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Vol. 13 (2021)

High Rate and Long Lifespan Sodium-Organic Batteries Using Pseudocapacitive Porphyrin Complexes-Based Cathode

https://doi.org/10.1007/s40820-021-00593-8
Xi Chen
Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, Key Laboratory for Green Organic Synthesis and Application of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China
Xin Feng
Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, Key Laboratory for Green Organic Synthesis and Application of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China
Bo Ren
Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, Key Laboratory for Green Organic Synthesis and Application of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China
Liangzhu Jiang
Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, Key Laboratory for Green Organic Synthesis and Application of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China
Hongbo Shu
Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, Key Laboratory for Green Organic Synthesis and Application of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China
Xiukang Yang
Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, Key Laboratory for Green Organic Synthesis and Application of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China
Zhi Chen
International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education, Institute of Microscale Optoelectronics, College of Chemistry and Enviromental Engineering, Shenzhen University, Shenzhen 518060, People’s Republic of China
Xiujuan Sun
Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, Key Laboratory for Green Organic Synthesis and Application of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China
Enhui Liu
Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, Key Laboratory for Green Organic Synthesis and Application of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China
Ping Gao
Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, Key Laboratory for Green Organic Synthesis and Application of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China

Corresponding Author: Ping Gao

ping.gao@xtu.edu.cn

Nano-Micro Letters, Vol. 13 (2021), Article Number: 71

Abstract

Sodium-organic batteries utilizing natural abundance of sodium element and renewable active materials gain great attentions for grid-scale applications. However, the development is still limited by lack of suitable organic cathode materials with high electronic conductivity that can be operated stably in liquid electrolyte. Herein, we present 5,15-bis(ethynyl)-10,20-diphenylporphyrin (DEPP) and [5,15-bis(ethynyl)-10,20-diphenylporphinato]copper(II) (CuDEPP) as new cathodes for extremely stable sodium-organic batteries. The copper(II) ion partially contributes the charge storage and significantly stabilizes the structure of porphyrin complex for electrochemical energy storage. In situ electrochemical stabilization of organic cathode with a lower charging current density was identified which enables both improved high energy density and power density. An excellent long-term cycling stability up to 600 cycles and an extremely high power density of 28 kW kg−1 were achieved for porphyrin-based cathode. This observation would open new pathway for developing highly stable sodium-organic cathode for electrochemical energy storage.


Highlights:


1 Functionalized porphyrin complexes are proposed as new pseudocapacitive cathodes for SIBs based on four-electron transfer.
2 The presence of copper(II) ion partially contributes the charge storage and significantly stabilizes the structure of porphyrin complex for electrochemical energy storage.
3 The electrochemical polymerization of porphyrin complex through the ethynyl groups in self-stabilization process contributes to high rate capability and excellent cycling stability.

