Issue

Vol. 16 (2024)

Ultrafast Response and Threshold Adjustable Intelligent Thermoelectric Systems for Next-Generation Self-Powered Remote IoT Fire Warning

https://doi.org/10.1007/s40820-024-01453-x
Zhaofu Ding
College of Materials Science and Engineering & College of Civil and Transportation Engineering, Shenzhen University, Shenzhen 518055, People’s Republic of China
Gang Li
College of Materials Science and Engineering & College of Civil and Transportation Engineering, Shenzhen University, Shenzhen 518055, People’s Republic of China
Yejun Wang
College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of MoE, Hangzhou Normal University, Hangzhou 311121, People’s Republic of China
Chunyu Du
College of Materials Science and Engineering & College of Civil and Transportation Engineering, Shenzhen University, Shenzhen 518055, People’s Republic of China
Zhenqiang Ye
College of Materials Science and Engineering & College of Civil and Transportation Engineering, Shenzhen University, Shenzhen 518055, People’s Republic of China
Lirong Liang
College of Materials Science and Engineering & College of Civil and Transportation Engineering, Shenzhen University, Shenzhen 518055, People’s Republic of China
Long‑Cheng Tang
College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of MoE, Hangzhou Normal University, Hangzhou 311121, People’s Republic of China
Guangming Chen
College of Materials Science and Engineering & College of Civil and Transportation Engineering, Shenzhen University, Shenzhen 518055, People’s Republic of China

Corresponding Author: Guangming Chen

chengm@szu.edu.cn

Nano-Micro Letters, Vol. 16 (2024), Article Number: 242

Abstract

Fire warning is vital to human life, economy and ecology. However, the development of effective warning systems faces great challenges of fast response, adjustable threshold and remote detecting. Here, we propose an intelligent self-powered remote IoT fire warning system, by employing single-walled carbon nanotube/titanium carbide thermoelectric composite films. The flexible films, prepared by a convenient solution mixing, display p-type characteristic with excellent high-temperature stability, flame retardancy and TE (power factor of 239.7 ± 15.8 μW m−1 K−2) performances. The comprehensive morphology and structural analyses shed light on the underlying mechanisms. And the assembled TE devices (TEDs) exhibit fast fire warning with adjustable warning threshold voltages (1–10 mV). Excitingly, an ultrafast fire warning response time of ~ 0.1 s at 1 mV threshold voltage is achieved, rivaling many state-of-the-art systems. Furthermore, TE fire warning systems reveal outstanding stability after 50 repeated cycles and desired durability even undergoing 180 days of air exposure. Finally, a TED-based wireless intelligent fire warning system has been developed by coupling an amplifier, analog-to-digital converter and Bluetooth module. By combining TE characteristics, high-temperature stability and flame retardancy with wireless IoT signal transmission, TE-based hybrid system developed here is promising for next-generation self-powered remote IoT fire warning applications.


Highlights:
1 The flexible single-walled carbon nanotube/titanium carbide composite films exhibit excellent thermoelectric (TE), high-temperature stable and flame-retardant properties.
2 The assembled TE device achieves an ultrafast fire warning response time of ~ 0.1 s with a threshold voltage of 1 mV.
3 The fire warning device demonstrates exceptional repeatability and long-term stability.
4 The designed intelligent system is promising for next-generation self-powered remote IoT fire warning applications.

