Issue

Vol. 15 (2023)

Hetero Nucleus Growth Stabilizing Zinc Anode for High-Biosecurity Zinc-Ion Batteries

https://doi.org/10.1007/s40820-023-01206-2
Jingjing Li
Department of Plastic Surgery and National Clinical Research Center for Geriatric Disorders, Xiangya Hospital, Central South University, Changsha 410008, People’s Republic of China
Zhexuan Liu
School of Materials Science and Engineering, Hunan Provincial Key Laboratory of Electronic Packaging and Advanced Functional Materials, Central South University, Changsha 410083, People’s Republic of China
Shaohua Han
School of Materials Science and Engineering, Hunan Provincial Key Laboratory of Electronic Packaging and Advanced Functional Materials, Central South University, Changsha 410083, People’s Republic of China
Peng Zhou
Hunan Provincial Key Defense Laboratory of High Temperature Wear‑Resisting Materials and Preparation Technology, Hunan University of Science and Technology, Xiangtan 411201, People’s Republic of China
Bingan Lu
School of Physics and Electronics, Hunan University, Changsha 410082, People’s Republic of China
Jianda Zhou
Department of Plastic Surgery, The Third Xiangya Hospital, Central South University, Changsha 410013, People’s Republic of China
Zhiyuan Zeng
Department of Materials Science and Engineering, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon 999077, Hong Kong, People’s Republic of China
Zhizhao Chen
Department of Plastic Surgery and National Clinical Research Center for Geriatric Disorders, Xiangya Hospital, Central South University, Changsha 410008, People’s Republic of China
Jiang Zhou
School of Materials Science and Engineering, Hunan Provincial Key Laboratory of Electronic Packaging and Advanced Functional Materials, Central South University, Changsha 410083, People’s Republic of China

Corresponding Author: Jiang Zhou

zhou_jiang@csu.edu.cn

Nano-Micro Letters, Vol. 15 (2023), Article Number: 237

Abstract

Biocompatible devices are widely employed in modernized lives and medical fields in the forms of wearable and implantable devices, raising higher requirements on the battery biocompatibility, high safety, low cost, and excellent electrochemical performance, which become the evaluation criteria toward developing feasible biocompatible batteries. Herein, through conducting the battery implantation tests and leakage scene simulations on New Zealand rabbits, zinc sulfate electrolyte is proved to exhibit higher biosecurity and turns out to be one of the ideal zinc salts for biocompatible zinc-ion batteries (ZIBs). Furthermore, in order to mitigate the notorious dendrite growth and hydrogen evolution in mildly acidic electrolyte as well as improve their operating stability, Sn hetero nucleus is introduced to stabilize the zinc anode, which not only facilitates the planar zinc deposition, but also contributes to higher hydrogen evolution overpotential. Finally, a long lifetime of 1500 h for the symmetrical cell, the specific capacity of 150 mAh g−1 under 0.5 A g−1 for the Zn–MnO2 battery and 212 mAh g−1 under 5 A g−1 for the Zn—NH4V4O10 battery are obtained. This work may provide unique perspectives on biocompatible ZIBs toward the biosecurity of their cell components.


Highlights:
1 Animal models are applied to evaluate the biosecurity and biocompatibility of the zinc-ion batteries with the electrolytes of different zinc salts.
2 Leakage scene simulations and histological analysis are employed in investigating the tissue response after battery implantations, in which ZnSO4 exhibits higher biosecurity.
3 Sn hetero nucleus is introduced to stabilize the zinc anode, which not only facilitates the planar zinc deposition, but also contributes to higher hydrogen evolution overpotential.

