Issue

Vol. 14 (2022)

Post-Synthetic and In Situ Vacancy Repairing of Iron Hexacyanoferrate Toward Highly Stable Cathodes for Sodium-Ion Batteries

https://doi.org/10.1007/s40820-021-00742-z
Min Wan
School of Mechanical Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China
Rui Zeng
School of Chemistry and Environmental Engineering, Wuhan Polytechnic University, Wuhan 430023, People’s Republic of China
Jingtao Meng
State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China
Zexiao Cheng
State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China
Weilun Chen
State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China
Jiayu Peng
State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China
Wuxing Zhang
State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China
Yunhui Huang
State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China

Corresponding Author: Yunhui Huang

huangyh@hust.edu.cn

Nano-Micro Letters, Vol. 14 (2022), Article Number: 9

Abstract

Iron hexacyanoferrate (FeHCF) is a promising cathode material for sodium-ion batteries. However, FeHCF always suffers from a poor cycling stability, which is closely related to the abundant vacancy defects in its framework. Herein, post-synthetic and in-situ vacancy repairing strategies are proposed for the synthesis of high-quality FeHCF in a highly concentrated Na4Fe(CN)6 solution. Both the post-synthetic and in-situ vacancy repaired FeHCF products (FeHCF-P and FeHCF-I) show the significant decrease in the number of vacancy defects and the reinforced structure, which can suppress the side reactions and activate the capacity from low-spin Fe in FeHCF. In particular, FeHCF-P delivers a reversible discharge capacity of 131 mAh g−1 at 1 C and remains 109 mAh g−1 after 500 cycles, with a capacity retention of 83%. FeHCF-I can deliver a high discharge capacity of 158.5 mAh g−1 at 1 C. Even at 10 C, the FeHCF-I electrode still maintains a discharge specific capacity of 103 mAh g−1 and retains 75% after 800 cycles. This work provides a new vacancy repairing strategy for the solution synthesis of high-quality FeHCF.


Highlights:


1 Post-synthetic and in-situ vacancy repairing strategies effectively decrease the defects in FeHCF.
2 Vacancy reduction improves the structure and cycling stability of FeHCF.
3 Vacancy reduction boosts the capacity contribution from low-spin Fe in FeHCF.

