Ding, Y. Shen, Z. Jiang, Thylakoid-inspired multi-shell g-C3N4 nanocapsules with enhanced visible-light harvesting and electron transfer properties for high-efficiency photocatalysis. ACS Nano 11(1), 1103–1112 (2017). doi:10.1021/acsnano.6b08251
  15. G. Wu, Y. Hu, Y. Liu, J. Zhao, X. Chen, V. Whoehling, C. Plesse, G.T. Nguyen, F. Vidal, W. Chen, Graphitic carbon nitride nanosheet electrode-based high-performance ionic actuator. Nat. Commun. 6, 7258 (2015). doi:10.1038/ncomms8258
  16. C. Li, Y. Du, D. Wang, S. Yin, W. Tu, Z. Chen, M. Kraft, G. Chen, R. Xu, Unique P-Co-N surface bonding states constructed on g-C3N4 nanosheets for drastically enhanced photocatalytic activity of H2 evolution. Adv. Funct. Mater. 27(4), 1604328 (2016). doi:10.1002/adfm.201604328
  17. X. Liu, L. Dai, Carbon-based metal-free catalysts. Nat. Rev. Mater. 1, 16064 (2016). doi:10.1038/natrevmats.2016.64
  18. Y. Zheng, Y. Jiao, Y. Zhu, L.H. Li, Y. Han, Y. Chen, A. Du, M. Jaroniec, S.Z. Qiao, Hydrogen evolution by a metal-free electrocatalyst. Nat. Commun. 5, 3783 (2014). doi:10.1038/ncomms4783
  19. Q. Guo, Y. Zhang, J. Qiu, G. Dong, Engineering the electronic structure and optical properties of g-C3N4 by non-metal ion doping. J. Mater. Chem. C 4(28), 6839–6847 (2016). doi:10.1039/c6tc01831a
  20. F. He, G. Chen, Y. Yu, Y. Zhou, Y. Zheng, S. Hao, The synthesis of condensed C-PDA-C3N4 composites with superior photocatalytic performance. Chem. Commun. 51(31), 6824–6827 (2015). doi:10.1039/c5cc01013f
  21. Y. Li, S. Ouyang, H. Xu, X. Wang, Y. Bi, Y. Zhang, J. Ye, Constructing solid–gas-interfacial fenton reaction over alkalinized-C3N4 photocatalyst to achieve apparent quantum yield of 49% at 420 nm. J. Am. Chem. Soc. 138(40), 13289–13297 (2016). doi:10.1021/jacs.6b07272
  22. S. Kumar, B. Kumar, A. Baruah, V. Shanker, Synthesis of magnetically separable and recyclable g-C3N4–Fe3O4 hybrid nanocomposites with enhanced photocatalytic performance under visible-light irradiation. J. Phys. Chem. 117(49), 26135–26143 (2013). doi:10.1021/jp409651g
  23. J. Zhang, M. Zhang, L. Lin, X. Wang, Sol processing of conjugated carbon nitride powders for thin-film fabrication. Angew. Chem. Int. Ed. 54(21), 6297–6301 (2015). doi:10.1002/anie.201501001
  24. J. Bian, Q. Li, C. Huang, J. Li, Y. Guo, M. Zaw, R.-Q. Zhang, Thermal vapor condensation of uniform graphitic carbon nitride films with remarkable photocurrent density for photoelectrochemical applications. Nano Energy 15, 353–361 (2015). doi:10.1016/j.nanoen.2015.04.012
  25. Y. Feng, J. Shen, Q. Cai, H. Yang, Q. Shen, The preparation and properties of a gC3N4/AgBr nanocomposite photocatalyst based on protonation pretreatment. New J. Chem. 39(2), 1132–1138 (2015). doi:10.1039/C4NJ01433B
  26. M. Shalom, S. Gimenez, F. Schipper, I. Herraiz-Cardona, J. Bisquert, M. Antonietti, Controlled carbon nitride growth on surfaces for hydrogen evolution electrodes. Angew. Chem. Int. Ed. 126(14), 3728–3732 (2014). doi:10.1002/ange.201309415
  27. P. Wu, J. Wang, J. Zhao, L. Guo, F.E. Osterloh, Structure defects in g-C3N4 limit visible light driven hydrogen evolution and photovoltage. J. Mater. Chem. A 2(47), 20338–20344 (2014). doi:10.1039/c4ta04100c
  28. K. Srinivasu, B. Modak, S.K. Ghosh, Porous graphitic carbon nitride: a possible metal-free photocatalyst for water splitting. J. Phys. Chem. C 118(46), 26479–26484 (2014). doi:10.1021/jp506538d
  29. J. Duan, S. Chen, M. Jaroniec, S.Z. Qiao, Porous C3N4 nanolayers@ N-graphene films as catalyst electrodes for highly efficient hydrogen evolution. ACS Nano 9(1), 931–940 (2015). doi:10.1021/nn506701x
  30. M. Tahir, C. Cao, N. Mahmood, F.K. Butt, A. Mahmood et al., Multifunctional g-C3N4 nanofibers: a template-free fabrication and enhanced optical, electrochemical, and photocatalyst properties. ACS Appl. Mater. Interfaces 6(2), 1258–1265 (2013). doi:10.1021/am405076b
  31. Y. Guo, F. Kong, C. Wang, S. Chu, J. Yang, Y. Wang, Z. Zou, Molecule-induced gradient electronic potential distribution on a polymeric photocatalyst surface and improved photocatalytic performance. J. Mater. Chem. A 1(16), 5142–5147 (2013). doi:10.1039/c3ta10528h
