Issue

Vol. 15 (2023)

Etching-Induced Surface Reconstruction of NiMoO4 for Oxygen Evolution Reaction

https://doi.org/10.1007/s40820-022-01011-3
Jinli Zhu
Key Laboratory for Magnetism and Magnetic Materials of MOE, Key Laboratory of Special Function Materials and Structure Design of MOE, Lanzhou University, Lanzhou 730000, People’s Republic of China
Jinmei Qian
Key Laboratory for Magnetism and Magnetic Materials of MOE, Key Laboratory of Special Function Materials and Structure Design of MOE, Lanzhou University, Lanzhou 730000, People’s Republic of China
Xuebing Peng
Key Laboratory for Magnetism and Magnetic Materials of MOE, Key Laboratory of Special Function Materials and Structure Design of MOE, Lanzhou University, Lanzhou 730000, People’s Republic of China
Baori Xia
Key Laboratory for Magnetism and Magnetic Materials of MOE, Key Laboratory of Special Function Materials and Structure Design of MOE, Lanzhou University, Lanzhou 730000, People’s Republic of China
Daqiang Gao
Key Laboratory for Magnetism and Magnetic Materials of MOE, Key Laboratory of Special Function Materials and Structure Design of MOE, Lanzhou University, Lanzhou 730000, People’s Republic of China

Corresponding Author: Daqiang Gao

gaodq@lzu.edu.cn

Nano-Micro Letters, Vol. 15 (2023), Article Number: 30

Abstract

Rational reconstruction of oxygen evolution reaction (OER) pre-catalysts and performance index of OER catalysts are crucial but still challenging for universal water electrolysis. Herein, we develop a double-cation etching strategy to tailor the electronic structure of NiMoO4, where the prepared NiMoO4 nanorods etched by H2O2 reconstruct their surface with abundant cation deficiencies and lattice distortion. Calculation results reveal that the double cation deficiencies can make the upshift of d-band center for Ni atoms and the active sites with better oxygen adsorption capacity. As a result, the optimized sample (NMO-30M) possesses an overpotential of 260 mV at 10 mA cm−2 and excellent long-term durability of 162 h. Importantly, in situ Raman test reveals the rapid formation of high-oxidation-state transition metal hydroxide species, which can further help to improve the catalytic activity of NiMoO4 in OER. This work highlights the influence of surface remodification and shed some light on activating catalysts.


Highlights:


1 Double-cation etching induces abundant vacancies serving as active sites and accelerates the surface reconstruction.
2 NMO-30M with cation deficiencies and oxygen vacancies exhibits outstanding OER performance and remarkable stability.
3 In situ Raman spectroscopy directly captures the surface reconstruction process.

