Issue

Vol. 14 (2022)

Multi-Dimensional Composite Frame as Bifunctional Catalytic Medium for Ultra-Fast Charging Lithium–Sulfur Battery

https://doi.org/10.1007/s40820-022-00941-2
Shuhao Tian
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China
Qi Zeng
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China
Guo Liu
School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Juanjuan Huang
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China
Xiao Sun
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China
Di Wang
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China
Hongcen Yang
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China
Zhe Liu
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China
Xichao Mo
School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Zhixia Wang
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China
Kun Tao
School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Shanglong Peng
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China

Corresponding Author: Shanglong Peng

pengshl@lzu.edu.cn

Nano-Micro Letters, Vol. 14 (2022), Article Number: 196

Abstract

The shuttle effect of soluble lithium polysulfides (LiPSs) between electrodes and slow reaction kinetics lead to extreme inefficiency and poor high current cycling stability, which limits the commercial application of Li–S batteries. Herein, the multi-dimensional composite frame has been proposed as the modified separator (MCCoS/PP) of Li–S battery, which is composed of CoS2 nanoparticles on alkali-treated MXene nanosheets and carbon nanotubes. Both experiments and theoretical calculations show that bifunctional catalytic activity can be achieved on the MCCoS/PP separator. It can not only promote the liquid–solid conversion in the reduction process, but also accelerate the decomposition of insoluble Li2S in the oxidation process. In addition, LiPSs shuttle effect has been inhibited without a decrease in lithium-ion transference numbers. Simultaneously, the MCCoS/PP separator with good LiPSs adsorption capability arouses redistribution and fixing of active substances, which is also beneficial to the rate performance and cycling stability. The Li–S batteries with the MCCoS/PP separator have a specific capacity of 368.6 mAh g−1 at 20C, and the capacity decay per cycle is only 0.033% in 1000 cycles at 7C. Also, high area capacity (6.34 mAh cm−2) with a high sulfur loading (7.7 mg cm−2) and a low electrolyte/sulfur ratio (7.5 μL mg−1) is achieved.


Highlights:


1 The presence of Ti–O-Co bonds of the multi-dimensional composite frame separator (MCCoS/PP) promotes kinetics and enables bifunctional catalysis.
2 The existence of MCCoS/PP cannot reduce the lithium-ion transference numbers.
3 The Li–S battery with MCCoS/PP achieves super-high rate (368.6 mAh g−1 at 20C) and ultra-low capacity attenuation rate.

Keywords

MXenes Transition metal sulfides Lithium-ion transference Bifunctional catalysis Reaction kinetics
Tian, Shuhao, Qi Zeng, Guo Liu, Juanjuan Huang, Xiao Sun, Di Wang, Hongcen Yang, Zhe Liu, Xichao Mo, Zhixia Wang, Kun Tao, and Shanglong Peng. 2022. “Multi-Dimensional Composite Frame As Bifunctional Catalytic Medium for Ultra-Fast Charging Lithium–Sulfur Battery”. Nano-Micro Letters 14 (October):196. https://doi.org/10.1007/s40820-022-00941-2.
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