  32. J. Liu, H. Wang, Z.P. Chen, H. Moehwald, S. Fiechter, R. van de Krol, L. Wen, L. Jiang, M. Antonietti, Microcontact-printing-assisted access of graphitic carbon nitride films with favorable textures toward photoelectrochemical application. Adv. Mater. 27(4), 712–718 (2015). doi:10.1002/adma.201404543
  33. Y.-P. Zhu, T.-Z. Ren, Z.-Y. Yuan, Mesoporous phosphorus-doped g-C3N4 nanostructured flowers with superior photocatalytic hydrogen evolution performance. ACS Appl. Mater. Interfaces 7(30), 16850–16856 (2015). doi:10.1021/acsami.5b04947
  34. Y. Kang, Y. Yang, L.C. Yin, X. Kang, G. Liu, H.M. Cheng, An amorphous carbon nitride photocatalyst with greatly extended visible-light-responsive range for photocatalytic hydrogen generation. Adv. Mater. 27(31), 4572–4577 (2015). doi:10.1002/adma.201501939
  35. Y. Shiraishi, S. Kanazawa, Y. Sugano, D. Tsukamoto, H. Sakamoto, S. Ichikawa, T. Hirai, Highly selective production of hydrogen peroxide on graphitic carbon nitride (g-C3N4) photocatalyst activated by visible light. ACS Catal. 4(3), 774–780 (2014). doi:10.1021/cs401208c
  36. Y. Chen, W. Huang, D. He, Y. Situ, H. Huang, Construction of heterostructured g-C3N4/Ag/TiO2 microspheres with enhanced photocatalysis performance under visible-light irradiation. ACS Appl. Mater. Interfaces 6(16), 14405–14414 (2014). doi:10.1021/am503674e
  37. F. Dong, Z. Zhao, Y. Sun, Y. Zhang, S. Yan, Z. Wu, An advanced semimetal–organic bi spheres–g-C3N4 nanohybrid with SPR-enhanced visible-light photocatalytic performance for NO purification. Environ. Sci. Technol. 49(20), 12432–12440 (2015). doi:10.1021/acs.est.5b03758
  38. J. Wang, Z. Guan, J. Huang, Q. Li, J. Yang, Enhanced photocatalytic mechanism for the hybrid g-C3N4/MoS2 nanocomposite. J. Mater. Chem. A 2(21), 7960–7966 (2014). doi:10.1039/c4ta00275j
  39. A. Thomas, A. Fischer, F. Goettmann, M. Antonietti, J.-O. Müller, R. Schlögl, J.M. Carlsson, Graphitic carbon nitride materials: variation of structure and morphology and their use as metal-free catalysts. J. Mater. Chem. 18(41), 4893–4908 (2008). doi:10.1039/b800274f
  40. W.-J. Ong, L.-L. Tan, Y.H. Ng, S.-T. Yong, S.-P. Chai, Graphitic carbon nitride (g-C3N4)-based photocatalysts for artificial photosynthesis and environmental remediation: are we a step closer to achieving sustainability? Chem. Rev. 116(12), 7159–7329 (2016). doi:10.1021/acs.chemrev.6b00075
  41. Z. Zhao, Y. Sun, F. Dong, Graphitic carbon nitride based nanocomposites: a review. Nanoscale 7(1), 15–37 (2015). doi:10.1039/C4NR03008G
  42. J. Zhu, P. Xiao, H. Li, S.A. Carabineiro, Graphitic carbon nitride: synthesis, properties, and applications in catalysis. ACS Appl. Mater. Interfaces 6(19), 16449–16465 (2014). doi:10.1021/am502925j
  43. L. Zhou, H. Zhang, H. Sun, S. Liu, M.O. Tade, S. Wang, W. Jin, Recent advances in non-metal modification of graphitic carbon nitride for photocatalysis: a historic review. Catal. Sci. Technol. 6(19), 7002–7023 (2016). doi:10.1039/C6CY01195K
  44. Y. Zheng, L. Lin, B. Wang, X. Wang, Graphitic carbon nitride polymers toward sustainable photoredox catalysis. Angew. Chem. Int. Ed. 54(44), 12868–12884 (2015). doi:10.1002/anie.201501788
  45. X.H. Li, M. Antonietti, Metal nanoparticles at mesoporous N-doped carbons and carbon nitrides: functional Mott-Schottky heterojunctions for catalysis. Chem. Soc. Rev. 42(16), 6593–6604 (2013). doi:10.1039/c3cs60067j
  46. J. Liu, W. Li, L. Duan, X. Li, L. Ji et al., A Graphene-like oxygenated carbon nitride material for improved cycle-life lithium/sulfur batteries. Nano Lett. 15(8), 5137–5142 (2015). doi:10.1021/acs.nanolett.5b01919
  47. G.S. Li, Z.C. Lian, W.C. Wang, D.Q. Zhang, H.X. Li, Nanotube-confinement induced size-controllable g-C3N4 quantum dots modified single-crystalline TiO2 nanotube arrays for stable synergetic photoelectrocatalysis. Nano Energy 19, 446–454 (2016). doi:10.1016/j.nanoen.2015.10.011