Keywords

Organic cathode Sodium-organic batteries Porphyrin complex Rechargeable batteries Pseudocapacitive effect
Chen, Xi, Xin Feng, Bo Ren, Liangzhu Jiang, Hongbo Shu, Xiukang Yang, Zhi Chen, Xiujuan Sun, Enhui Liu, and Ping Gao. 2021. “High Rate and Long Lifespan Sodium-Organic Batteries Using Pseudocapacitive Porphyrin Complexes-Based Cathode”. Nano-Micro Letters 13 (February):71. https://doi.org/10.1007/s40820-021-00593-8.
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References
  1. S.-W. Kim, D.-H. Seo, X. Ma, G. Ceder, K. Kang, Electrode materials for rechargeable sodium-ion batteries: potential alternatives to current lithium-ion batteries. Adv. Energy Mater. 2(7), 710–721 (2012). https://doi.org/10.1002/aenm.201200026
  2. M.D. Slater, D. Kim, E. Lee, C.S. Johnson, Sodium-ion batteries. Adv. Funct. Mater. 23(8), 947–958 (2013). https://doi.org/10.1002/adfm.201200691
  3. W. Deng, X. Liang, X. Wu, J. Qian, Y. Cao et al., A low cost, all-organic Na-ion battery based on polymeric cathode and anode. Sci. Rep. 3(1), 2671 (2013). https://doi.org/10.1038/srep02671
  4. J. Qian, X. Wu, Y. Cao, X. Ai, H. Yang, High capacity and rate capability of amorphous phosphorus for sodium ion batteries. Angew. Chem. Int. Ed. 52(17), 4633–4636 (2013). https://doi.org/10.1002/anie.201209689
  5. X. Xiang, K. Zhang, J. Chen, Recent advances and prospects of cathode materials for sodium-ion batteries. Adv. Mater. 27(36), 5343–5364 (2015). https://doi.org/10.1002/adma.201501527
  6. H. Kim, H. Kim, Z. Ding, M.H. Lee, K. Lim et al., Recent progress in electrode materials for sodium-ion batteries. Adv. Energy Mater. 6(19), 1600943 (2016). https://doi.org/10.1002/aenm.201600943
  7. N. Yabuuchi, M. Kajiyama, J. Iwatate, H. Nishikawa, S. Hitomi et al., P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries. Nat. Mater. 11(6), 512–517 (2012). https://doi.org/10.1038/nmat3309
  8. C. Zhu, K. Song, P.A. van Aken, J. Maier, Y. Yu, Carbon-coated Na3V2(PO4)3 embedded in porous carbon matrix: an ultrafast Na-storage cathode with the potential of outperforming Li cathodes. Nano Lett. 14(4), 2175–2180 (2014). https://doi.org/10.1021/nl500548a
  9. S. Guo, H. Yu, Z. Jian, P. Liu, Y. Zhu et al., A high-capacity, low-cost layered sodium manganese oxide material as cathode for sodium-ion batteries. Chemsuschem 7(8), 2115–2119 (2014). https://doi.org/10.1002/cssc.201402138
  10. J. Billaud, R.J. Clément, A.R. Armstrong, J. Canales-Vázquez, P. Rozier et al., β-NaMnO2: a high-performance cathode for sodium-ion batteries. J. Am. Chem. Soc. 136(49), 17243–17248 (2014). https://doi.org/10.1021/ja509704t
  11. D. Su, C. Wang, H.J. Ahn, G. Wang, Single crystalline Na0.7MnO2 nanoplates as cathode materials for sodium-ion batteries with enhanced performance. Chemistry 19(33), 10884–10889 (2013). https://doi.org/10.1002/chem.201301563
  12. S.-M. Oh, S.-T. Myung, J. Hassoun, B. Scrosati, Y.-K. Sun, Reversible NaFePO4 electrode for sodium secondary batteries. Electrochem. Commun. 22, 149–152 (2012). https://doi.org/10.1016/j.elecom.2012.06.014
  13. A. Sun, F.R. Beck, D. Haynes, J.A. Poston, S.R. Narayanan et al., Synthesis, characterization, and electrochemical studies of chemically synthesized NaFePO4. Mater. Sci. Engin. B 177(20), 1729–1733 (2012). https://doi.org/10.1016/j.mseb.2012.08.004
  14. D. Kundu, E. Talaie, V. Duffort, L.F. Nazar, The emerging chemistry of sodium ion batteries for electrochemical energy storage. Angew. Chem. Int. Ed. 54(11), 3431–3448 (2015). https://doi.org/10.1002/anie.201410376
  15. T. Sun, Z.-J. Li, H.-G. Wang, D. Bao, F.-L. Meng et al., A biodegradable polydopamine-derived electrode material for high-capacity and long-life lithium-ion and sodium-ion batteries. Angew. Chem. Int. Ed. 55(36), 10662–10666 (2016). https://doi.org/10.1002/anie.201604519
  16. M. Lee, J. Hong, J. Lopez, Y. Sun, D. Feng et al., High-performance sodium–organic battery by realizing four-sodium storage in disodium rhodizonate. Nat. Energy 2(11), 861–868 (2017). https://doi.org/10.1038/s41560-017-0014-y
  17. K. Sakaushi, E. Hosono, G. Nickerl, T. Gemming, H. Zhou et al., Aromatic porous-honeycomb electrodes for a sodium-organic energy storage device. Nat. Commun. 4, 1485 (2013). https://doi.org/10.1038/ncomms2481