Keywords

Etching Surface reconstruction Cation deficiencies OER
Zhu, Jinli, Jinmei Qian, Xuebing Peng, Baori Xia, and Daqiang Gao. 2023. “Etching-Induced Surface Reconstruction of NiMoO4 for Oxygen Evolution Reaction”. Nano-Micro Letters 15 (January):30. https://doi.org/10.1007/s40820-022-01011-3.
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. J.A. Turner, Sustainable hydrogen production. Science 305(5686), 972–974 (2004). https://doi.org/10.1126/science.1103197
  2. J.W. Ager, A.A. Lapkin, Chemical storage of renewable energy. Science 360(6390), 707–708 (2018). https://doi.org/10.1126/science.aat7918
  3. P. de Luna, C. Hahn, D.C. Higgins, S.A. Jaffer, T.F. Jaramillo et al., What would it take for renewably powered electrosynthesis to displace petrochemical processes? Science 364(6438), eaav3506 (2019). https://doi.org/10.1126/science.aav3506
  4. A. Buttler, H. Spliethoff, Current status of water electrolysis for energy storage, grid balancing and sector coupling via power-to-gas and power-to-liquids: a review. Renew. Sustain. Energy Rev. 82(3), 2440–2454 (2018). https://doi.org/10.1016/j.rser.2017.09.003
  5. V.R. Stamenkovic, D. Strmcnik, P.P. Lopes, N.M. Markovic, Energy and fuels from electrochemical interfaces. Nat. Mater. 16(1), 57–69 (2017). https://doi.org/10.1038/nmat4738
  6. J. Zhang, X. Bai, P. Xi, J. Wang, D. Gao et al., Bimetallic nickel cobalt sulfide as efficient electrocatalyst for Zn–air battery and water splitting. Nano-Micro Lett. 11(1), 1–13 (2019). https://doi.org/10.1007/s40820-018-0232-2
  7. W. Xu, Y. Wang, Recent progress on zinc-ion rechargeable batteries. Nano-Micro Lett. 11(1), 1–30 (2019). https://doi.org/10.1007/s40820-019-0322-9
  8. H. Dotan, A. Landman, S.W. Sheehan, K.D. Malviya, G.E. Shter et al., Decoupled hydrogen and oxygen evolution by a two-step electrochemical–chemical cycle for efficient overall water splitting. Nat. Energy 4(9), 786–795 (2019). https://doi.org/10.1038/s41560-019-0462-7
  9. Q. Wang, M. Nakabayashi, T. Hisatomi, S. Sun, S. Akiyama et al., Oxysulfide photocatalyst for visible-light-driven overall water splitting. Nat. Mater. 18(8), 827–832 (2019). https://doi.org/10.1038/nmat4410
  10. T. Hisatomi, K. Domen, Reaction systems for solar hydrogen production via water splitting with particulate semiconductor photocatalysts. Nat. Catal. 2(5), 387–399 (2019). https://doi.org/10.1038/s41929-019-0242-6
  11. B. Zhang, X. Zheng, O. Voznyy, R. Comin, M. Bajdich et al., Homogeneously dispersed multimetal oxygen-evolving catalysts. Science 352(6283), 333–337 (2016). https://doi.org/10.1126/science.aaf1525
  12. A. Grimaud, A. Demortière, M. Saubanère, W. Dachraoui, M. Duchamp et al., Activation of surface oxygen sites on an iridium-based model catalyst for the oxygen evolution reaction. Nat. Energy 2(16189), 1–10 (2017). https://doi.org/10.1038/nenergy
  13. L. Cao, Q. Luo, J. Chen, L. Wang, Y. Lin et al., Dynamic oxygen adsorption on single-atomic ruthenium catalyst with high performance for acidic oxygen evolution reaction. Nat. Commun. 10(1), 1–9 (2019). https://doi.org/10.1038/s41467-019-12886-z
  14. C. Yang, G. Rousse, K. Louise Svane, P.E. Pearce, A.M. Abakumov et al., Cation insertion to break the activity/stability relationship for highly active oxygen evolution reaction catalyst. Nat. Commun. 11(1), 1–10 (2020). https://doi.org/10.1038/s41467-020-15231-x
