Issue

Vol. 14 (2022)

Metal–Organic Frameworks Functionalized Separators for Robust Aqueous Zinc-Ion Batteries

https://doi.org/10.1007/s40820-022-00960-z
Yang Song
School of Chemical Engineering, North China University of Science and Technology, Tangshan 063009, People’s Republic of China
Pengchao Ruan
School of Materials Science and Engineering, Hunan Provincial Key Laboratory of Electronic Packaging and Advanced Functional Materials, Central South University, Changsha 410083, People’s Republic of China
Caiwang Mao
School of Chemical Engineering, North China University of Science and Technology, Tangshan 063009, People’s Republic of China
Yuxin Chang
School of Chemical Engineering, North China University of Science and Technology, Tangshan 063009, People’s Republic of China
Ling Wang
School of Chemical Engineering, North China University of Science and Technology, Tangshan 063009, People’s Republic of China
Lei Dai
School of Chemical Engineering, North China University of Science and Technology, Tangshan 063009, People’s Republic of China
Peng Zhou
Hunan Provincial Key Defense Laboratory of High Temperature Wear-Resisting Materials and Preparation Technology, Hunan University of Science and Technology, Xiangtan 411201, People’s Republic of China
Bingan Lu
School of Physics and Electronics, Hunan University, Changsha 410082, People’s Republic of China
Jiang Zhou
School of Materials Science and Engineering, Hunan Provincial Key Laboratory of Electronic Packaging and Advanced Functional Materials, Central South University, Changsha 410083, People’s Republic of China
Zhangxing He
School of Chemical Engineering, North China University of Science and Technology, Tangshan 063009, People’s Republic of China

Corresponding Author: Zhangxing He

zxhe@ncst.edu.cn

Nano-Micro Letters, Vol. 14 (2022), Article Number: 218

Abstract

Aqueous zinc-ion batteries (AZIBs) are one of the promising energy storage systems, which consist of electrode materials, electrolyte, and separator. The first two have been significantly received ample development, while the prominent role of the separators in manipulating the stability of the electrode has not attracted sufficient attention. In this work, a separator (UiO-66-GF) modified by Zr-based metal organic framework for robust AZIBs is proposed. UiO-66-GF effectively enhances the transport ability of charge carriers and demonstrates preferential orientation of (002) crystal plane, which is favorable for corrosion resistance and dendrite-free zinc deposition. Consequently, Zn|UiO-66-GF-2.2|Zn cells exhibit highly reversible plating/stripping behavior with long cycle life over 1650 h at 2.0 mA cm−2, and Zn|UiO-66-GF-2.2|MnO2 cells show excellent long-term stability with capacity retention of 85% after 1000 cycles. The reasonable design and application of multifunctional metal organic frameworks modified separators provide useful guidance for constructing durable AZIBs.


Highlights:


1 Metal-organic frameworks (UiO-66) functionalized glass fiber separator was constructed to accelerate the transport of charge carriers and provide a uniform electric field distribution on the surface of zinc anode.
2 Zinc anode demonstrates preferential orientation of (002) plane under the control of UiO-66-GF, which effectively inhibits dendrites.
3 Density functional theory calculation confirms that the adsorption effect of (002) plane on H is weaker, thus improving corrosion resistance and suppressing the hydrogen evolution reaction.
4 Symmetric cells exhibit highly reversible plating/stripping behavior with long cycle life over 1650 h and full cells demonstrate excellent long-term stability (85%) for 1000 cycles.

