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Vol. 15 (2023)

Metal-Free 2D/2D van der Waals Heterojunction Based on Covalent Organic Frameworks for Highly Efficient Solar Energy Catalysis

https://doi.org/10.1007/s40820-023-01100-x
Ge Yan
Institute of Clean Energy Chemistry, Key Laboratory for Green Synthesis and Preparative Chemistry of Adv. Mater., College of Chemistry, Liaoning University, Shenyang 110036, People’s Republic of China
Xiaodong Sun
Institute of Clean Energy Chemistry, Key Laboratory for Green Synthesis and Preparative Chemistry of Adv. Mater., College of Chemistry, Liaoning University, Shenyang 110036, People’s Republic of China
Yu Zhang
Institute of Clean Energy Chemistry, Key Laboratory for Green Synthesis and Preparative Chemistry of Adv. Mater., College of Chemistry, Liaoning University, Shenyang 110036, People’s Republic of China
Hui Li
School of Science, RMIT University, Melbourne, VIC 3000, Australia
Hongwei Huang
Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083, People’s Republic of China
Baohua Jia
School of Science, RMIT University, Melbourne, VIC 3000, Australia
Dawei Su
Faculty of Science, School of Mathematical and Physical Sciences, University of Technology Sydney, Sydney, NSW 2007, Australia
Tianyi Ma
School of Science, RMIT University, Melbourne, VIC 3000, Australia

Corresponding Author: Tianyi Ma

tianyi.ma@rmit.edu.au

Nano-Micro Letters, Vol. 15 (2023), Article Number: 132

Abstract

Covalent organic frameworks (COFs) have emerged as a kind of rising star materials in photocatalysis. However, their photocatalytic activities are restricted by the high photogenerated electron–hole pairs recombination rate. Herein, a novel metal-free 2D/2D van der Waals heterojunction, composed of a two-dimensional (2D) COF with ketoenamine linkage (TpPa-1-COF) and 2D defective hexagonal boron nitride (h-BN), is successfully constructed through in situ solvothermal method. Benefitting from the presence of VDW heterojunction, larger contact area and intimate electronic coupling can be formed between the interface of TpPa-1-COF and defective h-BN, which make contributions to promoting charge carriers separation. The introduced defects can also endow the h-BN with porous structure, thus providing more reactive sites. Moreover, the TpPa-1-COF will undergo a structural transformation after being integrated with defective h-BN, which can enlarge the gap between the conduction band position of the h-BN and TpPa-1-COF, and suppress electron backflow, corroborated by experimental and density functional theory calculations results. Accordingly, the resulting porous h-BN/TpPa-1-COF metal-free VDW heterojunction displays outstanding solar energy catalytic activity for water splitting without co-catalysts, and the H2 evolution rate can reach up to 3.15 mmol g−1 h−1, which is about 67 times greater than that of pristine TpPa-1-COF, also surpassing that of state-of-the-art metal-free-based photocatalysts reported to date. In particular, it is the first work for constructing COFs-based heterojunctions with the help of h-BN, which may provide new avenue for designing highly efficient metal-free-based photocatalysts for H2 evolution.


Highlights:


1 It is the first attempt to combine covalent organic frameworks with hexagonal boron nitride (h-BN) to construct efficient metal-free photocatalyst.
2 The composite displays superior photocatalytic hydrogen production performance in metal-free systems.
3 The integrated porous h-BN can suppress electron backflow to optimize the composite photocatalytic activity.

