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Vol. 6 No. 3 (2014)

Preparation of Palladium Supported on Ferric Oxide Nano-catalysts for Carbon Monoxide Oxidation in Low Temperature

https://doi.org/10.1007/BF03353787
Fagen Wang
National Engineering Research Center for Nanotechnology, Shanghai 200241, China
Yan Xu
National Engineering Research Center for Nanotechnology, Shanghai 200241, China
Kunfeng Zhao
National Engineering Research Center for Nanotechnology, Shanghai 200241, China
Dannong He
National Engineering Research Center for Nanotechnology, Shanghai 200241, China

Corresponding Author: Dannong He

hdnbill@sh163.net

Nano-Micro Letters, Vol. 6 No. 3 (2014), Article Number: 233-241

Abstract

Catalytic property of Pd/Fe2O3 catalysts on carbon monoxide (CO) oxidation at low temperature were investigated in this paper. Both the as-prepared and H2-pretreated Pd/Fe2O3 catalysts show catalytic performances on CO oxidation. The CO was completely converted at 333 K for the as-prepared sample, whereas at 313 K for H2-pretreated Pd/Fe2O3-573 catalyst. The catalytic performance of the Pd/Fe2O3 catalyst decreases with increased calcination temperature. This may be due to the increased crystallinity of the support and decreased metal-support interaction. Progressive deactivation of the catalysts during long-time reaction was associated with the formation of carbonates on the catalyst surface that inhibits CO activation or intermediate transformation.

