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Vol. 15 (2023)

Bending Resistance Covalent Organic Framework Superlattice: “Nano-Hourglass”-Induced Charge Accumulation for Flexible In-Plane Micro-Supercapacitors

https://doi.org/10.1007/s40820-022-00997-0
Xiaoyang Xu
College of Chemistry and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, People’s Republic of China
Zhenni Zhang
College of Chemistry and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, People’s Republic of China
Rui Xiong
College of Chemistry and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, People’s Republic of China
Guandan Lu
College of Chemistry and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, People’s Republic of China
Jia Zhang
College of Chemistry and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, People’s Republic of China
Wang Ning
College of Chemistry and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, People’s Republic of China
Shuozhen Hu
State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, People’s Republic of China
Qingliang Feng
School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi’an 710072, People’s Republic of China
Shanlin Qiao
College of Chemistry and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, People’s Republic of China

Corresponding Author: Shanlin Qiao

ccpeslqiao@hebust.edu.cn

Nano-Micro Letters, Vol. 15 (2023), Article Number: 25

Abstract

Covalent organic framework (COF) film with highly exposed active sites is considered as the promising flexible self-supported electrode for in-plane micro-supercapacitor (MSC). Superlattice configuration assembled alternately by different nanofilms based on van der Waals force can integrate the advantages of each isolated layer to exhibit unexpected performances as MSC film electrodes, which may be a novel option to ensure energy output. Herein, a mesoporous free-standing A-COF nanofilm (pore size is 3.9 nm, averaged thickness is 4.1 nm) with imine bond linkage and a microporous B-COF nanofilm (pore size is 1.5 nm, averaged thickness is 9.3 nm) with β-keto-enamine-linkages are prepared, and for the first time, we assembly the two lattice matching films into sandwich-type superlattices via layer-by-layer transfer, in which ABA–COF superlattice stacking into a “nano-hourglass” steric configuration that can accelerate the dynamic charge transportation/accumulation and promote the sufficient redox reactions to energy storage. The fabricated flexible MSC–ABA–COF exhibits the highest intrinsic CV of 927.9 F cm−3 at 10 mV s−1 than reported two-dimensional alloy, graphite-like carbon and undoped COF-based MSC devices so far, and shows a bending-resistant energy density of 63.2 mWh cm−3 even after high-angle and repeat arbitrary bending from 0 to 180°. This work provides a feasible way to meet the demand for future miniaturization and wearable electronics.


Highlights:


1 Covalent organic framework (COF) superlattices were assembled by free-standing COF nanofilms based on the van der Waals force for the first time.
2 Geometry-induced “nano-hourglass” steric configuration in COF superlattice can provide rapid charge transfer/accumulation at heterojunction interface for in-Plane Micro-supercapacitors.
3 The prepared MSC exhibited a high energy density of 63.2 mWh cm−3 even after high-angle and repeat arbitrary bending from 0 to 180°.

Keywords

In-plane micro-supercapacitor Covalent organic framework Free-standing nanofilm Superlattice Bending resistance
Xu, Xiaoyang, Zhenni Zhang, Rui Xiong, Guandan Lu, Jia Zhang, Wang Ning, Shuozhen Hu, Qingliang Feng, and Shanlin Qiao. 2022. “Bending Resistance Covalent Organic Framework Superlattice: ‘Nano-Hourglass’-Induced Charge Accumulation for Flexible In-Plane Micro-Supercapacitors”. Nano-Micro Letters 15 (December):25. https://doi.org/10.1007/s40820-022-00997-0.
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