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Vol. 12 (2020)

Sandwiching Sulfur into the Dents Between N, O Co-Doped Graphene Layered Blocks with Strong Physicochemical Confinements for Stable and High-Rate Li–S Batteries

https://doi.org/10.1007/s40820-020-00477-3
Mengjiao Shi
Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, People’s Republic of China
Su Zhang
Key Laboratory of Energy Materials Chemistry, Ministry of Education, Key Laboratory of Advanced Functional Materials, Autonomous Region, Institute of Applied Chemistry, Xinjiang University, Urumqi 830046, People’s Republic of China
Yuting Jiang
Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, People’s Republic of China
Zimu Jiang
Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, People’s Republic of China
Longhai Zhang
Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, People’s Republic of China
Jin Chang
Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, People’s Republic of China
Tong Wei
Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, People’s Republic of China
Zhuangjun Fan
Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, People’s Republic of China

Corresponding Author: Zhuangjun Fan

fanzhj666@163.com

Nano-Micro Letters, Vol. 12 (2020), Article Number: 146

Abstract

The development of lithium–sulfur batteries (LSBs) is restricted by their poor cycle stability and rate performance due to the low conductivity of sulfur and severe shuttle effect. Herein, an N, O co-doped graphene layered block (NOGB) with many dents on the graphene sheets is designed as effective sulfur host for high-performance LSBs. The sulfur platelets are physically confined into the dents and closely contacted with the graphene scaffold, ensuring structural stability and high conductivity. The highly doped N and O atoms can prevent the shuttle effect of sulfur species by strong chemical adsorption. Moreover, the micropores on the graphene sheets enable fast Li+ transport through the blocks. As a result, the obtained NOGB/S composite with 76 wt% sulfur content shows a high capacity of 1413 mAh g−1 at 0.1 C, good rate performance of 433 mAh g−1 at 10 C, and remarkable stability with 526 mAh g−1 at after 1000 cycles at 1 C (average decay rate: 0.038% per cycle). Our design provides a comprehensive route for simultaneously improving the conductivity, ion transport kinetics, and preventing the shuttle effect in LSBs.


Highlights:


1 N, O co-doped graphene layered block (NOGB) was prepared as sulfur host for lithium–sulfur batteries.
2 The NOGB/S shows good rate performance due to robust electrochemical kinetics.
3 The strong physicochemical confinement leads to an improved cycling stability.

Keywords

Graphene Physicochemical confinement Cycle stability Shuttle effect Li–S batteries
Shi, Mengjiao, Su Zhang, Yuting Jiang, Zimu Jiang, Longhai Zhang, Jin Chang, Tong Wei, and Zhuangjun Fan. 2020. “Sandwiching Sulfur into the Dents Between N, O Co-Doped Graphene Layered Blocks With Strong Physicochemical Confinements for Stable and High-Rate Li–S Batteries”. Nano-Micro Letters 12 (July):146. https://doi.org/10.1007/s40820-020-00477-3.
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