Issue

Vol. 12 (2020)

Nanohollow Carbon for Rechargeable Batteries: Ongoing Progresses and Challenges

https://doi.org/10.1007/s40820-020-00521-2
Jiangmin Jiang
Jiangsu Key Laboratory of Electrochemical Energy Storage Technology, College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, People’s Republic of China
Guangdi Nie
Department of Materials Science and Engineering, National University of Singapore, Singapore 117574, Singapore
Ping Nie
Jiangsu Key Laboratory of Electrochemical Energy Storage Technology, College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, People’s Republic of China
Zhiwei Li
Jiangsu Key Laboratory of Electrochemical Energy Storage Technology, College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, People’s Republic of China
Zhenghui Pan
Department of Materials Science and Engineering, National University of Singapore, Singapore 117574, Singapore
Zongkui Kou
Jiangsu Key Laboratory of Electrochemical Energy Storage Technology, College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, People’s Republic of China
Hui Dou
Jiangsu Key Laboratory of Electrochemical Energy Storage Technology, College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, People’s Republic of China
Xiaogang Zhang
Jiangsu Key Laboratory of Electrochemical Energy Storage Technology, College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, People’s Republic of China
John Wang
Department of Materials Science and Engineering, National University of Singapore, Singapore 117574, Singapore

Corresponding Author: John Wang

msewangj@nus.edu.sg

Nano-Micro Letters, Vol. 12 (2020), Article Number: 183

Abstract

Among the various morphologies of carbon-based materials, hollow carbon nanostructures are of particular interest for energy storage. They have been widely investigated as electrode materials in different types of rechargeable batteries, owing to their high surface areas in association with the high surface-to-volume ratios, controllable pores and pore size distribution, high electrical conductivity, and excellent chemical and mechanical stability, which are beneficial for providing active sites, accelerating electrons/ions transfer, interacting with electrolytes, and giving rise to high specific capacity, rate capability, cycling ability, and overall electrochemical performance. In this overview, we look into the ongoing progresses that are being made with the nanohollow carbon materials, including nanospheres, nanopolyhedrons, and nanofibers, in relation to their applications in the main types of rechargeable batteries. The design and synthesis strategies for them and their electrochemical performance in rechargeable batteries, including lithium-ion batteries, sodium-ion batteries, potassium-ion batteries, and lithium–sulfur batteries are comprehensively reviewed and discussed, together with the challenges being faced and perspectives for them.


Highlights
1 The synthesis strategies of nanohollow carbon materials, including nanospheres, nanopolyhedrons, and nanofibers are summarized.
2 Nanohollow carbon materials used as electrode materials in several types of rechargeable batteries are reviewed.
3 The challenges being faced and perspectives of nanohollow carbon materials are discussed.

Keywords

Hollow carbon nanospheres Nanopolyhedrons and nanofibers Template synthesis Rechargeable batteries Electrochemical performance
Jiang, Jiangmin, Guangdi Nie, Ping Nie, Zhiwei Li, Zhenghui Pan, Zongkui Kou, Hui Dou, Xiaogang Zhang, and John Wang. 2020. “Nanohollow Carbon for Rechargeable Batteries: Ongoing Progresses and Challenges”. Nano-Micro Letters 12 (September):183. https://doi.org/10.1007/s40820-020-00521-2.
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References
  1. B. Hu, K. Wang, L.H. Wu, S.H. Yu, M. Antonietti et al., Engineering carbon materials from the hydrothermal carbonization process of biomass. Adv. Mater. 22(7), 813–828 (2010). https://doi.org/10.1002/adma.200902812
  2. Y. Liu, J. Goebl, Y. Yin, Templated synthesis of nanostructured materials. Chem. Soc. Rev. 42(7), 2610–2653 (2013). https://doi.org/10.1039/C2CS35369E
  3. C. Wang, Y.V. Kaneti, Y. Bando, J. Lin, C. Liu et al., Metal-organic framework-derived one-dimensional porous or hollow carbon-based nanofibers for energy storage and conversion. Mater. Horiz. 5(3), 394–407 (2018). https://doi.org/10.1039/C8MH00133B
  4. J. Jiang, Y. Zhang, P. Nie, G. Xu, M. Shi et al., Progress of nanostructured electrode materials for supercapacitors. Adv. Sustain. Syst. 2(1), 1700110 (2018). https://doi.org/10.1002/adsu.201700110
  5. S. Li, A. Pasc, V. Fierro, A. Celzard, Hollow carbon spheres, synthesis and applications-a review. J. Mater. Chem. A 4(33), 12686–12713 (2016). https://doi.org/10.1039/C6TA03802F
  6. Z. Li, H.B. Wu, X.W.D. Lou, Rational designs and engineering of hollow micro-/nanostructures as sulfur hosts for advanced lithium-sulfur batteries. Energy Environ. Sci. 9(10), 3061–3070 (2016). https://doi.org/10.1039/C6EE02364A
  7. X. Liu, W.H. Lai, S. Chou, The application of hollow micro-/nanostructured cathodes for sodium-ion batteries. Mater. Chem. Front. 4(5), 1289–1303 (2020). https://doi.org/10.1039/C9QM00674E
  8. X. Wang, J. Feng, Y. Bai, Q. Zhang, Y. Yin, Synthesis, properties, and applications of hollow micro-/nanostructures. Chem. Rev. 116(18), 10983–11060 (2016). https://doi.org/10.1021/acs.chemrev.5b00731
  9. Z. Yang, Z. Li, M. Xu, Y. Ma, J. Zhang et al., Controllable synthesis of fluorescent carbon dots and their detection application as nanoprobes. Nano-Micro Lett. 5(4), 247–259 (2013). https://doi.org/10.1007/BF03353756
  10. T. Liu, L. Zhang, B. Cheng, J. Yu, Hollow carbon spheres and their hybrid nanomaterials in electrochemical energy storage. Adv. Energy Mater. 9(17), 1803900 (2019). https://doi.org/10.1002/aenm.201803900
  11. A. Fu, C. Wang, F. Pei, J. Cui, X. Fang et al., Recent advances in hollow porous carbon materials for lithium-sulfur batteries. Small 15(10), 1804786 (2019). https://doi.org/10.1002/smll.201804786
  12. H. Fan, F. Ran, X. Zhang, H. Song, X. Niu et al., Hollow carbon microspheres/MnO2 nanosheets composites: hydrothermal synthesis and electrochemical behaviors. Nano-Micro Lett. 7(1), 59–67 (2015). https://doi.org/10.1007/s40820-014-0019-z
  13. X.L. Ji, A paradigm of storage batteries. Energy Environ. Sci. 12(11), 3203–3224 (2019). https://doi.org/10.1039/c9ee02356a
  14. J. Jiang, Z. Pan, Z. Kou, P. Nie, C. Chen et al., Lithiophilic polymer interphase anchored on laser-punched 3D holey Cu matrix enables uniform lithium nucleation leading to super-stable lithium metal anodes. Energy Storage Mater. 29, 84–91 (2020). https://doi.org/10.1016/j.ensm.2020.04.006