Keywords

Covalent organic frameworks 2D/2D van der Waals heterojunction Metal-free photocatalyst
Yan, Ge, Xiaodong Sun, Yu Zhang, Hui Li, Hongwei Huang, Baohua Jia, Dawei Su, and Tianyi Ma. 2023. “Metal-Free 2D/2D Van Der Waals Heterojunction Based on Covalent Organic Frameworks for Highly Efficient Solar Energy Catalysis”. Nano-Micro Letters 15 (May):132. https://doi.org/10.1007/s40820-023-01100-x.
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References
  1. A. Gustafson, M.H. Goldberg, P. Bergquist, K. Lacroix, S.A. Rosenthal et al., The durable, bipartisan effects of emphasizing the cost savings of renewable energy. Nat. Energy 7, 1023–1030 (2022). https://doi.org/10.1038/s41560-022-01099-2
  2. T. Bolsen, Framing renewable energy. Nat. Energy 7, 1003–1004 (2022). https://doi.org/10.1038/s41560-022-01100-y
  3. G. Graziono, Homogeneous catalysis: an electrochemical and spectroscopic look at renewable energy. Nat. Rev. Chem. 2, 0130 (2018). https://doi.org/10.1038/s41570-018-0130
  4. D.M. Kammen, D.A. Sunter, City-integrated renewable energy for urban sustainability. Science 352, 922–928 (2016). https://doi.org/10.1126/science.aad9302
  5. J.W. Ager, A.A. Lapkin, Chemical storage of renewable energy. Science 360, 707–708 (2018). https://doi.org/10.1126/science.aat7918
  6. X.-B. Li, C.-H. Tung, L.-Z. Wu, Semiconducting quantum dots for artificial photosynthesis. Nat. Rev. Chem. 2, 160–173 (2018). https://doi.org/10.1038/s41570-018-0024-8
  7. M.-Y. Qi, M. Conte, M. Anpo, Z.-R. Tang, Y.-J. Xu, Cooperative coupling of oxidative organic synthesis and hydrogen production over semiconductor-based photocatalysts. Chem. Rev. 121, 13051–13085 (2021). https://doi.org/10.1021/acs.chemrev.1c00197
  8. G. Murali, J.K.R. Modigunta, Y.H. Park, J.-H. Lee, J. Rawal et al., A review on MXene synthesis, stability, and photocatalytic applications. ACS Nano 16, 13370–13429 (2022). https://doi.org/10.1021/acsnano.2c04750
  9. J. Pitchaimani, S.-F. Ni, L. Dang, Metal dithiolene complexes in olefin addition and purification, small molecule adsorption, H2 evolution and CO2 reduction. Coord. Chem. Rev. 420, 213398 (2020). https://doi.org/10.1016/j.ccr.2020.213398
  10. X. Ren, D. Philo, Y. Li, L. Shi, K. Chang et al., Recent advances of low-dimensional phosphorus-based nanomaterials for solar-driven photocatalytic reactions. Coord. Chem. Rev. 424, 213516 (2020). https://doi.org/10.1016/j.ccr.2020.213516
  11. A.K. Singh, C. Das, A. Indra, Scope and prospect of transition metal-based cocatalysts for visible light-driven photocatalytic hydrogen evolution with graphitic carbon nitride. Coord. Chem. Rev. 465, 214516 (2022). https://doi.org/10.1016/j.ccr.2022.214516
  12. M. Yasuda, T. Matsumoto, T. Yamashita, Sacrificial hydrogen production over TiO2-based photocatalysts: polyols, carboxylic acids, and saccharides. Renew. Sustain. Energy Rev. 81, 1627–1635 (2018). https://doi.org/10.1016/j.rser.2017.05.243
  13. X. Wang, K. Maeda, A. Thomas, K. Takanabe, G. Xin et al., A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nat. Mater. 8, 76–80 (2009). https://doi.org/10.1038/nmat2317
  14. L. Lin, Z. Lin, J. Zhang, X. Cai, W. Lin et al., Molecular-level insights on the reactive facet of carbon nitride single crystals photocatalysing overall water splitting. Nat. Catal. 3, 649–655 (2020). https://doi.org/10.1038/s41929-020-0476-3
  15. M. Liu, C. Wei, H. Zhuzhang, J. Zhou, Z. Pan et al., Fully condensed poly (triazine imide) crystals: extended π-conjugation and structural defects for overall water splitting. Angew. Chem. Int. Ed. 61, e202113389 (2022). https://doi.org/10.1002/anie.202113389