  15. J. Li, W. Xu, J. Luo, D. Zhou, D. Yuan et al., Synthesis of 3d hexagram-like cobalt–manganese sulfides nanosheets grown on nickel foam: a bifunctional electrocatalyst for overall water splitting. Nano-Micro Lett. 10(1), 1–10 (2018). https://doi.org/10.1007/s40820-017-0160-6
  16. Z.P. Wu, X.F. Lu, S.Q. Zang, X.W. Lou, Non-noble-metal-based electrocatalysts toward the oxygen evolution reaction. Adv. Funct. Mater. 30(15), 1910274 (2020). https://doi.org/10.1002/adfm.201910274
  17. J.O.M. Bockris, T. Otagawa, Mechanism of oxygen evolution on perovskites. J. Phys. Chem. 87(15), 2960–2971 (2002). https://doi.org/10.1021/j100238a048
  18. X. Zheng, B. Zhang, P. De Luna, Y. Liang, R. Comin et al., Theory-driven design of high-valence metal sites for water oxidation confirmed using in situ soft X-ray absorption. Nat. Chem. 10(2), 149–154 (2018). https://doi.org/10.1038/nchem.2886
  19. H.N. Nong, T. Reier, H.S. Oh, M. Gliech, P. Paciok et al., A unique oxygen ligand environment facilitates water oxidation in hole-doped irniox core–shell electrocatalysts. Nat. Catal. 1(11), 841–851 (2018). https://doi.org/10.1038/s41929-018-0153-y10
  20. Z. Huang, J. Song, S. Dou, X. Li, J. Wang, X. Wang, Strategies to break the scaling relation toward enhanced oxygen electrocatalysis. Matter 1(6), 1494–1518 (2019). https://doi.org/10.1016/j.matt.2019.09.011
  21. Z.W. Seh, J. Kibsgaard, C.F. Dickens, I. Chorkendorff, J.K. Nørskov et al., Combining theory and experiment in electrocatalysis: insights into materials design. Science 355(6321), eaad4998 (2017). https://doi.org/10.1126/science.aad4998
  22. H. Zhang, W. Zhou, J. Dong, X.F. Lu, X.W.D. Lou, Intramolecular electronic coupling in porous iron cobalt (oxy) phosphide nanoboxes enhances the electrocatalytic activity for oxygen evolution. Energy Environ. Sci. 12(11), 3348–3355 (2019). https://doi.org/10.1039/c9ee02787d
  23. Z.W. Gao, J.Y. Liu, X.M. Chen, X.L. Zheng, J. Mao et al., Engineering NiO/NiFe LDH intersection to bypass scaling relationship for oxygen evolution reaction via dynamic tridimensional adsorption of intermediates. Adv. Mater. 31(11), 1804769 (2019). https://doi.org/10.1002/adma.201804769
  24. Z. Cai, D. Zhou, M. Wang, S.M. Bak, Y. Wu et al., Introducing Fe2+ into nickel-iron layered double hydroxide: local structure modulated water oxidation activity. Angew. Chem. Int. Ed. 57(30), 9392–9396 (2018). https://doi.org/10.1002/anie.201804881
  25. P. Zhang, X.F. Lu, J. Nai, S.Q. Zang, X.W. Lou, Construction of hierarchical Co–Fe oxyphosphide microtubes for electrocatalytic overall water splitting. Adv. Sci. 6(17), 1900576 (2019). https://doi.org/10.1002/advs.201900576
  26. S. Jin, Are metal chalcogenides, nitrides, and phosphides oxygen evolution catalysts or bifunctional catalysts? ACS Energy Lett. 2(8), 1937–1938 (2017). https://doi.org/10.1021/acsenergylett.7b00679
  27. X. Liu, K. Ni, B. Wen, R. Guo, C. Niu et al., Deep reconstruction of nickel-based precatalysts for water oxidation catalysis. ACS Energy Lett. 4(11), 2585–2592 (2019). https://doi.org/10.1021/acsenergylett.9b01922