  15. J. Jiang, P. Nie, B. Ding, W. Wu, Z. Chang et al., Effect of graphene modified Cu current collector on the performance of Li4Ti5O12 anode for lithium-ion batteries. ACS Appl. Mater. Interfaces 8(45), 30926–30932 (2016). https://doi.org/10.1021/acsami.6b10038
  16. W. Chen, M. Wan, Q. Liu, X. Xiong, F. Yu et al., Heteroatom-doped carbon materials: synthesis, mechanism, and application for sodium-ion batteries. Small Methods 3(4), 1800323 (2019). https://doi.org/10.1002/smtd.201800323
  17. H. Geng, Y. Peng, L. Qu, H. Zhang, M. Wu, Structure design and composition engineering of carbon-based nanomaterials for lithium energy storage. Adv. Energy Mater. 10(10), 1903030 (2020). https://doi.org/10.1002/aenm.201903030
  18. L. Wang, J. Han, D. Kong, Y. Tao, Q. Yang, Enhanced roles of carbon architectures in high-performance lithium-ion batteries. Nano-Micro Lett. 11(1), 5 (2019). https://doi.org/10.1007/s40820-018-0233-1
  19. J. Jiang, P. Nie, B. Ding, Y. Zhang, G. Xu et al., Highly stable lithium ion capacitor enabled by hierarchical polyimide derived carbon microspheres combined with 3D current collectors. J. Mater. Chem. A 5(44), 23283–23291 (2017). https://doi.org/10.1039/C7TA05972H
  20. C. Wang, J. Kim, J. Tang, M. Kim, H. Lim et al., New strategies for novel MOF-derived carbon materials based on nanoarchitectures. Chem 6(1), 19–40 (2020). https://doi.org/10.1016/j.chempr.2019.09.005
  21. F. Marpaung, M. Kim, J.H. Khan, K. Konstantinov, Y. Yamauchi et al., Metal-organic framework (MOF)-derived nanoporous carbon materials. Chem. Asian J. 14(9), 1331–1343 (2019). https://doi.org/10.1002/asia.201900026
  22. J. Yin, W. Zhang, N.A. Alhebshi, N. Salah, H.N. Alshareef, Synthesis strategies of porous carbon for supercapacitor applications. Small Methods 4(3), 1900853 (2020). https://doi.org/10.1002/smtd.201900853
  23. F. Caruso, R.A. Caruso, H. Möhwald, Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating. Science 282(5391), 1111–1114 (1998). https://doi.org/10.1126/science.282.5391.1111
  24. J. Jiang, Y. Zhang, Y. An, L. Wu, Q. Zhu et al., Engineering ultrathin MoS2 nanosheets anchored on N-doped carbon microspheres with pseudocapacitive properties for high-performance lithium-ion capacitors. Small Methods 3(7), 1900081 (2019). https://doi.org/10.1002/smtd.201900081
  25. W.J. Lee, J. Lim, S.O. Kim, Nitrogen dopants in carbon nanomaterials: defects or a new opportunity? Small Methods 1(1–2), 1600014 (2017). https://doi.org/10.1002/smtd.201600014
  26. K.L. Zhang, X.H. Xia, S.J. Deng, Y. Zhong, D. Xie et al., Nitrogen-doped sponge Ni fibers as highly efficient electrocatalysts for oxygen evolution reaction. Nano-Micro Lett. 11(1), 21 (2019). https://doi.org/10.1007/s40820-019-0253-5
  27. Z. Wang, H. Gao, Q. Zhang, Y. Liu, J. Chen et al., Recent advances in 3D graphene architectures and their composites for energy storage applications. Small 15(3), 1803858 (2019). https://doi.org/10.1002/smll.201803858
  28. K. Chen, L. Shi, Y. Zhang, Z. Liu, Scalable chemical-vapour-deposition growth of three-dimensional graphene materials towards energy-related applications. Chem. Soc. Rev. 47(9), 3018–3036 (2018). https://doi.org/10.1039/C7CS00852J
  29. J. Mao, J. Iocozzia, J. Huang, K. Meng, Y. Lai et al., Graphene aerogels for efficient energy storage and conversion. Energy Environ. Sci. 11(4), 772–799 (2018). https://doi.org/10.1039/C7EE03031B
  30. Y. Zhang, J. Jiang, Y. An, L. Wu, H. Dou et al., Sodium ion capacitors: materials, mechanism and challenges. Chemsuschem 13(10), 2522–2539 (2020). https://doi.org/10.1002/cssc.201903440
  31. K. Li, J. Zhang, Recent advances in flexible supercapacitors based on carbon nanotubes and graphene. Sci. China Mater. 61(2), 210–232 (2018). https://doi.org/10.1007/s40843-017-9154-2
  32. X. Li, Y. Chen, H. Huang, Y. Mai, L. Zhou, Electrospun carbon-based nanostructured electrodes for advanced energy storage-a review. Energy Storage Mater. 5, 58–92 (2016). https://doi.org/10.1016/j.ensm.2016.06.002
  33. H. Feng, L. Tang, G. Zeng, J. Tang, Y. Deng et al., Carbon-based core-shell nanostructured materials for electrochemical energy storage. J. Mater. Chem. A 6(17), 7310–7337 (2018). https://doi.org/10.1039/C8TA01257A
  34. L. Jiang, X. Yuan, J. Liang, J. Zhang, H. Wang et al., Nanostructured core-shell electrode materials for electrochemical capacitors. J. Power Sources 331, 408–425 (2016). https://doi.org/10.1016/j.jpowsour.2016.09.054
  35. P. Russo, A. Hu, G. Compagnini, Synthesis, properties and potential applications of porous graphene: a review. Nano-Micro Lett. 5(4), 260–273 (2013). https://doi.org/10.1007/BF03353757
  36. O. Noonan, H. Zhang, H. Song, C. Xu, X. Huang et al., In situ Stöber templating: facile synthesis of hollow mesoporous carbon spheres from silica-polymer composites for ultra-high level in-cavity adsorption. J. Mater. Chem. A 4(23), 9063–9071 (2016). https://doi.org/10.1039/C6TA02265K
  37. Y. Han, X. Dong, C. Zhang, S. Liu, Hierarchical porous carbon hollow-spheres as a high performance electrical double-layer capacitor material. J. Power Sources 211, 92–96 (2012). https://doi.org/10.1016/j.jpowsour.2012.03.053
  38. G. Ferrero, A. Fuertes, M. Sevilla, N-doped porous carbon capsules with tunable porosity for high-performance supercapacitors. J. Mater. Chem. A 3(6), 2914–2923 (2015). https://doi.org/10.1039/C4TA06022A
  39. A. Chen, Y. Yu, H. Lv, Y. Wang, S. Shen et al., Thin-walled, mesoporous and nitrogen-doped hollow carbon spheres using ionic liquids as precursors. J. Mater. Chem. A 1(4), 1045–1047 (2013). https://doi.org/10.1039/C2TA01013E
  40. C. Wang, F. Wang, Z. Liu, Y. Zhao, Y. Liu et al., N-doped carbon hollow microspheres for metal-free quasi-solid-state full sodium-ion capacitors. Nano Energy 41, 674–680 (2017). https://doi.org/10.1016/j.nanoen.2017.10.025
  41. B.Y. Guan, L. Yu, X.W. Lou, Chemically assisted formation of monolayer colloidosomes on functional particles. Adv. Mater. 28(43), 9596–9601 (2016). https://doi.org/10.1002/adma.201603622
  42. M. Kim, S.B. Yoon, K. Sohn, J.Y. Kim, C.H. Shin et al., Synthesis and characterization of spherical carbon and polymer capsules with hollow macroporous core and mesoporous shell structures. Microporous Mesoporous Mater. 63(1–3), 1–9 (2003). https://doi.org/10.1016/S1387-1811(03)00410-4
  43. A.B. Fuertes, P. Valle-Vigón, M. Sevilla, One-step synthesis of silica@ resorcinol–formaldehyde spheres and their application for the fabrication of polymer and carbon capsules. Chem. Commun. 48(49), 6124–6126 (2012). https://doi.org/10.1039/C2CC32552G
  44. X. Fang, J. Zang, X. Wang, M.S. Zheng, N. Zheng, A multiple coating route to hollow carbon spheres with foam-like shells and their applications in supercapacitor and confined catalysis. J. Mater. Chem. A 2(17), 6191–6197 (2014). https://doi.org/10.1039/C3TA14881E
