Issue

Vol. 14 (2022)

Critical Review on cathode–electrolyte Interphase Toward High-Voltage Cathodes for Li-Ion Batteries

https://doi.org/10.1007/s40820-022-00917-2
Jijian Xu
Department of Chemical and Biomolecular Engineering, University of Maryland College Park, College Park, MD 20742, USA

Corresponding Author: Jijian Xu

jijianxu@umd.edu

Nano-Micro Letters, Vol. 14 (2022), Article Number: 166

Abstract

The thermal stability window of current commercial carbonate-based electrolytes is no longer sufficient to meet the ever-increasing cathode working voltage requirements of high energy density lithium-ion batteries. It is crucial to construct a robust cathode–electrolyte interphase (CEI) for high-voltage cathode electrodes to separate the electrolytes from the active cathode materials and thereby suppress the side reactions. Herein, this review presents a brief historic evolution of the mechanism of CEI formation and compositions, the state-of-art characterizations and modeling associated with CEI, and how to construct robust CEI from a practical electrolyte design perspective. The focus on electrolyte design is categorized into three parts: CEI-forming additives, anti-oxidation solvents, and lithium salts. Moreover, practical considerations for electrolyte design applications are proposed. This review will shed light on the future electrolyte design which enables aggressive high-voltage cathodes.


Highlights:


1 A critical assessment of cathode–electrolyte interphase (CEI) for high-voltage cathode electrodes in Li-ion cells.
2 Fundamental understanding of why interfacial interphase is important to electrochemical performance and further elaboration on how to design robust CEI interphase.
3 Emerging theoretical simulations and advanced in situ characterizations helps to unveil the mystery of CEI are summarized.

Keywords

Cathode–electrolyte interphase High-voltage cathodes Interfacial chemistry Electrolyte design Batteries
Xu, Jijian. 2022. “Critical Review on cathode–electrolyte Interphase Toward High-Voltage Cathodes for Li-Ion Batteries”. Nano-Micro Letters 14 (August):166. https://doi.org/10.1007/s40820-022-00917-2.
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