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Vol. 12 (2020)

Bifunctional Oxygen Electrocatalyst of Mesoporous Ni/NiO Nanosheets for Flexible Rechargeable Zn–Air Batteries

https://doi.org/10.1007/s40820-020-0406-6
Peitao Liu
Key Laboratory for Magnetism and Magnetic Materials of MOE, Key Laboratory of Special Function Materials and Structure Design of MOE, Lanzhou University, Lanzhou 730000, People’s Republic of China
Jiaqi Ran
Key Laboratory for Magnetism and Magnetic Materials of MOE, Key Laboratory of Special Function Materials and Structure Design of MOE, Lanzhou University, Lanzhou 730000, People’s Republic of China
Baorui Xia
Key Laboratory for Magnetism and Magnetic Materials of MOE, Key Laboratory of Special Function Materials and Structure Design of MOE, Lanzhou University, Lanzhou 730000, People’s Republic of China
Shibo Xi
Institute of Chemical and Engineering Sciences, A*STAR , 1 Pesek Road, Jurong Island 627833, Singapore
Daqiang Gao
Key Laboratory for Magnetism and Magnetic Materials of MOE, Key Laboratory of Special Function Materials and Structure Design of MOE, Lanzhou University, Lanzhou 730000, People’s Republic of China
John Wang
Department of Material Science and Engineering, National University of Singapore, Engineering Drive 3, Singapore 117575, Singapore

Corresponding Author: Daqiang Gao

gaodq@lzu.edu.cn

Nano-Micro Letters, Vol. 12 (2020), Article Number: 68

Abstract

One approach to accelerate the stagnant kinetics of both the oxygen reduction and evolution reactions (ORR/OER) is to develop a rationally designed multiphase nanocomposite, where the functions arising from each of the constituent phases, their interfaces, and the overall structure are properly controlled. Herein, we successfully synthesized an oxygen electrocatalyst consisting of Ni nanoparticles purposely interpenetrated into mesoporous NiO nanosheets (porous Ni/NiO). Benefiting from the contributions of the Ni and NiO phases, the well-established pore channels for charge transport at the interface between the phases, and the enhanced conductivity due to oxygen-deficiency at the pore edges, the porous Ni/NiO nanosheets show a potential of 1.49 V (10 mA cm−2) for the OER and a half-wave potential of 0.76 V for the ORR, outperforming their noble metal counterparts. More significantly, a Zn–air battery employing the porous Ni/NiO nanosheets exhibits an initial charging–discharging voltage gap of 0.83 V (2 mA cm−2), specific capacity of 853 mAh g−1Zn at 20 mA cm−2, and long-time cycling stability (120 h). In addition, the porous Ni/NiO-based solid-like Zn–air battery shows excellent electrochemical performance and flexibility, illustrating its great potential as a next-generation rechargeable power source for flexible electronics.


Highlights:


1 An oxygen electrocatalyst consisting of Ni nanoparticles interpenetrated in porous NiO nanosheets was successfully synthesized.
2 The liquid Zn–air battery reveals a large open-circuit potential of 1.47 V, the maximum power density at 225 mW cm−2, and excellent device stability of over 120 h.
3 The flexible solid-like rechargeable Zn–air battery shows excellent stability (no evident weakening after 240 cycles) and bendability.