  45. H. Zhang, M. Yu, H. Song, O. Noonan, J. Zhang et al., Self-organized mesostructured hollow carbon nanoparticles via a surfactant-free sequential heterogeneous nucleation pathway. Chem. Mater. 27(18), 6297–6304 (2015). https://doi.org/10.1021/acs.chemmater.5b01993
  46. F. Su, X. Zhao, Y. Wang, L. Wang, J.Y. Lee, Hollow carbon spheres with a controllable shell structure. J. Mater. Chem. 16(45), 4413–4419 (2006). https://doi.org/10.1021/acs.chemmater.5b01993
  47. X. Chen, K. Kierzek, K. Cendrowski, I. Pelech, X. Zhao et al., CVD generated mesoporous hollow carbon spheres as supercapacitors. Colloids Surf. A 396, 246–250 (2012). https://doi.org/10.1016/j.colsurfa.2012.01.002
  48. X. Chen, K. Kierzek, Z. Jiang, H. Chen, T. Tang et al., Synthesis, growth mechanism, and electrochemical properties of hollow mesoporous carbon spheres with controlled diameter. J. Phys. Chem. C 115(36), 17717–17724 (2011). https://doi.org/10.1021/jp205257u
  49. M.M. Titirici, A. Thomas, M. Antonietti, Replication and coating of silica templates by hydrothermal carbonization. Adv. Funct. Mater. 17(6), 1010–1018 (2007). https://doi.org/10.1002/adfm.200600501
  50. J. Fu, Q. Xu, J. Chen, Z. Chen, X. Huang et al., Controlled fabrication of uniform hollow core porous shell carbon spheres by the pyrolysis of core/shell polystyrene/cross-linked polyphosphazene composites. Chem. Commun. 46(35), 6563–6565 (2010). https://doi.org/10.1039/C0CC01185A
  51. A. Chen, Y. Li, Y. Yu, Y. Li, K. Xia et al., Synthesis of hollow mesoporous carbon spheres via “dissolution-capture” method for effective phenol adsorption. Carbon 103, 157–162 (2016). https://doi.org/10.1016/j.carbon.2016.02.091
  52. L.K. Gil-Herrera, Á. Blanco, B.H. Juárez, C. López, Seeded synthesis of monodisperse core-shell and hollow carbon spheres. Small 12(32), 4357–4362 (2016). https://doi.org/10.1002/smll.201600902
  53. A.H. Lu, T. Sun, W.C. Li, Q. Sun, F. Han et al., Synthesis of discrete and dispersible hollow carbon nanospheres with high uniformity by using confined nanospace pyrolysis. Angew. Chem. Int. Ed. 50(49), 11765–11768 (2011). https://doi.org/10.1002/anie.201105486
  54. J. Han, G. Xu, B. Ding, J. Pan, H. Dou et al., Porous nitrogen-doped hollow carbon spheres derived from polyaniline for high performance supercapacitors. J. Mater. Chem. A 2(15), 5352–5357 (2014). https://doi.org/10.1039/C3TA15271E
  55. L. Xin, R. Chen, Q. Liu, J. Liu, Z. Li et al., Composites of hierarchical metal-organic framework derived nitrogen-doped porous carbon and interpenetrating 3D hollow carbon spheres from lotus pollen for high-performance supercapacitors. New J. Chem. 41(21), 12835–12842 (2017). https://doi.org/10.1039/C7NJ02427D
  56. X. He, H. Sun, M. Zhu, M. Yaseen, D. Liao et al., N-doped porous graphitic carbon with multi-flaky shell hollow structure prepared using a green and ‘useful’ template of CaCO3 for VOC fast adsorption and small peptide enrichment. Chem. Commun. 53(24), 3442–3445 (2017). https://doi.org/10.1039/C7CC00242D
  57. W. Liu, X. Huang, H. Wei, K. Chen, J. Gao et al., Facile preparation of hollow crosslinked polyphosphazene submicrospheres with mesoporous shells. J. Mater. Chem. 21(34), 12964–12968 (2011). https://doi.org/10.1039/C1JM11802A
  58. H. Guo, B. Ding, J. Wang, Y. Zhang, X. Hao et al., Template-induced self-activation route for nitrogen-doped hierarchically porous carbon spheres for electric double layer capacitors. Carbon 136, 204–210 (2018). https://doi.org/10.1016/j.carbon.2018.04.079
  59. J. Liu, M. Shao, Q. Tang, X. Chen, Z. Liu, A medial-reduction route to hollow carbon spheres. Carbon 41(8), 1682–1685 (2003). https://doi.org/10.1016/S0008-6223(03)00143-X
  60. L. Shi, H. Lin, K. Bao, J. Cao, Y. Qian, Controlled growth of carbon spheres through the Mg-reduction route. Nanoscale Res. Lett. 5(1), 20 (2010). https://doi.org/10.1007/s11671-009-9436-1
  61. G. Hu, D. Ma, M. Cheng, L. Liu, X. Bao, Direct synthesis of uniform hollow carbon spheres by a self-assembly template approach. Chem. Commun. 17, 1948–1949 (2002). https://doi.org/10.1039/B205723A
  62. Z. Bai, Y. Zhang, N. Fan, C. Guo, B. Tang, One-step synthesis of ZnO@C nanospheres and their enhanced performance for lithium-ion batteries. Mater. Lett. 119, 16–19 (2014). https://doi.org/10.1016/j.matlet.2013.12.060
  63. R. Liu, N. Lun, Y. Qi, H. Zhu, Y. Bai et al., Synthesis of hollow carbon sphere/ZnO@C composite as a light-weight microwave absorber. J. Phys-D Appl. Phys. 44(26), 265502 (2011). https://doi.org/10.1088/0022-3727/44/26/265502
  64. F. Wang, L. Pang, Y. Jiang, B. Chen, D. Lin et al., Simple synthesis of hollow carbon spheres from glucose. Mater. Lett. 63(29), 2564–2566 (2009). https://doi.org/10.1016/j.matlet.2009.09.008
  65. J. Liu, T. Yang, D. Wang, G.Q.M. Lu, D. Zhao et al., A facile soft-template synthesis of mesoporous polymeric and carbonaceous nanospheres. Nat. Commun. 4(1), 1–7 (2013). https://doi.org/10.1038/ncomms3798
  66. B.Y. Guan, L. Yu, X.W. Lou, Formation of asymmetric bowl-like mesoporous particles via emulsion-induced interface anisotropic assembly. J. Am. Chem. Soc. 138(35), 11306–11311 (2016). https://doi.org/10.1021/jacs.6b06558
  67. D. Liu, N. Xue, L. Wei, Y. Zhang, Z. Qin et al., Surfactant assembly within pickering emulsion droplets for fabrication of interior-structured mesoporous carbon microspheres. Angew. Chem. Int. Ed. 130(34), 11065–11070 (2018). https://doi.org/10.1002/ange.201805022
  68. B.Y. Guan, S.L. Zhang, X.W. Lou, Realization of walnut-shaped particles with macro-/mesoporous open channels through pore architecture manipulation and their use in electrocatalytic oxygen reduction. Angew. Chem. Int. Ed. 57(21), 6176–6180 (2018). https://doi.org/10.1002/anie.201801876
  69. Y. Yang, S. Jin, Z. Zhang, Z. Du, H. Liu et al., Nitrogen-doped hollow carbon nanospheres for high-performance Li-ion batteries. ACS Appl. Mater. Interfaces. 9(16), 14180–14186 (2017). https://doi.org/10.1021/acsami.6b14840
  70. C. Yuan, X. Liu, M. Jia, Z. Luo, J. Yao, Facile preparation of N-and O-doped hollow carbon spheres derived from poly (o-phenylenediamine) for supercapacitors. J. Mater. Chem. A 3(7), 3409–3415 (2015). https://doi.org/10.1039/C4TA06411A
  71. H. Zhang, F. Ye, H. Xu, L. Liu, H. Guo, Synthesis of carbon hollow particles by a simple inverse-emulsion method. Mater. Lett. 64(13), 1473–1475 (2010). https://doi.org/10.1016/j.matlet.2010.03.065
  72. Z. Wen, Q. Wang, Q. Zhang, J. Li, Hollow carbon spheres with wide size distribution as anode catalyst support for direct methanol fuel cells. Electrochem. Commun. 9(8), 1867–1872 (2007). https://doi.org/10.1016/j.matlet.2010.03.065
