Issue

Vol. 9 No. 2 (2017)

Carbon-Based Flexible and All-Solid-State Micro-supercapacitors Fabricated by Inkjet Printing with Enhanced Performance

https://doi.org/10.1007/s40820-016-0119-z
Zhibin Pei
Anhui Key Laboratory of Nanomaterials and Technology, Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People’s Republic of China
Haibo Hu
Anhui Key Laboratory of Nanomaterials and Technology, Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People’s Republic of China
Guojin Liang
Anhui Key Laboratory of Nanomaterials and Technology, Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People’s Republic of China
Changhui Ye
Anhui Key Laboratory of Nanomaterials and Technology, Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People’s Republic of China

Corresponding Author: Changhui Ye

chye@issp.ac.cn

Nano-Micro Letters, Vol. 9 No. 2 (2017), Article Number: 19

Abstract

By means of inkjet printing technique, flexible and all-solid-state micro-supercapacitors (MSCs) were fabricated with carbon-based hybrid ink composed of graphene oxide (GO, 98.0 vol.%) ink and commercial pen ink (2.0 vol.%). A small amount of commercial pen ink was added to effectively reduce the agglomeration of the GO sheets during solvent evaporation and the following reduction processes in which the presence of graphite carbon nanoparticles served as nano-spacer to separate GO sheets. The printed device fabricated using the hybrid ink, combined with the binder-free microelectrodes and interdigital microelectrode configuration, exhibits nearly 780% enhancement in areal capacitance compared with that of pure GO ink. It also shows excellent flexibility and cycling stability with nearly 100% retention of the areal capacitance after 10,000 cycles. The all-solid-state device can be optionally connected in series or in parallel to meet the voltage and capacity requirements for a given application. This work demonstrates a promising future of the carbon-based hybrid ink for directly large-scale inkjet printing MSCs for disposable energy storage devices.


Highlights:


1 Flexible and all-solid-state micro-supercapacitors (MSCs) were fabricated by inkjet printing using carbon-based hybrid ink composed of graphene oxide (GO) and commercial pen ink.
2 The as-obtained MSCs based on hybrid ink exhibit great enhancement in areal capacitance, flexibility and cycling stability compared with that of pure GO ink.
3 This work provides a promising strategy for large-scale preparation of low-cost, lightweight, and flexible/wearable energy storage devices with carbon-based hybrid ink.

