Issue

Vol. 12 (2020)

Boosting High-Rate Zinc-Storage Performance by the Rational Design of Mn2O3 Nanoporous Architecture Cathode

https://doi.org/10.1007/s40820-019-0351-4
Danyang Feng
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, Jilin, People’s Republic of China
Tu‑Nan Gao
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, Jilin, People’s Republic of China
Ling Zhang
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, Jilin, People’s Republic of China
Bingkun Guo
Materials Genome Institute, Shanghai University, Shanghai 200444, People’s Republic of China
Shuyan Song
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, People’s Republic of China
Zhen‑An Qiao
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, Jilin, People’s Republic of China
Sheng Dai
Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA

Corresponding Author: Zhen‑An Qiao

qiaozhenan@jlu.edu.cn

Nano-Micro Letters, Vol. 12 (2020), Article Number: 14

Abstract

Manganese oxides are regarded as one of the most promising cathode materials in rechargeable aqueous Zn-ion batteries (ZIBs) because of the low price and high security. However, the practical application of Mn2O3 in ZIBs is still plagued by the low specific capacity and poor rate capability. Herein, highly crystalline Mn2O3 materials with interconnected mesostructures and controllable pore sizes are obtained via a ligand-assisted self-assembly process and used as high-performance electrode materials for reversible aqueous ZIBs. The coordination degree between Mn2+ and citric acid ligand plays a crucial role in the formation of the mesostructure, and the pore sizes can be easily tuned from 3.2 to 7.3 nm. Ascribed to the unique feature of nanoporous architectures, excellent zinc-storage performance can be achieved in ZIBs during charge/discharge processes. The Mn2O3 electrode exhibits high reversible capacity (233 mAh g−1 at 0.3 A g−1), superior rate capability (162 mAh g−1 retains at 3.08 A g−1) and remarkable cycling durability over 3000 cycles at a high current rate of 3.08 A g−1. Moreover, the corresponding electrode reaction mechanism is studied in depth according to a series of analytical methods. These results suggest that rational design of the nanoporous architecture for electrode materials can effectively improve the battery performance.


Highlights:


1 Highly crystalline Mn2O3 materials with tunable pore sizes are obtained and employed as high-performance cathode materials for reversible aqueous Zn-ion battery.
2 The Zn/Mn2O3 battery exhibits significantly improved rate capability and remarkable cycling durability due to the introduction of nanoporous architecture.
3 The Zn2+/H+ intercalations mechanism is put forward for the Zn/Mn2O3 battery.