  73. X. Sun, Y. Li, Hollow carbonaceous capsules from glucose solution. J. Colloid Interface Sci. 291(1), 7–12 (2005). https://doi.org/10.1016/j.jcis.2005.04.101
  74. Y. Qu, Z. Zhang, X. Wang, Y. Lai, Y. Liu et al., A simple SDS-assisted self-assembly method for the synthesis of hollow carbon nanospheres to encapsulate sulfur for advanced lithium-sulfur batteries. J. Mater. Chem. A 1(45), 14306–14310 (2013). https://doi.org/10.1039/C3TA13306K
  75. D. Fujikawa, M. Uota, G. Sakai, T. Kijima, Shape-controlled synthesis of nanocarbons from resorcinol-formaldehyde nanopolymers using surfactant-templated vesicular assemblies. Carbon 45(6), 1289–1295 (2007). https://doi.org/10.1016/j.carbon.2007.01.020
  76. D. Tashima, E. Yamamoto, N. Kai, D. Fujikawa, G. Sakai et al., Double layer capacitance of high surface area carbon nanospheres derived from resorcinol-formaldehyde polymers. Carbon 49(14), 4848–4857 (2011). https://doi.org/10.1016/j.carbon.2011.07.005
  77. H. Sun, Y. Zhu, B. Yang, Y. Wang, Y. Wu et al., Template-free fabrication of nitrogen-doped hollow carbon spheres for high-performance supercapacitors based on a scalable homopolymer vesicle. J. Mater. Chem. A 4(31), 12088–12097 (2016). https://doi.org/10.1039/C6TA04330E
  78. J. Jiang, J. Yuan, P. Nie, Q. Zhu, C. Chen et al., Hierarchical N-doped hollow carbon microspheres as advanced materials for high-performance lithium-ion capacitors. J. Mater. Chem. A 8(7), 3956–3966 (2020). https://doi.org/10.1039/C9TA08676E
  79. W. Sun, M. Chen, S. Zhou, L. Wu, Facile fabrication of carbon spheres with tunable morphologies from novel polymeric carbon precursors. Langmuir 30(40), 12011–12017 (2014). https://doi.org/10.1021/la5026476
  80. K. Niwase, T. Homae, K. Nakamura, K. Kondo, Generation of giant carbon hollow spheres from C60 fullerene by shock-compression. Chem. Phys. Lett. 362(1–2), 47–50 (2002). https://doi.org/10.1016/S0009-2614(02)00997-1
  81. F. Ma, L. Sun, H. Zhao, Q. Li, L. Huo et al., Supercapacitor performance of hollow carbon spheres by direct pyrolysis of melamine-formaldehyde resin spheres. Chem. Res. Chin. Univ. 29(4), 735–742 (2013). https://doi.org/10.1007/s40242-013-3181-9
  82. J. Zhou, Z. Sun, M. Chen, J. Wang, W. Qiao et al., Macroscopic and mechanically robust hollow carbon spheres with superior oil adsorption and light-to-heat evaporation properties. Adv. Funct. Mater. 26(29), 5368–5375 (2016). https://doi.org/10.1002/adfm.201600564
  83. H. Xu, J. Guo, K.S. Suslick, Porous carbon spheres from energetic carbon precursors using ultrasonic spray pyrolysis. Adv. Mater. 24(45), 6028–6033 (2012). https://doi.org/10.1002/adma.201201915
  84. P. Nie, G. Xu, J. Jiang, H. Dou, Y. Wu et al., Aerosol-spray pyrolysis toward preparation of nanostructured materials for batteries and supercapacitors. Small Methods 2(2), 1700272 (2018). https://doi.org/10.1002/smtd.201700272
  85. J.S. Park, J.K. Kim, J.H. Hong, J.S. Cho, S.K. Park et al., Advances in the synthesis and design of nanostructured materials by aerosol spray processes for efficient energy storage. Nanoscale 11(41), 19012–19057 (2019). https://doi.org/10.1039/C9NR05575D
  86. T. Zheng, J. Zhan, J. Pang, G.S. Tan, J. He et al., Mesoporous carbon nanocapsules from enzymatically polymerized poly(4-ethylphenol) confined in silica aerosol particles. Adv. Mater. 18(20), 2735–2738 (2006). https://doi.org/10.1002/adma.200600808
  87. S. Kim, E. Shibata, R. Sergiienko, T. Nakamura, Purification and separation of carbon nanocapsules as a magnetic carrier for drug delivery systems. Carbon 46(12), 1523–1529 (2008). https://doi.org/10.1016/j.carbon.2008.05.027
  88. H. Okuno, E. Grivei, F. Fabry, T.M. Gruenberger, J. Gonzalez-Aguilar et al., Synthesis of carbon nanotubes and nano-necklaces by thermal plasma process. Carbon 42(12–13), 2543–2549 (2004). https://doi.org/10.1016/j.carbon.2004.05.037
  89. P. González-García, E. Urones-Garrote, D. Ávila-Brande, L. Otero-Díaz, Carbon particles of variable shape produced by the chlorination of bis(benzene) chromium. J. Organomet. Chem. 740, 141–147 (2013). https://doi.org/10.1016/j.jorganchem.2013.05.011
  90. H.-F. Wang, L. Chen, H. Pang, S. Kaskel, Q. Xu, MOF-derived electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions. Chem. Soc. Rev. 49(5), 1414–1448 (2020). https://doi.org/10.1039/C9CS00906J
  91. R.R. Salunkhe, Y.V. Kaneti, J. Kim, J.H. Kim, Y. Yamauchi, Nanoarchitectures for metal-organic framework-derived nanoporous carbons toward supercapacitor applications. Acc. Chem. Res. 49(12), 2796–2806 (2016). https://doi.org/10.1021/acs.accounts.6b00460
  92. B. Liu, H. Shioyama, T. Akita, Q. Xu, Metal-organic framework as a template for porous carbon synthesis. J. Am. Chem. Soc. 130(16), 5390–5391 (2008). https://doi.org/10.1021/ja7106146
  93. M. Hu, J. Reboul, S. Furukawa, N.L. Torad, Q. Ji et al., Direct carbonization of al-based porous coordination polymer for synthesis of nanoporous carbon. J. Am. Chem. Soc. 134(6), 2864–2867 (2012). https://doi.org/10.1021/ja208940u
  94. X. Li, S. Zheng, L. Jin, Y. Li, P. Geng et al., Metal-organic framework-derived carbons for battery applications. Adv. Energy Mater. 8(23), 1800716 (2018). https://doi.org/10.1002/aenm.201800716
  95. W. Yang, X. Li, Y. Li, R. Zhu, H. Pang, Applications of metal-organic-framework-derived carbon materials. Adv. Mater. 31(6), 1804740 (2019). https://doi.org/10.1002/adma.201804740
  96. C. Liu, X. Huang, J. Wang, H. Song, Y. Yang et al., Hollow mesoporous carbon nanocubes: rigid-interface-induced outward contraction of metal-organic frameworks. Adv. Funct. Mater. 28(6), 1705253 (2018). https://doi.org/10.1002/adfm.201705253
  97. H. Zhou, D. He, A.I. Saana, J. Yang, Z. Wang et al., Mesoporous-silica induced doped carbon nanotube growth from metal-organic frameworks. Nanoscale 10(13), 6147–6154 (2018). https://doi.org/10.1039/C8NR00137E
  98. T. Feng, M. Zhang, A mixed-ion strategy to construct CNT-decorated Co/N-doped hollow carbon for enhanced oxygen reduction. Chem. Commun. 54(82), 11570–11573 (2018). https://doi.org/10.1039/C8CC05959D
  99. M.J. Wang, Z.X. Mao, L. Liu, L. Peng, N. Yang et al., Preparation of hollow nitrogen doped carbon via stresses induced orientation contraction. Small 14(52), 1804183 (2018). https://doi.org/10.1002/smll.201804183
  100. J. Wang, X. Luo, C. Young, J. Kim, Y.V. Kaneti et al., A glucose-assisted hydrothermal reaction for directly transforming metal-organic frameworks into hollow carbonaceous materials. Chem. Mater. 30(13), 4401–4408 (2018). https://doi.org/10.1021/acs.chemmater.8b01792
  101. W. Zhang, X. Jiang, Y. Zhao, A. Carné-Sánchez, V. Malgras et al., Hollow carbon nanobubbles: monocrystalline MOF nanobubbles and their pyrolysis. Chem. Sci. 8(5), 3538–3546 (2017). https://doi.org/10.1039/C6SC04903F