Keywords

Inkjet printing Flexible devices Graphene oxide (GO) Carbon-based ink Micro-supercapacitors
Pei, Zhibin, Haibo Hu, Guojin Liang, and Changhui Ye. 2016. “Carbon-Based Flexible and All-Solid-State Micro-Supercapacitors Fabricated by Inkjet Printing With Enhanced Performance”. Nano-Micro Letters 9 (2):19. https://doi.org/10.1007/s40820-016-0119-z.
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. Z. Wang, W. Wu, Nanotechnology-enabled energy harvesting for self-powered micro-/nanosystems. Angew. Chem. Int. Ed. 51(47), 11700–11721 (2012). doi:10.1002/anie.201201656
  2. Z. Wang, Self-powered nanosensors and nanosystems. Adv. Mater. 24(2), 280–285 (2012). doi:10.1002/adma.201102958
  3. Z. Wang, Toward self-powered sensor networks. Nano Today 5(6), 512–514 (2010). doi:10.1016/j.nantod.2010.09.001
  4. Z. Qi, A. Younis, D. Chu, S. Li, A facile and template-free one pot synthesis of Mn3O4 nanostructures as electrochemical supercapacitors. Nano–Micro Lett. 8(2), 165–173 (2016). doi:10.1007/s40820-015-0074-0
  5. H. Hu, Z. Pei, C. Ye, Recent advances in designing and fabrication of planar micro-supercapacitors for on-chip energy storage. Energy Storage Mater. 1, 82–102 (2015). doi:10.1016/j.ensm.2015.08.005
  6. J. Chmiola, C. Largeot, P.L. Taberna, P. Simon, Y. Gogotsi, Monolithic carbide-derived carbon films for micro-supercapacitors. Science 328(5977), 480–483 (2010). doi:10.1126/science.1184126
  7. D. Pech, M. Brunet, H. Durou, P. Huang, V. Mochalin, Y. Gogotsi, P.L. Taberna, P. Simon, Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon. Nat. Nanotechnol. 5(9), 651–654 (2010). doi:10.1038/nnano.2010.162
  8. K. Wang, W. Zou, B. Quan, A. Yu, H. Wu, P. Jiang, Z. Wei, An all-solid-state flexible micro-supercapacitor on a chip. Adv. Energy Mater. 1(6), 1068–1072 (2011). doi:10.1002/aenm.201100488
  9. J. Tao, W. Ma, N. Liu, X. Ren, Y. Shi, J. Su, Y. Gao, High performance solid-state supercapacitors fabricated by pencil drawing and polypyrrole depositing on paper substrate. Nano–Micro Lett. 7(3), 276–281 (2015). doi:10.1007/s40820-015-0039-3
  10. W. Si, C. Yan, Y. Chen, S. Oswald, L. Han, O. Schmidt, On chip, all solid-state and flexible micro-supercapacitors with high performance based on MnOx/Au multilayers. Energy Environ. Sci. 6(11), 3218–3223 (2013). doi:10.1039/c3ee41286e
  11. H. Hu, K. Zhang, S. Li, S. Ji, C. Ye, Flexible, in-plane, and all-solid-state micro-supercapacitors based on printed interdigital Au/polyaniline network hybrid electrodes on a chip. J. Mater. Chem. A 2(48), 20916–20922 (2014). doi:10.1039/C4TA05345A
  12. Y. Sun, Y. Cheng, K. He, A. Zhou, H. Duan, One-step synthesis of three-dimensional porous ionic liquid-carbon nanotube–graphene gel and MnO2–graphene gel as freestanding electrodes for asymmetric supercapacitors. RSC Adv. 5, 10178–10186 (2015). doi:10.1039/C4RA16071A
  13. Y. Sun, Z. Fang, C. Wang, K. Ariyawansha, A. Zhou, H. Duan, Sandwich-structured nanohybrid paper based on controllable growth of nanostructured MnO2 on ionic liquid functionalized graphene paper as a flexible supercapacitor electrode. Nanoscale 7, 7790–7801 (2015). doi:10.1039/C5NR00946D
  14. F. Xiao, S. Yang, Z. Zhang, H. Liu, J. Xiao, L. Wan, J. Luo, S. Wang, Y. Liu, Scalable synthesis of freestanding sandwich-structured graphene/polyaniline/graphene nanocomposite paper for flexible all-solid-state supercapacitor. Sci. Rep. 5, 9359 (2015). doi:10.1038/srep09359
