Conductivity Study of Polyaniline-Cobalt Ferrite (PANI-CoFe2O4) Nanocomposite
Corresponding Author: A. Baykal
Nano-Micro Letters,
Vol. 3 No. 2 (2011), Article Number: 99-107
Abstract
In this investigation, the structural and electrical properties of nanocomposites of polyaniline (PANI) and cobalt ferrite synthesized by hydrothermal route are reported for the first time (with weight ratios of CoFe2O4/PANI 1:2 and 2:1). Synthesized nanomaterials have been characterized by XRD, FT-IR, SEM and TEM techniques. FT-IR results confirm the presence of CoFe2O4 and PANI in the samples. Their detailed conductivity measurements have been investigated. It has been found that PANI has a more effective conducting mechanism in CoFe2O4-PANI composites. These results are also consistent with the change in AC conductivity orders in composites.
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- S. Ameen, M. S. Akhtar, S. G. Ansari, O. B. Yang and H. S. Shin, Superlattices Microst. 46, 872 (2009). http://dx.doi.org/10.1016/j.spmi.2009.09.007
- G. D. Prasanna, H. S. Jayanna and V. Prasad, J. Appl. Polym. Sci. 120, 2856 (2011). http://dx.doi.org/10.1002/app.33304
- M. J. Iqbal and B. Ismail, Journal of Alloys and Compounds 472, 434 (2009). http://dx.doi.org/10.1016/j.jallcom.2008.04.079
- P. Siwach, S. Singh and R. K. Gupta. Catal. Commun. 10, 1577 (2009). http://dx.doi.org/10.1016/j.catcom.2009.04.019
- A. R. Shyam, R. Dwivedi, V. S. Reddy, K. V. R. Chary and R. Prasad, Green Chem. 4, 558 (2002). http://dx.doi.org/10.1039/b207410a
- S. V. Reddy, S. A. Radhe, R. Dwivedi, R. K. Gupta, V. R. Chumbale and R. Prasad, J Chem. Technol. Biotechnol. 79, 1057 (2004). http://dx.doi.org/10.1002/jctb.1060
- S. D. Bhame and P. A. Joy, J. Phys. D: Appl. Phys. 40, 3263 (2007). http://dx.doi.org/10.1088/0022-3727/40/11/001
- S. A. Chambers, R. F. C. Farrow, S. Maat, M. F. Toney, L. Folks, J. G. Catalano, T. P. Trainor and G. E. Brown Jr., J. Magn. Magn. Mater. 246, 124 (2002). http://dx.doi.org/10.1016/S0304-8853(02)00039-2
- J. G. Do S. Duque, M. A. Macedo and N. O. Moreno, Phys. Stat. Sol. 220, 413 (2000).
- M. S. Khandekar, R. C. Kambale, J. Y. Patil, Y. D. Kolekar and S. S. Suryavanshi, J. Alloys Compd. 509, 1861 (2011). http://dx.doi.org/10.1016/j.jallcom.2010.10.073
- M. C. Terzzoli, S. Duhalde, S. Jacobo, L. Steren and C. Moina, J. Alloys Compd. 369, 209 (2004). http://dx.doi.org/10.1016/j.jallcom.2003.09.086
- R. C. Kambale, P. A. Shaikh, N. S. Harale, V. A. Bilur, Y. D. Kolekar, C. H. Bhosale and K. Y. Rajpure, J. Alloys Compd. 490, 568 (2010). http://dx.doi.org/10.1016/j.jallcom.2009.10.082
- R. W. McCallum, K. W. Dennis, D. C. Jiles, J. E. Snyder and Y. H. Chen, Low Temp. Phys. 27, 266 (2001). http://dx.doi.org/10.1063/1.1365598
- M. A. Ahmed, N. Okasha, S. F. Mansour and S. I. El-dek, J. Alloy. Compd. 496, 345 (2010).