Keywords

Aqueous zinc-ion batteries Separators Metal–organic frameworks Ion transport Dendrite-free
Song, Yang, Pengchao Ruan, Caiwang Mao, Yuxin Chang, Ling Wang, Lei Dai, Peng Zhou, Bingan Lu, Jiang Zhou, and Zhangxing He. 2022. “Metal–Organic Frameworks Functionalized Separators for Robust Aqueous Zinc-Ion Batteries”. Nano-Micro Letters 14 (November):218. https://doi.org/10.1007/s40820-022-00960-z.
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References
  1. N. Guo, W. Huo, X. Dong, Z. Sun, Y. Lu et al., A review on 3D zinc anodes for zinc ion batteries. Small Methods 6(9), 2200597 (2022). https://doi.org/10.1002/smtd.202200597
  2. P. Ruan, X. Xu, D. Zheng, X. Chen, X. Yin et al., Promoting reversible dissolution/deposition of MnO2 for high-energy-density zinc batteries via enhancing cut-off voltage. Chemsuschem 15(18), 202201118 (2022). https://doi.org/10.1002/cssc.202201118
  3. X. Li, Z. Chen, Y. Yang, S. Liang, B. Lu et al., The phosphate cathodes for aqueous zinc-ion batteries. Inorg. Chem. Front. 9(16), 3986–3998 (2022). https://doi.org/10.1039/D2QI01083F
  4. B. Li, X. Zhang, T. Wang, Z. He, B. Lu et al., Interfacial engineering strategy for high-performance zinc metal anode. Nano-Micro Lett. 14, 6 (2022). https://doi.org/10.1007/s40820-021-00764-7
  5. Z. Liu, Y. Yang, S. Liang, B. Lu, J. Zhou et al., pH-buffer contained electrolyte for self-adjusted cathode-free Zn-MnO2 batteries with coexistence of dual mechanisms. Small Struct. 2(11), 2100119 (2021). https://doi.org/10.1002/sstr.202100119
  6. C. Li, X. Xie, H. Liu, P. Wang, C. Deng et al., Integrated “all-in-one” strategy to stabilize zinc anodes for high-performance zinc-ion batteries. Natl. Sci. Rev. 9(3), 177 (2022). https://doi.org/10.1093/nsr/nwab177
  7. Y. Geng, L. Pan, Z. Peng, Z. Sun, H. Lin et al., Electrolyte additive engineering for aqueous Zn ion batteries. Energy Storage Mater. 51, 733–755 (2022). https://doi.org/10.1016/j.ensm.2022.07.017
  8. C. Xie, Y. Li, Q. Wang, D. Sun, Y. Tang et al., Issues and solutions toward zinc anode in aqueous zinc-ion batteries: a mini review. Carbon Energy 2(4), 540–560 (2020). https://doi.org/10.1002/cey2.67
  9. P. Ruan, S. Liang, B. Lu, H. Fan, J. Zhou et al., Design strategies for high-energy-density aqueous zinc batteries. Angew. Chem. Int. Ed. 61(17), 202200598 (2022). https://doi.org/10.1002/anie.202200598
  10. Y. Zhang, G. Yang, M.L. Lehmann, C. Wu, L. Zhao et al., Separator effect on zinc electrodeposition behavior and its implication for zinc battery lifetime. Nano Lett. 21(24), 10446–10452 (2021). https://doi.org/10.1021/acs.nanolett.1c03792
  11. G.A. Elia, J.B. Ducros, D. Sotta, V. Delhorbe, A. Brun et al., Polyacrylonitrile separator for high-performance aluminum batteries with improved interface stability. ACS Appl. Mater. Interfaces 9(44), 38381–38389 (2017). https://doi.org/10.1021/acsami.7b09378
  12. J. Cao, D. Zhang, X. Zhang, M. Sawangphruk, J. Qin et al., A universal and facile approach to suppress dendrite formation for a Zn and Li metal anode. J. Mater. Chem. A 8(18), 9331–9344 (2020). https://doi.org/10.1039/d0ta02486d
  13. C. Peng, Y. Zhang, S. Yang, L. Zhang, Z. Wang et al., Flexible zincophilic polypyrrole paper interlayers for stable Zn metal anodes: higher surface flatness promises better reversibility. Nano Energy 98, 107329 (2022). https://doi.org/10.1016/j.nanoen.2022.107329