Keywords

Pd/Fe2O3 Carbon monoxide Catalytic oxidation Low temperature
Wang, Fagen, Yan Xu, Kunfeng Zhao, and Dannong He. 2014. “Preparation of Palladium Supported on Ferric Oxide Nano-Catalysts for Carbon Monoxide Oxidation in Low Temperature”. Nano-Micro Letters 6 (3):233-41. https://doi.org/10.1007/BF03353787.
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References
  1. K. N. Rao, P. Bharali, G. Thrimurthulu and B. M. Reddy, “Supported Copper-ceria catalysts for low temperature CO oxidation”, Catal. Commun. 11(10), 863–866 (2010). http://dx.doi.org/10.1016/j.catcom.2010.03.009
  2. D. Gamarra, C. Belver, M. Garcia, and A. Arias, “Selective CO oxidation in excess H2 over copper-ceria catalysts: identification of active entities/species”, J. Am. Chem. Soc. 129(40), 12064–12065 (2007). http://dx.doi.org/10.1021/ja073926g
  3. W. Xie, Y. Li, Z. Liu, M. Haruta and W. Shen, “Lowtemperature oxidation of CO catalysed by Co3O4 nanorods”, Nature 458(7239), 746–749 (2009). http://dx.doi.org/10.1038/nature07877
  4. K. Zhao, B. Qiao, J. Wang, Y. Zhang and T. Zhang, “A highly active and sintering-resistant Au/FeOx− hydroxyapatite catalyst for CO oxidation”, Chem. Commun., 47(6), 1779–1781 (2011). http://dx.doi.org/10.1039/C0CC04171H
  5. S. Li, G. Liu, H. Lian, M. Jia, G. Zhao, D. Jiang and W. Zhang, “Low-temperature CO oxidation over supported Pt catalysts prepared by colloid-deposition method”, Catal. Commun. 9(6), 1045–1049 (2008). http://dx.doi.org/10.1016/j.catcom.2007.10.016
  6. A. Satsuma, K. Osaki, M. Yanagihara, J. Ohyama and K. Shimizu, “Activity controlling factors for low-temperature oxidation of CO over supported Pd catalysts”, Appl. Catal. B: Environ. 132–133, 511–518 (2013).http://dx.doi.org/10.1016/j.apcatb.2012.12.025
  7. M. Haruta, “Gold as a novel catalyst in the 21st century: Preparation, working mechanism and applications”, Gold Bull. 37(1–2), 27–36 (2004). http://dx.doi.org/10.1007/BF03215514
  8. J. Moghaddam, S. Mollaesmail and S. Karimi, “The Influence of Morphology on Photo-catalytic Activity and Optical Properties of Nano-crystalline ZnO Powder”, Nano-Micro Letters. 4(4), 197–201 (2012). http://dx.doi.org/10.3786/nml.v4i4.p197-201
  9. M. A. Bollinger and M. A. Vannice, “A kinetic and DRIFT study of low temperature carbon monoxide over Au-TiO2 catalysts”, Appl. Catal. B: Environ. 8(4), 417–443 (1996). http://dx.doi.org/10.1016/0926-3373(96)90129-0
  10. G. Y. Wang, H. L. Lian, W. X. Zhang, D. Z. Jiang and T. H. Wu, “Stability and deactivation of Au/Fe2O3 catalysts for CO oxidation at ambient temperature and moisture”, Kin. Catal. 43(3), 433–442 (2002). http://dx.doi.org/10.1023/A:1016026405985
  11. M. Dateand M. Haruta, “Moisture effect on CO oxidation over Au/TiO2 catalyst”, J. Catal. 201(2), 221–224 (2001). http://dx.doi.org/10.1006/jcat.2001.3254
  12. M. Jin, J. Park, J. Shon, Z. Li, Y. Park and J. Kim, “Low temperature CO oxidation over Pd catalysts supported on highly ordered mesoporous metal oxides”, Catal. Today 185(1), 183–190 (2012). http://dx.doi.org/10.1016/j.cattod.2011.09.019
  13. F. Liang, H. Zhu, Z. Qin, G. Wang and J. Wang, “Effects of CO2 on the stability of Pd/CeO2TiO2 catalyst for low-temperature CO oxidation”, Catal. Commun. 10(5), 737–740 (2009). http://dx.doi.org/10.1016/j.catcom.2008.11.031
  14. B. Qiao, L. Liu, J. Zhang and Y. Deng, “Preparation of highly effective ferric hydroxide supported noble metal catalysts for CO oxidations: From gold to palladium”, J. Catal. 261(2), 241–244 (2009). http://dx.doi.org/10.1016/j.jcat.2008.11.012
  15. S. Bernal, J. J. Calvino, M. A. Cauqui, J. M. Gatica, C. Larese, J. A. P. Omil and J. M. Pintado, “Some recent results on metal/support interaction effects in NM/CeO2 (NM: noble metal) catalysts”, Catal. Today 50(2), 175–206 (1999). http://dx.doi.org/10.1016/S0920-5861(98)00503-3
  16. B. Qiao, A. Wang, X. Yang, L. F. Allard, Z. Jiang, Y. Cui, J. Liu, J. Li and T. Zhang, “Single-atom catalysis of CO oxidation using Pt1/FeOx”, Nature Chem. 3(8), 634–641 (2011). http://dx.doi.org/10.1038/nchem.1095
  17. L. Liu, F. Zhou, L. Wang, X. Qi, F. Shi and Y. Deng, “Low-temperature CO oxidation over supported Pt, Pd catalysts: Particular role of FeOx support for oxygen supply during reactions”. J. Catal. 274(1), 1–10 (2010). http://dx.doi.org/10.1016/j.jcat.2010.05.022
