Issue

Vol. 14 (2022)

Multi-Dimensional Composite Frame as Bifunctional Catalytic Medium for Ultra-Fast Charging Lithium–Sulfur Battery

https://doi.org/10.1007/s40820-022-00941-2
Shuhao Tian
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China
Qi Zeng
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China
Guo Liu
School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Juanjuan Huang
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China
Xiao Sun
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China
Di Wang
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China
Hongcen Yang
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China
Zhe Liu
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China
Xichao Mo
School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Zhixia Wang
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China
Kun Tao
School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Shanglong Peng
National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology, School of Materials and Energy, Lanzhou University, Lanzhou 730000, People’s Republic of China

Corresponding Author: Shanglong Peng

pengshl@lzu.edu.cn

Nano-Micro Letters, Vol. 14 (2022), Article Number: 196

Abstract

The shuttle effect of soluble lithium polysulfides (LiPSs) between electrodes and slow reaction kinetics lead to extreme inefficiency and poor high current cycling stability, which limits the commercial application of Li–S batteries. Herein, the multi-dimensional composite frame has been proposed as the modified separator (MCCoS/PP) of Li–S battery, which is composed of CoS2 nanoparticles on alkali-treated MXene nanosheets and carbon nanotubes. Both experiments and theoretical calculations show that bifunctional catalytic activity can be achieved on the MCCoS/PP separator. It can not only promote the liquid–solid conversion in the reduction process, but also accelerate the decomposition of insoluble Li2S in the oxidation process. In addition, LiPSs shuttle effect has been inhibited without a decrease in lithium-ion transference numbers. Simultaneously, the MCCoS/PP separator with good LiPSs adsorption capability arouses redistribution and fixing of active substances, which is also beneficial to the rate performance and cycling stability. The Li–S batteries with the MCCoS/PP separator have a specific capacity of 368.6 mAh g−1 at 20C, and the capacity decay per cycle is only 0.033% in 1000 cycles at 7C. Also, high area capacity (6.34 mAh cm−2) with a high sulfur loading (7.7 mg cm−2) and a low electrolyte/sulfur ratio (7.5 μL mg−1) is achieved.


Highlights:


1 The presence of Ti–O-Co bonds of the multi-dimensional composite frame separator (MCCoS/PP) promotes kinetics and enables bifunctional catalysis.
2 The existence of MCCoS/PP cannot reduce the lithium-ion transference numbers.
3 The Li–S battery with MCCoS/PP achieves super-high rate (368.6 mAh g−1 at 20C) and ultra-low capacity attenuation rate.