  48. L. Shi, T. Wang, H. Zhang, K. Chang, J. Ye, Electrostatic self-assembly of nanosized carbon nitride nanosheet onto a zirconium metal-organic framework for enhanced photocatalytic CO2 reduction. Adv. Funct. Mater. 25(33), 5360–5367 (2015). doi:10.1002/adfm.201502253
  49. J.W. Fang, H.Q. Fan, M.M. Li, C.B. Long, Nitrogen self-doped graphitic carbon nitride as efficient visible light photocatalyst for hydrogen evolution. J. Mater. Chem. A 3(26), 13819–13826 (2015). doi:10.1039/c5ta02257f
  50. G. Zhang, M. Zhang, X. Ye, X. Qiu, S. Lin, X. Wang, Iodine modified carbon nitride semiconductors as visible light photocatalysts for hydrogen evolution. Adv. Mater. 26(5), 805–809 (2014). doi:10.1002/adma.201303611
  51. Q.H. Liang, Z. Li, Z.H. Huang, F.Y. Kang, Q.H. Yang, Holey graphitic carbon nitride nanosheets with carbon vacancies for highly improved photocatalytic hydrogen production. Adv. Funct. Mater. 25(44), 6885–6892 (2015). doi:10.1002/adfm.201503221
  52. T.Y. Ma, Y. Tang, S. Dai, S.Z. Qiao, Proton-functionalized two-dimensional graphitic carbon nitride nanosheet: an excellent metal-/label-free biosensing platform. Small 10(12), 2382–2389 (2014). doi:10.1002/smll.201303827
  53. G. Liu, T. Wang, H. Zhang, X. Meng, D. Hao, K. Chang, P. Li, T. Kako, J. Ye, Nature-inspired environmental phosphorylation boosts photocatalytic H2 production over carbon nitride nanosheets under visible-light irradiation. Angew. Chem. Int. Ed. 127(46), 13765–13769 (2015). doi:10.1002/ange.201505802
  54. X.D. Sun, Y.Y. Li, J. Zhou, C. Hai Ma, Y. Wang, J.H. Zhu, Facile synthesis of high photocatalytic active porous g-C3N4 with ZnCl2 template. J. Colloid Interface Sci. 451, 108–116 (2015). doi:10.1016/j.jcis.2015.03.059
  55. J. Zhu, Y. Wei, W. Chen, Z. Zhao, A. Thomas, Graphitic carbon nitride as a metal-free catalyst for NO decomposition. Chem. Commun. 46(37), 6965–6967 (2010). doi:10.1039/c0cc01432j
  56. Y. Shiraishi, Y. Kofuji, H. Sakamoto, S. Tanaka, S. Ichikawa, T. Hirai, Effects of surface defects on photocatalytic H2O2 production by mesoporous graphitic carbon nitride under visible light irradiation. ACS Catal. 5(5), 3058–3066 (2015). doi:10.1021/acscatal.5b00408
  57. J. Xiao, Y. Xie, F. Nawaz, Y. Wang, P. Du, H. Cao, Dramatic coupling of visible light with ozone on honeycomb-like porous g-C3N4 towards superior oxidation of water pollutants. Appl. Catal. B 183, 417–425 (2016). doi:10.1016/j.apcatb.2015.11.010
  58. K. Wang, Q. Li, B. Liu, B. Cheng, W. Ho, J. Yu, Sulfur-doped g-C3N4 with enhanced photocatalytic CO2-reduction performance. Appl. Catal. B 176, 44–52 (2015). doi:10.1016/j.apcatb.2015.03.045
  59. J. Xu, H.T. Wu, X. Wang, B. Xue, Y.X. Li, Y. Cao, A new and environmentally benign precursor for the synthesis of mesoporous g-C3N4 with tunable surface area. Phys. Chem. Chem. Phys. 15(13), 4510–4517 (2013). doi:10.1039/c3cp44402c
  60. Y.J. Chung, B.I. Lee, J.W. Ko, C.B. Park, Photoactive g-C3N4 nanosheets for light-induced suppression of alzheimer’s beta-amyloid aggregation and toxicity. Adv. Healthc. Mater. 5(13), 1560–1565 (2016). doi:10.1002/adhm.201500964
  61. W. Shan, Y. Hu, Z. Bai, M. Zheng, C. Wei, In situ preparation of g-C3N4/bismuth-based oxide nanocomposites with enhanced photocatalytic activity. Appl. Catal. B 188, 1–12 (2016). doi:10.1016/j.apcatb.2016.01.058
  62. M. Sevilla, R. Mokaya, Energy storage applications of activated carbons: supercapacitors and hydrogen storage. Energy Environ. Sci. 7(4), 1250–1280 (2014). doi:10.1039/c3ee43525c
  63. C.Y. Liu, Y.H. Zhang, F. Dong, X. Du, H.W. Huang, Easily and synchronously ameliorating charge separation and band energy level in porous g-C3N4 for boosting photooxidation and photoreduction ability. J. Phys. Chem. C 120(19), 10381–10389 (2016). doi:10.1021/acs.jpcc.6b01705
  64. S. Pandiaraj, H.B. Aiyappa, R. Banerjee, S. Kurungot, Post modification of MOF derived carbon via g-C3N4 entrapment for an efficient metal-free oxygen reduction reaction. Chem. Commun. 50(25), 3363–3366 (2014). doi:10.1039/c3cc47620k
  65. X. Zhang, X. Xie, H. Wang, J. Zhang, B. Pan, Y. Xie, Enhanced photoresponsive ultrathin graphitic-phase C3N4 nanosheets for bioimaging. J. Am. Chem. Soc. 135(1), 18–21 (2013). doi:10.1021/ja308249k