Keywords

Porous Ni/NiO Oxygen reduction reaction Oxygen evolution reaction Electrocatalysis Flexible Zn–air battery
Liu, Peitao, Jiaqi Ran, Baorui Xia, Shibo Xi, Daqiang Gao, and John Wang. 2020. “Bifunctional Oxygen Electrocatalyst of Mesoporous Ni/NiO Nanosheets for Flexible Rechargeable Zn–Air Batteries”. Nano-Micro Letters 12 (March):68. https://doi.org/10.1007/s40820-020-0406-6.
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References
  1. M.A. Green, S.P. Bremner, Energy conversion approaches and materials for high-efficiency photovoltaics. Nat. Mater. 16(1), 23–34 (2016). https://doi.org/10.1038/nmat4676
  2. N. Kittner, F. Lill, D.M. Kammen, Energy storage deployment and innovation for the clean energy transition. Nat. Energy 2(9), 17125 (2017). https://doi.org/10.1038/nenergy.2017.125
  3. B. Hua, M. Li, W. Pang, W. Tang, S. Zhao et al., Activating p-blocking centers in perovskite for efficient water splitting. Chem 4(12), 2902–2916 (2018). https://doi.org/10.1016/j.chempr.2018.09.012
  4. J. Zhang, X. Bai, T. Wang, W. Xiao, P. Xi, J. Wang, Bimetallic nickel cobalt sulfide as efficient electrocatalyst for Zn–air battery and water splitting. Nano-Micro Lett. 11(1), 2 (2019). https://doi.org/10.1007/s40820-018-0232-2
  5. W. Xu, Y. Wang, Recent progress on zinc-ion rechargeable batteries. Nano-Micro Lett. 11(1), 90 (2019). https://doi.org/10.1007/s40820-019-0322-9
  6. G. Fu, Z. Cui, Y. Chen, L. Xu, Y. Tang, J.B. Goodenough, Hierarchically mesoporous nickel–iron nitride as a cost efficient and highly durable electrocatalyst for Zn–air battery. Nano Energy 39, 77–85 (2017). https://doi.org/10.1016/j.nanoen.2017.06.029
  7. J. Fu, F.M. Hassan, J. Li, D.U. Lee, A.R. Ghannoum, G. Lui, M.A. Hoque, Z. Chen, Flexible rechargeable zinc–air batteries through morphological emulation of human hair array. Adv. Mater. 28(30), 6421–6428 (2016). https://doi.org/10.1002/adma.201600762
  8. W. Wan, X. Liu, H. Li, X. Peng, D. Xi, J. Luo, 3D carbon framework-supported CoNi nanoparticles as bifunctional oxygen electrocatalyst for rechargeable Zn–air batteries. Appl. Catal. B Environ. 240, 193–200 (2019). https://doi.org/10.1016/j.apcatb.2018.08.081
  9. D. Yang, L. Zhang, X. Yan, X. Yao, Recent progress in oxygen electrocatalysts for Zinc–air batteries. Small Methods 1(12), 1700209 (2017). https://doi.org/10.1002/smtd.201700209
  10. F. Meng, H. Zhong, D. Bao, J. Yan, X. Zhang, In situ coupling of strung Co4N and intertwined N–C fibers toward free-standing bifunctional cathode for robust, efficient, and flexible Zn–air batteries. J. Am. Chem. Soc. 138(32), 10226–10231 (2016). https://doi.org/10.1021/jacs.6b05046
  11. Y. Cheng, S. Dou, J.P. Veder, S. Wang, M. Saunders, S.P. Jiang, Efficient and durable bifunctional oxygen catalysts based on NiFeO@MnOx core-shell structures for rechargeable Zn–air batteries. ACS Appl. Mater. Interfaces 9(9), 8121–8133 (2017). https://doi.org/10.1021/acsami.6b16180
  12. H. Li, W. Wan, X. Liu, H. Liu, S. Shen, F. Iv, J. Luo, Poplar–catkin–derived N, P co-doped carbon microtubes as efficient oxygen electrocatalysts for Zn–air batteries. ChemElectroChem 5(7), 1113–1119 (2018). https://doi.org/10.1002/celc.201701224