Keywords

Porous Mn2O3 High-rate capability Zn-ion battery Cathode material Zn-storage mechanism
Feng, Danyang, Tu‑Nan Gao, Ling Zhang, Bingkun Guo, Shuyan Song, Zhen‑An Qiao, and Sheng Dai. 2019. “Boosting High-Rate Zinc-Storage Performance by the Rational Design of Mn2O3 Nanoporous Architecture Cathode”. Nano-Micro Letters 12 (December):14. https://doi.org/10.1007/s40820-019-0351-4.
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. H. Chen, M. Ling, L. Hencz, H.Y. Ling, G. Li, Z. Lin, G. Liu, S. Zhang, Exploring chemical, mechanical, and electrical functionalities of binders for advanced energy-storage devices. Chem. Rev. 118(18), 8936–8982 (2018). https://doi.org/10.1021/acs.chemrev.8b00241
  2. Z.P. Cano, D. Banham, S. Ye, A. Hintennach, J. Lu, M. Fowler, Z. Chen, Batteries and fuel cells for emerging electric vehicle markets. Nat. Energy 3(4), 279–289 (2018). https://doi.org/10.1038/s41560-018-0108-1
  3. J. Mei, T. Liao, L. Kou, Z. Sun, Two-dimensional metal oxide nanomaterials for next-generation rechargeable batteries. Adv. Mater. 29(48), 1700176 (2017). https://doi.org/10.1002/adma.201700176
  4. Z.W. Chang, J.J. Xu, X.B. Zhang, Recent progress in electrocatalyst for Li-O2 batteries. Adv. Energy Mater. 7(23), 1700875 (2017). https://doi.org/10.1002/aenm.201700875
  5. M. Winter, B. Barnett, K. Xu, Before Li ion batteries. Chem. Rev. 118(23), 11433–11456 (2018). https://doi.org/10.1021/acs.chemrev.8b00422
  6. F.A. Susai, H. Sclar, Y. Shilina, T.R. Penki, R. Raman et al., Horizons for Li-ion batteries relevant to electro-mobility: high-specific-energy cathodes and chemically active separators. Adv. Mater. 30(41), 1801348 (2018). https://doi.org/10.1002/adma.201801348
  7. J.-M. Tarascon, M. Armand, Issues and challenges facing rechargeable lithium batteries. Nature 414(6861), 359–367 (2001). https://doi.org/10.1038/35104644
  8. C. Zhan, T. Wu, J. Lu, K. Amine, Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes: a critical review. Energy Environ. Sci. 11(2), 243–257 (2018). https://doi.org/10.1039/C7EE03122J
  9. W. Zhou, S. Wang, Y. Li, S. Xin, A. Manthiram, J.B. Goodenough, Plating a dendrite-free lithium anode with a polymer/ceramic/polymer sandwich electrolyte. J. Am. Chem. Soc. 138(30), 9385–9388 (2016). https://doi.org/10.1021/jacs.6b05341
  10. L. Shen, L. Yu, X.Y. Yu, X. Zhang, X.W. Lou, Self-templated formation of uniform NiCo2O4 hollow spheres with complex interior structures for lithium-ion batteries and supercapacitors. Angew. Chem. Int. Ed. 54(6), 1868–1872 (2015). https://doi.org/10.1002/anie.201409776
  11. P.K. Nayak, L. Yang, W. Brehm, P. Adelhelm, From lithium-ion to sodium-ion batteries: advantages, challenges, and surprises. Angew. Chem. Int. Ed. 57(1), 102–120 (2018). https://doi.org/10.1002/ange.201703772
  12. Z. Zhang, S. Dong, Z. Cui, A. Du, G. Li, G. Cui, Rechargeable magnesium batteries using conversion-type cathodes: a perspective and minireview. Small Methods 2(10), 1800020 (2018). https://doi.org/10.1002/smtd.201800020
  13. X. Yu, B. Wang, D. Gong, Z. Xu, B. Lu, Graphene nanoribbons on highly porous 3D graphene for high-capacity and ultrastable Al-ion batteries. Adv. Mater. 29(4), 1604118 (2017). https://doi.org/10.1002/adma.201604118
  14. M. Song, H. Tan, D. Chao, H.J. Fan, Recent advances in Zn-ion batteries. Adv. Funct. Mater. 28(41), 1802564 (2018). https://doi.org/10.1002/adfm.201802564
  15. H. Li, L. McRae, C.J. Firby, A.Y. Elezzabi, Rechargeable aqueous electrochromic batteries utilizing Ti-substituted tungsten molybdenum oxide based Zn2+ ion intercalation cathodes. Adv. Mater. 31(15), 1807065 (2019). https://doi.org/10.1002/adma.201807065
  16. W. Xu, Y. Wang, Recent progress on zinc-ion rechargeable batteries. Nano-Micro Lett. 11, 90 (2019). https://doi.org/10.1007/s40820-019-0322-9
  17. Y.R. Qi, Y.X. Lu, F.X. Ding, Q.Q. Zhang, H. Li, J. Huang, L.Q. Chen, Y.S. Hu, Slope-dominated carbon anode with high specific capacity and superior rate capability for high safety Na-ion batteries. Angew. Chem. Int. Ed. 58(13), 4361–4365 (2019). https://doi.org/10.1002/anie.201900005