  66. K. Chen, Z. Chai, C. Li, L. Shi, M. Liu, Q. Xie, Y. Zhang, D. Xu, A. Manivannan, Z. Liu, Catalyst-free growth of three-dimensional graphene flakes and graphene/g-C(3)N(4) composite for hydrocarbon oxidation. ACS Nano 10(3), 3665–3673 (2016). doi:10.1021/acsnano.6b00113
  67. X. Yuan, C. Zhou, Y. Jin, Q. Jing, Y. Yang, X. Shen, Q. Tang, Y. Mu, A.K. Du, Facile synthesis of 3D porous thermally exfoliated g-C3N4 nanosheet with enhanced photocatalytic degradation of organic dye. J. Colloid Interface Sci. 468, 211–219 (2016). doi:10.1016/j.jcis.2016.01.048
  68. J.S. Zhang, Y. Chen, X.C. Wang, Two-dimensional covalent carbon nitride nanosheets: synthesis, functionalization, and applications. Energy Environ. Sci. 8(11), 3092–3108 (2015). doi:10.1039/c5ee01895a
  69. K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, Y. Zhang, S.V. Dubonos, I.V. Grigorieva, A.A. Firsov, Electric field effect in atomically thin carbon films. Science 306(5696), 666–669 (2004). doi:10.1126/science.1102896
  70. C. Wang, Y. Zhou, L. He, T.W. Ng, G. Hong, Q.H. Wu, F. Gao, C.S. Lee, W. Zhang, In situ nitrogen-doped graphene grown from polydimethylsiloxane by plasma enhanced chemical vapor deposition. Nanoscale 5(2), 600–605 (2013). doi:10.1039/c2nr32897f
  71. C.D. Wang, Y.S. Chui, R.G. Ma, T.L. Wong, J.G. Ren, Q.H. Wu, X.F. Chen, W.J. Zhang, A three-dimensional graphene scaffold supported thin film silicon anode for lithium-ion batteries. J. Mater. Chem. A 1(35), 10092–10098 (2013). doi:10.1039/c3ta11740e
  72. C.D. Wang, J.L. Xu, M.F. Yuen, J. Zhang, Y.Y. Li, X.F. Chen, W.J. Zhang, Hierarchical composite electrodes of nickel oxide nanoflake 3D graphene for high-performance pseudocapacitors. Adv. Funct. Mater. 24(40), 6372–6380 (2014). doi:10.1002/adfm.201401216
  73. Q. Han, F. Zhao, C. Hu, L. Lv, Z. Zhang, N. Chen, L. Qu, Facile production of ultrathin graphitic carbon nitride nanoplatelets for efficient visible-light water splitting. Nano Res. 8(5), 1718–1728 (2015). doi:10.1007/s12274-014-0675-9
  74. N. Cheng, P. Jiang, Q. Liu, J. Tian, A.M. Asiri, X. Sun, Graphitic carbon nitride nanosheets: one-step, high-yield synthesis and application for Cu2+ detection. Analyst 139(20), 5065–5068 (2014). doi:10.1039/c4an00914b
  75. P. Niu, L.L. Zhang, G. Liu, H.M. Cheng, Graphene-like carbon nitride nanosheets for improved photocatalytic activities. Adv. Funct. Mater. 22(22), 4763–4770 (2012). doi:10.1002/adfm.201200922
  76. K. Schwinghammer, M.B. Mesch, V. Duppel, C. Ziegler, J. Senker, B.V. Lotsch, Crystalline carbon nitride nanosheets for improved visible-light hydrogen evolution. J. Am. Chem. Soc. 136(5), 1730–1733 (2014). doi:10.1021/ja411321s
  77. J.S. Zhang, J.H. Sun, K. Maeda, K. Domen, P. Liu, M. Antonietti, X.Z. Fu, X.C. Wang, Sulfur-mediated synthesis of carbon nitride: band-gap engineering and improved functions for photocatalysis. Energy Environ. Sci. 4(3), 675–678 (2011). doi:10.1039/c0ee00418a
  78. S. Yang, X. Feng, X. Wang, K. Mullen, Graphene-based carbon nitride nanosheets as efficient metal-free electrocatalysts for oxygen reduction reactions. Angew. Chem. Int. Ed. 50(23), 5339–5343 (2011). doi:10.1002/anie.201100170
  79. S. Wang, C. Li, T. Wang, P. Zhang, A. Li, J. Gong, Controllable synthesis of nanotube-type graphitic C3N4 and their visible-light photocatalytic and fluorescent properties. J. Mater. Chem. A 2(9), 2885–2890 (2014). doi:10.1039/c3ta14576j
  80. Y. Zheng, L. Lin, X. Ye, F. Guo, X. Wang, Helical graphitic carbon nitrides with photocatalytic and optical activities. Angew. Chem. Int. Ed. 53(44), 11926–11930 (2014). doi:10.1002/anie.201407319
  81. J. Liu, J. Huang, H. Zhou, M. Antonietti, Uniform graphitic carbon nitride nanorod for efficient photocatalytic hydrogen evolution and sustained photoenzymatic catalysis. ACS Appl. Mater. Interfaces 6(11), 8434–8440 (2014). doi:10.1021/am501319v