- J. Cao, W. Fu, H. Yang, Q. Yu, Y. Zhang, S. Liu, P. Sun, X. Zhou, Y. Leng, S. Wang, B. Liu and G. Zou, J. Phys. Chem. B 113, 4642 (2009). http://dx.doi.org/10.1021/jp8093287
- F. Cheng, C. Liao, J. Kuang, Z. Xu, C. Yan, L. Chen, H. Zhao and Z. Liu, J. Appl. Phys. 85, 2782 (1999). http://dx.doi.org/10.1063/1.369594
- J. Ryu, S. Priya, K. Uchino and H. Kim, J. Electroceram. 8, 107 (2002). http://dx.doi.org/10.1023/A:1020599728432
- J. Deng, C. He, Y. Peng, J. Wang, X. Long, P. Li and A. S. C. Chan, Synth. Met. 139, 295 (2003). http://dx.doi.org/10.1016/S0379-6779(03)00166-8
- Z. Durmus, A. Baykal, H. Kavas and H. Sözeri, Physica B 406, 1114 (2011). http://dx.doi.org/10.1016/j.physb.2010.12.059
- Z. Hu, H. Zhao, C. Kong, Y. Yang, X. Shang, L. Ren and Y. Wang, J. Mater. Sci. Mater. Electron. 17, 859 (2006). http://dx.doi.org/10.1007/s10854-006-0042-z
- B. Su, X. Zuo, C. Hu and Z. Lei, Acta Phys. Chim. Sin. 24, 1932 (2008)–10.
- D. S. McLachlan and G. Sauti, J. Nanomater. 2007, Article ID 30389 (2007), http://dx.doi.org/10.1155/2007/30389
- A. M. El-Sayed, Ceram. Int. 28, 363 (2002). http://dx.doi.org/10.1016/S0272-8842(01)00103-1
- K. P. Chae, J. Lee, H. S. Kweon and Y. B. Lee, J. Magn. Magn. Mater. 283, 103 (2004). http://dx.doi.org/10.1016/j.jmmm.2004.05.010
- N. Gupta, A. Verma, S. C. Kashyap and D. C. Dube, J. Magn. Magn. Mater. 308, 137 (2007). http://dx.doi.org/10.1016/j.jmmm.2006.05.015
- A. Baykal, N. Kasapoglu, Y. Köseoglu, A. C. Basaran, H. Kavas and M. S. Toprak, Cent. Eur. J. Chem. 6, 125 (2008). http://dx.doi.org/10.2478/s11532-007-0070-4
- N. Kasapoğlu, A. Baykal, Y. Köseoğlu and M. S. Toprak, Scriptia Materialia 57, 441 (2007). http://dx.doi.org/10.1016/j.scriptamat.2007.04.042
- S. Quillard, G. Louarn, S. Lefrant and A. G. Mac-Diarmid, Phys. Rev. B 50, 12496 (1994). http://dx.doi.org/10.1103/PhysRevB.50.12496
- A. Ghosh, Phys. Rev. B 42, 1388 (1990). http://dx.doi.org/10.1103/PhysRevB.42.1388
- S. R. Elliott, Adv. Phys. 36, 135 (1987). http://dx.doi.org/10.1080/00018738700101971
- S. Ebrahim, A. Kashyout and M. Soliman, Current Applied Physics 9, 448 (2009).
- N. F. Mott and E. A. Davis, Electronic Processes in Non-crystalline Material, Oxford Press, London 1979.