  102. X. Wang, Z. Na, D. Yin, C. Wang, Y. Wu et al., Phytic acid-assisted formation of hierarchical porous CoP/C nanoboxes for enhanced lithium storage and hydrogen generation. ACS Nano 12(12), 12238–12246 (2018). https://doi.org/10.1021/acsnano.8b06039
  103. J. Zhang, J. Fang, J. Han, T. Yan, L. Shi et al., N, P, S co-doped hollow carbon polyhedra derived from MOF-based core-shell nanocomposites for capacitive deionization. J. Mater. Chem. A 6(31), 15245–15252 (2018). https://doi.org/10.1039/C8TA04813D
  104. Y. Chen, S. Ji, S. Zhao, W. Chen, J. Dong et al., Enhanced oxygen reduction with single-atomic-site iron catalysts for a zinc-air battery and hydrogen-air fuel cell. Nat. Commun. 9(1), 1–12 (2018). https://doi.org/10.1038/s41467-018-07850-2
  105. W. Ma, N. Wang, T. Tong, L. Zhang, K.-Y.A. Lin et al., Nitrogen, phosphorus, and sulfur tri-doped hollow carbon shells derived from ZIF-67@ poly (cyclotriphosphazene-co-4,4′-sulfonyldiphenol) as a robust catalyst of peroxymonosulfate activation for degradation of bisphenol a. Carbon 13, 291–303 (2018). https://doi.org/10.1016/j.carbon.2018.05.039
  106. V.S. Kale, M. Hwang, H. Chang, J. Kang, S.I. Chae et al., Microporosity-controlled synthesis of heteroatom codoped carbon nanocages by wrap-bake-sublime approach for flexible all-solid-state-supercapacitors. Adv. Funct. Mater. 28(37), 1803786 (2018). https://doi.org/10.1002/adfm.201803786
  107. H. Yang, S.J. Bradley, A. Chan, G.I. Waterhouse, T. Nann et al., Catalytically active bimetallic nanoparticles supported on porous carbon capsules derived from metal-organic framework composites. J. Am. Chem. Soc. 138(36), 11872–11881 (2016). https://doi.org/10.1021/jacs.6b06736
  108. P. Ramakrishnan, S.G. Park, S. Shanmugam, Three-dimensional hierarchical nitrogen-doped arch and hollow nanocarbons: morphological influences on supercapacitor applications. J. Mater. Chem. A 3(31), 16242–16250 (2015). https://doi.org/10.1039/C5TA03384E
  109. Q. Xu, X. Yu, Q. Liang, Y. Bai, Z.H. Huang et al., Nitrogen-doped hollow activated carbon nanofibers as high performance supercapacitor electrodes. J. Electroanal. Chem. 739, 84–88 (2015). https://doi.org/10.1016/j.jelechem.2014.12.027
  110. C. Zhan, Q. Xu, X. Yu, Q. Liang, Y. Bai et al., Nitrogen-rich hierarchical porous hollow carbon nanofibers for high-performance supercapacitor electrodes. RSC Adv. 6(47), 41473–41476 (2016). https://doi.org/10.1039/C6RA07128G
  111. J.G. Kim, H.C. Kim, N.D. Kim, M.S. Khil, N-doped hierarchical porous hollow carbon nanofibers based on PAN/PVP@SAN structure for high performance supercapacitor. Compos. B 186, 107825 (2020). https://doi.org/10.1016/j.compositesb.2020.107825
  112. T.H. Le, Y. Yang, L. Yu, T. Gao, Z. Huang et al., Polyimide-based porous hollow carbon nanofibers for supercapacitor electrode. J. Appl. Polym. Sci. 133(19), 43397 (2016). https://doi.org/10.1002/app.43397
  113. Y. Wang, G. Li, J. Jin, S. Yang, Hollow porous carbon nanofibers as novel support for platinum-based oxygen reduction reaction electrocatalysts. Int. J. Hydrogen Energy 42(9), 5938–5947 (2017). https://doi.org/10.1016/j.ijhydene.2017.02.012
  114. T. He, Q. Su, Z. Yildiz, K. Cai, Y. Wang, Ultrafine carbon fibers with hollow-porous multilayered structure for supercapacitors. Electrochim. Acta 222, 1120–1127 (2016). https://doi.org/10.1016/j.electacta.2016.11.083
  115. A. Sharma, Free standing hollow carbon nanofiber mats for supercapacitor electrodes. RSC Adv. 6(82), 78528–78537 (2016). https://doi.org/10.1039/C6RA17014E
  116. X. Li, X. Chen, Y. Zhao, Y. Deng, J. Zhu et al., Flexible all-solid-state supercapacitors based on an integrated electrode of hollow N-doped carbon nanofibers embedded with graphene nanosheets. Electrochim. Acta 332, 135398 (2020). https://doi.org/10.1016/j.electacta.2019.135398
  117. L.-F. Chen, Y. Lu, L. Yu, X.W.D. Lou, Designed formation of hollow particle-based nitrogen-doped carbon nanofibers for high-performance supercapacitors. Energy Environ. Sci. 10(8), 1777–1783 (2017). https://doi.org/10.1039/C7EE00488E
  118. C. Wang, C. Liu, J. Li, X. Sun, J. Shen et al., Electrospun metal-organic framework derived hierarchical carbon nanofibers with high performance for supercapacitors. Chem. Commun. 53(10), 1751–1754 (2017). https://doi.org/10.1039/C6CC09832K
  119. Y. Sun, R.B. Sills, X. Hu, Z.W. Seh, X. Xiao et al., A bamboo-inspired nanostructure design for flexible, foldable, and twistable energy storage devices. Nano Lett. 15(6), 3899–3906 (2015). https://doi.org/10.1021/acs.nanolett.5b00738
  120. L. Wang, G. Zhang, X. Zhang, H. Shi, W. Zeng et al., Porous ultrathin carbon nanobubbles formed carbon nanofiber webs for high-performance flexible supercapacitors. J. Mater. Chem. A 5(28), 14801–14810 (2017). https://doi.org/10.1039/C7TA03445H
  121. W. Xie, X. Jiang, T. Qin, H. Yang, D. Liu et al., Inner porous carbon nanofibers as binder-free electrodes for high-rate supercapacitors. Electrochim. Acta 258, 1064–1071 (2017). https://doi.org/10.1016/j.electacta.2017.11.159
  122. L. Zhang, L. Han, S. Liu, C. Zhang, S. Liu, High-performance supercapacitors based on electrospun multichannel carbon nanofibers. RSC Adv. 5(130), 107313–107317 (2015). https://doi.org/10.1039/C5RA23338K
  123. P. Ramakrishnan, S. Shanmugam, Nitrogen-doped porous multi-nano-channel nanocarbons for use in high-performance supercapacitor applications. ACS Sustain. Chem. Eng. 4(4), 2439–2448 (2016). https://doi.org/10.1021/acssuschemeng.6b00289
  124. Y. Chen, Z. Lu, L. Zhou, Y.W. Mai, H. Huang, Triple-coaxial electrospun amorphous carbon nanotubes with hollow graphitic carbon nanospheres for high-performance Li ion batteries. Energy Environ. Sci. 5(7), 7898–7902 (2012). https://doi.org/10.1039/C2EE22085G
  125. P. Yang, X. Pan, J. Wang, R. Yang, J. Chu et al., Nozzle-less electrospun nitrogen-doped hollow carbon nanofibers as enhanced sensing platform for carbendazim electrochemical detection. ChemistrySelect 4(7), 2059–2063 (2019). https://doi.org/10.1002/slct.201803056
  126. Y. Chen, X. Li, K. Park, W. Lu, C. Wang et al., Nitrogen-doped carbon for sodium-ion battery anode by self-etching and graphitization of bimetallic MOF-based composite. Chem 3(1), 152–163 (2017). https://doi.org/10.1016/j.chempr.2017.05.021
  127. Y. Chen, X. Li, K. Park, J. Song, J. Hong et al., Hollow carbon-nanotube/carbon-nanofiber hybrid anodes for Li-ion batteries. J. Am. Chem. Soc. 135(44), 16280–16283 (2013). https://doi.org/10.1021/ja408421n
  128. K. Huo, W. An, J. Fu, B. Gao, L. Wang et al., Mesoporous nitrogen-doped carbon hollow spheres as high-performance anodes for lithium-ion batteries. J. Power Sources 324, 233–238 (2016). https://doi.org/10.1016/j.jpowsour.2016.05.084