  18. Q. Fu, W. Li, Y. Yao, H. Liu, H. Su, D. Ma, X. Gu, L. Chen, Z. Wang, H. Zhang, B. Wang and X. H. Bao, “Interface-confined ferrous centers for catalytic oxidation”, Science 238(5982), 1141–1144 (2010). http://dx.doi.org/10.1126/science.1188267
  19. L. Li, A. Wang, B. Qiao, J. Lin, Y. Huang, X. Wang and T. Zhang, “Origin of the high activity of Au/FeOx for low-temperature CO oxidation: Direct evidence for a redox mechanism”, J. Catal. 299, 90–100 (2013). http://dx.doi.org/10.1016/j.jcat.2012.11.019
  20. L. Liu, B. Qiao, Y. He, F. Zhou, B. Yang and Y. Deng, “Catalytic co-oxidation of CO and H2 over FeOx-supported Pd catalyst at low temperatures”, J. Catal. 294, 29–36 (2012). http://dx.doi.org/10.1016/j.jcat.2012.06.018
  21. M. G. Musolino, C. Busacca, F. Mauriello and R. Pietropaolo, “Aliphatic carbonyl reduction promoted by palladium catalysts under mild conditions”, Appl. Catal. A: Gen. 379(1–2), 77–86 (2010). http://dx.doi.org/10.1016/j.apcata.2010.03.008
  22. J. Jia, J. Shen, L. Lin, Z. Xu, T. Zhang and D. Liang, “A study on reduction behaviors of the supported platinumiron catalysts”, J. Mol. Catal. A: Chem. 138(2–3), 177–184 (1999). http://dx.doi.org/10.1016/S1381-1169(98)00147-2
  23. W. C. Conner and J. L. Falconer, “Spillover in Heterogeneous Catalysis”, Chem. Rev. 95(3), 759–788 (1995). http://dx.doi.org/10.1021/cr00035a014
  24. X. Mou, B. Zhang, Y. Li, L. Yao, X. Wei, D. S. Su and W. Shen, “Rod-Shaped Fe2O3 as an Efficient Catalyst for the Selective Reduction of Nitrogen Oxide by Ammonia”, Angew. Chem. Int. Ed. 51(12), 2989–2993 (2012). http://dx.doi.org/10.1002/anie.201107113
  25. S. H. Oh and G. B. Hoflund, “Low-temperature catalytic carbon monoxide oxidation over hydrous and anhydrous palladium oxide powders”, J. Catal. 245(1), 35–44 (2007). http://dx.doi.org/10.1016/j.jcat.2006.09.016
  26. M. Jin, J. N. Park, J. K. Shon, J. H. Kim, Z. Li, Y. K. Park and J. M. Kim, “Low temperature CO oxidation over Pd catalysts supported on highly ordered mesoporous metal oxides”, Catal. Today 185(1), 183–190 (2012). http://dx.doi.org/10.1016/j.cattod.2011.09.019
  27. S. Y. Christou and A. M. Efstathiou, “Effects of Pd Particle Size on the Rates of Oxygen Back-Spillover and CO Oxidation under Dynamic Oxygen Storage and Release Measurements over Pd/CeO2 Catalysts”, Top Catal. 42–43(1–4), 351–355 (2007). http://dx.doi.org/10.1007/s11244-007-0204-0
  28. J. C. F. Gonzalez, V. A. Bhirud and B. C. Gates, “A highly active catalyst for CO oxidation at 298 K: mononuclear AuIII complexes anchored to La2O3 nanoparticles”, Chem. Commun. 5275–5277 (2005). http://dx.doi.org/10.1039/b509629d
  29. T. Na, F. Wang, H. Li and W. Shen, “Influence of Au particle size on Au/CeO2 catalysts for CO oxidation”, Catal. Today 175(1), 541–545 (2011). http://dx.doi.org/10.1016/j.cattod.2011.04.027
  30. N. W. Cant, P. C. Hicks and B. S. Lennon, “Steadystate oxidation of carbon monoxide over supported noble metals with particular reference to platinum”, J. Catal. 54(3), 372–383 (1978). http://dx.doi.org/10.1016/0021-9517(78)90085-4
  31. I. Stara, V. Nehasil and V. Matolin, “The influence of particle size on CO oxidation on Pd/alumina model catalyst”, Surf. Sci. 331–333, 173–177 (1995). http://dx.doi.org/10.1016/0039-6028(95)00183-2
  32. F. Boccuzzi, A. Chiorino, S. Tsubota and M. Haruta, “FTIR study of carbon monoxide and scrambling at room temperature over gold supported on ZnO and TiO2”, J. Phys. Chem. 100(9), 3625–3631 (1996). http://dx.doi.org/10.1021/jp952259n
  33. T. Shido and Y. Iwasawa, “Reactant-promoted reaction mechanism for water-gas shift reaction on Rhdoped CeO2”, J. Catal. 141(1), 71–81 (1993). http://dx.doi.org/10.1006/jcat.1993.1119
  34. B. Chang, B. W. Jang, S. Dai and S. H. Overbury, “Transient studies of the mechanism of CO oxidation over Au/TiO2 using time-resolved FTIR spectroscopy and product analysis”, J. Catal. 236(2), 392–400 (2005). http://dx.doi.org/10.1016/j.jcat.2005.10.006
  35. Y. Shen, Y. Guo, L. Wang, Y. Wang, Y. Guo, X. Gong and G. Lu, “The stability and deactivation of Pd-Cu- Clx/Al2O3 catalyst for low temperature CO oxidation: an effect of moisture”, Catal. Sci. Techno. 1, 1202–1207 (2011). http://dx.doi.org/10.1039/c1cy00146a
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