Issue

Vol. 12 (2020)

Two-Dimensional Black Phosphorus Nanomaterials: Emerging Advances in Electrochemical Energy Storage Science

https://doi.org/10.1007/s40820-020-00510-5
Junye Cheng
Guangdong Provincial Key Laboratory of Micro/Nano Optomechatronics Engineering, College of Mechatronics and Control Engineering, Shenzhen University, Shenzhen, 518060, People’s Republic of China
Lingfeng Gao
Collaborative Innovation Center for Optoelectronic Science and Technology, International Collaborative Laboratory of 2D Materials for Optoelectronic Science and Technology of Ministry of Education and Guangdong Province, Shenzhen University, Shenzhen 518060, People’s Republic of China
Tian Li
Department of Mechanical Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, People’s Republic of China
Shan Mei
Department of Materials Science and Engineering, Drexel University, Philadelphia, PA 19104, USA
Cong Wang
Collaborative Innovation Center for Optoelectronic Science and Technology, International Collaborative Laboratory of 2D Materials for Optoelectronic Science and Technology of Ministry of Education
Bo Wen
Collaborative Innovation Center for Optoelectronic Science and Technology, International Collaborative Laboratory of 2D Materials for Optoelectronic Science and Technology of Ministry of Education and Guangdong Province, Shenzhen University, Shenzhen 518060, People’s Republic of China
Weichun Huang
Nantong Key Lab of Intelligent and New Energy Materials, College of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, Jiangsu, People’s Republic of China
Chao Li
Collaborative Innovation Center for Optoelectronic Science and Technology, International Collaborative Laboratory of 2D Materials for Optoelectronic Science and Technology of Ministry of Education and Guangdong Province, Shenzhen University, Shenzhen 518060, People’s Republic of China
Guangping Zheng
Department of Mechanical Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, People’s Republic of China
Hao Wang
Guangdong Provincial Key Laboratory of Micro/Nano Optomechatronics Engineering, College of Mechatronics and Control Engineering, Shenzhen University, Shenzhen 518060, People’s Republic of China
Han Zhang
Collaborative Innovation Center for Optoelectronic Science and Technology, International Collaborative Laboratory of 2D Materials for Optoelectronic Science and Technology of Ministry of Education

Corresponding Author: Han Zhang

hzhang@szu.edu.cn

Nano-Micro Letters, Vol. 12 (2020), Article Number: 179

Abstract

Two-dimensional black phosphorus (2D BP), well known as phosphorene, has triggered tremendous attention since the first discovery in 2014. The unique puckered monolayer structure endows 2D BP intriguing properties, which facilitate its potential applications in various fields, such as catalyst, energy storage, sensor, etc. Owing to the large surface area, good electric conductivity, and high theoretical specific capacity, 2D BP has been widely studied as electrode materials and significantly enhanced the performance of energy storage devices. With the rapid development of energy storage devices based on 2D BP, a timely review on this topic is in demand to further extend the application of 2D BP in energy storage. In this review, recent advances in experimental and theoretical development of 2D BP are presented along with its structures, properties, and synthetic methods. Particularly, their emerging applications in electrochemical energy storage, including Li−/K−/Mg−/Na-ion, Li–S batteries, and supercapacitors, are systematically summarized with milestones as well as the challenges. Benefited from the fast-growing dynamic investigation of 2D BP, some possible improvements and constructive perspectives are provided to guide the design of 2D BP-based energy storage devices with high performance.


Highlights:


1 Two-dimensional black phosphorus (2D BP) possesses huge potential in electrochemical energy storage field owing to its unique electronic structure, high charge carrier mobility, and large interlayer spacing.


2 Comparison on the different preparation methods and processes, characteristics, and applications of few-layer BP is presented.


3 The applications of 2D BP in electrochemical energy storage devices in these years are well reviewed.

Keywords

2D black phosphorus Electronic structure Supercapacitors Batteries
Cheng, Junye, Lingfeng Gao, Tian Li, Shan Mei, Cong Wang, Bo Wen, Weichun Huang, Chao Li, Guangping Zheng, Hao Wang, and Han Zhang. 2020. “Two-Dimensional Black Phosphorus Nanomaterials: Emerging Advances in Electrochemical Energy Storage Science”. Nano-Micro Letters 12 (September):179. https://doi.org/10.1007/s40820-020-00510-5.
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