  28. X. Liu, R. Guo, K. Ni, F. Xia, C. Niu et al., Reconstruction-determined alkaline water electrolysis at industrial temperatures. Adv. Mater. 32(40), 2001136 (2020). https://doi.org/10.1002/adma.202001136
  29. J. Chen, Q. Long, K. Xiao, T. Ouyang, Z.-Q. Liu et al., Vertically-interlaced NiFeP/mxene electrocatalyst with tunable electronic structure for high-efficiency oxygen evolution reaction. Sci. Bull. 66(11), 1063–1072 (2021). https://doi.org/10.1016/j.scib.2021.02.033
  30. C. Roy, B. Sebok, S. Scott, E. Fiordaliso, J. Sørensen et al., Impact of nanop size and lattice oxygen on water oxidation on NiFeOxHy. Nat. Catal. 1(11), 820–829 (2018). https://doi.org/10.1038/s41929-018-062-x
  31. H. Jiang, Q. He, X. Li, X. Su, Y. Zhang et al., Tracking structural self-reconstruction and identifying true active sites toward cobalt oxychloride pre-catalyst of oxygen evolution reaction. Adv. Mater. 31(8), 1805127 (2019). https://doi.org/10.1002/adma.201805127
  32. B. Zhang, K. Jiang, H. Wang, S. Hu, Fluoride-induced dynamic surface self-reconstruction produces unexpectedly efficient oxygen-evolution catalyst. Nano Lett. 19(1), 530–537 (2018). https://doi.org/10.1021/acs.nanolett.8b04466
  33. E. Fabbri, M. Nachtegaal, T. Binninger, X. Cheng, B.J. Kim et al., Dynamic surface self-reconstruction is the key of highly active perovskite nano-electrocatalysts for water splitting. Nat. Mater. 16(9), 925–931 (2017). https://doi.org/10.1038/nmat4938
  34. M. Risch, A. Grimaud, K.J. May, K.A. Stoerzinger, T.J. Chen et al., Structural changes of cobalt-based perovskites upon water oxidation investigated by EXAFS. J. Phys. Chem. C 117(17), 8628–8635 (2013). https://doi.org/10.1021/jp3126768
  35. X. Cheng, B.-J. Kim, E. Fabbri, T.J. Schmidt, Co/Fe oxyhydroxides supported on perovskite oxides as oxygen evolution reaction catalyst systems. ACS Appl. Mater. Interfaces 11(38), 34787–34795 (2019). https://doi.org/10.1021/acsami.9b04456
  36. W.K. Han, J.X. Wei, K. Xiao, T. Ouyang, Z.Q. Liu et al., Activating lattice oxygen in layered lithium oxides through cation vacancies for enhanced urea electrolysis. Angew. Chem. Int. Ed. 61(31), e202206050 (2022). https://doi.org/10.1002/anie.202206050
  37. K. Xiao, R.-T. Lin, J.-X. Wei, N. Li, Z.-Q. Liu et al., Electrochemical disproportionation strategy to in-situ fill cation vacancies with Ru single atoms. Nano Res. 15, 4980–4985 (2022). https://doi.org/10.1007/s12274-022-4140-x
  38. B.-J. Kim, E. Fabbri, D.F. Abbott, X. Cheng, A.H. Clark et al., Functional role of Fe-doping in Co-based perovskite oxide catalysts for oxygen evolution reaction. J. Am. Chem. Soc. 141(13), 5231–5240 (2019). https://doi.org/10.1021/jacs.8b12101
  39. W.-K. Han, X.-P. Li, L.-N. Lu, T. Ouyang, Z.-Q. Liu et al., Partial S substitution activates NiMoO4 for efficient and stable electrocatalytic urea oxidation. Chem. Commun. 56(75), 11038–11041 (2020). https://doi.org/10.1039/D0CC03177A
  40. Y. Zhang, C. Chang, H. Gao, S. Wang, J. Yan et al., High-performance supercapacitor electrodes based on NiMoO4 nanorods. J. Mater. Res. 34(14), 2435–2444 (2019). https://doi.org/10.1557/jmr.2019.165
  41. J. Hafner, Ab-initio simulations of materials using VASP: density-functional theory and beyond. J. Comput. Chem. 29(13), 2044–2078 (2008). https://doi.org/10.1002/jcc.21057