  82. X.-H. Li, X. Wang, M. Antonietti, Mesoporous g-C3N4 nanorods as multifunctional supports of ultrafine metal nanoparticles: hydrogen generation from water and reduction of nitrophenol with tandem catalysis in one step. Chem. Sci. 3(6), 2170–2174 (2012). doi:10.1039/c2sc20289a
  83. F. He, G. Chen, J. Miao, Z. Wang, D. Su et al., Sulfur-mediated self-templating synthesis of tapered C-PAN/g-C3N4 composite nanotubes toward efficient photocatalytic H2 evolution. ACS Energy Lett. 1(5), 969–975 (2016). doi:10.1021/acsenergylett.6b00398
  84. S. Panneri, M. Thomas, P. Ganguly, B.N. Nair, A.M. Peer, K.G.K. Warrier, H.U.N. Saraswathy, C3N4 anchored ZIF 8 composites: photo-regenerable, high capacity sorbents as adsorptive photocatalysts for the effective removal of tetracycline from water. Catal. Sci. Technol. 7, 2118–2128 (2017). doi:10.1039/C7CY00348J
  85. Z. Tong, D. Yang, Y. Sun, Y. Nan, Z. Jiang, Tubular g-C3N4 isotype heterojunction: enhanced visible-light photocatalytic activity through cooperative manipulation of oriented electron and hole transfer. Small 12(30), 4093–4101 (2016). doi:10.1002/smll.201601660
  86. W. Wang, C.Y. Jimmy, Z. Shen, D.K. Chan, T. Gu, g-C3N4 quantum dots: direct synthesis, upconversion properties and photocatalytic application. Chem. Commun. 50(70), 10148–10150 (2014). doi:10.1039/c4cc02543a
  87. X.D. Zhang, H.X. Wang, H. Wang, Q. Zhang, J.F. Xie, Y.P. Tian, J. Wang, Y. Xie, Single-layered graphitic-C3N4 quantum dots for two-photon fluorescence imaging of cellular nucleus. Adv. Mater. 26(26), 4438–4443 (2014). doi:10.1002/adma.201400111
  88. J. Wu, S. Yang, J. Li, Y. Yang, G. Wang et al., Electron injection of phosphorus doped g-C3N4 quantum dots: controllable photoluminescence emission wavelength in the whole visible light range with high quantum yield. Adv. Opt. Mater. 4(12), 2095–2101 (2016). doi:10.1002/adom.201600570
  89. X. Cao, J. Ma, Y. Lin, B. Yao, F. Li, W. Weng, X. Lin, A facile microwave-assisted fabrication of fluorescent carbon nitride quantum dots and their application in the detection of mercury ions. Spectrochim. Acta A 151, 875–880 (2015). doi:10.1016/j.saa.2015.07.034
  90. Y.-C. Lu, J. Chen, A.-J. Wang, N. Bao, J.-J. Feng, W. Wang, L. Shao, Facile synthesis of oxygen and sulfur co-doped graphitic carbon nitride fluorescent quantum dots and their application for mercury (II) detection and bioimaging. J. Mater. Chem. C 3(1), 73–78 (2015). doi:10.1039/c4tc02111h
  91. P. Niu, L.C. Yin, Y.Q. Yang, G. Liu, H.M. Cheng, Increasing the visible light absorption of graphitic carbon nitride (melon) photocatalysts by homogeneous self-modification with nitrogen vacancies. Adv. Mater. 26(47), 8046–8052 (2014). doi:10.1002/adma.201404057
  92. J. Sun, Y. Fu, G. He, X. Sun, X. Wang, Green Suzuki-Miyaura coupling reaction catalyzed by palladium nanoparticles supported on graphitic carbon nitride. Appl. Catal. B 165, 661–667 (2015). doi:10.1016/j.apcatb.2014.10.072
  93. A. Kumar, P. Kumar, C. Joshi, S. Ponnada, A.K. Pathak, A. Ali, B. Sreedhar, S.L. Jain, A [Fe(bpy)(3)](2 +) grafted graphitic carbon nitride hybrid for visible light assisted oxidative coupling of benzylamines under mild reaction conditions. Green Chem. 18(8), 2514–2521 (2016). doi:10.1039/c5gc02090e
  94. P. Sharma, Y. Sasson, A photoactive catalyst Ru–g-C3N4 for hydrogen transfer reaction of aldehydes and ketones. Green Chem. 19, 844–852 (2017). doi:10.1039/c6gc02949c
  95. H. Wang, S. Jiang, S. Chen, D. Li, X. Zhang et al., Enhanced singlet oxygen generation in oxidized graphitic carbon nitride for organic synthesis. Adv. Mater. 28(32), 6940–6945 (2016). doi:10.1002/adma.201601413
  96. M. Zhang, X. Wang, Two dimensional conjugated polymers with enhanced optical absorption and charge separation for photocatalytic hydrogen evolution. Energy Environ. Sci. 7(6), 1902–1906 (2014). doi:10.1039/C3EE44189J
  97. J. Liu, Y. Liu, N. Liu, Y. Han, X. Zhang et al., Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway. Science 347(6225), 970–974 (2015). doi:10.1126/science.aaa3145