Keywords

Iron hexacyanoferrate Cathode Vacancy repairing Sodium-ion batteries
Wan, Min, Rui Zeng, Jingtao Meng, Zexiao Cheng, Weilun Chen, Jiayu Peng, Wuxing Zhang, and Yunhui Huang. 2021. “Post-Synthetic and In Situ Vacancy Repairing of Iron Hexacyanoferrate Toward Highly Stable Cathodes for Sodium-Ion Batteries”. Nano-Micro Letters 14 (December):9. https://doi.org/10.1007/s40820-021-00742-z.
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. M. Armand, J.M. Tarascon, Building better batteries. Nature 451(7179), 652–657 (2008). https://doi.org/10.1038/451652a
  2. B.L. Ellis, L.F. Nazar, Sodium and sodium-ion energy storage batteries. Curr. Opin. Solid State Mater. Sci. 16(4), 168–177 (2012). https://doi.org/10.1016/j.cossms.2012.04.002
  3. I. Hasa, S. Mariyappan, D. Saurel, P. Adelhelm, A.Y. Koposov et al., Challenges of today for Na-based batteries of the future: from materials to cell metrics. J. Power Sour. 482, 228872 (2021). https://doi.org/10.1016/j.jpowsour.2020.228872
  4. V. Palomares, P. Serras, I. Villaluenga, K.B. Hueso, J.C. Gonzalez et al., Na-ion batteries, recent advances and present challenges to become low cost energy storage systems. Energy Environ. Sci. 5(3), 5884–5901 (2012). https://doi.org/10.1039/c2ee02781j
  5. H. Kim, J. Hong, K.Y. Park, H. Kim, S.W. Kim et al., Aqueous rechargeable Li and Na ion batteries. Chem. Rev. 114(23), 11788–11827 (2014). https://doi.org/10.1021/cr500232y
  6. H. Lee, Y.I. Kim, J.K. Park, J.W. Choi, Sodium zinc hexacyanoferrate with a well-defined open framework as a positive electrode for sodium ion batteries. Chem. Commun. 48(67), 8416–8418 (2012). https://doi.org/10.1039/c2cc33771a
  7. H.W. Lee, R. Wang, M. Pasta, S.W. Lee, N. Liu et al., Manganese hexacyanomanganate open framework as a high-capacity positive electrode material for sodium-ion batteries. Nat. Commun. 5, 5280 (2014). https://doi.org/10.1038/ncomms6280
  8. K. Hurlbutt, S. Wheeler, I. Capone, M. Pasta, Prussian blue analogs as battery materials. Joule 2(10), 1950–1960 (2018). https://doi.org/10.1016/j.joule.2018.07.017
  9. Z. Shen, S. Guo, C. Liu, Y. Sun, Z. Chen et al., Na-rich Prussian white cathodes for long-life sodium-ion batteries. ACS Sustain. Chem. Eng. 6(12), 16121–16129 (2018). https://doi.org/10.1021/acssuschemeng.8b02758
  10. M. Chen, S.L. Chou, S.X. Dou, Understanding challenges of cathode materials for sodium-ion batteries using synchrotron-based X-ray absorption spectroscopy. Batteries Supercaps 2(10), 842–851 (2019). https://doi.org/10.1002/batt.201900054
  11. J. Li, Y. Zan, Z. Zhang, M. Dou, F. Wang, Prussian blue nanocubes decorated on nitrogen-doped hierarchically porous carbon network for efficient sorption of radioactive cesium. J. Hazard. Mater. 385, 121568 (2020). https://doi.org/10.1016/j.jhazmat.2019.121568
  12. A. Zhou, W. Cheng, W. Wang, Q. Zhao, J. Xie et al., Hexacyanoferrate-type Prussian blue analogs: principles and advances toward high-performance sodium and potassium ion batteries. Adv. Energy Mater. 11(2), 2000943 (2020). https://doi.org/10.1002/aenm.202000943
  13. M. Qin, W. Ren, R. Jiang, Q. Li, X. Yao et al., Highly crystallized Prussian blue with enhanced kinetics for highly efficient sodium storage. ACS Appl. Mater. Interfaces 13(3), 3999–4007 (2021). https://doi.org/10.1021/acsami.0c20067
  14. W. Gong, M. Wan, R. Zeng, Z. Rao, S. Su et al., Ultrafine Prussian blue as a high-rate and long-life sodium-ion battery cathode. Energy Tech. 7(7), 1900108 (2019). https://doi.org/10.1002/ente.201900108
  15. W. Ren, Z. Zhu, M. Qin, S. Chen, X. Yao et al., Prussian white hierarchical nanotubes with surface-controlled charge storage for sodium-ion batteries. Adv. Funct. Mater. 29(15), 1806405 (2019). https://doi.org/10.1002/adfm.201806405
  16. J. Peng, M. Ou, H. Yi, X. Sun, Y. Zhang et al., Defect-free-induced Na+ disordering in electrode materials. Energy Environ. Sci. 14(5), 3130–3140 (2021). https://doi.org/10.1039/d1ee00087j
  17. Y. You, X. Wu, Y. Yin, Y. Guo, High-quality Prussian blue crystals as superior cathode materials for room-temperature sodium-ion batteries. Energy Environ. Sci. 7(5), 1643–1647 (2014). https://doi.org/10.1039/c3ee44004d
  18. L. Wang, J. Song, R. Qiao, L.A. Wray, M.A. Hossain et al., Rhombohedral Prussian white as cathode for rechargeable sodium-ion batteries. J. Am. Chem. Soc. 137(7), 2548–2554 (2015). https://doi.org/10.1021/ja510347s
  19. Y. Liu, Y. Qiao, W. Zhang, Z. Li, X. Ji et al., Sodium storage in Na-rich NaxFeFe(CN)6 nanocubes. Nano Energy 12, 386–393 (2015). https://doi.org/10.1016/j.nanoen.2015.01.012