  18. M.S. Kim, W.J. Lee, S.M. Paek, J.K. Park, Covalent organic nanosheets as effective sodium-ion storage materials. ACS Appl. Mater. Interfaces 10(38), 32102–32111 (2018). https://doi.org/10.1021/acsami.8b09546
  19. F. Wang, Z. Liu, C. Yang, H. Zhong, G. Nam et al., Fully conjugated phthalocyanine copper metal-organic frameworks for sodium-iodine batteries with long-time-cycling durability. Adv. Mater. 32(4), e1905361 (2020). https://doi.org/10.1002/adma.201905361
  20. Z. Luo, L. Liu, Q. Zhao, F. Li, J. Chen, An insoluble benzoquinone-based organic cathode for use in rechargeable lithium-ion batteries. Angew. Chem. Int. Ed. 56(41), 12561–12565 (2017). https://doi.org/10.1002/anie.201706604
  21. H. Kim, J.E. Kwon, B. Lee, J. Hong, M. Lee et al., High energy organic cathode for sodium rechargeable batteries. Chem. Mater. 27(21), 7258–7264 (2015). https://doi.org/10.1021/acs.chemmater.5b02569
  22. Q. Zhao, Y. Lu, J. Chen, Advanced organic electrode materials for rechargeable sodium-ion batteries. Adv. Energy Mater. 7(8), 1601792 (2017). https://doi.org/10.1002/aenm.201601792
  23. M. Tang, S. Zhu, Z. Liu, C. Jiang, Y. Wu et al., Tailoring π-conjugated systems: From π-π stacking to high-rate-performance organic cathodes. Chem 4(11), 2600–2614 (2018). https://doi.org/10.1016/j.chempr.2018.08.014
  24. Z. Song, Y. Qian, T. Zhang, M. Otani, H. Zhou, Poly (benzoquinonyl sulfide) as a high-energy organic cathode for rechargeable Li and Na batteries. Adv Sci. 2(9), 1500124 (2015). https://doi.org/10.1002/advs.201500124
  25. S.H. Kang, M.J. Jeong, Y.K. Eom, I.T. Choi, S.M. Kwon et al., Porphyrin sensitizers with donor structural engineering for superior performance dye-sensitized solar cells and tandem solar cells for water splitting applications. Adv. Energy Mater. 7(7), 1602117 (2017). https://doi.org/10.1002/aenm.201602117
  26. S.N. Habisreutinger, L. Schmidt-Mende, J.K. Stolarczyk, Photocatalytic reduction of CO2 on TiO2 and other semiconductors. Angew. Chem. Int. Ed. 52(29), 7372–7408 (2013). https://doi.org/10.1002/anie.201207199
  27. J. Min Park, J.H. Lee, W.-D. Jang, Applications of porphyrins in emerging energy conversion technologies. Coord. Chem. Rev. 407, 213157 (2020). https://doi.org/10.1016/j.ccr.2019.213157
  28. K. Jeong, J.M. Kim, S.H. Kim, G.Y. Jung, J. Yoo et al., Carbon-nanotube-cored cobalt porphyrin as a 1D nanohybrid strategy for high-performance lithium-ion battery anodes. Adv. Funct. Mater. 29(24), 1806937 (2019). https://doi.org/10.1002/adfm.201806937
  29. J.-Y. Shin, T. Yamada, H. Yoshikawa, K. Awaga, H. Shinokubo, An antiaromatic electrode-active material enabling high capacity and stable performance of rechargeable batteries. Angew. Chem. Int. Ed. 53(12), 3096–3101 (2014). https://doi.org/10.1002/anie.201310374
  30. P. Gao, Z. Chen, Z. Zhao-Karger, J.E. Mueller, C. Jung et al., A porphyrin complex as a self-conditioned electrode material for high-performance energy storage. Angew. Chem. Int. Ed. 56(35), 10341–10346 (2017). https://doi.org/10.1002/anie.201702805
  31. L. Sun, J. Xie, Z. Chen, J. Wu, L. Li, Reversible lithium storage in a porphyrin-based MOF (PCN-600) with exceptionally high capacity and stability. Dalton Trans. 47(30), 9989–9993 (2018). https://doi.org/10.1039/C8DT02161A
  32. Z. Chen, P. Gao, W. Wang, S. Klyatskaya, Z. Zhao-Karger et al., A lithium-free energy-storage device based on an alkyne-substituted-porphyrin complex. Chemsuschem 12(16), 3737–3741 (2019). https://doi.org/10.1002/cssc.201901541
  33. H. Wu, J. Zhang, X. Du, M. Zhang, J. Yang et al., A large π-conjugated tetrakis (4-carboxyphenyl) porphyrin anode enables high specific capacity and superior cycling stability in lithium-ion batteries. Chem. Commun. 55(76), 11370–11373 (2019). https://doi.org/10.1039/c9cc05474j
  34. H. Yang, S. Zhang, L. Han, Z. Zhang, Z. Xue et al., High conductive two-dimensional covalent organic framework for lithium storage with large capacity. ACS Appl. Mater. Interfaces 8(8), 5366–5375 (2016). https://doi.org/10.1021/acsami.5b12370
  35. H. Liao, H. Wang, H. Ding, X. Meng, H. Xu et al., A 2D porous porphyrin-based covalent organic framework for sulfur storage in lithium–sulfur batteries. J. Mater. Chem. A 4(19), 7416–7421 (2016). https://doi.org/10.1039/C6TA00483K