Keywords

MXenes Transition metal sulfides Lithium-ion transference Bifunctional catalysis Reaction kinetics
Tian, Shuhao, Qi Zeng, Guo Liu, Juanjuan Huang, Xiao Sun, Di Wang, Hongcen Yang, Zhe Liu, Xichao Mo, Zhixia Wang, Kun Tao, and Shanglong Peng. 2022. “Multi-Dimensional Composite Frame As Bifunctional Catalytic Medium for Ultra-Fast Charging Lithium–Sulfur Battery”. Nano-Micro Letters 14 (October):196. https://doi.org/10.1007/s40820-022-00941-2.
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References
  1. J. Kim, D.J. Lee, H.G. Jung, Y.K. Sun, J. Hassoun et al., An advanced lithium-sulfur battery. Adv. Funct. Mater. 23(8), 1076–1080 (2013). https://doi.org/10.1002/adfm.201200689
  2. J. Wang, S. Yi, J. Liu, S. Sun, Y. Liu et al., Suppressing the shuttle effect and dendrite growth in lithium–sulfur batteries. ACS Nano 14(8), 9819–9831 (2020). https://doi.org/10.1021/acsnano.0c02241
  3. B. Jiang, D. Tian, Y. Qiu, X. Song, Y. Zhang et al., High index faceted nanocrystals as highly efficient bifunctional electrocatalysts for high-performance lithium–sulfur batteries. Nano-Micro Lett. 14, 40 (2022). https://doi.org/10.1007/s40820-021-00769-2
  4. Z. Ye, Y. Jiang, L. Li, F. Wu, R. Chen, Rational design of MOF-based materials for next-generation rechargeable batteries. Nano-Micro Lett. 13, 203 (2021). https://doi.org/10.1007/s40820-021-00726-z
  5. R. Wu, S. Chen, J. Deng, X. Huang, Y. Song et al., Hierarchically porous nitrogen-doped carbon as cathode for lithium–sulfur batteries. J. Energy Chem. 27(6), 1661–1667 (2018). https://doi.org/10.1016/j.jechem.2018.02.010
  6. T. Li, X. Bai, U. Gulzar, Y.J. Bai, C. Capiglia et al., A comprehensive understanding of lithium–sulfur battery technology. Adv. Funct. Mater. 29(32), 1901730 (2019). https://doi.org/10.1002/adfm.201901730
  7. M. Zhang, W. Chen, L. Xue, Y. Jiao, T. Lei et al., Adsorption-catalysis design in the lithium-sulfur battery. Adv. Energy Mater. 10(2), 1903008 (2020). https://doi.org/10.1002/aenm.201903008
  8. X. Huang, J. Tang, B. Luo, R. Knibbe, T. Lin et al., Sandwich-like ultrathin TiS2 nanosheets confined within N, S codoped porous carbon as an effective polysulfide promoter in lithium-sulfur batteries. Adv. Energy Mater. 9(32), 1901872 (2019). https://doi.org/10.1002/aenm.201901872
  9. Z. Cheng, Z. Xiao, H. Pan, S. Wang, R. Wang, Elastic sandwich-Type rGO–VS2/S composites with high tap density: structural and chemical cooperativity enabling lithium–sulfur batteries with high energy density. Adv. Energy Mater. 8(10), 1702337 (2018). https://doi.org/10.1002/aenm.201702337
  10. S.D. Seo, D. Park, S. Park, D.W. Kim, “Brain-coral-like” mesoporous hollow CoS2@N-doped graphitic carbon nanoshells as efficient sulfur reservoirs for lithium–sulfur batteries. Adv. Funct. Mater. 29(38), 1903712 (2019). https://doi.org/10.1002/adfm.201903712
  11. S. Li, P. Xu, M.K. Aslam, C. Chen, A. Rashid et al., Propelling polysulfide conversion for high-loading lithium–sulfur batteries through highly sulfiphilic NiCo2S4 nanotubes. Energy Storage Mater. 27, 51–60 (2020). https://doi.org/10.1016/j.ensm.2020.01.017
  12. Y. Wei, P. Zhang, R.A. Soomro, Q. Zhu, B. Xu, Advances in the Synthesis of 2D MXenes. Adv. Mater. 33(39), 2103148 (2021). https://doi.org/10.1002/adma.202103148
