Issue

Vol. 15 (2023)

Sulfide-Based All-Solid-State Lithium–Sulfur Batteries: Challenges and Perspectives

https://doi.org/10.1007/s40820-023-01053-1
Xinxin Zhu
College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, People’s Republic of China
Liguang Wang
College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, People’s Republic of China
Zhengyu Bai
Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals Key Laboratory of Green Chemical Media and Reactions Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, People’s Republic of China
Jun Lu
College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, People’s Republic of China
Tianpin Wu
College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, People’s Republic of China

Corresponding Author: Tianpin Wu

tianpinwu@zju.edu.cn

Nano-Micro Letters, Vol. 15 (2023), Article Number: 75

Abstract

Lithium–sulfur batteries with liquid electrolytes have been obstructed by severe shuttle effects and intrinsic safety concerns. Introducing inorganic solid-state electrolytes into lithium–sulfur systems is believed as an effective approach to eliminate these issues without sacrificing the high-energy density, which determines sulfide-based all-solid-state lithium–sulfur batteries. However, the lack of design principles for high-performance composite sulfur cathodes limits their further application. The sulfur cathode regulation should take several factors including the intrinsic insulation of sulfur, well-designed conductive networks, integrated sulfur-electrolyte interfaces, and porous structure for volume expansion, and the correlation between these factors into account. Here, we summarize the challenges of regulating composite sulfur cathodes with respect to ionic/electronic diffusions and put forward the corresponding solutions for obtaining stable positive electrodes. In the last section, we also outlook the future research pathways of architecture sulfur cathode to guide the develop high-performance all-solid-state lithium–sulfur batteries.


Highlights:


1 The composite cathode composition, preparation method, and chemical compatibility play critical roles in constructing triple-phase interfaces.
2 Understanding the electrolyte degradation is critical for boosting the high-performance composite sulfur cathode.
3 The volume change of sulfur challenges the mechanical stability of composite sulfur cathode.

Keywords

All-solid-state lithium–sulfur battery Sulfur cathode Triple-phase interfaces Electrolyte decomposition Volume change
Zhu, Xinxin, Liguang Wang, Zhengyu Bai, Jun Lu, and Tianpin Wu. 2023. “Sulfide-Based All-Solid-State Lithium–Sulfur Batteries: Challenges and Perspectives”. Nano-Micro Letters 15 (March):75. https://doi.org/10.1007/s40820-023-01053-1.
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