  16. Z.-A. Lan, M. Wu, Z. Fang, Y. Zhang, X. Chen et al., Ionothermal synthesis of covalent triazine frameworks in a NaCl–KCl–ZnCl2 eutectic salt for the hydrogen evolution reaction. Angew. Chem. Int. Ed. 61, e202201482 (2022). https://doi.org/10.1002/anie.202201482
  17. Z.-A. Lan, X. Chi, M. Wu, X. Zhang, X. Chen et al., Molecular design of covalent triazine frameworks with anisotropic charge migration for photocatalytic hydrogen production. Small 18, 2200129 (2022). https://doi.org/10.1002/smll.202200129
  18. R. Sun, B. Tan, Covalent triazine frameworks (CTFs): synthesis, crystallization, and photocatalytic water splitting. Chem. Eur. J. (2022). https://doi.org/10.1002/chem.202203077
  19. R.S. Sprick, J.-X. Jiang, B. Bonillo, S. Ren, T. Ratvijitvech et al., Tunable organic photocatalysts for visible-light-driven hydrogen evolution. J. Am. Chem. Soc. 137, 3265–3270 (2015). https://doi.org/10.1021/ja511552k
  20. Z.-A. Lan, W. Ren, X. Chen, Y. Zhang, X. Wang, Conjugated donor-acceptor polymer photocatalysts with electron-output “tentacles” for efficient hydrogen evolution. Appl. Catal. B Environ. 245, 596–603 (2019). https://doi.org/10.1016/j.apcatb.2019.01.010
  21. G. Li, Z. Xie, Q. Wang, X. Chen, Y. Zhang et al., Asymmetric acceptor–donor–acceptor polymers with fast charge carrier transfer for solar hydrogen production. Chem. Eur. J. 27, 939–943 (2021). https://doi.org/10.1002/chem.202003856
  22. Z.-A. Lan, G. Zhang, X. Chen, Y. Zhang, K.A.I. Zhang et al., Reducing the exciton binding energy of donor–acceptor-based conjugated polymers to promote charge-induced reactions. Angew. Chem. Int. Ed. 58, 10236–10240 (2019). https://doi.org/10.1002/anie.201904904
  23. Z.-A. Lan, M. Wu, Z. Fang, X. Chi, X. Chen et al., A fully coplanar donor–acceptor polymeric semiconductor with promoted charge separation kinetics for photochemistry. Angew. Chem. Int. Ed. 60, 16355–16359 (2021). https://doi.org/10.1002/anie.202103992
  24. C. Dai, B. Liu, Conjugated polymers for visible-light-driven photocatalysis. Energy Environ. Sci. 13, 24–52 (2020). https://doi.org/10.1039/C9EE01935A
  25. H. Zhang, G. Liu, L. Shi, H. Liu, T. Wang et al., Engineering coordination polymers for photocatalysis. Nano Energy 22, 149–168 (2016). https://doi.org/10.1016/j.nanoen.2016.01.029
  26. Y. Li, M. Liu, L. Chen, Polyoxometalate built-in conjugated microporous polymers for visible-light heterogeneous photocatalysis. J. Mater. Chem. A 5, 13757–13762 (2017). https://doi.org/10.1039/C7TA03776G
  27. Y. Wan, L. Wang, H. Xu, X. Wu, J. Yang, A simple molecular design strategy for two-dimensional covalent organic framework capable of visible-light-driven water splitting. J. Am. Chem. Soc. 142, 4508–4516 (2020). https://doi.org/10.1021/jacs.0c00564
  28. D. Mullangi, V. Dhavale, S. Shalini, S. Nandi, S. Collins et al., Low-overpotential electrocatalytic water splitting with noble-metal-free nanops supported in a sp3 N-rich flexible COF. Adv. Energy Mater. 6, 1600110 (2016). https://doi.org/10.1002/aenm.201600110
  29. W. Li, X. Huang, T. Zeng, Y.A. Liu, W. Hu et al., Cover Picture: Thiazolo [5,4-d] thiazole-based donor–acceptor covalent organic framework for sunlight-driven hydrogen evolution. Angew. Chem. Int. Ed. 60, 1661–1661 (2021). https://doi.org/10.1002/anie.202016354
  30. Z. Mi, T. Zhou, W. Weng, J. Unruangsri, K. Hu et al., Covalent organic frameworks enabling site isolation of viologen-derived electron-transfer mediators for stable photocatalytic hydrogen evolution. Angew. Chem. Int. Ed. 60, 9642–9649 (2021). https://doi.org/10.1002/anie.202016618