  14. Z. Hou, Y. Gao, H. Tan, B. Zhang, Realizing high-power and high-capacity zinc/sodium metal anodes through interfacial chemistry regulation. Nat. Commun. 12, 3083 (2021). https://doi.org/10.1038/s41467-021-23352-0
  15. R. Yuksel, O. Buyukcakir, P.K. Panda, S.H. Lee, Y. Jiang et al., Necklace-like nitrogen-doped tubular carbon 3D frameworks for electrochemical energy storage. Adv. Funct. Mater. 30(10), 1909725 (2020). https://doi.org/10.1002/adfm.201909725
  16. T. Liu, J. Hong, J. Wang, Y. Xu, Y. Wang, Uniform distribution of zinc ions achieved by functional supramolecules for stable zinc metal anode with long cycling lifespan. Energy Storage Mater. 45, 1074–1083 (2022). https://doi.org/10.1016/j.ensm.2021.11.002
  17. Y. Liang, D. Ma, N. Zhao, Y. Wang, M. Yang et al., Novel concept of separator design: efficient ions transport modulator enabled by dual-interface engineering toward ultra-stable Zn metal anodes. Adv. Funct. Mater. 32(25), 2112936 (2022). https://doi.org/10.1002/adfm.202112936
  18. Y. Guo, W. Cai, Y. Lin, Y. Zhang, S. Luo et al., An ion redistributor enabled by cost-effective weighing paper interlayer for dendrite free aqueous zinc-ion battery. Energy Storage Mater. 50, 580–588 (2022). https://doi.org/10.1016/j.ensm.2022.06.001
  19. P. Cao, H. Zhou, X. Zhou, Q. Du, J. Tang et al., Stabilizing zinc anodes by a cotton towel separator for aqueous zinc-ion batteries. ACS Sustain. Chem. Eng. 10(26), 8350–8359 (2022). https://doi.org/10.1021/acssuschemeng.2c01133
  20. G. Gao, Y. Wang, S. Wang, R. Yang, Y. Chen et al., Stepped channels integrated lithium-sulfur separator via photoinduced multidimensional fabrication of metal-organic frameworks. Angew. Chem. Int. Ed. 60(18), 10147–10154 (2021). https://doi.org/10.1002/anie.202016608
  21. R. Rego, M. Kurkuri, M. Kigga, A comprehensive review on water remediation using UiO-66 MOFs and their derivatives. Chemosphere 302, 134845 (2022). https://doi.org/10.1016/j.chemosphere.2022.134845
  22. M. Sun, J. Li, H. Yuan, X. Zeng, J. Lan et al., Fast Li+ transport pathways of quasi-solid-state electrolyte constructed by 3D MOF composite nanofibrous network for dendrite-free lithium metal battery. Mater. Today Energy 29, 101117 (2022). https://doi.org/10.1016/j.mtener.2022.101117
  23. X. Liu, F. Yang, W. Xu, Y. Zeng, J. He et al., Zeolitic imidazolate frameworks as Zn2+ modulation layers to enable dendrite-free Zn anodes. Adv. Sci. 7(21), 2002173 (2020). https://doi.org/10.1002/advs.202002173
  24. L. Wang, Y. Zhu, C. Du, X. Ma, C. Cao, Advances and challenges in metal-organic framework derived porous materials for batteries and electrocatalysis. J. Mater. Chem. A 8(47), 24895–24919 (2020). https://doi.org/10.1039/d0ta08311a
  25. K. Wu, J. Yi, X. Liu, Y. Sun, J. Cui et al., Regulating Zn deposition via an artificial solid-electrolyte interface with aligned dipoles for long life Zn anode. Nano-Micro Lett. 13, 79 (2021). https://doi.org/10.1007/s40820-021-00599-2
  26. Y. Fu, Q. Wei, G. Zhang, X. Wang, J. Zhang et al., High-performance reversible aqueous Zn-ion battery based on porous MnOx nanorods coated by MOF-derived N-doped carbon. Adv. Energy Mater. 8(26), 1801445 (2018). https://doi.org/10.1002/aenm.201801445
