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Vol. 14 (2022)

Electrochemical Proton Storage: From Fundamental Understanding to Materials to Devices

https://doi.org/10.1007/s40820-022-00864-y
Tiezhu Xu
Jiangsu Key Laboratory of Electrochemical Energy Storage Technologies, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, People’s Republic of China
Di Wang
Jiangsu Key Laboratory of Electrochemical Energy Storage Technologies, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, People’s Republic of China
Zhiwei Li
Jiangsu Key Laboratory of Electrochemical Energy Storage Technologies, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, People’s Republic of China
Ziyang Chen
Jiangsu Key Laboratory of Electrochemical Energy Storage Technologies, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, People’s Republic of China
Jinhui Zhang
Jiangsu Key Laboratory of Electrochemical Energy Storage Technologies, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, People’s Republic of China
Tingsong Hu
Jiangsu Key Laboratory of Electrochemical Energy Storage Technologies, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, People’s Republic of China
Xiaogang Zhang
Jiangsu Key Laboratory of Electrochemical Energy Storage Technologies, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, People’s Republic of China
Laifa Shen
Jiangsu Key Laboratory of Electrochemical Energy Storage Technologies, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, People’s Republic of China

Corresponding Author: Laifa Shen

lfshen@nuaa.edu.cn

Nano-Micro Letters, Vol. 14 (2022), Article Number: 126

Abstract

Simultaneously improving the energy density and power density of electrochemical energy storage systems is the ultimate goal of electrochemical energy storage technology. An effective strategy to achieve this goal is to take advantage of the high capacity and rapid kinetics of electrochemical proton storage to break through the power limit of batteries and the energy limit of capacitors. This article aims to review the research progress on the physicochemical properties, electrochemical performance, and reaction mechanisms of electrode materials for electrochemical proton storage. According to the different charge storage mechanisms, the surface redox, intercalation, and conversion materials are classified and introduced in detail, where the influence of crystal water and other nanostructures on the migration kinetics of protons is clarified. Several reported advanced full cell devices are summarized to promote the commercialization of electrochemical proton storage. Finally, this review provides a framework for research directions of charge storage mechanism, basic principles of material structure design, construction strategies of full cell device, and goals of practical application for electrochemical proton storage.


Highlights:


1 Fundamental principles and advantages of electrochemical proton storage are briefly reviewed.
2 Research progresses and strategies to promote the development of electrochemical proton storage based on various charge storage mechanisms, electrode materials, and devices are discussed and summarized.
3 Challenges and perspectives of the next-generation electrochemical proton storage technology are discussed.

Keywords

Electrochemical proton storage Rapid kinetics Charge storage mechanism Material design Device construction
Xu, Tiezhu, Di Wang, Zhiwei Li, Ziyang Chen, Jinhui Zhang, Tingsong Hu, Xiaogang Zhang, and Laifa Shen. 2022. “Electrochemical Proton Storage: From Fundamental Understanding to Materials to Devices”. Nano-Micro Letters 14 (June):126. https://doi.org/10.1007/s40820-022-00864-y.
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