  36. B.Q. Li, S.Y. Zhang, L. Kong, H.J. Peng, Q. Zhang, Porphyrin organic framework hollow spheres and their applications in lithium-sulfur batteries. Adv. Mater. 30(23), e1707483 (2018). https://doi.org/10.1002/adma.201707483
  37. X. Hu, J. Jian, Z. Fang, L. Zhong, Z. Yuan et al., Hierarchical assemblies of conjugated ultrathin COF nanosheets for high-sulfur-loading and long-lifespan lithium–sulfur batteries: fully-exposed porphyrin matters. Energy Storage Mater. 22, 40–47 (2019). https://doi.org/10.1016/j.ensm.2018.12.021
  38. N.A. Kumar, R.R. Gaddam, M. Suresh, S.R. Varanasi, D. Yang et al., Porphyrin-graphene oxide frameworks for long life sodium ion batteries. J. Mater. Chem. A 5(25), 13204–13211 (2017). https://doi.org/10.1039/C7TA02370G
  39. F.-Z. Cui, Z. Liu, D.-L. Ma, L. Liu, T. Huang et al., Polyarylimide and porphyrin based polymer microspheres for zinc ion hybrid capacitors. Chem. Eng. J. 405, 127038 (2021). https://doi.org/10.1016/j.cej.2020.127038
  40. T. Ma, Z. Pan, L. Miao, C. Chen, M. Han et al., Porphyrin-based symmetric redox-flow batteries towards cold-climate energy storage. Angew. Chem. Int. Ed. 57(12), 3158–3162 (2018). https://doi.org/10.1002/anie.201713423
  41. H. Zhang, Y. Zhang, C. Gu, Y. Ma, Electropolymerized conjugated microporous poly(zinc-porphyrin) films as potential electrode materials in supercapacitors. Adv. Energy. Mater. 5(10), 1402175 (2015). https://doi.org/10.1002/aenm.201402175
  42. F. Xu, H. Xu, X. Chen, D. Wu, Y. Wu et al., Radical covalent organic frameworks: a general strategy to immobilize open-accessible polyradicals for high-performance capacitive energy storage. Angew. Chem. Int. Ed. 54(23), 6814–6818 (2015). https://doi.org/10.1002/anie.201501706
  43. M.-S. Liao, S. Scheiner, Electronic structure and bonding in metal porphyrins, metal=Fe Co, Ni, Cu. Zn. J. Chem. Phys. 117(1), 205–219 (2002). https://doi.org/10.1063/1.1480872
  44. P.K. Sonkar, K. Prakash, M. Yadav, V. Ganesan, M. Sankar et al., Co(2)-porphyrin-decorated carbon nanotubes as catalysts for oxygen reduction reactions: an approach for fuel cell improvement. J. Mater. Chem. A 5(13), 6263–6276 (2017). https://doi.org/10.1039/c6ta10482g
  45. J. Yuan, B. Ren, X. Feng, P. Gao, E. Liu et al., A coupled polymeric porphyrin complex as a novel cathode for highly stable lithium organic batteries. Chem. Commun. 56(40), 5437–5440 (2020). https://doi.org/10.1039/C9CC09846A
  46. M. Sathiya, G. Rousse, K. Ramesha, C.P. Laisa, H. Vezin et al., Reversible anionic redox chemistry in high-capacity layered-oxide electrodes. Nat. Mater. 12(9), 827–835 (2013). https://doi.org/10.1038/nmat3699
  47. Y. Xie, M. Saubanère, M.L. Doublet, Requirements for reversible extra-capacity in Li-rich layered oxides for Li-ion batteries. Energy Environ. Sci. 10(1), 266–274 (2017). https://doi.org/10.1039/C6EE02328B
  48. B. Li, Y. Wang, N. Jiang, L. An, J. Song et al., Electrolytic-anion-redox adsorption pseudocapacitance in nanosized lithium-free transition metal oxides as cathode materials for Li-ion batteries. Nano Energy 72, 104727 (2020). https://doi.org/10.1016/j.nanoen.2020.104727
  49. Z. Zhang, H. Yoshikawa, K. Awaga, Discovery of a “bipolar charging” mechanism in the solid-state electrochemical process of a flexible metal-organic framework. Chem. Mater. 28(5), 1298–1303 (2016). https://doi.org/10.1021/acs.chemmater.5b04075
  50. V. Augustyn, P. Simon, B. Dunn, Pseudocapacitive oxide materials for high-rate electrochemical energy storage. Energy Environ. Sci. 7(5), 1597–1614 (2014). https://doi.org/10.1039/C3EE44164D
  51. H. Lindström, S. Södergren, A. Solbrand, H. Rensmo, J. Hjelm et al., Li+ ion insertion in TiO2 (Anatase). 2. Voltammetry on nanoporous films. J. Phys. Chem. B 101(39), 7717–7722 (1997). https://doi.org/10.1021/jp970490q
  52. Y. Ma, X. Dong, Y. Wang, Y. Xia, Decoupling hydrogen and oxygen production in acidic water electrolysis using a polytriphenylamine-based battery electrode. Angew. Chem. Int. Ed. 57(11), 2904–2908 (2018). https://doi.org/10.1002/anie.201800436
  53. Q. Wei, Y. Jiang, X. Qian, L. Zhang, Q. Li et al., Sodium ion capacitor using pseudocapacitive layered ferric vanadate nanosheets cathode. iScience 6, 212–221 (2018). https://doi.org/10.1016/j.isci.2018.07.020
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