  27. S. Wang, W. Morris, Y. Liu, C.M. McGuirk, Y. Zhou et al., Surface-specific functionalization of nanoscale metal-organic frameworks. Angew. Chem. Int. Ed. 54(49), 14738–14742 (2015). https://doi.org/10.1002/anie.201506888
  28. F. Ahmadijokani, R. Mohammadkhani, S. Ahmadipouya, A. Shokrgozar, M. Rezakazemi et al., Superior chemical stability of UiO-66 metal-organic frameworks (MOFs) for selective dye adsorption. Chem. Eng. J. 399, 125346 (2020). https://doi.org/10.1016/j.cej.2020.125346
  29. Y. Jiang, G. Cheng, Y. Li, Z. He, J. Zhu et al., Promoting vanadium redox flow battery performance by ultra-uniform ZrO2@C from metal-organic framework. Chem. Eng. J. 415, 129014 (2021). https://doi.org/10.1016/j.cej.2021.129014
  30. W. Li, J. Liu, C. Yan, Multi-walled carbon nanotubes used as an electrode reaction catalyst for VO2+/VO2+ for a vanadium redox flow battery. Carbon 49(11), 3463–3470 (2011). https://doi.org/10.1016/j.carbon.2011.04.045
  31. H. Zhou, Y. Shen, J. Xi, X. Qiu, L. Chen, ZrO2-nanop-modified graphite felt: bifunctional effects on vanadium flow batteries. ACS Appl. Mater. Interfaces 8(24), 15369–15378 (2016). https://doi.org/10.1021/acsami.6b03761
  32. C. Chen, D. Chen, S. Xie, H. Quan, X. Luo et al., Adsorption behaviors of organic micropollutants on zirconium metal-organic framework UiO-66: analysis of surface interactions. ACS Appl. Mater. Interfaces 9(46), 41043–41054 (2017). https://doi.org/10.1021/acsami.7b13443
  33. X. Min, X. Wu, P. Shao, Z. Ren, L. Ding et al., Ultra-high capacity of lanthanum-doped UiO-66 for phosphate capture: unusual doping of lanthanum by the reduction of coordination number. Chem. Eng. J. 358, 321–330 (2019). https://doi.org/10.1016/j.cej.2018.10.043
  34. Q. Li, F. Zeng, Y. Guan, Z. Jin, Y. Huang et al., Poly (dimethylsiloxane) modified lithium anode for enhanced performance of lithium-sulfur batteries. Energy Storage Mater. 13, 151–159 (2018). https://doi.org/10.1016/j.ensm.2018.01.002
  35. Z. Man, Y. Meng, X. Lin, X. Dai, L. Wang et al., Assembling UiO-66@TiO2 nanocomposites for efficient photocatalytic degradation of dimethyl sulfide. Chem. Eng. J. 431, 133952 (2022). https://doi.org/10.1016/j.cej.2021.133952
  36. X. Yang, C. Li, Z. Sun, S. Yang, Z. Shi et al., Interfacial manipulation via in-situ grown ZnSe overlayer toward highly reversible Zn metal anodes. Adv. Mater. 33(52), 2105951 (2021). https://doi.org/10.21203/rs.3.rs-400312/v1
  37. W. Deng, N. Zhang, X. Wang, Hybrid interlayer enables dendrite-free and deposition-modulated zinc anodes. Chem. Eng. J. 432, 134378 (2022). https://doi.org/10.1016/j.cej.2021.134378
  38. J. Yan, M. Ye, Y. Zhang, Y. Tang, C. Li, Layered zirconium phosphate-based artificial solid electrolyte interface with zinc ion channels towards dendrite-free Zn metal anodes. Chem. Eng. J. 432, 134227 (2022). https://doi.org/10.1016/j.cej.2021.134227
  39. Y. Wang, Y. Liu, H. Wang, S. Dou, W. Gan et al., MOF-based ionic sieve interphase for regulated Zn2+ flux toward dendrite-free aqueous zinc-ion batteries. J. Mater. Chem. A 10(8), 4366–4375 (2022). https://doi.org/10.1039/d1ta10245a
  40. H. He, H. Tong, X. Song, X. Song, J. Liu, Highly stable Zn metal anodes enabled by atomic layer deposited Al2O3 coating for aqueous zinc-ion batteries. J. Mater. Chem. A 8(16), 7836–7846 (2020). https://doi.org/10.1039/d0ta00748j