  13. Q. Zhao, Q. Zhu, Y. Liu, B. Xu, Status and prospects of MXene-based lithium–sulfur batteries. Adv. Funct. Mater. 31(21), 2100457 (2021). https://doi.org/10.1002/adfm.202100457
  14. J.Q. Huang, Q. Zhang, F. Wei, Multi-functional separator/interlayer system for high-stable lithium-sulfur batteries: progress and prospects. Energy Storage Mater. 1, 127–145 (2015). https://doi.org/10.1016/j.ensm.2015.09.008
  15. L. Fan, M. Li, X. Li, W. Xiao, Z. Chen et al., Interlayer material selection for lithium-sulfur batteries. Joule 3(2), 361–386 (2019). https://doi.org/10.1016/j.joule.2019.01.003
  16. J. Luo, E. Matios, H. Wang, X. Tao, W. Li, Interfacial structure design of MXene-based nanomaterials for electrochemical energy storage and conversion. Infomat 2(6), 1057–1076 (2020). https://doi.org/10.1002/inf2.12118
  17. K. Liang, A. Tabassum, A. Majed, C. Dun, F. Yang et al., Synthesis of new two-dimensional titanium carbonitride Ti2C0.5N0.5Tx MXene and its performance as an electrode material for sodium-ion battery. Infomat 3(12), 1422–1430 (2021). https://doi.org/10.1002/inf2.12269
  18. S. Zhang, N. Zhong, X. Zhou, M. Zhang, X. Huang et al., Comprehensive design of the high-sulfur-loading Li–S battery based on MXene nanosheets. Nano-Micro Lett. 12, 112 (2020). https://doi.org/10.1007/s40820-020-00449-7
  19. L. Jiao, C. Zhang, C. Geng, S. Wu, H. Li et al., Capture and catalytic conversion of polysulfides by in situ built TiO2-MXene heterostructures for lithium–sulfur batteries. Adv. Energy Mater. 9(19), 1900219 (2019). https://doi.org/10.1002/aenm.201900219
  20. D. Xiong, S. Huang, D. Fang, D. Yan, G. Li et al., Porosity engineering of MXene membrane towards polysulfide inhibition and fast lithium ion transportation for lithium–sulfur batteries. Small 17(34), 2007442 (2021). https://doi.org/10.1002/smll.202007442
  21. P. Li, H. Lv, Z. Li, X. Meng, Z. Lin et al., The electrostatic attraction and catalytic effect enabled by ionic–covalent organic nanosheets on MXene for separator modification of lithium–sulfur batteries. Adv. Mater. 33(17), 2007803 (2021). https://doi.org/10.1002/adma.202007803
  22. J. Xia, W. Chen, Y. Yang, X. Guan, T. Yang et al., In-situ growth of ultrathin sulfur microcrystal on MXene-based 3D matrice for flexible lithium–sulfur batteries. EcoMat 4(3), e12183 (2022). https://doi.org/10.1002/eom2.12183
  23. M. Xu, L. Liang, J. Qi, T. Wu, D. Zhou et al., Intralayered Ostwald ripening-induced self-catalyzed growth of CNTs on MXene for robust lithium–sulfur batteries. Small 17(17), 2007446 (2021). https://doi.org/10.1002/smll.202007446
  24. S. Nam, J. Kim, V.H. Nguyen, M. Mahato, S. Oh et al., Collectively exhaustive MXene and graphene oxide multilayer for suppressing shuttling effect in flexible lithium sulfur battery. Adv. Mater. Technol. 7(5), 2101025 (2022). https://doi.org/10.1002/admt.202101025
  25. J. Nan, X. Guo, J. Xiao, X. Li, W. Chen et al., Nanoengineering of 2D MXene-based materials for energy storage applications. Small 17(9), 1902085 (2019). https://doi.org/10.1002/smll.201902085
  26. X. Tang, X. Guo, W. Wu, G. Wang, 2d metal carbides and nitrides (mxenes) as high-performance electrode materials for lithium-based batteries. Adv. Energy Mater. 8(33), 1801897 (2018). https://doi.org/10.1002/aenm.201801897
  27. M. Zhao, X. Xie, C.E. Ren, T. Makaryan, B. Anasori et al., Hollow MXene spheres and 3D macroporous MXene frameworks for Na-ion storage. Adv. Mater. 29(37), 1702410 (2017). https://doi.org/10.1002/adma.201702410
