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Vol. 12 (2020)

Wire-Shaped 3D-Hybrid Supercapacitors as Substitutes for Batteries

https://doi.org/10.1007/s40820-019-0356-z
Kyeong‑Nam Kang
School of Energy and Chemical Engineering, Low Dimensional Carbon Materials Center, Ulsan National Institute of Science and Technology, Ulsan 44919, Republic of Korea
Ananthakumar Ramadoss
Laboratory for Advanced Research in Polymeric Materials, Central Institute of Plastic Engineering and Technology, Bhubaneswar 751024, India
Jin‑Wook Min
School of Energy and Chemical Engineering, Low Dimensional Carbon Materials Center, Ulsan National Institute of Science and Technology, Ulsan 44919, Republic of Korea
Jong‑Chul Yoon
School of Energy and Chemical Engineering, Low Dimensional Carbon Materials Center, Ulsan National Institute of Science and Technology, Ulsan 44919, Republic of Korea
Deokjung Lee
School of Mechanical, Aerospace and Nuclear Engineering, Ulsan National Institute of Science and Technology, Ulsan 44919, Republic of Korea
Seok Ju Kang
School of Energy and Chemical Engineering, Low Dimensional Carbon Materials Center, Ulsan National Institute of Science and Technology, Ulsan 44919, Republic of Korea
Ji‑Hyun Jang
School of Energy and Chemical Engineering, Low Dimensional Carbon Materials Center, Ulsan National Institute of Science and Technology, Ulsan 44919, Republic of Korea

Corresponding Author: Ji‑Hyun Jang

clau@unist.ac.kr

Nano-Micro Letters, Vol. 12 (2020), Article Number: 28

Abstract

We report a wire-shaped three-dimensional (3D)-hybrid supercapacitor with high volumetric capacitance and high energy density due to an interconnected 3D-configuration of the electrode allowing for large number of electrochemical active sites, easy access of electrolyte ions, and facile charge transport for flexible wearable applications. The interconnected and compact electrode delivers a high volumetric capacitance (gravimetric capacitance) of 73 F cm−3 (2446 F g−1), excellent rate capability, and cycle stability. The 3D-nickel cobalt-layered double hydroxide onto 3D-nickel wire (NiCo LDH/3D-Ni)//the 3D-manganese oxide onto 3D-nickel wire (Mn3O4/3D-Ni) hybrid supercapacitor exhibits energy density of 153.3 Wh kg−1 and power density of 8810 W kg−1. The red light-emitting diode powered by the as-prepared hybrid supercapacitor can operate for 80 min after being charged for tens of seconds and exhibit excellent electrochemical stability under various deformation conditions. The results verify that such wire-shaped 3D-hybrid supercapacitors are promising alternatives for batteries with long charge–discharge times, for smart wearable and implantable devices.


Highlights:


1 The flexible 3D porous structure with a large surface area provides pathways for rapid ion/electron transport and ion diffusion as well as numerous electroactive sites.
2 The wire-shaped supercapacitor exhibits a high energy density of 153.3 Wh kg−1 and a power density of 8810 W kg−1.
3 The hybrid device demonstrates excellent durability under various mechanical deformations.

Keywords

Three-dimensional (3D) metal current collector Flexible hybrid supercapacitor Wire-shaped supercapacitor High energy density device Fast charging energy storage system
Kang, Kyeong‑Nam, Ananthakumar Ramadoss, Jin‑Wook Min, Jong‑Chul Yoon, Deokjung Lee, Seok Ju Kang, and Ji‑Hyun Jang. 2020. “Wire-Shaped 3D-Hybrid Supercapacitors As Substitutes for Batteries”. Nano-Micro Letters 12 (January):28. https://doi.org/10.1007/s40820-019-0356-z.
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