  13. Q. Shao, J. Liu, Q. Wu, Q. Li, H.G. Wang, Y. Li, D. Qian, In situ coupling strategy for anchoring monodisperse Co9S8 nanoparticles on S and N dual-doped graphene as a bifunctional electrocatalyst for rechargeable Zn–air battery. Nano-Micro Lett. 11(1), 4 (2019). https://doi.org/10.1007/s40820-018-0231-3
  14. Z. Qian, Y. Chen, Z. Tang, Z. Liu, X. Wang, Y. Tian, W. Gao, Hollow nanocages of NixCo1−xSe for efficient zinc–air batteries and overall water splitting. Nano-Micro Lett. 11(1), 28 (2019). https://doi.org/10.1007/s40820-019-0258-0
  15. F. Cheng, T. Zhang, Y. Zhang, J. Du, X. Han, J. Chen, Enhancing electrocatalytic oxygen reduction on MnO2 with vacancies. Angew. Chem. Int. Ed. 52(9), 2474–2477 (2013). https://doi.org/10.1002/anie.201208582
  16. X. Chen, C. Zhong, B. Liu, Z. Liu, X. Bi et al., Atomic layer Co3O4 nanosheets: the key to knittable Zn–air batteries. Small 14(43), 1702987 (2018). https://doi.org/10.1002/smll.201702987
  17. P.T. Babar, A.C. Lokhande, M.G. Gang, B.S. Pawar, S.M. Pawar, J.H. Kim, Thermally oxidized porous NiO as an efficient oxygen evolution reaction (OER) electrocatalyst for electrochemical water splitting application. J. Ind. Eng. Chem. 60, 493–497 (2018). https://doi.org/10.1016/j.jiec.2017.11.037
  18. L. Zhuang, L. Ge, Y. Yang, M. Li, Y. Jia, X. Yao, Z. Zhu, Ultrathin iron–cobalt oxide nanosheets with abundant oxygen vacancies for the oxygen evolution reaction. Adv. Mater. 29(17), 1606793 (2017). https://doi.org/10.1002/adma.201606793
  19. K. Fominykh, P. Chernev, I. Zaharieva, J. Sicklinger, G. Stefanic et al., Iron-doped nickel oxide nanocrystals as highly efficient electrocatalysts for alkaline water splitting. ACS Nano 9(5), 5180–5188 (2015). https://doi.org/10.1021/acsnano.5b00520
  20. X. Zou, J. Su, R. Silva, A. Goswami, B.R. Sathe, T. Asefa, Efficient oxygen evolution reaction catalyzed by low-density Ni-doped Co3O4 nanomaterials derived from metal-embedded graphitic C3N4. Chem. Commun. 49(68), 7522–7524 (2013). https://doi.org/10.1039/c3cc42891e
  21. J. Wang, K. Li, H. Zhong, D. Xu, Z. Wang, Z. Jiang, Z. Wu, X. Zhang, Synergistic effect between metal–nitrogen–carbon sheets and NiO nanoparticles for enhanced electrochemical water oxidation performance. Angew. Chem. Int. Ed. 54(36), 10530–10534 (2015). https://doi.org/10.1002/anie.201504358
  22. H. Zhang, Y. Wang, D. Wang, Y. Li, X. Liu et al., Homologous NiO//Ni2P nanoarrays grown on nickel foams: a well matched electrode pair with high stability in overall water splitting. Nanoscale 9(13), 4409–4418 (2017). https://doi.org/10.1039/C6NR07953A
  23. D.H. Guo, R. Shibuya, C. Akiba, S. Saji, T. Kondo, J. Nakamura, Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts. Science 351(6271), 361–365 (2015). https://doi.org/10.1126/science.aad0832
  24. H. Zhang, Y. Wang, D. Wang, Y. Li, X. Liu et al., Hydrothermal transformation of dried grass into graphitic carbon-based high performance electrocatalyst for oxygen reduction reaction. Small 10(16), 3371–3378 (2014). https://doi.org/10.1002/smll.201400781
  25. G. Fu, X. Yan, Y. Chen, L. Xu, D. Sun, J.M. Lee, Y. Tang, Boosting bifunctional oxygen electrocatalysis with 3D graphene aerogel-supported Ni/MnO particles. Adv. Mater. 30(5), 1704609 (2018). https://doi.org/10.1002/adma.201704609
  26. C. Zhu, A.L. Wang, W. Xiao, D. Chao, X. Zhang et al., In situ grown epitaxial heterojunction exhibits high-performance electrocatalytic water splitting. Adv. Mater. 30(13), e1705516 (2018). https://doi.org/10.1002/adma.201705516