  28. C.F. Du, X. Sun, H. Yu, W. Fang, Y. Jing et al., V4C3Tx MXene: a promising active substrate for reactive surface modification and the enhanced electrocatalytic oxygen evolution activity. Infomat 2(5), 950–959 (2020). https://doi.org/10.1002/inf2.12078
  29. P. Zeng, L. Huang, X. Zhang, Y. Han, Y. Chen, Inhibiting polysulfides diffusion of lithium-sulfur batteries using an acetylene Black-CoS2 modified separator: mechanism research and performance improvement. Appl. Surf. Sci. 427, 242–252 (2018). https://doi.org/10.1016/j.apsusc.2017.08.062
  30. Y. Boyjoo, H. Shi, Q. Tian, S. Liu, J. Liang et al., Engineering nanoreactors for metal–chalcogen batteries. Energy Environ. Sci. 14(2), 540–575 (2021). https://doi.org/10.1039/D0EE03316B
  31. H. Shi, J. Qin, P. Lu, C. Dong, J. He et al., Interfacial engineering of bifunctional niobium (V)-based heterostructure nanosheet toward high efficiency lean-electrolyte lithium–sulfur full batteries. Adv. Funct. Mater. 31(28), 2102314 (2021). https://doi.org/10.1002/adfm.202102314
  32. H. Shi, X. Zhao, Z. Wu, Y. Dong, P. Lu et al., Free-standing integrated cathode derived from 3D graphene/carbon nanotube aerogels serving as binder-free sulfur host and interlayer for ultrahigh volumetric-energy-density lithium sulfur batteries. Nano Energy 60, 743–751 (2019). https://doi.org/10.1016/j.nanoen.2019.04.006
  33. C. Zhang, L. Cui, S. Abdolhosseinzadeh, J. Heier, Two-dimensional MXenes for lithium–sulfur batteries. Infomat 2(4), 613–638 (2020). https://doi.org/10.1002/inf2.12080
  34. D. Xiong, X. Li, Z. Bai, S. Lu, Recent advances in layered Ti3C2Tx MXene for electrochemical energy storage. Small 14(17), 1703419 (2018). https://doi.org/10.1002/smll.201703419
  35. J. Liu, A. Wei, G. Pan, Q. Xiong, F. Chen et al., Atomic layer deposition-assisted construction of binder-free Ni@N-doped carbon nanospheres films as advanced host for sulfur cathode. Nano-Micro Lett. 11, 64 (2019). https://doi.org/10.1007/s40820-019-0295-8
  36. Q. Zhao, Q. Zhu, J. Miao, P. Zhang, P. Wan et al., Flexible 3D porous MXene foam for high-performance lithium-ion batteries. Small 15(51), 1904293 (2019). https://doi.org/10.1002/smll.201904293
  37. P. Liu, L. Qu, X. Tian, Y. Yi, J. Xia et al., Ti3C2Tx/graphene oxide free-standing membranes as modified separators for lithium–sulfur batteries with enhanced rate performance. ACS Appl. Energy Mater. 3, 2708–2718 (2020). https://doi.org/10.1021/acsaem.9b02385
  38. Y. Dong, S. Zheng, J. Qin, X. Zhao, H. Shi et al., All-MXene-based integrated electrode constructed by Ti3C2 nanoribbon framework host and nanosheet interlayer for high-energy-density Li–S batteries. ACS Nano 12(3), 2381–2388 (2018). https://doi.org/10.1021/acsnano.7b07672
  39. H. Tang, W. Li, L. Pan, C.P. Cullen, Y. Liu et al., In situ formed protective barrier enabled by sulfur@titanium carbide (MXene) ink for achieving high-capacity, long lifetime Li–S batteries. Adv. Sci. 5(9), 1800502 (2018). https://doi.org/10.1002/advs.201800502
  40. Y. Boyjoo, H. Shi, E. Olsson, Q. Cai, Z. Wu et al., Molecular-level design of pyrrhotite electrocatalyst decorated hierarchical porous carbon spheres as nanoreactors for lithium–sulfur batteries. Adv. Energy Mater. 10(20), 2000651 (2020). https://doi.org/10.1002/aenm.202000651