Keywords

Thermoelectric Self-powered IoT fire warning Ultrafast response Threshold adjustable
Ding, Zhaofu, Gang Li, Yejun Wang, Chunyu Du, Zhenqiang Ye, Lirong Liang, Long‑Cheng Tang, and Guangming Chen. 2024. “Ultrafast Response and Threshold Adjustable Intelligent Thermoelectric Systems for Next-Generation Self-Powered Remote IoT Fire Warning”. Nano-Micro Letters 16 (July):242. https://doi.org/10.1007/s40820-024-01453-x.
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References
  1. D.M.J.S. Bowman, J.K. Balch, P. Artaxo, W.J. Bond, J.M. Carlson et al., Fire in the earth system. Science 324, 481–484 (2009). https://doi.org/10.1126/science.1163886
  2. L.-Y. Lv, C.-F. Cao, Y.-X. Qu, G.-D. Zhang, L. Zhao et al., Smart fire-warning materials and sensors: design principle, performances, and applications. Mater. Sci. Eng. R. Rep. 150, 100698 (2022). https://doi.org/10.1016/j.mser.2022.100690
  3. X. Li, A. Vázquez-López, J.S. Del Río Sáez, D.-Y. Wang, Recent advances on early-stage fire-warning systems: mechanism, performance, and perspective. Nano-Micro Lett. 14, 197 (2022). https://doi.org/10.1007/s40820-022-00938-x
  4. L. Liu, J. Feng, Y. Xue, V. Chevali, Y. Zhang et al., 2D MXenes for fire retardancy and fire-arning applications: promises and prospects. Adv. Funct. Mater. 33, 2212124 (2022). https://doi.org/10.1002/adfm.202212124
  5. S. Araby, B. Philips, Q. Meng, J. Ma, T. Laoui et al., Recent advances in carbon-based nanomaterials for flame retardant polymers and composites. Compos. Part B Eng. 212, 108675 (2021). https://doi.org/10.1016/j.compositesb.2021.108675
  6. J. Chen, H. Xie, X. Lai, H. Li, J. Gao et al., An ultrasensitive fire-warning chitosan/montmorillonite/carbon nanotube composite aerogel with high fire-resistance. Chem. Eng. J. 399, 125729 (2020). https://doi.org/10.1016/j.cej.2020.125729
  7. Z. Ding, C. Du, W. Long, C.-F. Cao, L. Liang et al., Thermoelectrics and thermocells for fire warning applications. Sci. Bull. 68, 3261–3277 (2023). https://doi.org/10.1016/j.scib.2023.08.057
  8. T. Fu, X. Zhao, L. Chen, W. Wu, Q. Zhao et al., Bioinspired color changing molecular sensor toward early fire detection based on transformation of phthalonitrile to phthalocyanine. Adv. Funct. Mater. 29, 1806586 (2019). https://doi.org/10.1002/adfm.201806586
  9. L. Chen, H.-B. Zhao, Y.-P. Ni, T. Fu, W.-S. Wu et al., 3D printable robust shape memory PET copolyesters with fire safety via π-stacking and synergistic crosslinking. J. Mater. Chem. A 7, 17037–17045 (2019). https://doi.org/10.1039/C9TA04187G
  10. L. Zhang, Y. Huang, H. Dong, R. Xu, S. Jiang, Flame-retardant shape memory polyurethane/MXene paper and the application for early fire alarm sensor. Compos. Part B Eng. 223, 109149 (2021). https://doi.org/10.1016/j.compositesb.2021.109149
  11. Q. Zeng, B. Wang, X. Lai, H. Li, Z. Chen et al., Multifunctional MXene-coated cotton fabric with enhanced thermopower for smart fire protection. Compos. Part A Appl. Sci. Manuf. 164, 107305 (2023). https://doi.org/10.1016/j.compositesa.2022.107305
  12. Y. Wang, L. Yang, X.-L. Shi, X. Shi, L. Chen et al., Flexible thermoelectric materials and generators: challenges and innovations. Adv. Mater. 31, e1807916 (2019). https://doi.org/10.1002/adma.201807916
  13. H. Li, Z. Ding, Q. Zhou, J. Chen, Z. Liu et al., Harness high-temperature thermal energy via elastic thermoelectric aerogels. Nano-Micro Lett. 16, 151 (2024). https://doi.org/10.1007/s40820-024-01370-z