  31. M.-L. Xu, M. Lu, G.-Y. Qin, X.-M. Wu, T. Yu et al., Piezo-photocatalytic synergy in BiFeO3@COF Z-scheme heterostructures for high-efficiency overall water splitting. Angew. Chem. Int. Ed. 61, e202210700 (2022). https://doi.org/10.1002/anie.202210700
  32. M.K. Lee, M. Shokouhimehr, S.Y. Kim, H.W. Jang, Two-dimensional metal–organic frameworks and covalent–organic frameworks for electrocatalysis: distinct merits by the reduced dimension. Adv. Energy Mater. 12, 2003990 (2022). https://doi.org/10.1002/aenm.202003990
  33. Q. Yang, M. Luo, K. Liu, H. Cao, H. Yan, Covalent organic frameworks for photocatalytic applications. Appl. Catal. B Environ. 276, 119174 (2020). https://doi.org/10.1016/j.apcatb.2020.119174
  34. S. Ma, T. Deng, Z. Li, Z. Zhang, J. Jia et al., Photocatalytic hydrogen production on a sp2-carbon-linked covalent organic framework. Angew. Chem. Int. Ed. 61, e202208919 (2022). https://doi.org/10.1002/anie.202208919
  35. W. Chen, L. Wang, D. Mo, F. He, Z. Wen et al., Modulating benzothiadiazole-based covalent organic frameworks via halogenation for enhanced photocatalytic water splitting. Angew. Chem. Int. Ed. 59, 16902–16909 (2020). https://doi.org/10.1002/anie.202006925
  36. S. Tao, D. Jiang, Covalent organic frameworks for energy conversions: Current status, challenges, and perspectives. CCS Chem. 3, 2003–2024 (2020). https://doi.org/10.31635/ccschem.020.202000491
  37. Y. Lv, Y. Li, G. Zhang, Z. Peng, L. Ye et al., An in situ film-to-film transformation approach toward highly crystalline covalent organic framework films. CCS Chem. 4, 1519–1525 (2021). https://doi.org/10.31635/ccschem.021.202101025
  38. C. Mo, M. Yang, F. Sun, J. Jian, L. Zhong et al., Alkene-linked covalent organic frameworks boosting photocatalytic hydrogen evolution by efficient charge separation and transfer in the presence of sacrificial electron donors. Adv. Sci. 7, 1902988 (2020). https://doi.org/10.1002/advs.201902988
  39. Z. Zhao, X. Chen, B. Li, S. Zhao, L. Niu et al., Spatial regulation of acceptor units in olefin-linked COFs toward highly efficient photocatalytic H2 evolution. Adv. Sci. 9, 2203832 (2022). https://doi.org/10.1002/advs.202203832
  40. M. Luo, Q. Yang, W. Yang, J. Wang, F. He et al., Defects engineering leads to enhanced photocatalytic H2 evolution on graphitic carbon nitride–covalent organic framework nanosheet composite. Small 16, 2001100 (2020). https://doi.org/10.1002/smll.202001100
  41. Y. Liu, W. Zhou, W.L. Teo, K. Wang, L. Zhang et al., Covalent-organic-framework-based composite materials. Chem 6, 3172–3202 (2020). https://doi.org/10.1016/j.chempr.2020.08.021
  42. F.-M. Zhang, J.-L. Sheng, Z.-D. Yang, X.-J. Sun, H.-L. Tang et al., Rational design of MOF/COF hybrid materials for photocatalytic H2 evolution in the presence of sacrificial electron donors. Angew. Chem. Int. Ed. 57, 12106–12110 (2018). https://doi.org/10.1002/anie.201806862
  43. L. Sun, L. Li, J. Yang, J. Fan, Q. Xu, Fabricating covalent organic framework/CdS S-scheme heterojunctions for improved solar hydrogen generation. Chin. J. Catal. 43, 350–358 (2022). https://doi.org/10.1016/S1872-2067(21)63869-X
  44. L. Sun, L. Li, J. Fan, Q. Xu, D. Ma, Construction of highly active WO3/TpPa-1-COF S-scheme heterojunction toward photocatalytic H2 generation. J. Mater. Sci. Technol. 123, 41–48 (2022). https://doi.org/10.1016/j.jmst.2021.12.065