  42. J.P. Perdew, K. Burke, M. Ernzerhof, Generalized gradient approximation made simple. Phys. Rev. Lett. 77(18), 3865 (1996). https://doi.org/10.1002/jcc.21057
  43. M. Ernzerhof, G.E. Scuseria, Assessment of the Perdew–Burke–Ernzerhof exchange-correlation functional. J. Chem. Phys. 110(11), 5029–5036 (1999). https://doi.org/10.1063/1.478401
  44. H. Rietveld, Line profiles of neutron powder-diffraction peaks for structure refinement. Acta Crystallogr. 22(1), 151–152 (1967). https://doi.org/10.1107/S0365110X67000234
  45. H.M. Abdel-Dayem, Dynamic phenomena during reduction of α-NiMoO4 in different atmospheres: in-situ thermo-Raman spectroscopy study. Ind. Eng. Chem. Res. 46(8), 2466–2472 (2007). https://doi.org/10.1021/ie0613467
  46. C.G. Barraclough, J. Lewis, R.S. Nyholm, 713. The stretching frequencies of metal–oxygen double bonds. J. Chem. Soc. 0(0), 3552–3555 (1959). https://doi.org/10.1039/JR9590003552
  47. I.E. Wachs, Raman and IR studies of surface metal oxide species on oxide supports: supported metal oxide catalysts. Catal. Today 27(3–4), 437–455 (1996). https://doi.org/10.1016/0920-5861(95)00203-0
  48. D. Wang, H. Li, N. Du, W. Hou, Single platinum atoms immobilized on monolayer tungsten trioxide nanosheets as an efficient electrocatalyst for hydrogen evolution reaction. Adv. Funct. Mater. 31(23), 2009770 (2021). https://doi.org/10.1002/adfm.202009770
  49. J. Zhang, J. Qian, J. Ran, P. Xi, L. Yang et al., Engineering lower coordination atoms onto NiO/Co3O4 heterointerfaces for boosting oxygen evolution reactions. ACS Catal. 10(21), 12376–12384 (2020). https://doi.org/10.1021/acscatal.0c03756
  50. H. Shin, H. Xiao, W.A. Goddard III., In silico discovery of new dopants for Fe-doped Ni oxyhydroxide (Ni1–xFexOOH) catalysts for oxygen evolution reaction. J. Am. Chem. Soc. 140(22), 6745–6748 (2018). https://doi.org/10.1021/jacs.8b02225
  51. Y. Xu, M. Zhou, X. Wang, C. Wang, Y. Lei et al., Enhancement of sodium ion battery performance enabled by oxygen vacancies. Angew. Chem. Int. Ed. 127(30), 8892–8895 (2015). https://doi.org/10.1002/ange.201503477
  52. H. Cheng, T. Kamegawa, K. Mori, H. Yamashita, Surfactant-free nonaqueous synthesis of plasmonic molybdenum oxide nanosheets with enhanced catalytic activity for hydrogen generation from ammonia borane under visible light. Angew. Chem. Int. Ed. 126(11), 2954–2958 (2014). https://doi.org/10.1002/ange.201309759
  53. Y. Tong, P. Chen, M. Zhang, T. Zhou, Y. Xie et al., Oxygen vacancies confined in nickel molybdenum oxide porous nanosheets for promoted electrocatalytic urea oxidation. ACS Catal. 8(1), 1–7 (2018). https://doi.org/10.1021/acscatal.7b03177
  54. L. Zhuang, L. Ge, Y. Yang, M. Li, Z. Zhu et al., Ultrathin iron-cobalt oxide nanosheets with abundant oxygen vacancies for the oxygen evolution reaction. Adv. Mater. 29(17), 1606793 (2017). https://doi.org/10.1002/adma.201606793
  55. J. Bao, X. Zhang, B. Fan, J. Zhang, Y. Xie et al., Ultrathin spinel-structured nanosheets rich in oxygen deficiencies for enhanced electrocatalytic water oxidation. Angew. Chem. Int. Ed. 127(25), 7507–7512 (2015). https://doi.org/10.1002/ange.201502226