- N. Parvatikar and M. V. N. Ambika Prasad, Journal of Applied Polymer Science 100, 1403 (2006). http://dx.doi.org/10.1002/app.22950
- F. Legros and A. Fourrier-Lamer, Mater. Res. Bull. 19, 1109 (1984). http://dx.doi.org/10.1016/0025-5408(84)90060-6
- C. W. Chu, F. Chen, J. Shulman, S. Tsui, Y. Y. Xue, W. Wen and P. Sheng, Proc. SPIE 5932, 59320X (2005). http://dx.doi.org/10.1117/12.626267
- P. Barber, S. Balasubramanian, Y. Anguchamy, S. Gong, A. Wibowo, H. Gao, H. J. Ploehn and H. Loye, Materials 2, 1697 (2009). http://dx.doi.org/10.3390/ma2041697
- D. Yoon, H. Zhang and J. Lee, B. I. Mater. Res. Bull. 38, 765 (2003). http://dx.doi.org/10.1016/S0025-5408(03)00075-8
References
S. Ameen, M. S. Akhtar, S. G. Ansari, O. B. Yang and H. S. Shin, Superlattices Microst. 46, 872 (2009). http://dx.doi.org/10.1016/j.spmi.2009.09.007
G. D. Prasanna, H. S. Jayanna and V. Prasad, J. Appl. Polym. Sci. 120, 2856 (2011). http://dx.doi.org/10.1002/app.33304
M. J. Iqbal and B. Ismail, Journal of Alloys and Compounds 472, 434 (2009). http://dx.doi.org/10.1016/j.jallcom.2008.04.079
P. Siwach, S. Singh and R. K. Gupta. Catal. Commun. 10, 1577 (2009). http://dx.doi.org/10.1016/j.catcom.2009.04.019
A. R. Shyam, R. Dwivedi, V. S. Reddy, K. V. R. Chary and R. Prasad, Green Chem. 4, 558 (2002). http://dx.doi.org/10.1039/b207410a
S. V. Reddy, S. A. Radhe, R. Dwivedi, R. K. Gupta, V. R. Chumbale and R. Prasad, J Chem. Technol. Biotechnol. 79, 1057 (2004). http://dx.doi.org/10.1002/jctb.1060
S. D. Bhame and P. A. Joy, J. Phys. D: Appl. Phys. 40, 3263 (2007). http://dx.doi.org/10.1088/0022-3727/40/11/001
S. A. Chambers, R. F. C. Farrow, S. Maat, M. F. Toney, L. Folks, J. G. Catalano, T. P. Trainor and G. E. Brown Jr., J. Magn. Magn. Mater. 246, 124 (2002). http://dx.doi.org/10.1016/S0304-8853(02)00039-2
J. G. Do S. Duque, M. A. Macedo and N. O. Moreno, Phys. Stat. Sol. 220, 413 (2000).
M. S. Khandekar, R. C. Kambale, J. Y. Patil, Y. D. Kolekar and S. S. Suryavanshi, J. Alloys Compd. 509, 1861 (2011). http://dx.doi.org/10.1016/j.jallcom.2010.10.073
M. C. Terzzoli, S. Duhalde, S. Jacobo, L. Steren and C. Moina, J. Alloys Compd. 369, 209 (2004). http://dx.doi.org/10.1016/j.jallcom.2003.09.086
R. C. Kambale, P. A. Shaikh, N. S. Harale, V. A. Bilur, Y. D. Kolekar, C. H. Bhosale and K. Y. Rajpure, J. Alloys Compd. 490, 568 (2010). http://dx.doi.org/10.1016/j.jallcom.2009.10.082
R. W. McCallum, K. W. Dennis, D. C. Jiles, J. E. Snyder and Y. H. Chen, Low Temp. Phys. 27, 266 (2001). http://dx.doi.org/10.1063/1.1365598