  15. K. Chi, Z. Zhang, J. Xi, Y. Huang, F. Xiao, S. Wang, Y. Liu, Freestanding graphene paper supported three-dimensional porous graphene–polyaniline nanocomposite synthesized by inkjet printing and in flexible all-solid-state supercapacitor. ACS Appl. Mater. Interfaces 6, 16312–16319 (2014). doi:10.1021/am504539k
  16. Z. Zhang, F. Xiao, L. Qian, J. Xiao, S. Wang, Y. Liu, Facile synthesis of 3D MnO2–graphene and carbon nanotube–graphene composite networks for high-performance, flexible, all-solid-state asymmetric supercapacitors. Adv. Energy Mater. 4, 1400064 (2014). doi:10.1002/aenm.201400064
  17. X. Lang, A. Hirata, T. Fujita, M. Chen, Nanoporous metal/oxide hybrid electrodes for electrochemical supercapacitors. Nat. Nanotechnol. 6(4), 232–236 (2011). doi:10.1038/nnano.2011.13
  18. L. Yuan, B. Yao, B. Hu, K. Huo, W. Chen, J. Zhou, Polypyrrole-coated paper for flexible solid-state energy storage. Energy Environ. Sci. 6(2), 470–476 (2013). doi:10.1039/c2ee23977a
  19. Y. He, W. Chen, X. Li, Z. Zhang, J. Fu, C. Zhao, E. Xie, Freestanding three-dimensional graphene/MnO2 composite networks as ultra light and flexible supercapacitor electrodes. ACS Nano 7(1), 174–182 (2013). doi:10.1021/nn304833s
  20. L. Yuan, X. Xiao, T. Ding, J. Zhong, X. Zhang, Y. Shen, B. Hu, Y. Huang, J. Zhou, Z. Wang, Paper-based supercapacitors for self-powered nanosystems. Angew. Chem. Int. Ed. 51(20), 4934–4938 (2012). doi:10.1002/anie.201109142
  21. F. Meng, Y. Ding, Sub-micrometer-thick all-solid-state supercapacitors with high power and energy densities. Adv. Mater. 23(35), 4098–4102 (2011). doi:10.1002/adma.201101678
  22. Z. Weng, Y. Su, D. Wang, F. Li, J. Du, H. Cheng, Graphene-cellulose paper flexible supercapacitors. Adv. Energy Mater. 1(5), 917–922 (2011). doi:10.1002/aenm.201100312
  23. K. Zhang, H. Hu, W. Yao, C. Ye, Flexible and all-solid-state supercapacitors with long-time stability constructed on PET/Au/polyaniline hybrid electrodes. J. Mater. Chem. A 3(2), 617–623 (2015). doi:10.1039/C4TA05605A
  24. M. Beidaghi, C. Wang, Micro-supercapacitors based on interdigital electrodes of reduced graphene oxide and carbon nanotube composites with ultrahigh power handling performance. Adv. Funct. Mater. 22(21), 4501–4510 (2012). doi:10.1002/adfm.201201292
  25. Z. Niu, L. Zhang, L. Liu, B. Zhu, H. Dong, X. Chen, All-solid-state flexible ultrathin micro-supercapacitors based on graphene. Adv. Mater. 25(29), 4035–4042 (2013). doi:10.1002/adma.201301332
  26. M. El-Kady, R. Kaner, Scalable fabrication of high-power graphene micro-supercapacitors for flexible and on-chip energy storage. Nat. Commun. 4, 1475–1482 (2013). doi:10.1038/ncomms2446
  27. T. Dinh, K. Armstrong, D. Guay, D. Pech, High-resolution on-chip supercapacitors with ultra-high scan rate ability. J. Mater. Chem. A 2(20), 7170–7174 (2014). doi:10.1039/c4ta00640b
  28. M. Laurenti, D. Perrone, A. Verna, C.F. Pirri, A. Chiolerio, Development of a flexible lead-free piezoelectric transducer for health monitoring in the space environment. Micromachines 6, 1729–1744 (2015). doi:10.3390/mi6111453
  29. J. Lin, C. Zhang, Z. Yan, Y. Zhu, Z. Peng, R. Hauge, D. Natelson, J. Tour, 3-Dimensional graphene carbon nanotube carpet-based microsupercapacitors with high electrochemical performance. Nano Lett. 13(1), 72–78 (2013). doi:10.1021/nl3034976