Keywords

Aqueous zinc-ion batteries Biocompatible devices Operating stability Zinc anode Zinc salts electrolyte
Li, Jingjing, Zhexuan Liu, Shaohua Han, Peng Zhou, Bingan Lu, Jianda Zhou, Zhiyuan Zeng, Zhizhao Chen, and Jiang Zhou. 2023. “Hetero Nucleus Growth Stabilizing Zinc Anode for High-Biosecurity Zinc-Ion Batteries”. Nano-Micro Letters 15 (October):237. https://doi.org/10.1007/s40820-023-01206-2.
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References
  1. S.A. Hashemi, S. Ramakrishna, A.G. Aberle, Recent progress in flexible-wearable solar cells for self-powered electronic devices. Energy Environ. Sci. 13, 685–743 (2020). https://doi.org/10.1039/c9ee03046h
  2. Y. Lv, Y. Xiao, L. Ma, C. Zhi, S. Chen, Recent advances in electrolytes for “beyond aqueous” zinc-ion batteries. Adv. Mater. 34, 2106409 (2022). https://doi.org/10.1002/adma.202106409
  3. S. Lei, Z. Liu, C. Liu, J. Li, B. Lu et al., Opportunities for biocompatible and safe zinc-based batteries. Energy Environ. Sci. 15, 4911–4927 (2022). https://doi.org/10.1039/d2ee02267b
  4. C.M. Boutry, Y. Kaizawa, B.C. Schroeder, A. Chortos, A. Legrand et al., A stretchable and biodegradable strain and pressure sensor for orthopaedic application. Nat. Electron. 1, 314–321 (2018). https://doi.org/10.1038/s41928-018-0071-7
  5. J. Zhao, Y. Lin, J. Wu, H.Y.Y. Nyein, M. Bariya et al., A fully integrated and self-powered smartwatch for continuous sweat glucose monitoring. ACS Sens. 4, 1925–1933 (2019). https://doi.org/10.1021/acssensors.9b00891
  6. D. Chao, C.R. Zhu, M. Song, P. Liang, X. Zhang et al., A high-rate and stable quasi-solid-state zinc-ion battery with novel 2D layered zinc orthovanadate array. Adv. Mater. 30, 1803181 (2018). https://doi.org/10.1002/adma.201803181
  7. C. Yang, J. Xia, C. Cui, T.P. Pollard, J. Vatamanu et al., All-temperature zinc batteries with high-entropy aqueous electrolyte. Nat. Sustain. 6, 325–335 (2023). https://doi.org/10.1038/s41893-022-01028-x
  8. A.M. Zamarayeva, A.E. Ostfeld, M. Wang, J.K. Duey, I. Deckman et al., Flexible and stretchable power sources for wearable electronics. Sci. Adv. 3, 1602051 (2017). https://doi.org/10.1126/sciadv.1602051
  9. X. Shi, Y. Zuo, P. Zhai, J. Shen, Y. Yang et al., Large-area display textiles integrated with functional systems. Nature 591, 240–245 (2021). https://doi.org/10.1038/s41586-021-03295-8
  10. X. Huang, L. Wang, H. Wang, B. Zhang, X. Wang et al., Materials strategies and device architectures of emerging power supply devices for implantable bioelectronics. Small 16, 1902827 (2020). https://doi.org/10.1002/smll.201902827
  11. X. Huang, D. Wang, Z. Yuan, W. Xie, Y. Wu et al., A fully biodegradable battery for self-powered transient implants. Small 14, 1800994 (2018). https://doi.org/10.1002/smll.201800994
  12. T. Ye, J. Wang, Y. Jiao, L. Li, E. He et al., A tissue-like soft all-hydrogel battery. Adv. Mater. 34, 2105120 (2022). https://doi.org/10.1002/adma.202105120
  13. J. Li, P. Ruan, X. Chen, S. Lei, B. Lu et al., Aqueous batteries for human body electronic devices. ACS Energy Lett. 8, 2904–2918 (2023). https://doi.org/10.1021/acsenergylett.3c00678
  14. M. Shi, R. Wang, L. Li, N. Chen, P. Xiao et al., Redox-active polymer integrated with MXene for ultra-stable and fast aqueous proton storage. Adv. Funct. Mater. 33, 2209777 (2022). https://doi.org/10.1002/adfm.202209777