  98. K. Dai, L. Lu, Q. Liu, G. Zhu, X. Wei, J. Bai, L. Xuan, H. Wang, Sonication assisted preparation of graphene oxide/graphitic-C3N4 nanosheet hybrid with reinforced photocurrent for photocatalyst applications. Dalton Trans. 43(17), 6295–6299 (2014). doi:10.1039/c3dt53106f
  99. Z. Ma, R. Sa, Q. Li, K. Wu, Interfacial electronic structure and charge transfer of hybrid graphene quantum dot and graphitic carbon nitride nanocomposites: insights into high efficiency for photocatalytic solar water splitting. Phys. Chem. Chem. Phys. 18(2), 1050–1058 (2016). doi:10.1039/c5cp05847c
  100. L. Gu, J. Wang, Z. Zou, X. Han, Graphitic-C3N4-hybridized TiO2 nanosheets with reactive 001 facets to enhance the UV-and visible-light photocatalytic activity. J. Hazard. Mater. 268, 216–223 (2014). doi:10.1016/j.jhazmat.2014.01.021
  101. Z. Li, B. Li, S. Peng, D. Li, S. Yang, Y. Fang, Novel visible light-induced g-C3N4 quantum dot/BiPO4 nanocrystal composite photocatalysts for efficient degradation of methyl orange. RSC Adv. 4(66), 35144–35148 (2014). doi:10.1039/c4ra05749j
  102. S. Zhu, Q. Meng, L. Wang, J. Zhang, Y. Song et al., Highly photoluminescent carbon dots for multicolor patterning, sensors, and bioimaging. Angew. Chem. Int. Ed. 52(14), 3953–3957 (2013). doi:10.1002/anie.201300519
  103. J. Tian, Q. Liu, A.M. Asiri, A.O. Al-Youbi, X. Sun, Ultrathin graphitic carbon nitride nanosheet: a highly efficient fluorosensor for rapid, ultrasensitive detection of Cu(2+). Anal. Chem. 85(11), 5595–5599 (2013). doi:10.1021/ac400924j
  104. A. Wang, L. Fu, T. Rao, W. Cai, M.-F. Yuen, J. Zhong, Effect of metal ions on the quenching of photoluminescent CdTe QDs and their recovery. Opt. Mater. 42, 548–552 (2015). doi:10.1016/j.optmat.2015.01.010
  105. S. Zhang, J. Li, M. Zeng, J. Xu, X. Wang, W. Hu, Polymer nanodots of graphitic carbon nitride as effective fluorescent probes for the detection of Fe3+ and Cu2+ ions. Nanoscale 6(8), 4157–4162 (2014). doi:10.1039/C3NR06744K
  106. M. Rong, L. Lin, X. Song, Y. Wang, Y. Zhong, J. Yan, Y. Feng, X. Zeng, X. Chen, Fluorescence sensing of chromium (VI) and ascorbic acid using graphitic carbon nitride nanosheets as a fluorescent switch. Biosens. Bioelectron. 68, 210–217 (2015). doi:10.1016/j.bios.2014.12.024
  107. H. Huang, R. Chen, J. Ma, L. Yan, Y. Zhao, Y. Wang, W. Zhang, J. Fan, X. Chen, Graphitic carbon nitride solid nanofilms for selective and recyclable sensing of Cu2+ and Ag+ in water and serum. Chem. Commun. 50(97), 15415–15418 (2014). doi:10.1039/c4cc06659f
  108. J. Tian, Q. Liu, A.M. Asiri, X. Sun, Y. He, Ultrathin graphitic C3N4 nanofibers: hydrolysis-driven top-down rapid synthesis and application as a novel fluorosensor for rapid, sensitive, and selective detection of Fe3+. Sens. Actuators B 216, 453–460 (2015). doi:10.1016/j.snb.2015.04.075
  109. G. Shiravand, A. Badiei, G.M. Ziarani, Carboxyl-rich g-C3N4 nanoparticles: Synthesis, characterization and their application for selective fluorescence sensing of Hg2+ and Fe3+ in aqueous media. Sens. Actuators B 242, 244–252 (2017). doi:10.1016/j.snb.2016.11.038
  110. S. Barman, M. Sadhukhan, Facile bulk production of highly blue fluorescent graphitic carbon nitride quantum dots and their application as highly selective and sensitive sensors for the detection of mercuric and iodide ions in aqueous media. J. Mater. Chem. 22(41), 21832–21837 (2012). doi:10.1039/C2JM35501A
  111. X.L. Zhang, C. Zheng, S.S. Guo, J. Li, H.H. Yang, G. Chen, Turn-on fluorescence sensor for intracellular imaging of glutathione using g-C(3)N(4) nanosheet-MnO(2) sandwich nanocomposite. Anal. Chem. 86(7), 3426–3434 (2014). doi:10.1021/ac500336f
  112. Y. Xu, X. Niu, H. Zhang, L. Xu, S. Zhao, H. Chen, X. Chen, Switch-on fluorescence sensing of glutathione in food samples based on a graphitic carbon nitride quantum dot (g-CNQD)–Hg2+ chemosensor. J. Agric. Food Chem. 63(6), 1747–1755 (2015). doi:10.1021/jf505759z
  113. J. Han, H.Y. Zou, M.X. Gao, C.Z. Huang, A graphitic carbon nitride based fluorescence resonance energy transfer detection of riboflavin. Talanta 148, 279–284 (2016). doi:10.1016/j.talanta.2015.10.038