  30. Z. Wu, K. Parvez, A. Winter, H. Vieker, X. Liu, S. Han, A. Turchanin, X. Feng, K. Müllen, Layer-by-layer assembled heteroatom-doped graphene films with ultrahigh volumetric capacitance and rate capability for micro-supercapacitors. Adv. Mater. 26(26), 4552–4558 (2014). doi:10.1002/adma.201401228
  31. Z. Wu, K. Parvez, S. Li, S. Yang, Z. Liu, S. Liu, X. Feng, K. Müllen, Alternating stacked graphene-conducting polymer compact films with ultrahigh areal and volumetric capacitances for high-energy micro-supercapacitors. Adv. Mater. 27(27), 4054–4061 (2015). doi:10.1002/adma.201501643
  32. Y. Wang, Y. Shi, C. Zhao, J. Wong, X. Sun, H. Yang, Printed all-solid flexible microsupercapacitors: towards the general route for high energy storage devices. Nanotechnology 25(9), 094010 (2014). doi:10.1088/0957-4484/25/9/094010
  33. S. Kim, H. Koo, A. Lee, P. Braun, Selective wetting-induced micro-electrode patterning for flexible micro-supercapacitors. Adv. Mater. 26(30), 5108–5112 (2014). doi:10.1002/adma.201401525
  34. M. Xue, Z. Xie, L. Zhang, X. Ma, X. Wu, Y. Guo, W. Song, Z. Li, T. Cao, Microfluidic etching for fabrication of flexible and all-solid-state micro supercapacitor based on MnO2 nanoparticles. Nanoscale 3(7), 2703–2708 (2011). doi:10.1039/c0nr00990c
  35. W. Gao, N. Singh, L. Song, Z. Liu, A. Reddy et al., Direct laser writing of micro-supercapacitors on hydrated graphite oxide films. Nat. Nanotechnol. 6(8), 496–500 (2011). doi:10.1038/nnano.2011.110
  36. B. Hsia, J. Marschewski, S. Wang, J. In, C. Carraro, D. Poulikakos, C. Grigoropoulos, R. Maboudian, Highly flexible, all solid-state micro-supercapacitors from vertically aligned carbon nanotubes. Nanotechnology 25(5), 055401 (2014). doi:10.1088/0957-4484/25/5/055401
  37. D. Pech, M. Brunet, P. Taberna, P. Simon, N. Fabre, F. Mesnilgrente, V. Conédéra, H. Durou, Elaboration of a microstructured inkjet-printed carbon electrochemical capacitor. J. Power Sources 195(4), 1266–1269 (2010). doi:10.1016/j.jpowsour.2009.08.085
  38. J. Li, F. Ye, S. Vaziri, M. Muhammed, M. Lemme, M. Östling, Efficient inkjet printing of graphene. Adv. Mater. 25(29), 3985–3992 (2013). doi:10.1002/adma.201300361
  39. A. Kamyshny, S. Magdassi, Conductive nanomaterials for printed electronics. Small 10(17), 3515–3535 (2014). doi:10.1002/smll.201303000
  40. M. Singh, H. Haverinen, P. Dhagat, G. Jabbour, Inkjet printing-process and its applications. Adv. Mater. 22(6), 673–685 (2010). doi:10.1002/adma.200901141
  41. B. de Gans, P. Duineveld, U. Schubert, Inkjet printing of polymers: state of the art and future developments. Adv. Mater. 16(3), 203–213 (2004). doi:10.1002/adma.200300385
  42. T. van Osch, J. Perelaer, A. de Laat, U. Schubert, Inkjet printing of narrow conductive tracks on untreated polymeric substrates. Adv. Mater. 20(2), 343–345 (2008). doi:10.1002/adma.200701876
  43. T. Wei, J. Ruan, Z. Fan, G. Luo, F. Wei, Preparation of a carbon nanotube film by ink-jet printing. Carbon 45(13), 2712–2716 (2007). doi:10.1016/j.carbon.2007.08.009
  44. W. Small, M. Panhuis, Inkjet printing of transparent, electrically conducting single-walled carbon-nanotube composites. Small 3(9), 1500–1503 (2007). doi:10.1002/smll.200700110