  15. R. Wang, M. Shi, L. Li, Y. Zhao, L. Zhao et al., In-situ investigation and application of cyano-substituted organic electrode for rechargeable aqueous Na-ion batteries. Chem. Eng. J. 451, 138652 (2023). https://doi.org/10.1016/j.cej.2022.138652
  16. C. Chen, H. Zhu, M. Shi, L. Hu, Z. Xue et al., Oxygen vacancies-modulated tungsten oxide anode for ultra-stable and fast aqueous aluminum-ion storage. Energy Storge Mater. 49, 370–379 (2022). https://doi.org/10.1016/j.ensm.2022.04.013
  17. C. Li, X. Xie, S. Liang, J. Zhou, Issues and future perspective on zinc metal anode for rechargeable aqueous zinc-ion batteries. Energy Environ. Mater. 3, 146–159 (2020). https://doi.org/10.1002/eem2.12067
  18. Z. Xing, Y. Sun, X. Xie, Y. Tang, G. Xu et al., Zincophilic electrode interphase with appended proton reservoir ability stabilizes Zn metal anodes. Angew. Chem. Int. Ed. 62, 202215324 (2023). https://doi.org/10.1002/anie.202215324
  19. M. Li, X. Wang, J. Hu, J. Zhu, C. Niu et al., Comprehensive H2O molecules regulation via deep eutectic solvents for ultra-stable zinc metal anode. Angew. Chem. Int. Ed. 62, 202215552 (2023). https://doi.org/10.1002/anie.202215552
  20. Y. Yang, S. Guo, Y. Pan, B. Lu, S. Liang et al., Dual mechanism of ion (de)intercalation and iodine redox towards advanced zinc batteries. Energy Environ. Sci. 16, 2358–2367 (2023). https://doi.org/10.1039/D3EE00501A
  21. R. Xu, J. Zhou, H. Gong, L. Qiao, Y. Li et al., Environment-friendly degradable zinc-ion battery based on guar gum-cellulose aerogel electrolyte. Biomater. Sci. 10, 1476–1485 (2022). https://doi.org/10.1039/D1BM01747K
  22. J. Zhou, Y. Li, L. Xie, R. Xu, R. Zhang et al., Humidity-sensitive, shape-controllable, and transient zinc-ion batteries based on plasticizing gelatin-silk protein electrolytes. Mater. Today Energy 21, 100712 (2021). https://doi.org/10.1016/j.mtener.2021.100712
  23. H. Dong, J. Li, J. Guo, F. Lai, F. Zhao et al., Insights on flexible zinc-ion batteries from lab research to commercialization. Adv. Mater. 33, 2007548 (2021). https://doi.org/10.1002/adma.202007548
  24. B. Li, X. Zhang, T. Wang, Z. He, B. Lu et al., Interfacial engineeringstrategy for high-performance Zn metal anodes. Nano-Micro Lett. 14, 6 (2021). https://doi.org/10.1007/s40820-021-00764-7
  25. Y. Song, P. Ruan, C. Mao, Y. Chang, L. Wang et al., Metal–organic frameworks functionalized separators for robust aqueous zinc-ion batteries. Nano-Micro Lett. 14, 218 (2022). https://doi.org/10.1007/s40820-022-00960-z
  26. R. Yi, X. Shi, Y. Tang, Y. Yang, P. Zhou et al., Carboxymethyl chitosan-modified zinc anode for high-performance zinc-iodine battery with narrow operating voltage. Small Struct. (2023). https://doi.org/10.1002/sstr.202300020
  27. Y. Liu, X. Zhou, Y. Bai, R. Liu, X. Li et al., Engineering integrated structure for high-performance flexible zinc-ion batteries. Chem. Eng. J. 417, 127955 (2021). https://doi.org/10.1016/j.cej.2020.127955
  28. Z. Tian, Z. Sun, Y. Shao, L. Gao, R. Huang et al., Ultrafast rechargeable Zn micro-batteries endowing a wearable solar charging system with high overall efficiency. Energy Environ. Sci. 14, 1602–1611 (2021). https://doi.org/10.1039/d0ee03623d