  114. Q.-M. Feng, Y.-Z. Shen, M.-X. Li, Z.-L. Zhang, W. Zhao, J.-J. Xu, H.-Y. Chen, Dual-wavelength electrochemiluminescence ratiometry based on resonance energy transfer between Au nanoparticles functionalized g-C3N4 nanosheet and Ru (bpy) 32+ for microRNA detection. Anal. Chem. 88(1), 937–944 (2015). doi:10.1021/acs.analchem.5b03670
  115. Y. Tang, H. Song, Y. Su, Y. Lv, Turn-on persistent luminescence probe based on graphitic carbon nitride for imaging detection of biothiols in biological fluids. Anal. Chem. 85(24), 11876–11884 (2013). doi:10.1021/ac403517u
  116. D. Das, S.L. Shinde, K.K. Nanda, Temperature-dependent photoluminescence of g-C3N4: implication for temperature sensing. ACS Appl. Mater. Interfaces 8(3), 2181–2186 (2016). doi:10.1021/acsami.5b10770
  117. L. Feng, F. He, G. Yang, S. Gai, Y. Dai, C. Li, P. Yang, NIR-driven graphitic-phase carbon nitride nanosheets for efficient bioimaging and photodynamic therapy. J. Mater. Chem. B 4(48), 8000–8008 (2016). doi:10.1039/c6tb02232d
  118. L. Feng, F. He, B. Liu, G. Yang, S. Gai, P. Yang, C. Li, Y. Dai, R. Lv, J. Lin, g-C3N4 coated upconversion nanoparticles for 808 nm near-infrared light triggered phototherapy and multiple imaging. Chem. Mater. 28(21), 7935–7946 (2016). doi:10.1021/acs.chemmater.6b03598
  119. A. Wang, C. Lee, H. Bian, Z. Li, Y. Zhan, J. He, Y. Wang, J. Lu, Y.Y. Li, Synthesis of g-C3N4/silica gels for white-light-emitting devices. Part. Part. Syst. Charact. 34(1), 1600258 (2017). doi:10.1002/ppsc.201600258
  120. S. Bayan, N. Gogurla, A. Midya, S.K. Ray, White light emission characteristics of two dimensional graphitic carbon nitride and ZnO nanorod hybrid heterojunctions. Carbon 108, 335–342 (2016). doi:10.1016/j.carbon.2016.07.032
  121. J. Tian, Q. Liu, A.M. Asiri, K.A. Alamry, X. Sun, Ultrathin graphitic C3N4 nanosheets/graphene composites: efficient organic electrocatalyst for oxygen evolution reaction. Chemsuschem 7(8), 2125–2130 (2014). doi:10.1002/cssc.201402118
  122. J. Tian, R. Ning, Q. Liu, A.M. Asiri, A.O. Al-Youbi, X. Sun, Three-dimensional porous supramolecular architecture from ultrathin g-C(3)N(4) nanosheets and reduced graphene oxide: solution self-assembly construction and application as a highly efficient metal-free electrocatalyst for oxygen reduction reaction. ACS Appl. Mater. Interfaces 6(2), 1011–1017 (2014). doi:10.1021/am404536w
  123. J. Tian, Q. Liu, A.M. Asiri, A.H. Qusti, A.O. Al-Youbi, X. Sun, Ultrathin graphitic carbon nitride nanosheets: a novel peroxidase mimetic, Fe doping-mediated catalytic performance enhancement and application to rapid, highly sensitive optical detection of glucose. Nanoscale 5(23), 11604–11609 (2013). doi:10.1039/c3nr03693f
  124. J. Tian, Q. Liu, C. Ge, Z. Xing, A.M. Asiri, A.O. Al-Youbi, X. Sun, Ultrathin graphitic carbonnitride nanosheets: a low-cost, green, and highly efficient electrocatalyst toward the reduction of hydrogen peroxide and its glucose biosensing application. Nanoscale 5(19), 8921–8924 (2013). doi:10.1039/C3NR02031B
  125. L. Shi, L. Liang, F.X. Wang, J. Ma, J.M. Sun, Polycondensation of guanidine hydrochloride into a graphitic carbon nitride semiconductor with a large surface area as a visible light photocatalyst. Catal. Sci. Technol. 4(9), 3235–3243 (2014). doi:10.1039/C4CY00411F
  126. B.H. Long, J.L. Lin, X.C. Wang, Thermally-induced desulfurization and conversion of guanidine thiocyanate into graphitic carbon nitride catalysts for hydrogen photosynthesis. J. Mater. Chem. A 2(9), 2942–2951 (2014). doi:10.1039/c3ta14339b
  127. S. Yuan, Q. Zhang, B. Xu, S. Liu, J. Wang, J. Xie, M. Zhang, T. Ohno, A new precursor to synthesize g-C3N4 with superior visible light absorption for photocatalytic application. Catal. Sci. Technol. 7(9), 1826–1830 (2017). doi:10.1039/c7cy00213k
  128. J.S. Zhang, F.S. Guo, X.C. Wang, An optimized and general synthetic strategy for fabrication of polymeric carbon nitride nanoarchitectures. Adv. Funct. Mater. 23(23), 3008–3014 (2013). doi:10.1002/adfm.201203287