  41. S. Zhang, H. Shi, J. Tang, W. Shi, Z. Wu et al., Super-aligned films of sub-1 nm Bi2O3-polyoxometalate nanowires as interlayers in lithium-sulfur batteries. Sci. China Mater. 64, 2949–2957 (2021). https://doi.org/10.1007/s40843-021-1688-7
  42. H. Shi, Y. Dong, F. Zhou, J. Chen, Z. Wu, 2D hybrid interlayer of electrochemically exfoliated graphene and Co(OH)2 nanosheet as a bi-functionalized polysulfide barrier for high-performance lithium–sulfur batteries. J. Phys. Energy 1(1), 015002 (2018). https://doi.org/10.1088/2515-7655/aadef6
  43. Z. Zhao, H. Su, S. Li, C. Li, Z. Liu et al., Ball-in-ball structured SnO2@FeOOH@C nanospheres toward advanced anode material for sodium ion batteries. J. Alloys Comput. 838, 155394 (2020). https://doi.org/10.1016/j.jallcom.2020.155394
  44. D. Zhao, R. Zhao, S. Dong, X. Miao, Z. Zhang et al., Alkali-induced 3D crinkled porous Ti3C2 MXene architectures coupled with NiCoP bimetallic phosphide nanops as anodes for high-performance sodium-ion batteries. Energy Environ. Sci. 12(8), 2422–2432 (2019). https://doi.org/10.1039/C9EE00308H
  45. W. Bao, X. Xie, J. Xu, X. Guo, J. Song et al., Confined sulfur in 3 D MXene/reduced graphene oxide hybrid nanosheets for lithium–sulfur battery. Chem. A Eur. J. 23(51), 12613–12619 (2017). https://doi.org/10.1002/chem.201702387
  46. G. Ai, Q. Hu, L. Zhang, K. Dai, J. Wang et al., Investigation of the nanocrystal CoS2 embedded in 3D honeycomb-like graphitic carbon with a synergistic effect for high-performance lithium sulfur batteries. ACS Appl. Mater. Interfaces 11(37), 33987–33999 (2019). https://doi.org/10.1021/acsami.9b11561
  47. L. Hong, S. Ju, Y. Yang, J. Zheng, G. Xia et al., Hollow-shell structured porous CoSe2 microspheres encapsulated by MXene nanosheets for advanced lithium storage. Sustain. Energy Fuels 4(5), 2352–2362 (2020). https://doi.org/10.1039/C9SE01271K
  48. M. Jing, M. Zhou, G. Li, Z. Chen, W. Xu et al., Graphene-embedded Co3O4 rose-spheres for enhanced performance in lithium ion batteries. ACS Appl. Mater. Interfaces 9(11), 9662–9668 (2017). https://doi.org/10.1021/acsami.6b16396
  49. Y. Li, R. Guo, Y. Sun, Y. Wang, W. Liu et al., Synthesis of CoS2 nanops/nitrogen-doped graphitic carbon/carbon nanotubes composite as an advanced anode for sodium-ion batteries. ChemElectroChem 7(13), 2752–2761 (2020). https://doi.org/10.1002/celc.201902053
  50. C. Ma, Y. Zhang, Y. Feng, N. Wang, L. Zhou et al., Engineering Fe–N coordination structures for fast redox conversion in lithium–sulfur batteries. Adv. Mater. 33, 2100171 (2021). https://doi.org/10.1002/adma.202100171
  51. Z. Ye, Y. Jiang, L. Li, F. Wu, R. Chen, Self-assembly of 0D–2D heterostructure electrocatalyst from MOF and MXene for boosted lithium polysulfide conversion reaction. Adv. Mater. 33, 2101204 (2021). https://doi.org/10.1002/adma.202101204
  52. X. Huang, J. Tang, T. Qiu, R. Knibbe, Y. Hu et al., Nanoconfined topochemical conversion from MXene to ultrathin non-layered tin nanomesh toward superior electrocatalysts for lithium-sulfur batteries. Small 17(32), 2101360 (2021). https://doi.org/10.1002/smll.202101360
  53. J. Xu, L. Yang, S. Cao, J. Wang, Y. Ma et al., Sandwiched cathodes assembled from CoS2-modified carbon clothes for high-performance lithium-sulfur batteries. Adv. Sci. 8(16), 2101019 (2021). https://doi.org/10.1002/advs.202101019