  41. Z. Miao, Q. Liu, W. Wei, X. Zhao, M. Du et al., Unveiling unique steric effect of threonine additive for highly reversible Zn anode. Nano Energy 97, 107145 (2022). https://doi.org/10.1016/j.nanoen.2022.107145
  42. Z. Cao, X. Zhu, D. Xu, P. Dong, M.O.L. Chee et al., Eliminating Zn dendrites by commercial cyanoacrylate adhesive for zinc ion battery. Energy Storage Mater. 36, 132–138 (2021). https://doi.org/10.1016/j.ensm.2020.12.022
  43. L. Dong, W. Yang, W. Yang, H. Tian, Y. Huang et al., Flexible and conductive scaffold-stabilized zinc metal anodes for ultralong-life zinc-ion batteries and zinc-ion hybrid capacitors. Chem. Eng. J. 384, 123355 (2020). https://doi.org/10.1016/j.cej.2019.123355
  44. C. Li, Z. Sun, T. Yang, L. Yu, N. Wei et al., Directly grown vertical graphene carpets as Janus separators toward stabilized Zn metal anodes. Adv. Mater. 32(33), 2003425 (2020). https://doi.org/10.1002/adma.202003425
  45. C. Deng, X. Xie, J. Han, Y. Tang, J. Gao et al., A sieve-functional and uniform-porous kaolin layer toward stable zinc metal anode. Adv. Funct. Mater. 30(21), 2000599 (2020). https://doi.org/10.1002/adfm.202000599
  46. Z. Wang, L. Dong, W. Huang, H. Jia, Q. Zhao et al., Simultaneously regulating uniform Zn2+ flux and electron conduction by MOF/rGO interlayers for high-performance Zn anodes. Nano-Micro Lett. 13, 73 (2021). https://doi.org/10.1007/s40820-021-00594-7
  47. B.S. Lee, S. Cui, X. Xing, H. Liu, X. Yue et al., Dendrite suppression membranes for rechargeable zinc batteries. ACS Appl. Mater. Interfaces 10(45), 38928–38935 (2018). https://doi.org/10.1021/acsami.8b14022
  48. Q. Yang, G. Liang, Y. Guo, Z. Liu, B. Yan et al., Do zinc dendrites exist in neutral zinc batteries: a developed electrohealing strategy to in situ rescue in-service batteries. Adv. Mater. 31(43), 1903778 (2019). https://doi.org/10.1002/adma.201903778
  49. Y. Zeng, P. Sun, Z. Pei, Q. Jin, X. Zhang et al., Nitrogen-doped carbon fibers embedded with zincophilic Cu nanoboxes for stable Zn-metal anodes. Adv. Mater. 34(18), 2200342 (2022). https://doi.org/10.1002/adma.202200342
  50. W. Zhou, M. Chen, Q. Tian, J. Chen, X. Xu et al., Cotton-derived cellulose film as a dendrite-inhibiting separator to stabilize the zinc metal anode of aqueous zinc ion batteries. Energy Storage Mater. 44, 57–65 (2022). https://doi.org/10.1016/j.ensm.2021.10.002
  51. Y. Zeng, X. Zhang, R. Qin, X. Liu, P. Fang et al., Dendrite-free zinc deposition induced by multifunctional CNT frameworks for stable flexible Zn-ion batteries. Adv. Mater. 31(36), 1903675 (2019). https://doi.org/10.1002/adma.201903675
  52. Y. Chu, S. Zhang, S. Wu, Z. Hu, G. Cui et al., In situ built interphase with high interface energy and fast kinetics for high performance Zn metal anodes. Energy Environ. Sci. 14(6), 3609–3620 (2021). https://doi.org/10.1039/d1ee00308a
  53. X. Pu, B. Jiang, X. Wang, W. Liu, L. Dong et al., High-performance aqueous zinc-ion batteries realized by MOF materials. Nano-Micro Lett. 12, 152 (2020). https://doi.org/10.1007/s40820-020-00487-1
  54. L. Hong, X. Wu, L. Wang, M. Zhong, P. Zhang et al., Highly reversible zinc anode enabled by a cation-exchange coating with Zn-ion selective channels. ACS Nano 16(4), 6906–6915 (2022). https://doi.org/10.1021/acsnano.2c02370
  55. W. Shang, Q. Li, F. Jiang, B. Huang, J. Song, B. Zn et al., I2 battery’s performance by coating a zeolite-based cation-exchange protecting layer. Nano-Micro Lett. 14, 82 (2022). https://doi.org/10.1007/s40820-022-00825-5