  20. C. Yan, A. Zhao, F. Zhong, X. Feng, W. Chen et al., A low-defect and Na-enriched Prussian blue lattice with ultralong cycle life for sodium-ion battery cathode. Electrochim. Acta 332, 135533 (2020). https://doi.org/10.1016/j.electacta.2019.135533
  21. W. Wang, Z. Hu, Z. Yan, J. Peng, M. Chen et al., Understanding rhombohedral iron hexacyanoferrate with three different sodium positions for high power and long stability sodium-ion battery. Energy Stor. Mater. 30, 42–51 (2020). https://doi.org/10.1016/j.ensm.2020.04.027
  22. J. Song, L. Wang, Y. Lu, J. Liu, B. Guo et al., Removal of interstitial H2O in hexacyanometallates for a superior cathode of a sodium-ion battery. J. Am. Chem. Soc. 137(7), 2658–2664 (2015). https://doi.org/10.1021/ja512383b
  23. W. Tang, F. Peng, Y. Yang, F. Feng, X.Z. Liao et al., Electrochemical performance of NaFeFe(CN)6 prepared by solid reaction for sodium ion batteries. J. Electrochem. Soc. 165(16), A3910–A3917 (2019). https://doi.org/10.1149/2.0701816jes
  24. J. Cattermull, S. Wheeler, K. Hurlbutt, M. Pasta, A.L. Goodwin, Filling vacancies in a Prussian blue analogue using mechanochemical post-synthetic modification. Chem. Commun. 56(57), 7873–7876 (2020). https://doi.org/10.1039/d0cc02922j
  25. M. Wan, Y. Tang, L. Wang, X. Xiang, X. Li et al., Core-shell hexacyanoferrate for superior Na-ion batteries. J. Power Sour. 329, 290–296 (2016). https://doi.org/10.1016/j.jpowsour.2016.08.059
  26. S.J. Clark, M.D. Segall, C.J. Pickard, P.J. Hasnip, M.I.J. Probert et al., First principles methods using CASTEP. Z. Kristallogr. 220(5–6), 567–570 (2015). https://doi.org/10.1524/zkri.220.5.567.65075
  27. H. Dodziuk, Reply to the ‘Comment on ‘Modelling complexes of H2 molecules in fullerenes’ by H. Dodziuk [Chem. Phys. Lett. 410 (2005) 39]’ by L. Turker and S. Erkoc. Chem. Phys. Lett. 426(1–3): 224–225 (2006). https://doi.org/10.1016/j.cplett.2006.05.054
  28. Y. Ren, T.Y. Ng, K.M. Liew, State of hydrogen molecules confined in C60 fullerene and carbon nanocapsule structures. Carbon 44(3), 397–406 (2006). https://doi.org/10.1016/j.carbon.2005.09.009
  29. B.G. Pfrommer, M. Cote, S.G. Louie, M.L. Cohen, Relaxation of crystals with the Quasi-Newton method. J. Comput. Phys. 131(1), 233–240 (1997). https://doi.org/10.1006/jcph.1996.5612
  30. Z. Xing, S. Liu, G. Zhang, Y. Zou, L. Wang et al., Na-rich metal hexacyanoferrate with water-mediated room-temperature fast Na+-ion conductance. Microporous Mesoporous Mater. 292, 109715 (2020). https://doi.org/10.1016/j.micromeso.2019.109715
  31. M. Luo, Y. Dou, H. Kang, Y. Ma, X. Ding et al., A novel interlocked Prussian blue/reduced graphene oxide nanocomposites as high-performance supercapacitor electrodes. J. Solid State Electr. 19(6), 1621–1631 (2015). https://doi.org/10.1007/s10008-015-2785-z
  32. Y. Tang, W. Li, P. Feng, M. Zhou, K. Wang et al., High-performance manganese hexacyanoferrate with cubic structure as superior cathode material for sodium-ion batteries. Adv. Funct. Mater. 30(10), 1908754 (2020). https://doi.org/10.1002/adfm.201908754
  33. Y. Huang, M. Xie, J. Zhang, Z. Wang, Y. Jiang et al., A novel border-rich Prussian blue synthetized by inhibitor control as cathode for sodium ion batteries. Nano Energy 39, 273–283 (2017). https://doi.org/10.1016/j.nanoen.2017.07.005
  34. Y. Jiang, S. Yu, B. Wang, Y. Li, W. Sun et al., Prussian blue@C composite as an ultrahigh-rate and long-life sodium-ion battery cathode. Adv. Funct. Mater. 26(29), 5315–5321 (2016). https://doi.org/10.1002/adfm.201600747
  35. D.S. Kim, H. Yoo, M.S. Park, H. Kim, Boosting the sodium storage capability of Prussian blue nanocubes by overlaying PEDOT PSS layer. J. Alloys Compd. 791, 385–390 (2019). https://doi.org/10.1016/j.jallcom.2019.03.317
  36. X. Ma, Y. Wei, Y. Wu, J. Wang, W. Jia et al., High crystalline Na2Ni[Fe(CN)6] particles for a high-stability and low-temperature sodium-ion batteries cathode. Electrochim. Acta 297, 392–397 (2019). https://doi.org/10.1016/j.electacta.2018.11.063
  37. Y. Liu, D. He, Y. Cheng, L. Li, Z. Lu et al., A heterostructure coupling of bioinspired, adhesive polydopamine, and porous Prussian blue nanocubics as cathode for high-performance sodium-ion battery. Small 16(11), 1906946 (2020). https://doi.org/10.1002/smll.201906946
Read More
Author biographies are not available.
Download this PDF file
PDF SUPPLEMENTARY MATERIAL
Statistic
Read Counter : 1990 Download : 1483

Most read articles by the same author(s)