  14. G. Li, Y. Hu, J. Chen, L. Liang, Z. Liu et al., Thermoelectric and photoelectric dual modulated sensors for human internet of things application in accurate fire recognition and warning. Adv. Funct. Mater. 33, 2303861 (2023). https://doi.org/10.1002/adfm.202303861
  15. Y. Jia, Q. Jiang, H. Sun, P. Liu, D. Hu et al., Wearable thermoelectric materials and devices for self-owered electronic systems. Adv. Mater. 33, 2102990 (2021). https://doi.org/10.1002/adma.202102990
  16. S. Liu, H. Deng, Y. Zhao, S. Ren, Q. Fu, The optimization of thermoelectric properties in a PEDOT: PSS thin film through post-treatment. RSC Adv. 5, 1910–1917 (2015). https://doi.org/10.1039/C4RA09147G
  17. T. Zou, D. Zhang, T. Xu, X. Peng, H. Zhang et al., Smart fire-safety cotton fabric with fire-warning capability via dual working mechanisms. Cellulose 30, 6015–6030 (2023). https://doi.org/10.1007/s10570-023-05227-3
  18. T. Cao, X.-L. Shi, Z.-G. Chen, Advances in the design and assembly of flexible thermoelectric device. Prog. Mater. Sci. 131, 101003 (2023). https://doi.org/10.1016/j.pmatsci.2022.101003
  19. D. Qu, X. Li, H. Wang, G. Chen, Assembly strategy and performance evaluation of flexible thermoelectric devices. Adv. Sci. 6, 1900584 (2019). https://doi.org/10.1002/advs.201900584
  20. J. Li, Q. Shi, J.R. Röhr, H. Wu, B. Wu et al., Flexible 3D porous MoS2/CNTs architectures with ZT of 0.17 at room temperature for wearable thermoelectric applications. Adv. Funct. Mater. 30(36), 2002508 (2020). https://doi.org/10.1002/adfm.202002508
  21. W. Zhao, J. Ding, Y. Zou, C.-A. Di, D. Zhu, Chemical doping of organic semiconductors for thermoelectric applications. Chem. Soc. Rev. 49, 7210–7228 (2020). https://doi.org/10.1039/D0CS00204F
  22. C. Gao, G. Chen, Conducting polymer/carbon p thermoelectric composites: emerging green energy materials. Compos. Sci. Technol. 124, 52–70 (2016). https://doi.org/10.1016/j.compscitech.2016.01.014
  23. M. He, F. Qiu, Z. Lin, Towards high-performance polymer-based thermoelectric materials. Energy Environ. Sci. 6, 1352–1361 (2013). https://doi.org/10.1039/C3EE24193A
  24. M. Massetti, F. Jiao, A.J. Ferguson, D. Zhao, K. Wijeratne et al., Unconventional thermoelectric materials for energy harvesting and sensing applications. Chem. Rev. 121, 12465–12547 (2021). https://doi.org/10.1021/acs.chemrev.1c00218
  25. Z. Chen, X. Guan, N. Wen, L. Pan, Z. Fan, Construction of flexible, self-supporting, and in-plane anisotropic PEDOT: PSS thermoelectric films via the wet-winding approach. ACS Appl. Polym. Mater. 5, 2905–2916 (2023). https://doi.org/10.1021/acsapm.3c00122
  26. L. Zhang, Y. Harima, I. Imae, Highly improved thermoelectric performances of PEDOT: PSS/SWCNT composites by solvent treatment. Org. Electron. 51, 304–307 (2017). https://doi.org/10.1016/j.orgel.2017.09.030
  27. K. Wan, Y. Liu, G. Santagiuliana, G. Barandun, P. Taroni Junior et al., Self-powered ultrasensitive and highly stretchable temperature–strain sensing composite yarns. Mater. Horiz. 8, 2513–2519 (2021). https://doi.org/10.1039/D1MH00908G
  28. I. Imae, H. Yamane, K. Imato, Y. Ooyama, Thermoelectric properties of PEDOT: PSS/SWCNT composite films with controlled carrier density. Compos. Commun. 27, 100897 (2021). https://doi.org/10.1016/j.coco.2021.100897
  29. Y. Zhao, Q. Zeng, C. Jiang, X. Lai, H. Li et al., Self-powered, durable and high fire-safety ionogel towards Internet of Things. Nano Energy 116, 108785 (2023). https://doi.org/10.1016/j.nanoen.2023.108785