  56. J. Zhao, J. Zhang, W. Yang, B. Chen, Z. Zhao et al., “Water-in-deep eutectic solvent” electrolytes enable zinc metal anodes for rechargeable aqueous batteries. Nano Energy 57, 625–634 (2019). https://doi.org/10.1016/j.nanoen.2018.12.086
  57. T. Wang, Q. Xi, Y. Li, H. Fu, Y. Hua et al., Regulating dendrite-free zinc deposition by red phosphorous-derived artificial protective layer for zinc metal batteries. Adv. Sci. 9(18), 2200155 (2022). https://doi.org/10.1002/advs.202200155
  58. X. Chen, P. Ruan, X. Wu, S. Liang, J. Zhou, Crystal structures, reaction mechanisms, and optimization strategies of MnO2 cathode for aqueous rechargeable zinc batteries. Acta Phys. Chim. Sin. 38(12), 2111003 (2022). https://doi.org/10.3866/pku.Whxb202111003
  59. H. Yu, Y. Chen, H. Wang, X. Ni, W. Wei et al., Engineering multi-functionalized molecular skeleton layer for dendrite-free and durable zinc batteries. Nano Energy 99, 107426 (2022). https://doi.org/10.1016/j.nanoen.2022.107426
  60. D. Zuo, S. Song, C. An, L. Tang, Z. He et al., Synthesis of sandwich-like structured Sn/SnOx@MXene composite through in-situ growth for highly reversible lithium storage. Nano Energy 62, 401–409 (2019). https://doi.org/10.1016/j.nanoen.2019.05.062
  61. H. Moon, K.H. Ha, Y. Park, J. Lee, M.S. Kwon et al., Direct proof of the reversible dissolution/deposition of Mn2+/Mn4+ for mild-acid Zn-MnO2 batteries with porous carbon interlayers. Adv. Sci. 8(6), 2003714 (2021). https://doi.org/10.1002/advs.202003714
  62. J. Hao, J. Long, B. Li, X. Li, S. Zhang et al., Toward high-performance hybrid Zn-based batteries via deeply understanding their mechanism and using electrolyte additive. Adv. Funct. Mater. 29(34), 1903605 (2019). https://doi.org/10.1002/adfm.201903605
  63. P. Ruan, X. Xu, X. Gao, J. Feng, L. Yu et al., Achieving long-cycle-life Zn-ion batteries through interfacial engineering of MnO2-polyaniline hybrid networks. Sustain. Mater. Technol. 28, 00254 (2021). https://doi.org/10.1016/j.susmat.2021.e00254
  64. Y. Tang, C. Liu, H. Zhu, X. Xie, J. Gao et al., Ion-confinement effect enabled by gel electrolyte for highly reversible dendrite-free zinc metal anode. Energy Storage Mater. 27, 109–116 (2020). https://doi.org/10.1016/j.ensm.2020.01.023
  65. Y. Liu, X. Zhou, X. Wang, G. Chen, R. Liu et al., Hydrated titanic acid as an ultralow-potential anode for aqueous zinc-ion full batteries. Chem. Eng. J. 420, 129629 (2021). https://doi.org/10.1016/j.cej.2021.129629
  66. Z. Huang, T. Wang, H. Song, X. Li, G. Liang et al., Effects of anion carriers on capacitance and self-discharge behaviors of zinc ion capacitors. Angew. Chem. Int. Ed. 60(2), 1011–1021 (2021). https://doi.org/10.1002/anie.202012202
  67. D. Yuan, J. Zhao, H. Ren, Y. Chen, R. Chua et al., Anion texturing towards dendrite-free Zn anode for aqueous rechargeable batteries. Angew. Chem. Int. Ed. 60(13), 7213–7219 (2021). https://doi.org/10.1002/anie.202015488
  68. Y. Zhong, Z. Cheng, H. Zhang, J. Li, D. Liu et al., Monosodium glutamate, an effective electrolyte additive to enhance cycling performance of Zn anode in aqueous battery. Nano Energy 98, 107220 (2022). https://doi.org/10.1016/j.nanoen.2022.107220
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