  27. L. Lv, D. Zha, Y. Ruan, Z. Li, X. Ao et al., A universal method to engineer metal oxide–metal–carbon interface for highly efficient oxygen reduction. ACS Nano 12(3), 3042–3051 (2018). https://doi.org/10.1021/acsnano.8b01056
  28. Z. Zhuang, Y. Li, Z. Li, F. Lv, Z. Lang et al., MoB/g-C3N4 interface materials as a Schottky catalyst to boost hydrogen evolution. Angew. Chem. Int. Ed. 57(2), 496–500 (2018). https://doi.org/10.1002/anie.201708748
  29. E. Navarro-Flores, Z. Chong, S. Omanovic, Characterization of Ni, NiMo, NiW and NiFe electroactive coatings as electrocatalysts for hydrogen evolution in an acidic medium. J. Mol. Catal. A: Chem. 226(2), 179–197 (2005). https://doi.org/10.1016/j.molcata.2004.10.029
  30. D.S. Hall, C. Bock, B.R. MacDougall, The electrochemistry of metallic nickel: oxides, hydroxides, hydrides and alkaline hydrogen evolution. J. Electrochem. Soc. 160(3), F235–F243 (2013). https://doi.org/10.1149/2.026303jes
  31. M. Gong, W. Zhou, M.C. Tsai, J. Zhou, M. Guan et al., Nanoscale nickel oxide/nickel heterostructures for active hydrogen evolution electrocatalysis. Nat. Commun. 5, 4695–4700 (2015). https://doi.org/10.1038/ncomms5695
  32. Y. Zeng, Y. Meng, Z. Lai, X. Zhang, M. Yu, P. Fang, M. Wu, Y. Tong, X. Lu, An ultrastable and high-performance flexible fiber-shaped Ni–Zn battery based on a Ni–NiO heterostructured nanosheet cathode. Adv. Mater. 29(44), 1702698 (2017). https://doi.org/10.1002/adma.201702698
  33. W. Niu, S. Pakhira, K. Marcus, Z. Li, J.L. Mendoza-Cortes, Y. Yang, Apically dominant mechanism for improving catalytic activities of N-doped carbon nanotube arrays in rechargeable zinc–air battery. Adv. Energy Mater. 8(20), 1800480 (2018). https://doi.org/10.1002/aenm.20180048
  34. Y. Li, C. Zhong, J. Liu, X. Zeng, S. Qu, X. Han, Y. Deng, W. Hu, J. Lu, Atomically thin mesoporous Co3O4 layers strongly coupled with N-rGO nanosheets as high-performance bifunctional catalysts for 1D knittable zinc–air batteries. Adv. Mater. 30(4), 1703657 (2018). https://doi.org/10.1002/adma.201703657
  35. A. Rohrbach, J. Hafner, G. Kresse, Molecular adsorption on the surface of strongly correlated transition-metal oxides: a case study for CO/NiO(100). Phys. Rev. B 69(7), 075413 (2004). https://doi.org/10.1103/PhysRevB.69.075413
  36. S. Park, H.S. Ahn, C.K. Lee, H. Kim, H. Jin, H.S. Lee, S. Seo, J. Yu, S. Han, Interaction and ordering of vacancy defects in NiO. Phys. Rev. B 77(13), 134103 (2008). https://doi.org/10.1103/PhysRevB.77.134103
  37. L. Qiao, X. Wang, L. Qiao, X. Sun, X. Li, Y. Zheng, D. He, Single electrospun porous NiO–ZnO hybrid nanofibers as anode materials for advanced lithium-ion batteries. Nanoscale 5(7), 3037–3042 (2013). https://doi.org/10.1039/c3nr34103h
  38. V.A. Bharathan, R. Jain, C.S. Gopinath, C.P. Vinod, Diverse reactivity trends of Ni surfaces in Au@Ni core–shell nanoparticles probed by near ambient pressure (NAP) XPS. Catal. Sci. Technol. 7(19), 4489–4498 (2017). https://doi.org/10.1039/C7CY01070B
  39. L. Del Bianco, F. Boscherini, M. Tamisari, F. Spizzo, M. Vittori Antisari, E. Piscopiello, Exchange bias and interface structure in the Ni/NiO nanogranular system. J. Phys. D Appl. Phys. 41(13), 134008 (2008). https://doi.org/10.1088/0022-3727/41/13/134008