  30. C. Jiang, X. Lai, Z. Wu, H. Li, X. Zeng et al., A high-thermopower ionic hydrogel for intelligent fire protection. J. Mater. Chem. A 10, 21368–21378 (2022). https://doi.org/10.1039/d2ta05737a
  31. T. Peng, S. Wang, Z. Xu, T. Tang, Y. Zhao, Multifunctional MXene/aramid nanofiber composite films for efficient electromagnetic interference shielding and repeatable early fire detection. ACS Omega 7, 29161–29170 (2022). https://doi.org/10.1021/acsomega.2c03219
  32. Y. Zhao, J. Chen, X. Lai, H. Li, X. Zeng et al., Efficient flame-retardant and multifunctional polyimide/MXene composite aerogel for intelligent fire protection. Compos. Part A Appl. Sci. Manuf. 163, 107210 (2022). https://doi.org/10.1016/j.compositesa.2022.107210
  33. C. Jiang, J. Chen, X. Lai, H. Li, X. Zeng et al., Mechanically robust and multifunctional polyimide/MXene composite aerogel for smart fire protection. Chem. Eng. J. 434, 134630 (2022). https://doi.org/10.1016/j.cej.2022.134630
  34. B. Wang, X. Lai, H. Li, C. Jiang, J. Gao et al., Multifunctional MXene/chitosan-coated cotton fabric for intelligent fire protection. ACS Appl. Mater. Interfaces 13, 23020–23029 (2021). https://doi.org/10.1021/acsami.1c05222
  35. Q. Zeng, Y. Zhao, X. Lai, C. Jiang, B. Wang et al., Skin-inspired multifunctional MXene/cellulose nanocoating for smart and efficient fire protection. Chem. Eng. J. 446, 136899 (2022). https://doi.org/10.1016/j.cej.2022.136899
  36. H. He, Y. Qin, Z. Zhu, Q. Jiang, S. Ouyang et al., Temperature-arousing self-powered fire warning e-textile based on p-n segment coaxial aerogel fibers for active fire protection in firefighting clothing. Nano-Micro Lett. 15, 226 (2023). https://doi.org/10.1007/s40820-023-01200-8
  37. A.A. Ashcheulov, I.V. Gutsul, V.S. Maevski, Device for monitoring the radiation temperature in coal mines. J. Opt. Technol. 67, 281 (2000). https://doi.org/10.1364/JOT.67.000281
  38. J.L. Blackburn, A.J. Ferguson, C. Cho, J.C. Grunlan, Carbon-nanotube-based thermoelectric materials and devices. Adv. Mater. 30, 1704386 (2018). https://doi.org/10.1002/adma.201704386
  39. H. Deng, L. Lin, M. Ji, S. Zhang, M. Yang et al., Progress on the morphological control of conductive network in conductive polymer composites and the use as electroactive multifunctional materials. Prog. Polym. Sci. 39, 627–655 (2014). https://doi.org/10.1016/j.progpolymsci.2013.07.007
  40. T.T. Tung, C. Pham-Huu, I. Janowska, T. Kim, M. Castro et al., Hybrid films of graphene and carbon nanotubes for high performance chemical and temperature sensing applications. Small 11, 3485–3493 (2015). https://doi.org/10.1002/smll.201403693
  41. C. Zeng, P. Stenier, K. Chen, K. Wan, M. Dong et al., Optimization of thermoelectric properties of carbon nanotube veils by defect engineering. Mater. Horiz. 10, 3601–3609 (2023). https://doi.org/10.1039/d3mh00525a
  42. D. Huang, H. Kim, G. Zou, X. Xu, Y. Zhu et al., All-MXene thermoelectric nanogenerator. Mater. Today Energy 29, 101129 (2022). https://doi.org/10.1016/j.mtener.2022.101129
  43. F. Shahzad, A. Iqbal, H. Kim, C.M. Koo, 2D transition metal carbides (MXenes): applications as an electrically conducting material. Adv. Mater. 32, e2002159 (2020). https://doi.org/10.1002/adma.202002159
  44. Y. Wang, T. Guo, Z. Tian, K. Bibi, Y.-Z. Zhang et al., MXenes for energy harvesting. Adv. Mater. 34, e2108560 (2022). https://doi.org/10.1002/adma.202108560
  45. C.-Y. Yang, W.-L. Jin, J. Wang, Y.-F. Ding, S. Nong et al., Enhancing the n-type conductivity and thermoelectric performance of donor-acceptor copolymers through donor engineering. Adv. Mater. 30, e1802850 (2018). https://doi.org/10.1002/adma.201802850
