Issue

Vol. 16 (2024)

A Molecular-Sieving Interphase Towards Low-Concentrated Aqueous Sodium-Ion Batteries

https://doi.org/10.1007/s40820-024-01340-5
Tingting Liu
Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, People’s Republic of China
Han Wu
School of Chemical Engineering and Advanced Materials, The University of Adelaide, Adelaide, SA 5005, Australia
Hao Wang
Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, People’s Republic of China
Yiran Jiao
School of Chemical Engineering and Advanced Materials, The University of Adelaide, Adelaide, SA 5005, Australia
Xiaofan Du
Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, People’s Republic of China
Jinzhi Wang
Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, People’s Republic of China
Guangying Fu
Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, People’s Republic of China
Yaojian Zhang
Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, People’s Republic of China
Jingwen Zhao
Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, People’s Republic of China
Guanglei Cui
Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, People’s Republic of China

Corresponding Author: Guanglei Cui

cuigl@qibebt.ac.cn

Nano-Micro Letters, Vol. 16 (2024), Article Number: 144

Abstract

Aqueous sodium-ion batteries are known for poor rechargeability because of the competitive water decomposition reactions and the high electrode solubility. Improvements have been reported by salt-concentrated and organic-hybridized electrolyte designs, however, at the expense of cost and safety. Here, we report the prolonged cycling of ASIBs in routine dilute electrolytes by employing artificial electrode coatings consisting of NaX zeolite and NaOH-neutralized perfluorinated sulfonic polymer. The as-formed composite interphase exhibits a molecular-sieving effect jointly played by zeolite channels and size-shrunken ionic domains in the polymer matrix, which enables high rejection of hydrated Na+ ions while allowing fast dehydrated Na+ permeance. Applying this coating to electrode surfaces expands the electrochemical window of a practically feasible 2 mol kg–1 sodium trifluoromethanesulfonate aqueous electrolyte to 2.70 V and affords Na2MnFe(CN)6//NaTi2(PO4)3 full cells with an unprecedented cycling stability of 94.9% capacity retention after 200 cycles at 1 C. Combined with emerging electrolyte modifications, this molecular-sieving interphase brings amplified benefits in long-term operation of ASIBs.


Highlights:
1 A molecular-sieving electrode coating towards low-concentrated aqueous sodium-ion batteries is constructed by applying a composite of NaX zeolite and NaOH-neutralized Nafion.
2 Resulting from a molecular sieving effect of zeolite channels and size-shrunken ionic domains in Nafion, the as-prepared coating layer reject hydrated Na+ ions and allow fast dehydrated Na+ permeance.
3 200 cycles of Na2MnFe(CN)6//NaTi2(PO4)3 full cells can be achieved in a practically feasible 2 m aqueous electrolyte.

Keywords

Molecular sieving effect Electrode coatings Aqueous sodium ion batteries Dilute aqueous electrolytes
Liu, Tingting, Han Wu, Hao Wang, Yiran Jiao, Xiaofan Du, Jinzhi Wang, Guangying Fu, Yaojian Zhang, Jingwen Zhao, and Guanglei Cui. 2024. “A Molecular-Sieving Interphase Towards Low-Concentrated Aqueous Sodium-Ion Batteries”. Nano-Micro Letters 16 (March):144. https://doi.org/10.1007/s40820-024-01340-5.
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