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Vol. 14 (2022)

Atomically Dispersed Fe-Co Bimetallic Catalysts for the Promoted Electroreduction of Carbon Dioxide

https://doi.org/10.1007/s40820-021-00746-9
Zhangsen Chen
Institut National de la Recherche Scientifique-Énergie Matériaux et Télécommunications, Varennes, QC J3X 1P7, Canada
Gaixia Zhang
Institut National de la Recherche Scientifique-Énergie Matériaux et Télécommunications, Varennes, QC J3X 1P7, Canada
Yuren Wen
School of Materials Science and Engineering, University of Science and Technology, 100083 Beijing, People’s Republic of China
Ning Chen
Canadian Light Source, University of Saskatchewan, Saskatoon, SK S7N 2V3, Canada
Weifeng Chen
Canadian Light Source, University of Saskatchewan, Saskatoon, SK S7N 2V3, Canada
Tom Regier
Canadian Light Source, University of Saskatchewan, Saskatoon, SK S7N 2V3, Canada
James Dynes
Canadian Light Source, University of Saskatchewan, Saskatoon, SK S7N 2V3, Canada
Yi Zheng
Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou 350116, People’s Republic of China
Shuhui Sun
Institut National de la Recherche Scientifique-Énergie Matériaux et Télécommunications, Varennes, QC J3X 1P7, Canada

Corresponding Author: Shuhui Sun

shuhui@emt.inrs.ca

Nano-Micro Letters, Vol. 14 (2022), Article Number: 25

Abstract

The electroreduction reaction of CO2 (ECO2RR) requires high-performance catalysts to convert CO2 into useful chemicals. Transition metal-based atomically dispersed catalysts are promising for the high selectivity and activity in ECO2RR. This work presents a series of atomically dispersed Co, Fe bimetallic catalysts by carbonizing the Fe-introduced Co-zeolitic-imidazolate-framework (C–Fe–Co–ZIF) for the syngas generation from ECO2RR. The synergistic effect of the bimetallic catalyst promotes CO production. Compared to the pure C–Co–ZIF, C–Fe–Co–ZIF facilitates CO production with a CO Faradaic efficiency (FE) boost of 10%, with optimal FECO of 51.9%, FEH2 of 42.4% at − 0.55 V, and CO current density of 8.0 mA cm−2 at − 0.7 V versus reversible hydrogen electrode (RHE). The H2/CO ratio is tunable from 0.8 to 4.2 in a wide potential window of − 0.35 to − 0.8 V versus RHE. The total FECO+H2 maintains as high as 93% over 10 h. The proper adding amount of Fe could increase the number of active sites and create mild distortions for the nanoscopic environments of Co and Fe, which is essential for the enhancement of the CO production in ECO2RR. The positive impacts of Cu–Co and Ni–Co bimetallic catalysts demonstrate the versatility and potential application of the bimetallic strategy for ECO2RR.


Highlights:


1 X-ray photoelectron spectroscopy results confirmed the increased number of M–N sites in the bimetallic Fe–Co catalyst.
2 Synchrotron-based X-ray absorption fine structure demonstrated that the interaction in the coordination environments of the different transition metal sites facilitated the CO production in electroreduction reaction of CO2 (ECO2RR).
3 This bimetallic strategy has also been extended to fabricate other catalysts such as Cu–Co and Ni–Co, which also exhibited enhanced performance for ECO2RR.

Keywords

CO2 reduction Electrocatalysis Syngas production Cobalt Iron Bimetallic catalysts
Chen, Zhangsen, Gaixia Zhang, Yuren Wen, Ning Chen, Weifeng Chen, Tom Regier, James Dynes, Yi Zheng, and Shuhui Sun. 2021. “Atomically Dispersed Fe-Co Bimetallic Catalysts for the Promoted Electroreduction of Carbon Dioxide”. Nano-Micro Letters 14 (December):25. https://doi.org/10.1007/s40820-021-00746-9.
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