  54. Z. Du, X. Chen, W. Hu, C. Chuang, S. Xie et al., Cobalt in nitrogen-doped graphene as single-atom catalyst for high-sulfur content lithium–sulfur batteries. J. Am. Chem. Soc. 141(9), 3977–3985 (2019). https://doi.org/10.1021/jacs.8b12973
  55. D. Yang, Z. Liang, C. Zhang, J.J. Biendicho, M. Botifoll et al., NbSe2 meets C2N: a 2D–2D heterostructure catalysts as multifunctional polysulfide mediator in ultra-long-life lithium–sulfur batteries. Adv. Energy Mater. 11(36), 2101250 (2021). https://doi.org/10.1002/aenm.202101250
  56. W. Wang, L. Huai, S. Wu, J. Shan, J. Zhu et al., Ultrahigh-volumetric-energy-density lithium–sulfur batteries with lean electrolyte enabled by cobalt-doped MoSe2/Ti3C2Tx MXene bifunctional catalyst. ACS Nano 15(7), 11619–11633 (2021). https://doi.org/10.1021/acsnano.1c02047
  57. Z. Xiao, Z. Li, P. Li, X. Meng, Z. Lin et al., Ultrafine Ti3C2 MXene nanodots-interspersed nanosheet for high-energy-density lithium–sulfur batteries. ACS Nano 13(3), 3608–3617 (2019). https://doi.org/10.1021/acsnano.9b00177
  58. D. Zhang, S. Wang, R. Hu, J. Gu, Y. Cui et al., Catalytic conversion of polysulfides on single atom zinc implanted MXene toward high-rate lithium–sulfur batteries. Adv. Funct. Mater. 30(30), 2002471 (2020). https://doi.org/10.1002/adfm.202002471
  59. Y. Li, P. Zhou, H. Li, T. Gao, L. Zhou et al., A freestanding flexible single-atom cobalt-based multifunctional interlayer toward reversible and durable lithium-sulfur batteries. Small Methods 4(3), 1900701 (2020). https://doi.org/10.1002/smtd.201900701
  60. Z. Cao, J. Guo, S. Chen, Z. Zhang, Z. Shi et al., In situ synthesis of an ultrafine heterostructural Nb2O5–NbC polysulfide promotor for high-performance Li–S batteries. J. Mater. Chem. A 9(38), 21867–21876 (2021). https://doi.org/10.1039/D1TA05657C
  61. W. Bao, L. Liu, C. Wang, S. Choi, D. Wang et al., Facile synthesis of crumpled Nitrogen-doped MXene nanosheets as a new sulfur host for lithium–sulfur batteries. Adv. Energy Mater. 8(13), 1702485 (2018). https://doi.org/10.1002/aenm.201702485
  62. L.P. Lv, C.F. Guo, W. Sun, Y. Wang, Strong surface-bound sulfur in carbon nanotube bridged hierarchical Mo2C-based MXene nanosheets for lithium–sulfur batteries. Small 15(3), 1804338 (2019). https://doi.org/10.1002/smll.201804338
  63. W. Bao, D. Su, W. Zhang, X. Guo, G. Wang, 3D metal Carbide@Mesoporous carbon hybrid architecture as a new polysulfide reservoir for lithium-sulfur batteries. Adv. Funct. Mater. 26(47), 8746–8756 (2016). https://doi.org/10.1002/adfm.201603704
  64. Y. Zhang, Z. Mu, C. Yang, Z. Xu, S. Zhang et al., Rational design of MXene/1T-2H MoS2-C nanohybrids for high-performance lithium–sulfur batteries. Adv. Funct. Mater. 28(38), 1707578 (2018). https://doi.org/10.1002/adfm.201707578
  65. B. Zhang, C. Luo, G. Zhou, Z.Z. Pan, J. Ma et al., Lamellar MXene composite aerogels with sandwiched carbon nanotubes enable stable lithium–sulfur batteries with a high sulfur loading. Adv. Funct. Mater. 31(26), 2100793 (2021). https://doi.org/10.1002/adfm.202100793
  66. H. Zhang, L. Yang, P. Zhang, C. Lu, D. Sha et al., MXene-derived TinO2n−1 quantum dots distributed on porous carbon nanosheets for stable and long-life Li–S batteries: enhanced polysulfide mediation via defect engineering. Adv. Mater. 33(21), 2008447 (2021). https://doi.org/10.1002/adma.202008447
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