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Vol. 15 (2023)

Cerium Methacrylate Assisted Preparation of Highly Thermally Conductive and Anticorrosive Multifunctional Coatings for Heat Conduction Metals Protection

https://doi.org/10.1007/s40820-023-01163-w
Fei Xu
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, People’s Republic of China
Peng Ye
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, People’s Republic of China
Jianwen Peng
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, People’s Republic of China
Haolei Geng
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, People’s Republic of China
Yexiang Cui
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, People’s Republic of China
Di Bao
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, People’s Republic of China
Renjie Lu
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, People’s Republic of China
Hongyu Zhu
Tianjin Key Lab Composite & Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, People’s Republic of China
Yanji Zhu
Tianjin Key Lab Composite & Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, People’s Republic of China
Huaiyuan Wang
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, People’s Republic of China

Corresponding Author: Huaiyuan Wang

huaiyuanwang@tju.edu.cn

Nano-Micro Letters, Vol. 15 (2023), Article Number: 201

Abstract

Preparing polymeric coatings with well corrosion resistance and high thermal conductivity (TC) to prolong operational life and ensure service reliability of heat conductive metallic materials has long been a substantive and urgent need while a difficult task. Here we report a multifunctional epoxy composite coating (F-CB/CEP) by synthesizing cerium methacrylate and ingeniously using it as a novel curing agent with corrosion inhibit for epoxy resin and modifier for boron nitride through "cation-π" interaction. The prepared F-CB/CEP coating presents a high TC of 4.29 W m−1 K−1, which is much higher than other reported anti-corrosion polymer coatings and thereby endowing metal materials coated by this coating with outstanding thermal management performance compared with those coated by pure epoxy coating. Meanwhile, the low-frequency impedance remains at 5.1 × 1011 Ω cm2 even after 181 days of immersion in 3.5 wt% NaCl solution. Besides, the coating also exhibits well hydrophobicity, self-cleaning properties, temperature resistance and adhesion. This work provides valuable insights for the preparation of high-performance composite coatings with potential to be used as advanced multifunctional thermal management materials, especially for heat conduction metals protection.


Highlights:
1 Cerium methacrylate was prepared and ingeniously used as curing agent for epoxy, surface modifier for BN, and effective corrosion inhibitor.
2 The coating integrates high thermal conductivity (4.29 W m−1 K−1), corrosion resistance (low-frequency impedance is 5.1 × 1011 Ω cm2 at 181 day), hydrophobicity (WCA: ~ 148.35° and WSA: ~ 20°), temperature resistance and adhesion.
3 The coating can extend service life of metal materials without sacrificing their inherent heat conduction property.

Keywords

Epoxy coatings Thermal conductivity Anti-corrosion Hydrophobicity Cerium methacrylate
Xu, Fei, Peng Ye, Jianwen Peng, Haolei Geng, Yexiang Cui, Di Bao, Renjie Lu, Hongyu Zhu, Yanji Zhu, and Huaiyuan Wang. 2023. “Cerium Methacrylate Assisted Preparation of Highly Thermally Conductive and Anticorrosive Multifunctional Coatings for Heat Conduction Metals Protection”. Nano-Micro Letters 15 (August):201. https://doi.org/10.1007/s40820-023-01163-w.
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