  45. V. Dua, S. Surwade, S. Ammu, S. Agnihotra, S. Jain et al., All-organic vapor sensor using inkjet-printed reduced graphene oxide. Angew. Chem. Int. Ed. 49(12), 2154–2157 (2010). doi:10.1002/anie.200905089
  46. F. Torrisi, T. Hasan, W. Wu, Z. Sun, A. Lombardo et al., Inkjet-printed graphene electronics. ACS Nano 6(4), 2992–3006 (2012). doi:10.1021/nn2044609
  47. Y. Xu, I. Hennig, D. Freyberg, A. Strudwick, M. Schwab, T. Weitz, K. Cha, Inkjet-printed energy storage device using graphene/polyaniline inks. J. Power Sources 248, 483–488 (2014). doi:10.1016/j.jpowsour.2013.09.096
  48. L. Huang, Y. Huang, J. Liang, X. Wan, Y. Chen, Graphene-based conducting inks for direct inkjet printing of flexible conductive patterns and their applications in electric circuits and chemical sensors. Nano Res. 4(7), 675–684 (2011). doi:10.1007/s12274-011-0123-z
  49. L. Le, M. Ervin, H. Qiu, B. Fuchs, W. Lee, Graphene supercapacitor electrodes fabricated by inkjet printing and thermal reduction of graphene oxide. Electrochem. Commun. 13(4), 355–358 (2011). doi:10.1016/j.elecom.2011.01.023
  50. X. Huang, X. Qi, F. Boey, H. Zhang, Graphene-based composites. Chem. Soc. Rev. 41(2), 666–686 (2012). doi:10.1039/C1CS15078B
  51. Y. Zhu, S. Murali, W. Cai, X. Li, J. Suk, J. Potts, R. Ruoff, Graphene and graphene oxide: synthesis, properties, and applications. Adv. Mater. 22(35), 3906–3924 (2010). doi:10.1002/adma.201001068
  52. R. Giardi, S. Porro, A. Chiolerio, E. Celasco, M. Sangermano, Inkjet printed acrylic formulations based on UV-reduced graphene oxide nanocomposites. J. Mater. Sci. 48, 1249–1255 (2013). doi:10.1007/s10853-012-6866-4
  53. W. Hummers, R. Offeman, Preparation of graphitic oxide. J. Am. Chem. Soc. 80(6), 1339 (1958). doi:10.1021/ja01539a017
  54. S. Magdassi, M. Ben Moshe, Patterning of organic nanoparticles by ink-jet printing of microemulsions. Langmuir 19(3), 939–942 (2003). doi:10.1021/la026439h
  55. D. Li, M. Muller, S. Gilje, R. Kaner, G. Wallace, Processable aqueous dispersions of graphene nanosheets. Nat. Nanotechnol. 3(2), 101–105 (2008). doi:10.1038/nnano.2007.451
  56. P. Simon, Y. Gogotsi, Materials for electrochemical capacitors. Nat. Mater. 7(11), 845–854 (2008). doi:10.1038/nmat2297
  57. H. Jung, M. Karimi, M. Hahm, P. Ajayan, Y. Jung, Transparent, flexible supercapacitors from nano-engineered carbon films. Sci. Rep. 2, 773–778 (2012). doi:10.1038/srep00773
  58. T. Qian, J. Zhou, N. Xu, T. Yang, X. Shen, X. Liu, S. Wu, C. Yan, On-chip supercapacitors with ultrahigh volumetric performance based on electrochemically co-deposited CuO/polypyrrole nanosheet arrays. Nanotechnology 26, 425402 (2015). doi:10.1088/0957-4484/26/42/425402
  59. W. Yang, Z. Gao, J. Ma, X. Zhang, J. Wang, J.Y. Liu, Hierarchical NiCo2O4@NiO core–shell heterostructured nanowire arrays on carbon cloth for a high-performance flexible all-solid-state electrochemical capacitor. J. Mater. Chem. A 2, 1448–1457 (2014). doi:10.1039/C3TA14488G
  60. T. Qian, N. Xu, J. Zhou, T. Yang, X. Liu, X. Shen, J. Liang, C. Yan, Interconnected three-dimensional V2O5/polypyrrole network nanostructures for high performance solid-state supercapacitors. J. Mater. Chem. A 3, 488–493 (2015). doi:10.1039/C4TA05769D
Read More
Author biographies are not available.
Statistic
Read Counter : 4964 Download : 3759