  40. L. Del Bianco, F. Boscherini, A.L. Fiorini, M. Tamisari, F. Spizzo, M.V. Antisari, E. Piscopiello, Exchange bias and structural disorder in the nanogranular Ni∕NiO system produced by ball milling and hydrogen reduction. Phys. Rev. B 77(9), 094408 (2008). https://doi.org/10.1103/PhysRevB.77.094408
  41. M. Patange, S. Biswas, A.K. Yadav, S.N. Jha, D. Bhattacharyya, Morphology controlled synthesis of monodispersed graphitic carbon coated core/shell structured Ni/NiO nanoparticles with enhanced magnetoresistance. Phys. Chem. Chem. Phys. 17(48), 32398–32412 (2015). https://doi.org/10.1039/C5CP05830A
  42. Uhlenbrockt, C. Scharfschwerdtt, M. Neumannt, G. Illing, H.J. Freund, The influence of defects on the Ni 2p and O 1s XPS of NiO. J. Phys.: Condens. Matter 4, 7973–7978 (1992). https://doi.org/10.1088/0953-8984/4/40/009
  43. M.A. Peck, M.A. Langell, Comparison of nanoscaled and bulk NiO structural and environmental characteristics by XRD, XAFS, and XPS. Chem. Mater. 24(23), 4483–4490 (2012). https://doi.org/10.1021/cm300739y
  44. J. Masa, I. Sinev, H. Mistry, E. Ventosa, M. de la Mata et al., Ultrathin high surface area nickel boride (NixB) nanosheets as highly efficient electrocatalyst for oxygen evolution. Adv. Energy Mater. 7(17), 1700381 (2017). https://doi.org/10.1002/aenm.201700381
  45. D.Q. Gao, G.J. Yang, J.Y. Li, J. Zhang, J.L. Zhang, D.S. Xue, Room-temperature ferromagnetism of flowerlike CuO nanostructures. J. Phys. Chem. C 114(43), 18347–18351 (2010). https://doi.org/10.1021/jp106015t
  46. H. Xu, Z.X. Shi, Y.X. Tong, G.R. Li, Porous microrod arrays constructed by carbon-confined NiCo@NiCoO2 core@shell nanoparticles as efficient electrocatalysts for oxygen evolution. Adv. Mater. 30(21), 1705442 (2018). https://doi.org/10.1002/adma.201705442
  47. K. Fan, H. Chen, Y. Ji, H. Huang, P.M. Claesson et al., Nickel–vanadium monolayer double hydroxide for efficient electrochemical water oxidation. Nat. Commun. 7, 11981 (2016). https://doi.org/10.1038/ncomms11981
  48. X. Liu, W. Xi, C. Li, X. Li, J. Shi et al., Nanoporous Zn-doped Co3O4 sheets with single-unit-cell-wide lateral surfaces for efficient oxygen evolution and water splitting. Nano Energy 44, 371–377 (2018). https://doi.org/10.1016/j.nanoen.2017.12.016
  49. H. Yin, C. Zhang, F. Liu, Y. Hou, Hybrid of iron nitride and nitrogen-doped graphene aerogel as synergistic catalyst for oxygen reduction reaction. Adv. Funct. Mater. 24(20), 2930–2937 (2014). https://doi.org/10.1002/adfm.201303902
  50. M. Zhang, Q. Dai, H. Zheng, M. Chen, L. Dai, Novel MOF-derived Co@N-C bifunctional catalysts for highly efficient Zn–air batteries and water splitting. Adv. Mater. 30(10), 1705431 (2018). https://doi.org/10.1002/adma.201705431
  51. X. Liu, W. Liu, M. Ko, M. Park, M.G. Kim et al., Metal (Ni, Co)-metal oxides/graphene nanocomposites as multifunctional electrocatalysts. Adv. Funct. Mater. 25(36), 5799–5808 (2015). https://doi.org/10.1002/adfm.201502217
  52. B. Chen, X. He, F. Yin, H. Wang, D.-J. Liu, R. Shi, J. Chen, H. Yin, MO-Co@N-doped carbon (M = Zn or Co): vital roles of inactive Zn and highly efficient activity toward oxygen reduction/evolution reactions for rechargeable Zn–air battery. Adv. Funct. Mater. 27(37), 1700795 (2017). https://doi.org/10.1002/adfm.201700795
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