  18. Q. Liang, F. Chen, S. Wang, Q. Ru, Q. He, X. Hou, C.Y. Su, Y. Shi, An organic flow desalination battery. Energy Storage Mater. 20, 203–207 (2019). https://doi.org/10.1016/j.ensm.2018.11.006
  19. H. Pan, Y. Shao, P. Yan, Y. Cheng, K.S. Han et al., Reversible aqueous zinc/manganese oxide energy storage from conversion reactions. Nat. Energy 1, 16039 (2016). https://doi.org/10.1038/nenergy.2016.39
  20. N. Zhang, F. Cheng, Y. Liu, Q. Zhao, K. Lei, C. Chen, X. Liu, J. Chen, Cation-deficient spinel ZnMn2O4 cathode in Zn(CF3SO3)2 electrolyte for rechargeable aqueous Zn-ion battery. J. Am. Chem. Soc. 138(39), 12894–12901 (2016). https://doi.org/10.1021/jacs.6b05958
  21. N. Zhang, F. Cheng, J. Liu, L. Wang, X. Long, X. Liu, F. Li, J. Chen, Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities. Nat. Commun. 8, 405 (2017). https://doi.org/10.1038/s41467-017-00467-x
  22. T. Luo, S. Wang, X. Hou, F. Chen, X. Liu, Z. Shao, H. Yan, Cr–Zn redox battery with NiFe2O4 as catalyst for enhanced degradation of Cr(VI) pollution. ACS Sustain. Chem. Eng. 7(1), 111–116 (2019). https://doi.org/10.1021/acssuschemeng.8b05299
  23. R. Trócoli, G. Kasiri, F. La Mantia, Phase transformation of copper hexacyanoferrate (KCuFe(CN)6) during zinc insertion: effect of co-ion intercalation. J. Power Sources 400, 167–171 (2018). https://doi.org/10.1016/j.jpowsour.2018.08.015
  24. G. Li, Z. Yang, Y. Jiang, C. Jin, W. Huang, X. Ding, Y. Huang, Towards polyvalent ion batteries: a zinc-ion battery based on NASICON structured Na3V2(PO4)3. Nano Energy 25, 211–217 (2016). https://doi.org/10.1016/j.nanoen.2016.04.051
  25. L. Shan, J. Zhou, M. Han, G. Fang, X. Cao, X. Wu, S. Liang, Reversible Zn-driven reduction displacement reaction in aqueous zinc-ion battery. J. Mater. Chem. A 7(13), 7355–7359 (2019). https://doi.org/10.1039/C9TA00125E
  26. X. Hou, Q. Liang, X. Hu, Y. Zhou, Q. Ru, F. Chen, S. Hu, Coupling desalination and energy storage with redox flow electrodes. Nanoscale 10(26), 12308–12314 (2018). https://doi.org/10.1039/C8NR02737D
  27. B. Jiang, C. Xu, C. Wu, L. Dong, J. Li, F. Kang, Manganese sesquioxide as cathode material for multivalent zinc ion battery with high capacity and long cycle life. Electrochim. Acta 229, 422–428 (2017). https://doi.org/10.1016/j.electacta.2017.01.163
  28. Y. Liu, X. Zhou, R. Liu, X. Li, Y. Bai, H. Xiao, Y. Wang, G. Yuan, Tailoring three-dimensional composite architecture for advanced zinc-ion batteries. ACS Appl. Mater. Interfaces 11(21), 19191–19199 (2019). https://doi.org/10.1021/acsami.9b04583
  29. F. Cheng, H. Wang, Z. Zhu, Y. Wang, T. Zhang, Z. Tao, J. Chen, Porous LiMn2O4 nanorods with durable high-rate capability for rechargeable Li-ion batteries. Energy Environ. Sci. 4(9), 3668–3675 (2011). https://doi.org/10.1039/C1EE01795K
  30. D. Wang, D. Choi, Z. Yang, V.V. Viswanathan, Z. Nie et al., Synthesis and Li-ion insertion properties of highly crystalline mesoporous rutile TiO2. Chem. Mater. 20(10), 3435–3442 (2008). https://doi.org/10.1021/cm8002589
  31. X. Li, G. Wu, X. Liu, W. Li, M. Li, Orderly integration of porous TiO2(B) nanosheets into bunchy hierarchical structure for high-rate and ultralong-lifespan lithium-ion batteries. Nano Energy 31, 1–8 (2017). https://doi.org/10.1016/j.nanoen.2016.11.002
  32. A.S. Poyraz, C.H. Kuo, S. Biswas, C.K. King’ondu, S.L. Suib, A general approach to crystalline and monomodal pore size mesoporous materials. Nat. Commun. 4, 2952 (2013). https://doi.org/10.1038/ncomms3952
  33. D. Feng, T.-N. Gao, M. Fan, A. Li, K. Li, T. Wang, Q. Huo, Z.-A. Qiao, A general ligand-assisted self-assembly approach to crystalline mesoporous metal oxides. NPG Asia Mater. 10, 800–809 (2018). https://doi.org/10.1038/s41427-018-0072-z
  34. L. Zhang, H. Dai, Y. Xia, H. Jiang, H. Zhang, H. He, Ultrasound-assisted nanocasting fabrication of ordered mesoporous MnO2 and Co3O4 with high surface areas and polycrystalline walls. J. Phys. Chem. C 114(6), 2694–2700 (2010). https://doi.org/10.1021/jp910159b