  129. Q. Chen, G. Ping, X. Zhang, R. Zhao, Q. Wu et al., Nitrogen-doped mesoporous hollow carbon nanoflowers as high performance anode materials of lithium ion batteries. RSC Adv. 6(96), 93519–93524 (2016). https://doi.org/10.1039/C6RA21011B
  130. C.P. Xu, D.C. Niu, N. Zheng, H.N. Yu, J.P. He et al., Facile synthesis of nitrogen-doped double-shelled hollow mesoporous carbon nanospheres as high-performance anode materials for lithium ion batteries. ACS Sustain. Chem. Eng. 6(5), 5999–6007 (2018). https://doi.org/10.1021/acssuschemeng.7b04617
  131. X.Y. Yue, W. Sun, J. Zhang, F. Wang, Y.X. Yang et al., Macro-mesoporous hollow carbon spheres as anodes for lithium-ion batteries with high rate capability and excellent cycling performance. J. Power Sources 331, 10–15 (2016). https://doi.org/10.1016/j.jpowsour.2016.09.029
  132. K. Tang, R.J. White, X.K. Mu, M.M. Titirici, P.A. van Aken et al., Hollow carbon nanospheres with a high rate capability for lithium-based batteries. Chemsuschem 5(2), 400–403 (2012). https://doi.org/10.1002/cssc.201100609
  133. Z. Sun, X.F. Song, P. Zhang, L. Gao, Template-assisted synthesis of multi-shelled carbon hollow spheres with an ultralarge pore volume as anode materials in Li-ion batteries. RSC Adv. 5(5), 3657–3664 (2015). https://doi.org/10.1039/c4ra10591e
  134. L. Song, S. Xin, D.W. Xu, H.Q. Li, H.P. Cong et al., Graphene-wrapped graphitic carbon hollow spheres: bioinspired synthesis and applications in batteries and supercapacitors. ChemNanoMat 2(6), 540–546 (2016). https://doi.org/10.1002/cnma.201600079
  135. J.H. Zhu, Y.P. Wu, X.K. Huang, L. Huang, M.Y. Cao et al., Self-healing liquid metal nanoparticles encapsulated in hollow carbon fibers as a free-standing anode for lithium-ion batteries. Nano Energy 62, 883–889 (2019). https://doi.org/10.1016/j.nanoen.2019.06.023
  136. Y.Q. Zhang, Q. Ma, S.L. Wang, X. Liu, L. Li, Poly(vinyl alcohol)-assisted fabrication of hollow carbon spheres/reduced graphene oxide nanocomposites for high-performance lithium-ion battery anodes. ACS Nano 12(5), 4824–4834 (2018). https://doi.org/10.1021/acsnano.8b01549
  137. B.S. Lee, S.B. Son, K.M. Park, W.R. Yu, K.H. Oh et al., Anodic properties of hollow carbon nanofibers for Li-ion battery. J. Power Sources 199, 53–60 (2012). https://doi.org/10.1016/j.jpowsour.2011.10.030
  138. J. Jang, H.E. Kim, S. Kang, J.H. Bang, C.S. Lee, Urea-assisted template-less synthesis of heavily nitrogen-doped hollow carbon fibers for the anode material of lithium-ion batteries. New J. Chem. 43(9), 3821–3828 (2019). https://doi.org/10.1039/c8nj05807e
  139. Z. Chen, Y. Liu, Y. Zhang, F. Shen, G. Yang et al., Ultrafine layered graphite as an anode material for lithium ion batteries. Mater. Lett. 229, 134–137 (2018). https://doi.org/10.1016/j.matlet.2018.06.104
  140. F. Xiao, X. Chen, J. Zhang, C. Huang, T. Hu et al., Large-scale production of holey graphite as high-rate anode for lithium ion batteries. J. Energy Chem. 48, 122–127 (2020). https://doi.org/10.1016/j.jechem.2019.12.026
  141. S. Heng, X. Shan, W. Wang, Y. Wang, G. Zhu et al., Controllable solid electrolyte interphase precursor for stabilizing natural graphite anode in lithium ion batteries. Carbon 159, 390–400 (2020). https://doi.org/10.1016/j.carbon.2019.12.054
  142. D.S. Bin, Y.M. Li, Y.G. Sun, S.Y. Duan, Y.X. Lu et al., Structural engineering of multishelled hollow carbon nanostructures for high-performance Na-ion battery anode. Adv. Energy Mater. 8(26), 1800855 (2018). https://doi.org/10.1002/aenm.201800855
  143. K. Tang, L.J. Fu, R.J. White, L.H. Yu, M.M. Titirici et al., Hollow carbon nanospheres with superior rate capability for sodium-based batteries. Adv. Energy Mater. 2(7), 873–877 (2012). https://doi.org/10.1002/aenm.201100691
  144. L. Liu, Q.Y. Li, Z.J. Wang, Y. Chen, Phosphorus-doped hollow carbon sphere derived from phytic acid for superior sodium-ion batteries. Mater. Technol. 33(11), 748–753 (2018). https://doi.org/10.1080/10667857.2018.1500131
  145. J.C. Ye, J. Zang, Z.W. Tian, M.S. Zheng, Q.F. Dong, Sulfur and nitrogen co-doped hollow carbon spheres for sodium-ion batteries with superior cyclic and rate performance. J. Mater. Chem. A 4(34), 13223–13227 (2016). https://doi.org/10.1039/c6ta04592h
  146. Y.H. Qu, Z. Zhang, K. Du, W. Chen, Y.Q. Lai et al., Synthesis of nitrogen-containing hollow carbon microspheres by a modified template method as anodes for advanced sodium-ion batteries. Carbon 105, 103–112 (2016). https://doi.org/10.1016/j.carbon.2016.04.029
  147. Y.L. Cao, L.F. Xiao, M.L. Sushko, W. Wang, B. Schwenzer et al., Sodium ion insertion in hollow carbon nanowires for battery applications. Nano Lett. 12(7), 3783–3787 (2012). https://doi.org/10.1021/nl3016957
  148. H.X. Han, X.Y. Chen, J.F. Qian, F.P. Zhong, X.M. Feng et al., Hollow carbon nanofibers as high-performance anode materials for sodium-ion batteries. Nanoscale 11(45), 21999–22005 (2019). https://doi.org/10.1039/c9nr07675a
  149. Z.G. Luo, S.N. Liu, Y.S. Cai, S. Li, A.Q. Pan et al., Nitrogen/sulfur co-doped hollow carbon nanofiber anode obtained from polypyrrole with enhanced electrochemical performance for Na-ion batteries. Sci. Bull. 63(2), 126–132 (2018). https://doi.org/10.1016/j.scib.2017.12.024
  150. H.C. Tao, L.Y. Xiong, S.L. Du, Y.Q. Zhang, X.L. Yang et al., Interwoven n and p dual-doped hollow carbon fibers/graphitic carbon nitride: an ultrahigh capacity and rate anode for Li and Na ion batteries. Carbon 122, 54–63 (2017). https://doi.org/10.1016/j.carbon.2017.06.040
  151. W.P. Shi, Y.M. Zhang, Z.Q. Tian, Z.Y. Pan, J.L. Key et al., Low temperature synthesis of polyhedral hollow porous carbon with high rate capability and long-term cycling stability as Li-ion and Na-ion battery anode material. J. Power Sources 398, 149–158 (2018). https://doi.org/10.1016/j.jpowsour.2018.07.038
  152. W.B. Li, J.F. Huang, L.L. Feng, L.Y. Cao, Y.J. Ren et al., Controlled synthesis of macroscopic three-dimensional hollow reticulate hard carbon as long-life anode materials for Na-ion batteries. J. Alloys Compd. 716, 210–219 (2017). https://doi.org/10.1016/j.jallcom.2017.05.062
  153. N. Sun, H. Liu, B. Xu, Facile synthesis of high performance hard carbon anode materials for sodium ion batteries. J. Mater. Chem. A 3(41), 20560–20566 (2015). https://doi.org/10.1039/C5TA05118E
  154. A. Saha, T. Sharabani, E. Evenstein, G.D. Nessim, M. Noked et al., Probing electrochemical behaviour of lignocellulosic, orange peel derived hard carbon as anode for sodium ion battery. J. Electrochem. Soc. 167(9), 090505 (2020). https://doi.org/10.1149/1945-7111/ab7c55
  155. Z. Li, Y. Chen, Z. Jian, H. Jiang, J.J. Razink et al., Defective hard carbon anode for Na-ion batteries. Chem. Mater. 30(14), 4536–4542 (2018). https://doi.org/10.1021/acs.chemmater.8b00645