M. A. Ahmed, N. Okasha, S. F. Mansour and S. I. El-dek, J. Alloy. Compd. 496, 345 (2010).
J. Cao, W. Fu, H. Yang, Q. Yu, Y. Zhang, S. Liu, P. Sun, X. Zhou, Y. Leng, S. Wang, B. Liu and G. Zou, J. Phys. Chem. B 113, 4642 (2009). http://dx.doi.org/10.1021/jp8093287
F. Cheng, C. Liao, J. Kuang, Z. Xu, C. Yan, L. Chen, H. Zhao and Z. Liu, J. Appl. Phys. 85, 2782 (1999). http://dx.doi.org/10.1063/1.369594
J. Ryu, S. Priya, K. Uchino and H. Kim, J. Electroceram. 8, 107 (2002). http://dx.doi.org/10.1023/A:1020599728432
J. Deng, C. He, Y. Peng, J. Wang, X. Long, P. Li and A. S. C. Chan, Synth. Met. 139, 295 (2003). http://dx.doi.org/10.1016/S0379-6779(03)00166-8
Z. Durmus, A. Baykal, H. Kavas and H. Sözeri, Physica B 406, 1114 (2011). http://dx.doi.org/10.1016/j.physb.2010.12.059
Z. Hu, H. Zhao, C. Kong, Y. Yang, X. Shang, L. Ren and Y. Wang, J. Mater. Sci. Mater. Electron. 17, 859 (2006). http://dx.doi.org/10.1007/s10854-006-0042-z
B. Su, X. Zuo, C. Hu and Z. Lei, Acta Phys. Chim. Sin. 24, 1932 (2008)–10.
D. S. McLachlan and G. Sauti, J. Nanomater. 2007, Article ID 30389 (2007), http://dx.doi.org/10.1155/2007/30389
A. M. El-Sayed, Ceram. Int. 28, 363 (2002). http://dx.doi.org/10.1016/S0272-8842(01)00103-1
K. P. Chae, J. Lee, H. S. Kweon and Y. B. Lee, J. Magn. Magn. Mater. 283, 103 (2004). http://dx.doi.org/10.1016/j.jmmm.2004.05.010
N. Gupta, A. Verma, S. C. Kashyap and D. C. Dube, J. Magn. Magn. Mater. 308, 137 (2007). http://dx.doi.org/10.1016/j.jmmm.2006.05.015
A. Baykal, N. Kasapoglu, Y. Köseoglu, A. C. Basaran, H. Kavas and M. S. Toprak, Cent. Eur. J. Chem. 6, 125 (2008). http://dx.doi.org/10.2478/s11532-007-0070-4
N. Kasapoğlu, A. Baykal, Y. Köseoğlu and M. S. Toprak, Scriptia Materialia 57, 441 (2007). http://dx.doi.org/10.1016/j.scriptamat.2007.04.042
S. Quillard, G. Louarn, S. Lefrant and A. G. Mac-Diarmid, Phys. Rev. B 50, 12496 (1994). http://dx.doi.org/10.1103/PhysRevB.50.12496
A. Ghosh, Phys. Rev. B 42, 1388 (1990). http://dx.doi.org/10.1103/PhysRevB.42.1388
S. R. Elliott, Adv. Phys. 36, 135 (1987). http://dx.doi.org/10.1080/00018738700101971
S. Ebrahim, A. Kashyout and M. Soliman, Current Applied Physics 9, 448 (2009).
N. F. Mott and E. A. Davis, Electronic Processes in Non-crystalline Material, Oxford Press, London 1979.
N. Parvatikar and M. V. N. Ambika Prasad, Journal of Applied Polymer Science 100, 1403 (2006). http://dx.doi.org/10.1002/app.22950
F. Legros and A. Fourrier-Lamer, Mater. Res. Bull. 19, 1109 (1984). http://dx.doi.org/10.1016/0025-5408(84)90060-6
C. W. Chu, F. Chen, J. Shulman, S. Tsui, Y. Y. Xue, W. Wen and P. Sheng, Proc. SPIE 5932, 59320X (2005). http://dx.doi.org/10.1117/12.626267
P. Barber, S. Balasubramanian, Y. Anguchamy, S. Gong, A. Wibowo, H. Gao, H. J. Ploehn and H. Loye, Materials 2, 1697 (2009). http://dx.doi.org/10.3390/ma2041697
D. Yoon, H. Zhang and J. Lee, B. I. Mater. Res. Bull. 38, 765 (2003). http://dx.doi.org/10.1016/S0025-5408(03)00075-8