  35. X. Zhou, Y. Zhu, W. Luo, Y. Ren, P. Xu et al., Chelation-assisted soft-template synthesis of ordered mesoporous zinc oxides for low concentration gas sensing. J. Mater. Chem. A 4(39), 15064–15071 (2016). https://doi.org/10.1039/c6ta05687c
  36. P. Kar, S. Sardar, S. Ghosh, M.R. Parida, B. Liu, O.F. Mohammed, P. Lemmens, S.K. Pal, Nano surface engineering of Mn2O3 for potential light-harvesting application. J. Mater. Chem. C 3(31), 8200–8211 (2015). https://doi.org/10.1039/C5TC01475A
  37. M.S. Kolathodi, S.N. Hanumantha Rao, T.S. Natarajan, G. Singh, Beaded manganese oxide (Mn2O3) nanofibers: preparation and application for capacitive energy storage. J. Mater. Chem. A 4(20), 7883–7891 (2016). https://doi.org/10.1039/C6TA01948J
  38. D. Ji, H. Zhou, J. Zhang, Y. Dan, H. Yang, A. Yuan, Facile synthesis of a metal–organic framework-derived Mn2O3 nanowire coated three-dimensional graphene network for high-performance freestanding supercapacitor electrodes. J. Mater. Chem. A 4(21), 8283–8290 (2016). https://doi.org/10.1039/c6ta01377e
  39. K. Möller, J. Kobler, T. Bein, Colloidal suspensions of nanometer-sized mesoporous silica. Adv. Funct. Mater. 17(4), 605–612 (2007). https://doi.org/10.1002/adfm.200600578
  40. S.D. Han, S. Kim, D. Li, V. Petkov, H.D. Yoo et al., Mechanism of Zn insertion into nanostructured δ-MnO2: a nonaqueous rechargeable Zn metal battery. Chem. Mater. 29(11), 4874–4884 (2017). https://doi.org/10.1021/acs.chemmater.7b00852
  41. S. Islam, M.H. Alfaruqi, V. Mathew, J. Song, S. Kim et al., Facile synthesis and the exploration of the zinc storage mechanism of β-MnO2 nanorods with exposed (101) planes as a novel cathode material for high performance eco-friendly zinc-ion batteries. J. Mater. Chem. A 5(44), 23299–23309 (2017). https://doi.org/10.1039/c7ta07170a
  42. W. Sun, F. Wang, S. Hou, C. Yang, X. Fan et al., Zn/MnO2 battery chemistry with H+ and Zn2+ coinsertion. J. Am. Chem. Soc. 139(29), 9775–9778 (2017). https://doi.org/10.1021/jacs.7b04471
  43. B. Tang, G. Fang, J. Zhou, L. Wang, Y. Lei et al., Potassium vanadates with stable structure and fast ion diffusion channel as cathode for rechargeable aqueous zinc-ion batteries. Nano Energy 51, 579–587 (2018). https://doi.org/10.1016/j.nanoen.2018.07.014
  44. L. Ma, S. Chen, H. Li, Z. Ruan, Z. Tang et al., Initiating a mild aqueous electrolyte Co3O4/Zn battery with 2.2 V-high voltage and 5000-cycle lifespan by a Co(III) rich-electrode. Energy Environ. Sci. 11(9), 2521–2530 (2018). https://doi.org/10.1039/C8EE01415A
  45. Z. Guo, Y. Ma, X. Dong, J. Huang, Y. Wang, Y. Xia, An environmentally friendly and flexible aqueous zinc battery using an organic cathode. Angew. Chem. Int. Ed. 57(36), 11737–11741 (2018). https://doi.org/10.1002/anie.201807121
  46. C. Pan, R.G. Nuzzo, A.A. Gewirth, ZnAlxCo2−xO4 spinels as cathode materials for non-aqueous Zn batteries with an open circuit voltage of ≤ 2 V. Chem. Mater. 29(21), 9351–9359 (2017). https://doi.org/10.1021/acs.chemmater.7b03340
  47. B. Sambandam, V. Soundharrajan, S. Kim, M.H. Alfaruqi, J. Jo et al., Aqueous rechargeable Zn-ion batteries: an imperishable and high-energy Zn2V2O7 nanowire cathode through intercalation regulation. J. Mater. Chem. A 6(9), 3850–3856 (2018). https://doi.org/10.1039/c7ta11237h
  48. W. Li, K. Wang, S. Cheng, K. Jiang, A long-life aqueous Zn-ion battery based on Na3V2(PO4)2F3 cathode. Energy Storage Mater. 15, 14–21 (2018). https://doi.org/10.1016/j.ensm.2018.03.003
  49. F. Ming, H. Liang, Y. Lei, S. Kandambeth, M. Eddaoudi, H.N. Alshareef, Layered MgxV2O5·nH2O as cathode material for high-performance aqueous zinc ion batteries. ACS Energy Lett. 3(10), 2602–2609 (2018). https://doi.org/10.1021/acsenergylett.8b01423
Read More
Author biographies are not available.
Download this PDF file
PDF SUPPLEMENTARY MATERIAL
Statistic
Read Counter : 4085 Download : 3080

Most read articles by the same author(s)