  156. J. Ding, H.L. Zhang, H. Zhou, J. Feng, X.R. Zheng et al., Sulfur-grafted hollow carbon spheres for potassium-ion battery anodes. Adv. Mater. 31(30), 1900429 (2019). https://doi.org/10.1002/adma.201900429
  157. G. Wang, X.H. Xiong, D. Xie, Z.H. Lin, J. Zheng et al., Chemically activated hollow carbon nanospheres as a high-performance anode material for potassium ion batteries. J. Mater. Chem. A 6(47), 24317–24323 (2018). https://doi.org/10.1039/c8ta09751h
  158. J.F. Ruan, X. Wu, Y. Wang, S.Y. Zheng, D.L. Sun et al., Nitrogen-doped hollow carbon nanospheres towards the application of potassium ion storage. J. Mater. Chem. A 7(33), 19305–19315 (2019). https://doi.org/10.1039/c9ta05205d
  159. D.S. Bin, X.J. Lin, Y.G. Sun, Y.S. Xu, K. Zhang et al., Engineering hollow carbon architecture for high-performance K-ion battery anode. J. Am. Chem. Soc. 140(23), 7127–7134 (2018). https://doi.org/10.1021/jacs.8b02178
  160. Z.L. Zhang, B.R. Jia, L. Liu, Y.Z. Zhao, H.Y. Wu et al., Hollow multihole carbon bowls: a stress-release structure design for high-stability and high-volumetric-capacity potassium-ion batteries. ACS Nano 13(10), 11363–11371 (2019). https://doi.org/10.1021/acsnano.9b04728
  161. X.P. Wang, K. Han, D.D. Qin, Q. Li, C.Y. Wang et al., Polycrystalline soft carbon semi-hollow microrods as anode for advanced K-ion full batteries. Nanoscale 9(46), 18216–18222 (2017). https://doi.org/10.1039/c7nr06645g
  162. Z. Jian, W. Luo, X. Ji, Carbon electrodes for K-ion batteries. J. Am. Chem. Soc. 137(36), 11566–11569 (2015). https://doi.org/10.1021/jacs.5b06809
  163. X. Niu, L. Li, J. Qiu, J. Yang, J. Huang et al., Salt-concentrated electrolytes for graphite anode in potassium ion battery. Solid State Ionics 341, 115050 (2019). https://doi.org/10.1016/j.ssi.2019.115050
  164. L. Wang, J. Yang, J. Li, T. Chen, S. Chen et al., Graphite as a potassium ion battery anode in carbonate-based electrolyte and ether-based electrolyte. J. Power Sources 409, 24–30 (2019). https://doi.org/10.1016/j.jpowsour.2018.10.092
  165. Z.L. Li, Z.B. Xiao, S.Q. Wang, Z.B. Cheng, P.Y. Li et al., Engineered interfusion of hollow nitrogen-doped carbon nanospheres for improving electrochemical behavior and energy density of lithium-sulfur batteries. Adv. Funct. Mater. 29(31), 1902322 (2019). https://doi.org/10.1002/adfm.201902322
  166. Y.J. Zhong, Q. Lu, Y.P. Zhu, Y.L. Zhu, W. Zhou et al., Fructose-derived hollow carbon nanospheres with ultrathin and ordered mesoporous shells as cathodes in lithium-sulfur batteries for fast energy storage. Adv. Sustain. Syst. 1(8), 1700081 (2017). https://doi.org/10.1002/adsu.201700081
  167. Z. Zhang, G.C. Wang, Y.Q. Lai, J. Li, Z.Y. Zhang et al., Nitrogen-doped porous hollow carbon sphere-decorated separators for advanced lithium-sulfur batteries. J. Power Sources 300, 157–163 (2015). https://doi.org/10.1016/j.jpowsour.2015.09.067
  168. D.H. Yang, H.Y. Zhou, H. Liu, B.H. Han, Hollow N-doped carbon polyhedrons with hierarchically porous shell for confinement of polysulfides in lithium-sulfur batteries. Science 13, 243–253 (2019). https://doi.org/10.1016/j.isci.2019.02.019
  169. G.Y. Zheng, Q.F. Zhang, J.J. Cha, Y. Yang, W.Y. Li et al., Amphiphilic surface modification of hollow carbon nanofibers for improved cycle life of lithium sulfur batteries. Nano Lett. 13(3), 1265–1270 (2013). https://doi.org/10.1021/nl304795g
  170. X.Q. Zhang, B. He, W.C. Li, A.H. Lu, Hollow carbon nanofibers with dynamic adjustable pore sizes and closed ends as hosts for high-rate lithium-sulfur battery cathodes. Nano Res. 11(3), 1238–1246 (2018). https://doi.org/10.1007/s12274-017-1737-6
  171. G.Y. Zheng, Y. Yang, J.J. Cha, S.S. Hong, Y. Cui, Hollow carbon nanofiber-encapsulated sulfur cathodes for high specific capacity rechargeable lithium batteries. Nano Lett. 11(10), 4462–4467 (2011). https://doi.org/10.1021/nl2027684
  172. D. Yang, W. Ni, J.L. Cheng, Z.P. Wang, T. Wang et al., Flexible three-dimensional electrodes of hollow carbon bead strings as graded sulfur reservoirs and the synergistic mechanism for lithium-sulfur batteries. Appl. Surf. Sci. 413, 209–218 (2017). https://doi.org/10.1016/j.apsusc.2017.04.046
  173. S.Q. Chen, X.D. Huang, H. Liu, B. Sun, W.K. Yeoh et al., 3D hyperbranched hollow carbon nanorod architectures for high-performance lithium-sulfur batteries. Adv. Energy Mater. 4(8), 1301761 (2014). https://doi.org/10.1002/aenm.201301761
  174. F. Pei, T.H. An, J. Zang, X.J. Zhao, X.L. Fang et al., From hollow carbon spheres to n-doped hollow porous carbon bowls: rational design of hollow carbon host for Li-S batteries. Adv. Energy Mater. 6(8), 2502539 (2016). https://doi.org/10.1002/aenm.201502539
  175. Y.B. An, Q.Z. Zhu, L.F. Hu, S.K. Yu, Q. Zhao et al., A hollow carbon foam with ultra-high sulfur loading for an integrated cathode of lithium-sulfur batteries. J. Mater. Chem. A 4(40), 15605–15611 (2016). https://doi.org/10.1039/c6ta06088a
  176. M. Li, Y.N. Zhang, X.L. Wang, W. Ahn, G.P. Jiang et al., Gas pickering emulsion templated hollow carbon for high rate performance lithium sulfur batteries. Adv. Funct. Mater. 26(46), 8408–8417 (2016). https://doi.org/10.1002/adfm.201603241
  177. C.L. Ma, J. Dong, Y. Zhao, J. Li, H.L. Chen, Dual-template synthesis of novel pomegranate-like hollow carbon nanoparticles with improved electrochemical performance for Li-ion batteries. Carbon 110, 180–188 (2016). https://doi.org/10.1016/j.carbon.2016.09.020
  178. J. Zang, J.C. Ye, X.L. Fang, X.W. Zhang, M.S. Zheng et al., Hollow-in-hollow carbon spheres for lithium-ion batteries with superior capacity and cyclic performance. Electrochim. Acta 186, 436–441 (2015). https://doi.org/10.1016/j.electacta.2015.11.002
  179. B.S. Lee, S.B. Son, K.M. Park, G. Lee, K.H. Oh et al., Effect of pores in hollow carbon nanofibers on their negative electrode properties for a lithium rechargeable battery. ACS Appl. Mater. Interfaces. 4(12), 6701–6709 (2012). https://doi.org/10.1021/am301873d
  180. Z.Y. Pan, H. Sun, J. Pan, J. Zhang, B.J. Wang et al., The creation of hollow walls in carbon nanotubes for high-performance lithium ion batteries. Carbon 133, 384–389 (2018). https://doi.org/10.1016/j.carbon.2018.03.021
  181. Q.L. Huang, S.L. Wang, Y. Zhang, B.W. Yu, L.Z. Hou et al., Hollow carbon nanospheres with extremely small size as anode material in lithium-ion batteries with outstanding cycling stability. J. Phys. Chem. C 120(6), 3139–3144 (2016). https://doi.org/10.1021/acs.jpcc.5b10455
  182. S.G. Liu, C.P. Mao, L. Wang, M. Jia, Q.Q. Sun et al., Bio-inspired synthesis of carbon hollow microspheres from Aspergillus flavus conidia for lithium-ion batteries. RSC Adv. 5(73), 59655–59658 (2015). https://doi.org/10.1039/c5ra12059d
