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Vol. 13 (2021)

A General Self-Sacrifice Template Strategy to 3D Heteroatom-Doped Macroporous Carbon for High-Performance Potassium-Ion Hybrid Capacitors

https://doi.org/10.1007/s40820-021-00659-7
Junwei Li
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research On the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People’s Republic of China
Xiang Hu
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research On the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People’s Republic of China
Guobao Zhong
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research On the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People’s Republic of China
Yangjie Liu
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research On the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People’s Republic of China
Yaxin Ji
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research On the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People’s Republic of China
Junxiang Chen
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research On the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People’s Republic of China
Zhenhai Wen
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research On the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People’s Republic of China

Corresponding Author: Zhenhai Wen

wen@fjirsm.ac.cn

Nano-Micro Letters, Vol. 13 (2021), Article Number: 131

Abstract

Potassium-ion hybrid capacitors (PIHCs) tactfully combining capacitor-type cathode with battery-type anode have recently attracted increasing attentions due to their advantages of decent energy density, high power density, and low cost; the mismatches of capacity and kinetics between capacitor-type cathode and battery-type anode in PIHCs yet hinder their overall performance output. Herein, based on prediction of density functional theory calculations, we find Se/N co-doped porous carbon is a promising candidate for K+ storage and thus develop a simple and universal self-sacrifice template method to fabricate Se and N co-doped three-dimensional (3D) macroporous carbon (Se/N-3DMpC), which features favorable properties of connective hierarchical pores, expanded interlayer structure, and rich activity site for boosting pseudocapacitive activity and kinetics toward K+ storage anode and enhancing capacitance performance for the reversible anion adsorption/desorption cathode. As expected, the as-assembled PIHCs full cell with a working voltage as high as 4.0 V delivers a high energy density of 186 Wh kg−1 and a power output of 8100 W kg−1 as well as excellent long service life. The proof-of-concept PIHCs with excellent performance open a new avenue for the development and application of high-performance hybrid capacitors.


Highlights:


1 A newly versatile self-sacrifice method to fabricate selenium and nitrogen co-doped 3D macroporous carbon was developed.
2 The K+ storage mechanism of Se and N active sites was deeply studied by systematic electrochemical characterization combined with theoretical calculations.
3 The assembled K-ion hybrid capacitor possesses high energy/power densities and excellent cycling stability for practical applications.

Keywords

Potassium-ion hybrid capacitors Self-sacrifice template Se/N co-doped 3D macroporous Long service life
Li, Junwei, Xiang Hu, Guobao Zhong, Yangjie Liu, Yaxin Ji, Junxiang Chen, and Zhenhai Wen. 2021. “A General Self-Sacrifice Template Strategy to 3D Heteroatom-Doped Macroporous Carbon for High-Performance Potassium-Ion Hybrid Capacitors”. Nano-Micro Letters 13 (May):131. https://doi.org/10.1007/s40820-021-00659-7.
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