Surface Texturing of TiO2 Film by Mist Deposition of TiO2 Nanoparticles
Corresponding Author: Akira Watanabe
Nano-Micro Letters,
Vol. 5 No. 2 (2013), Article Number: 129-134
Abstract
Unique and various microstructures of titanium oxide (TiO2) film including macroporous structure, chromatic veins and rings, have been easily fabricated by mist deposition method on silicon substrate with mild preparation conditions. Rutile phase TiO2 nanoparticles were directly used as starting material to prepare film and led to a simple preparation process. It was found that several different microstructures existed in the sample and changed with the varied positions from the center to the edge of the film when the concentration of the TiO2 suspension is 0.06 mol/l, the deposition time is 30 min, the flow rate is 1 l/min and the temperature is 150°C. The surface texturing shows apparent distinction as the concentration of the TiO2 suspension decreased to 0.03 mol/l and 0.01 mol/l.
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- C. P. Kang, Z. X. Zhang, Y. Z. Zhang, Y. M. He, Xie and E. Q. Xie, “Enhanced efficiency in dye-sensitised solar cells using a TiO2-based sandwiched film as photoanode”, Micro Nano Lett. 6(8), 579–581 (2011). http://dx.doi.org/10.1049/mnl.2011.0225
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References
C. P. Kang, Z. X. Zhang, Y. Z. Zhang, Y. M. He, Xie and E. Q. Xie, “Enhanced efficiency in dye-sensitised solar cells using a TiO2-based sandwiched film as photoanode”, Micro Nano Lett. 6(8), 579–581 (2011). http://dx.doi.org/10.1049/mnl.2011.0225
M. A. Ponce, R. Parra, R. Savu, E. Joanni, P. R. Bueno, M. Cilense, J. A. Varela and M. S. Castro, “Impedance spectroscopy analysis of TiO2 thin film gas sensors obtained from water-based anatase colloids”, Sensor Actuat. B: Chem. 139(2), 447–452 (2009). http://dx.doi.org/10.1016/j.snb.2009.03.066
W. X. Que, Z. Sun, Y. Zhou, Y. L. Lam, S. D. Cheng, Y. C. Chan and C. H. Kam, Mater. Lett. 42, 326 (2000). http://dx.doi.org/10.1016/S0167-577X(99)00207-4
W. Y. Zhao, W. Y. Fu, H. B. Yang, C. J. Tian, M. H. Li, J. Ding, W. Zhang, X. M. Zhou, H. Zhao and Y. X. Li, “Synthesis and photocatalytic activity of Fedoped TiO2 supported on hollow glass microbeads”, Nano-Micro Lett. 3(1), 20–24 (2011). http://dx.doi.org/10.3786/nml.v3i1.p20-24
L. Wan, M. C. Long, D. Y. Zhou, L. Y. Zhang and W. M. Cai, “Preparation and characterization of free-standing hierarchical porous TiO2 monolith modified with graphene oxide”, Nano-Micro Lett. 4(2), 90–97 (2012). http://dx.doi.org/10.3786/nml.v4i2.p90-97
H. Li, Y. Zhou, C. X. Lv and M. M. Dang, “Templated synthesis of ordered porous TiO2 films and their application in dye-sensitized solar cell”, Mater. Lett. 65(12), 1808–1810 (2011). http://dx.doi.org/10.1016/j.matlet.2011.03.044
A. B. Dros, D. Grosso, C. Boissière, G. J. A. A. Soler-Illia, P. A. Albouy, H. Amenitsch and C. Sanchez, “Niobia-stabilised anatase TiO2 highly porous mesostructured thin films”, Micropor. Mesopor. Mater. 94(1–3), 208–213 (2006). http://dx.doi.org/10.1016/j.micromeso.2006.03.034
G. Q. Li, Z. G. Jin, X. X. Liu, T. Wang and Z. F. Liu, “Anatase TiO2 porous thin films prepared by solgel method using CTAB surfactant”, J. Sol-Gel Sci. Techn. 41(1), 49–55 (2007). http://link.springer.com/article/10.1007/s10971-006-0122-9
Z. Lan, J. H. Wu, J. M. Lin and M. L. Huang, “PF127 aided preparation of super-porous TiO2 film used in highly efficient quasi-solid-state dyesensitized solar cell”, J. Mater. Sci. Mater. Electron. 21(10), 1000–1004 (2012). http://dx.doi.org/10.1007/s10854-010-0083-1
J. C. Yu, J. G. Yu and J. C. Zhao, “Enhanced photocatalytic activity of mesoporous and ordinary TiO2 thin films by sulfuric acid treatment”, Appl. Catal. B: Environmental 36(1), 31–43 (2002). http://dx.doi.org/10.1016/S0926-3373(01)00277-6
O. Sugiyama, M. Okuya and S. Kaneko, “Photocatalytic ability of TiO2 porous film prepared by modified spray pyrolysis deposition technique”, J. Ceram. Soc. Jpn. 117, 203–207 (2009). http://dx.doi.org/10.2109/jcersj2.117.203
J. Ryu, B. D. Hahn, J. J. Choi, W. H. Yoon, B. K. Lee, J. H. Choi and D. S. Park, “Porous photocatalytic TiO2thin films by aerosol deposition”, J. Am. Ceram. Soc. 93(1), 55–58 (2010). http://dx.doi.org/10.1111/j.1551-2916.2009.03391.x
S. Karuppuchamy, K. Nonomura, T. Yoshida, T. Sugiura and H. Minoura, “Cathodic electrodeposition of oxide semiconductor thin films and their application to dye-sensitized solar cells”, Solid State Ionics 151(1–4), 19–27 (2002). http://dx.doi.org/10.1016/S0167-2738(02)00599-4
J. G. Lu, T. Kawaharamura, H. Nishinaka, Y. Kamada, T. Ohshima and S. Fujita, “ZnO-based thin films synthesized by atmospheric pressure mist chemical vapor deposition”, J. Cryst. Growth 299(1), 1–10 (2007). http://dx.doi.org/10.1016/j.jcrysgro.2006.10.251
P. Singh, A. Kumar, Deepak and D. Kaur, “ZnO nanocrystalline powder synthesized by ultrasonic mistchemical vapour deposition”, Opt. Mater. 30(8), 1316–1322 (2008). http://dx.doi.org/10.1016/j.optmat.2007.06.012
A. Naumenko, I. Gnatiuk, N. Smirnova and A. Eremenko, “Characterization of sol-gel derived TiO2/ZrO2 films and powders by Raman spectroscopy”, Thin Solid Films, 520(14), 4541–4546 (2005). http://dx.doi.org/10.1016/j.tsf.2011.10.189
W. Thongsuwan, T. Kumpika and P. Singjai, “Effect of high roughness on a long aging time of superhydrophilic TiO2 nanoparticle thin films”, Curr. Appl. Phys. 11(5), 1237–1242 (2011). http://dx.doi.org/10.1016/j.cap.2011.03.002