  183. X.H. Dai, H.X. Fan, J.J. Zhang, S.J. Yuan, Sewage sludge-derived porous hollow carbon nanospheres as high-performance anode material for lithium ion batteries. Electrochim. Acta 319, 277–285 (2019). https://doi.org/10.1016/j.electacta.2019.07.006
  184. Q.Q. Li, K. Yao, G.C. Zhang, J. Gong, E. Mijowska et al., Controllable synthesis of 3d hollow-carbon-spheres/graphene-flake hybrid nanostructures from polymer nanocomposite by self-assembly and feasibility for lithium-ion batteries. Part. Part. Syst. Charact. 32(9), 874–879 (2015). https://doi.org/10.1002/ppsc.201500037
  185. F.D. Han, Y.J. Bai, R. Liu, B. Yao, Y.X. Qi et al., Template-free synthesis of interconnected hollow carbon nanospheres for high-performance anode material in lithium-ion batteries. Adv. Energy Mater. 1(5), 798–801 (2011). https://doi.org/10.1002/aenm.201100340
  186. P. Nie, Z.Y. Le, G. Chen, D. Liu, X.Y. Liu et al., Graphene caging silicon particles for high-performance lithium-ion batteries. Small 14(25), 1800635 (2018). https://doi.org/10.1002/smll.201800635
  187. S.M. Zou, X.Y. Xu, Y.Q. Zhu, C.B. Cao, Microwave-assisted preparation of hollow porous carbon spheres and as anode of lithium-ion batteries. Microporous Mesoporous Mater. 251, 114–121 (2017). https://doi.org/10.1016/j.micromeso.2017.05.062
  188. Y.F. Wen, B. Wang, B. Luo, L.Z. Wang, Long-term cycling performance of nitrogen-doped hollow carbon nanospheres as anode materials for sodium-ion batteries. Eur. J. Inorg. Chem. 13–14, 2051–2055 (2016). https://doi.org/10.1002/ejic.201501172
  189. K.L. Zhang, X.N. Li, J.W. Liang, Y.C. Zhu, L. Hu et al., Nitrogen-doped porous interconnected double-shelled hollow carbon spheres with high capacity for lithium ion batteries and sodium ion batteries. Electrochim. Acta 155, 174–182 (2015). https://doi.org/10.1016/j.electacta.2014.12.108
  190. W.C. Zhang, C.W. Lan, X.H. Xie, Q.Y. Cao, M.T. Zheng et al., Facile construction of hollow carbon nanosphere-interconnected network for advanced sodium-ion battery anode. J. Colloid Interface Sci. 546, 53–59 (2019). https://doi.org/10.1016/j.jcis.2019.03.043
  191. Y.H. Qu, Y.M. Deng, Q. Li, Z. Zhang, F.Y. Zeng et al., Core-shell-structured hollow carbon nanofiber@nitrogen-doped porous carbon composite materials as anodes for advanced sodium-ion batteries. J. Mater. Sci. 52(4), 2356–2365 (2017). https://doi.org/10.1007/s10853-016-0528-x
  192. J.S. Park, S.Y. Jeong, K.M. Jeon, Y.C. Kang, J.S. Cho, Iron diselenide combined with hollow graphitic carbon nanospheres as a high-performance anode material for sodium-ion batteries. Chem. Eng. J. 339, 97–107 (2018). https://doi.org/10.1016/j.cej.2018.01.118
  193. Y.X. Luan, G.D. Nie, X.W. Zhao, N. Qiao, X.C. Liu et al., The integration of sno2 dots and porous carbon nanofibers for flexible supercapacitors. Electrochim. Acta 308, 121–130 (2019). https://doi.org/10.1016/j.electacta.2019.03.204
  194. X.W. Zhao, G.D. Nie, Y.X. Luan, X.X. Wang, S.Y. Yan et al., Nitrogen-doped carbon networks derived from the electrospun polyacrylonitrile@branched polyethylenimine nanofibers as flexible supercapacitor electrodes. J. Alloys Compd. 808, 151737 (2019). https://doi.org/10.1016/j.jallcom.2019.151737
  195. S.Z. Zeng, Y.C. Yao, L. Huang, H.L. Wu, B.L. Peng et al., Facile synthesis of ultrahigh-surface-area hollow carbon nanospheres and their application in lithium-sulfur batteries. Chem. Eur. J. 24(8), 1988–1997 (2018). https://doi.org/10.1002/chem.201705211
  196. K. Zhang, Q. Zhao, Z.L. Tao, J. Chen, Composite of sulfur impregnated in porous hollow carbon spheres as the cathode of Li-S batteries with high performance. Nano Res. 6(1), 38–46 (2013). https://doi.org/10.1007/s12274-012-0279-1
  197. W.D. Zhou, X.C. Xiao, M. Cai, L. Yang, Polydopamine-coated, nitrogen-doped, hollow carbon sulfur double-layered core-shell structure for improving lithium sulfur batteries. Nano Lett. 14(9), 5250–5256 (2014). https://doi.org/10.1021/nl502238b
  198. C.F. Zhang, H.B. Wu, C.Z. Yuan, Z.P. Guo, X.W. Lou, Confining sulfur in double-shelled hollow carbon spheres for lithium-sulfur batteries. Angew. Chem. Int. Ed. 51(38), 9592–9595 (2012). https://doi.org/10.1002/anie.201205292
  199. W.D. Zhou, C.M. Wang, Q.L. Zhang, H.D. Abruna, Y. He et al., Tailoring pore size of nitrogen-doped hollow carbon nanospheres for confining sulfur in lithium-sulfur batteries. Adv. Energy Mater. 5(16), 1401752 (2015). https://doi.org/10.1002/aenm.201401752
  200. X.J. Zhou, J. Tian, Q.P. Wu, J.L. Hu, C.L. Li, N/O dual-doped hollow carbon microspheres constructed by holey nanosheet shells as large-grain cathode host for high loading Li-S batteries. Energy Storage Mater. 24, 644–654 (2020). https://doi.org/10.1016/j.ensm.2019.06.009
  201. L. Zhang, B.W. Zhang, Y.H. Dou, Y.X. Wang, M. Al-Mamun et al., Self-assembling hollow carbon nanobeads into double-shell microspheres as a hierarchical sulfur host for sustainable room-temperature sodium sulfur batteries. ACS Appl. Mater. Interfaces 10(24), 20422–20428 (2018). https://doi.org/10.1021/acsami.8b03850
  202. Y.J. Zhong, S.F. Wang, Y.J. Sha, M.L. Liu, R. Cai et al., Trapping sulfur in hierarchically porous, hollow indented carbon spheres: a high-performance cathode for lithium-sulfur batteries. J. Mater. Chem. A 4(24), 9526–9535 (2016). https://doi.org/10.1039/c6ta03187k
  203. Y.P. Xie, L. Fang, H.W. Cheng, C.J. Hu, H.B. Zhao et al., Biological cell derived N-doped hollow porous carbon microspheres for lithium-sulfur batteries. J. Mater. Chem. A 4(40), 15612–15620 (2016). https://doi.org/10.1039/c6ta06164h
  204. S.N. Liu, T.Q. Zhao, X.H. Tan, L.M. Guo, J.X. Wu et al., 3D pomegranate-like structures of porous carbon microspheres self-assembled by hollow thin-walled highly-graphitized nanoballs as sulfur immobilizers for Li-S batteries. Nano Energy (2019). https://doi.org/10.1016/j.nanoen.2019.103894
  205. N. Jayaprakash, J. Shen, S.S. Moganty, A. Corona, L.A. Archer, Porous hollow carbon@sulfur composites for high-power lithium-sulfur batteries. Angew. Chem. Int. Ed. 50(26), 5904–5908 (2011). https://doi.org/10.1002/anie.201100637
  206. G.L. Xia, L.J. Zhang, X.W. Chen, Y.Q. Huang, D.L. Sun et al., Carbon hollow nanobubbles on porous carbon nanofibers: an ideal host for high-performance sodium-sulfur batteries and hydrogen storage. Energy Storage Mater. 14, 314–323 (2018). https://doi.org/10.1016/j.ensm.2018.05.008
  207. G. Nie, X. Zhao, Y. Luan, J. Jiang, Z. Kou et al., Key issues facing electrospun carbon nanofibers in energy applications: on-going approaches and challenges. Nanoscale 12, 13225–13248 (2020). https://doi.org/10.1039/D0NR03425H
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