  29. X. Fan, J. Liu, Z. Song, X. Han, Y. Deng et al., Porous nanocomposite gel polymer electrolyte with high ionic conductivity and superior electrolyte retention capability for long-cycle-life flexible zinc-air batteries. Nano Energy 56, 454–462 (2019). https://doi.org/10.1016/j.nanoen.2018.11.057
  30. X. Xie, J. Li, Z. Xing, B. Lu, S. Liang et al., Biocompatible zinc battery with programmable electro-cross-linked electrolyte. Natl. Sci. Rev. 10, nwac281 (2023). https://doi.org/10.1093/nsr/nwac281
  31. P. Li, M. Liao, J. Li, L. Ye, X. Cheng et al., Rechargeable micro-batteries for wearable and implantable applications. Small Struct. 3, 2200058 (2022). https://doi.org/10.1002/sstr.202200058
  32. J. Zhou, R. Zhang, R. Xu, Y. Li, W. Tian et al., Super-assembled hierarchical cellulose aerogel-gelatin solid electrolyte for implantable and biodegradable zinc-ion battery. Adv. Funct. Mater. 32, 2111406 (2022). https://doi.org/10.1002/adfm.202111406
  33. J.S. Chae, S.K. Park, K.C. Roh, H.S. Park, Electrode materials for biomedical patchable and implantable energy storage devices. Energy Storge Mater. 24, 113–128 (2020). https://doi.org/10.1016/j.ensm.2019.04.032
  34. Z. Zhang, X. Yang, P. Li, Y. Wang, X. Zhao et al., Biomimetic dendrite-free multivalent metal batteries. Adv. Mater. 34, 2206970 (2022). https://doi.org/10.1002/adma.202206970
  35. X. Chen, X. Shi, P. Ruan, Y. Tang, Y. Sun et al., Construction of an artificial interfacial layer with porous structure toward stable zinc-metal anodes. Small Sci. 3, 2300007 (2023). https://doi.org/10.1002/smsc.202300007
  36. P. Ruan, X. Chen, L. Qin, Y. Tang, B. Lu et al., Achieving highly proton-resistant Zn–Pb anode through low hydrogen affinity and strong bonding for long-life electrolytic Zn//MnO2 battery. Adv. Mater. 35, 2300577 (2023). https://doi.org/10.1002/adma.202300577
  37. F. Mo, G. Liang, Q. Meng, Z. Liu, H. Li et al., A flexible rechargeable aqueous zinc manganese-dioxide battery working at − 20 °C. Energy Environ. Sci. 12, 706–715 (2019). https://doi.org/10.1039/c8ee02892c
  38. Q. Li, D. Wang, B. Yan, Y. Zhao, J. Fan et al., Dendrite issues for zinc anodes in a flexible cell configuration for zinc-based wearable energy-storage devices. Angew. Chem. Int. Ed. 61, 202202780 (2022). https://doi.org/10.1002/anie.202202780
  39. X. Xie, H. Fu, Y. Fang, B. Lu, J. Zhou et al., Manipulating ion concentration to boost two-electron Mn4+/Mn2+ redox kinetics through a colloid electrolyte for high-capacity zinc batteries. Adv. Energy Mater. 12, 2102393 (2021). https://doi.org/10.1002/aenm.202102393
  40. T. Wang, C. Li, X. Xie, B. Lu, Z. He et al., Anode materials for aqueous zinc ion batteries: mechanisms, properties, and perspectives. ACS Nano 12, 16321–16347 (2020). https://doi.org/10.1021/acsnano.0c07041
  41. B. Sambandam, V. Mathew, S. Kim, S. Lee, S. Kim et al., An analysis of the electrochemical mechanism of manganese oxides in aqueous zinc batteries. Chem 8, 924–946 (2022). https://doi.org/10.1016/j.chempr.2022.03.019
  42. Z. Liu, Y. Yang, B. Lu, S. Liang, H.J. Fan et al., Insights into complexing effects in acetate-based Zn–MnO2 batteries and performance enhancement by all-round strategies. Energy Storge Mater. 52, 104–110 (2022). https://doi.org/10.1016/j.ensm.2022.07.043
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