  129. L. Shi, L. Liang, F.X. Wang, M.S. Liu, K.L. Chen, K.N. Sun, N.Q. Zhang, J.M. Sun, Higher yield urea-derived polymeric graphitic carbon nitride with mesoporous structure and superior visible-light-responsive activity. ACS Sustain. Chem. Eng. 3(12), 3412–3419 (2015). doi:10.1021/acssuschemeng.5b01139
  130. J.H. Sun, J.S. Zhang, M.W. Zhang, M. Antonietti, X.Z. Fu, X.C. Wang, Bioinspired hollow semiconductor nanospheres as photosynthetic nanoparticles. Nat. Commun. 3, 1139 (2012). doi:10.1038/Ncomms2152
  131. H. Yan, Soft-templating synthesis of mesoporous graphitic carbon nitride with enhanced photocatalytic H2 evolution under visible light. Chem. Commun. 48(28), 3430–3432 (2012). doi:10.1039/c2cc00001f
  132. Q.J. Fan, J.J. Liu, Y.C. Yu, S.L. Zuo, A template induced method to synthesize nanoporous graphitic carbon nitride with enhanced photocatalytic activity under visible light. RSC Adv. 4(106), 61877–61883 (2014). doi:10.1039/C4RA12033G
  133. L. Shi, L. Liang, F. Wang, M. Liu, T. Liang, K. Chen, J. Sun, In situ bubble template promoted facile preparation of porous g-C3N4 with excellent visible-light photocatalytic performance. RSC Adv. 5(78), 63264–63270 (2015). doi:10.1039/C5RA09645F
  134. F. He, G. Chen, Y. Yu, Y. Zhou, Y. Zheng, S. Hao, The sulfur-bubble template-mediated synthesis of uniform porous g-C3N4 with superior photocatalytic performance. Chem. Commun. 51(2), 425–427 (2015). doi:10.1039/C4CC07106A
  135. J. Xu, Y. Wang, Y. Zhu, Nanoporous graphitic carbon nitride with enhanced photocatalytic performance. Langmuir 29(33), 10566–10572 (2013). doi:10.1021/la402268u
  136. M. Zhang, J. Xu, R. Zong, Y. Zhu, Enhancement of visible light photocatalytic activities via porous structure of g-C3N4. Appl. Catal. B 147, 229–235 (2014). doi:10.1016/j.apcatb.2013.09.002
  137. H. Xu, J. Yan, Y. Xu, Y. Song, H. Li, J. Xia, C. Huang, H. Wan, Novel visible-light-driven AgX/graphite-like C3N4 (X = Br, I) hybrid materials with synergistic photocatalytic activity. Appl. Catal. B 129, 182–193 (2013). doi:10.1016/j.apcatb.2012.08.015
  138. Y. Li, L. Fang, R. Jin, Y. Yang, X. Fang, Y. Xing, S. Song, Preparation and enhanced visible light photocatalytic activity of novel g-C3N4 nanosheets loaded with Ag2CO3 nanoparticles. Nanoscale 7(2), 758–764 (2015). doi:10.1039/c4nr06565d
  139. S. Zhan, F. Zhou, N. Huang, Y. Yang, Y. Liu, Y. Yin, Y. Fang, g-C3N4/ZnWO4 films: preparation and its enhanced photocatalytic decomposition of phenol in UV. Appl. Surf. Sci. 358, 328–335 (2015). doi:10.1016/j.apsusc.2015.07.180
  140. L. Shi, L. Liang, J. Ma, F. Wang, J. Sun, Enhanced photocatalytic activity over the Ag2O–g-C3N4 composite under visible light. Catal. Sci. Technol. 4(3), 758–765 (2014). doi:10.1039/c3cy00871a
  141. M.J. Muñoz-Batista, O. Fontelles-Carceller, M. Ferrer, M. Fernández-García, A. Kubacka, Disinfection capability of Ag/g-C3N4 composite photocatalysts under UV and visible light illumination. Appl. Catal. B 183, 86–95 (2016). doi:10.1016/j.apcatb.2015.10.024
  142. L. Shi, L. Liang, J. Ma, F. Wang, J. Sun, Remarkably enhanced photocatalytic activity of ordered mesoporous carbon/gC3N4 composite photocatalysts under visible light. Dalton Trans. 43(19), 7236–7244 (2014). doi:10.1039/C4DT00087K
  143. P. Gibot, F. Schnell, D. Spitzer, Enhancement of the graphitic carbon nitride surface properties from calcium salts as templates. Micropor. Mesopor. Mater. 219, 42–47 (2016). doi:10.1016/j.micromeso.2015.07.026
  144. X. Gao, X. Jiao, L. Zhang, W. Zhu, X. Xu, H. Ma, T. Chen, Cosolvent-free nanocasting synthesis of ordered mesoporous g-C3N4 and its remarkable photocatalytic activity for methyl orange degradation. RSC Adv. 5(94), 76963–76972 (2015). doi:10.1039/C5RA13438B
  145. J. Wen, J. Xie, X. Chen, X. Li, A review on g-C3N4-based photocatalysts. Appl. Surf. Sci. 391, 72–123 (2017). doi:10.1016/j.apsusc.2016.07.030
  146. K. Vignesh, S. Kang, B.S. Kwak, M. Kang, Meso-porous ZnO nano-triangles@ graphitic-C3N4 nano-foils: fabrication and Recyclable photocatalytic activity. Sep. Purif. Technol. 147, 257–265 (2015). doi:10.1016/j.seppur.2015.04.043
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