Issue

Vol. 17 (2025)

Prussian Blue Analogue-Templated Nanocomposites for Alkali-Ion Batteries: Progress and Perspective

https://doi.org/10.1007/s40820-024-01517-y
Jian‑En Zhou
Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, School of Chemistry, South China Normal University, Guangzhou 510006, People’s Republic of China
Yilin Li
Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, School of Chemistry, South China Normal University, Guangzhou 510006, People’s Republic of China
Xiaoming Lin
Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, School of Chemistry, South China Normal University, Guangzhou 510006, People’s Republic of China
Jiaye Ye
School of Chemistry and Physics, Faculty of Science, Queensland University of Technology, 2 George Street, Brisbane, QLD 4000, Australia

Corresponding Author: Jiaye Ye

jiaye.ye@qut.edu.au

Nano-Micro Letters, Vol. 17 (2025), Article Number: 9

Abstract

Lithium-ion batteries (LIBs) have dominated the portable electronic and electrochemical energy markets since their commercialisation, whose high cost and lithium scarcity have prompted the development of other alkali-ion batteries (AIBs) including sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs). Owing to larger ion sizes of Na+ and K+ compared with Li+, nanocomposites with excellent crystallinity orientation and well-developed porosity show unprecedented potential for advanced lithium/sodium/potassium storage. With enticing open rigid framework structures, Prussian blue analogues (PBAs) remain promising self-sacrificial templates for the preparation of various nanocomposites, whose appeal originates from the well-retained porous structures and exceptional electrochemical activities after thermal decomposition. This review focuses on the recent progress of PBA-derived nanocomposites from their fabrication, lithium/sodium/potassium storage mechanism, and applications in AIBs (LIBs, SIBs, and PIBs). To distinguish various PBA derivatives, the working mechanism and applications of PBA-templated metal oxides, metal chalcogenides, metal phosphides, and other nanocomposites are systematically evaluated, facilitating the establishment of a structure–activity correlation for these materials. Based on the fruitful achievements of PBA-derived nanocomposites, perspectives for their future development are envisioned, aiming to narrow down the gap between laboratory study and industrial reality.


Highlights:
1 The synthetic protocols of various Prussian blue analogue (PBA)-templated nanocomposites are discussed.
2 Alkali-ion storage mechanisms based on intercalation, alloying, or conversion reactions are analysed.
3 The properties of PBA-templated nanocomposites in alkali-ion batteries (AIBs) are evaluated and compared to outline the structure–activity correlation.
4 Perspectives for the future development of PBA-templated AIB electrodes are envisaged.

Keywords

Prussian blue analogues Self-sacrificial template Lithium-ion batteries Sodium-ion batteries Potassium-ion batteries
Zhou, Jian‑En, Yilin Li, Xiaoming Lin, and Jiaye Ye. 2024. “Prussian Blue Analogue-Templated Nanocomposites for Alkali-Ion Batteries: Progress and Perspective”. Nano-Micro Letters 17 (September):9. https://doi.org/10.1007/s40820-024-01517-y.
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