  46. Z. Fan, Y. Zhang, L. Pan, J. Ouyang, Q. Zhang, Recent developments in flexible thermoelectrics: from materials to devices. Renew. Sustain. Energy Rev. 137, 110448 (2021). https://doi.org/10.1016/j.rser.2020.110448
  47. S. Wei, J. Ma, D. Wu, B. Chen, C. Du et al., Constructing flexible film electrode with porous layered structure by MXene/SWCNTs/PANI ternary composite for efficient low-grade thermal energy harvest. Adv. Funct. Mater. 33, 2209806 (2023). https://doi.org/10.1002/adfm.202209806
  48. W. Ding, P. Liu, Z. Bai, Y. Wang, G. Liu et al., Constructing layered MXene/CNTs composite film with 2D–3D sandwich structure for high thermoelectric performance. Adv. Mater. Interfaces 7, 2001340 (2020). https://doi.org/10.1002/admi.202001340
  49. J. Wei, D. Wu, C. Liu, F. Zhong, G. Cao et al., Free-standing p-type SWCNT/MXene composite films with low thermal conductivity and enhanced thermoelectric performance. Chem. Eng. J. 439, 135706 (2022). https://doi.org/10.1016/j.cej.2022.135706
  50. K. Song, I. Ganguly, I. Eastin, A.B. Dichiara, Lignin-modified carbon nanotube/graphene hybrid coating as efficient flame retardant. Int. J. Mol. Sci. 18, 2368 (2017). https://doi.org/10.3390/ijms18112368
  51. B. Yu, B. Tawiah, L.Q. Wang, A.C. Yin Yuen, Z.C. Zhang et al., Interface decoration of exfoliated MXene ultra-thin nanosheets for fire and smoke suppressions of thermoplastic polyurethane elastomer. J. Hazard. Mater. 374, 110–119 (2019). https://doi.org/10.1016/j.jhazmat.2019.04.026
  52. M. Mao, K.-X. Yu, C.-F. Cao, L.-X. Gong, G.-D. Zhang et al., Facile and green fabrication of flame-retardant Ti3C2Tx MXene networks for ultrafast, reusable and weather-resistant fire warning. Chem. Eng. J. 427, 131615 (2022). https://doi.org/10.1016/j.cej.2021.131615
  53. J. Guo, X. Wang, T. Wang, Thermal characterization of microscale conductive and nonconductive wires using transient electrothermal technique. J. Appl. Phys. 101, 063537 (2007). https://doi.org/10.1063/1.2714679
  54. C.-P. Feng, F. Wei, K.-Y. Sun, Y. Wang, H.-B. Lan et al., Emerging flexible thermally conductive films: mechanism, fabrication, application. Nano-Micro Lett. 14, 127 (2022). https://doi.org/10.1007/s40820-022-00868-8
  55. Y. Jung, M. Kim, T. Kim, J. Ahn, J. Lee et al., Functional materials and innovative strategies for wearable thermal management applications. Nano-Micro Lett. 15, 160 (2023). https://doi.org/10.1007/s40820-023-01126-1
  56. H. Xie, X. Lai, H. Li, J. Gao, X. Zeng et al., A highly efficient flame retardant nacre-inspired nanocoating with ultrasensitive fire-warning and self-healing capabilities. Chem. Eng. J. 369, 8–17 (2019). https://doi.org/10.1016/j.cej.2019.03.045
  57. H. Xie, X. Lai, H. Li, J. Gao, X. Zeng, Skin-inspired thermoelectric nanocoating for temperature sensing and fire safety. J. Colloid Interface Sci. 602, 756–766 (2021). https://doi.org/10.1016/j.jcis.2021.06.054
  58. H. He, Y. Qin, J. Liu, Y. Wang, J. Wang et al., A wearable self-powered fire warning e-textile enabled by aramid nanofibers/MXene/silver nanowires aerogel fiber for fire protection used in firefighting clothing. Chem. Eng. J. 460, 141661 (2023). https://doi.org/10.1016/j.cej.2023.141661
  59. J.R. Qualey, Fire test comparisons of smoke detector response times. Fire Technol. 36, 89–108 (2000). https://doi.org/10.1023/A:1015498224060
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