  56. M. Amir, H. Gungunes, A. Baykal, M.A. Almessiere, H. Sözeri et al., Effect of annealing temperature on magnetic and mössbauer properties of ZnFe2O4 nanops by sol-gel approach. J. Supercond. Nov. Magn. 31(10), 3347–3356 (2018). https://doi.org/10.1007/s10948-018-4610-2
  57. A. Baykal, S. Guner, H. Gungunes, K. Batoo, M. Amir et al., Magneto optical properties and hyperfine interactions of Cr3+ ion substituted copper ferrite nanops. J. Inorg. Organomet. Polym. 28(6), 2533–2544 (2018). https://doi.org/10.1007/s10904-018-0903-y
  58. C.C. McCrory, S. Jung, J.C. Peters, T.F. Jaramillo, Benchmarking heterogeneous electrocatalysts for the oxygen evolution reaction. J. Am. Chem. Soc. 135(45), 16977–16987 (2013). https://doi.org/10.1021/ja407115p
  59. S. Royer, D. Duprez, F. Can, X. Courtois, C. Batiot-Dupeyrat et al., Perovskites as substitutes of noble metals for heterogeneous catalysis: dream or reality. Chem. Rev. 114(20), 10292–10368 (2014). https://doi.org/10.1021/cr500032a
  60. K.N. Dinh, X. Sun, Z. Dai, Y. Zheng, P. Zheng et al., O2 plasma and cation tuned nickel phosphide nanosheets for highly efficient overall water splitting. Nano Energy 54, 82–90 (2018). https://doi.org/10.1016/j.nanoen.2018.10.004
  61. J. Rossmeisl, Z.-W. Qu, H. Zhu, G.-J. Kroes, J.K. Nørskov, Electrolysis of water on oxide surfaces. J. Electroanal. Chem. 607(1–2), 83–89 (2007). https://doi.org/10.1016/j.jelechem.2006.11.008
  62. Z. Chen, Y. Song, J. Cai, X. Zheng, D. Han et al., Tailoring the d-band centers enables Co4N nanosheets to be highly active for hydrogen evolution catalysis. Angew. Chem. Int. Ed. 130(18), 5170–5174 (2018). https://doi.org/10.1002/anie.201801834
  63. W. Gou, Y. Chen, Y. Zhong, Q. Xue, Y. Ma et al., Phytate-coordinated nickel foam with enriched NiOOH intermediates for 5-hydroxymethylfurfural electrooxidation. Chem. Commun. 58(55), 7626–7629 (2022). https://doi.org/10.1039/d2cc02182j
  64. S.S. Saleem, Infrared and Raman spectroscopic studies of the polymorphic forms of nickel, cobalt and ferric molybdates. Infrared Phys. 27(5), 309–315 (1987). https://doi.org/10.1016/0020-0891(87)90072-8
  65. B. Zhou, Y. Li, Y. Zou, J. Liu, Y. Wang et al., Platinum modulates redox properties and 5-hydroxymethylfurfural adsorption kinetics of Ni (OH)2 for biomass upgrading. Angew. Chem. Int. Ed. 60(42), 22908–22914 (2021). https://doi.org/10.1002/anie.202109211
  66. J. Huang, Y. Li, Y. Zhang, G. Rao, C. Wu et al., Identification of key reversible intermediates in self-reconstructed nickel-based hybrid electrocatalysts for oxygen evolution. Angew. Chem. Int. Ed. 131(48), 17619–17625 (2019). https://doi.org/10.1002/anie.201910716
  67. X. Liu, J. Meng, K. Ni, R. Guo, F. Xia et al., Complete reconstruction of hydrate pre-catalysts for ultrastable water electrolysis in industrial-concentration alkali media. Cell Rep. Phys. Sci. 1(11), 100241 (2020). https://doi.org/10.1016/j.xcrp.2020.100241
  68. Y. Wang, Y. Zhu, S. Zhao, S. She, F. Zhang et al., Anion etching for accessing rapid and deep self-reconstruction of pre-catalysts for water oxidation. Matter 3(6), 2124–2137 (2020). https://doi.org/10.1016/j.matt.2020.09.016
Read More
Author biographies are not available.
Download this PDF file
PDF SUPPLEMENTARY MATERIAL
Statistic
Read Counter : 2337 Download : 1736

Most read articles by the same author(s)