  45. C.-C. Li, M.-Y. Gao, X.-J. Sun, H.-L. Tang, H. Dong et al., Rational combination of covalent-organic framework and nano TiO2 by covalent bonds to realize dramatically enhanced photocatalytic activity. Appl. Catal. B Environ. 266, 118586 (2020). https://doi.org/10.1016/j.apcatb.2020.118586
  46. Y.-P. Zhang, H.-L. Tang, H. Dong, M.-Y. Gao, C.-C. Li et al., Covalent-organic framework based Z-scheme heterostructured noble-metal-free photocatalysts for visible-light-driven hydrogen evolution. J. Mater. Chem. A 8, 4334–4340 (2020). https://doi.org/10.1039/C9TA12870K
  47. J. Mao, L. Wang, S. Qu, Y. Zhang, J. Huang et al., Defect engineering in CuSx/COF hybridized heterostructures: synergistic facilitation of the charge migration for an efficacious photocatalytic conversion of CO2 into CO. Inorg. Chem. 61(49), 20064–20072 (2022). https://doi.org/10.1021/acs.inorgchem.2c03481
  48. H. Yan, Y.-H. Liu, Y. Yang, H.-Y. Zhang, X.-R. Liu et al., Covalent organic framework based WO3@COF/rGO for efficient visible-light-driven H2 evolution by two-step separation mode. Chem. Eng. J. 431, 133404 (2022). https://doi.org/10.1016/j.cej.2021.133404
  49. X. An, J. Bian, K. Zhu, R. Liu, H. Liu et al., Facet-dependent activity of TiO2/covalent organic framework S-scheme heterostructures for CO2 photoreduction. Chem. Eng. J. 442, 135279 (2022). https://doi.org/10.1016/j.cej.2022.135279
  50. Y. Wang, Z. Hu, W. Wang, H. He, L. Deng et al., Design of well-defined shell–core covalent organic frameworks/metal sulfide as an efficient Z-scheme heterojunction for photocatalytic water splitting. Chem. Sci. 12, 16065–16073 (2021). https://doi.org/10.1039/D1SC05893B
  51. Y. Qin, H. Li, J. Lu, Y. Feng, F. Meng et al., Synergy between van der Waals heterojunction and vacancy in ZnIn2S4/g-C3N4 2D/2D photocatalysts for enhanced photocatalytic hydrogen evolution. Appl. Catal. B Environ. 277, 119254 (2020). https://doi.org/10.1016/j.apcatb.2020.119254
  52. Z. Wang, B. Cheng, L. Zhang, J. Yu, Y. Li et al., S-Scheme 2D/2D Bi2MoO6/BiOI van der Waals heterojunction for CO2 photoreduction. Chin. J. Catal. 43, 1657–1666 (2022). https://doi.org/10.1016/S1872-2067(21)64010-X
  53. J. Xiong, J. Di, W. Zhu, H. Li, Hexagonal boron nitride adsorbent: synthesis, performance tailoring and applications. J. Energy Chem. 40, 99–111 (2020). https://doi.org/10.1016/j.jechem.2019.03.002
  54. Z. He, C. Kim, L. Lin, T.H. Jeon, S. Lin et al., Formation of heterostructures via direct growth CN on h-BN porous nanosheets for metal-free photocatalysis. Nano Energy 42, 58–68 (2017). https://doi.org/10.1016/j.nanoen.2017.10.043
  55. M.-Y. Gao, C.-C. Li, H.-L. Tang, X.-J. Sun, H. Dong et al., Boosting visible-light-driven hydrogen evolution of covalent organic frameworks through compositing with MoS2: a promising candidate for noble-metal-free photocatalysts. J. Mater. Chem. A 7, 20193–20200 (2019). https://doi.org/10.1039/C9TA07319A
  56. G. Kresse, J. Hafner, Ab initio molecular dynamics for liquid metals. Phys. Rev. B 47(1), 558–561 (1993). https://doi.org/10.1103/PhysRevB.47.558
  57. G. Kresse, J. Hafner, Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium. Phys. Rev. B 49(20), 14251–14269 (1994). https://doi.org/10.1103/PhysRevB.49.14251
  58. G. Kresse, J. Furthmüller, Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comp. Mater. Sci. 6(1), 15–50 (1996). https://doi.org/10.1016/0927-0256(96)00008-0
  59. G. Kresse, J. Furthmüller, Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 54(16), 11169–11186 (1996). https://doi.org/10.1103/PhysRevB.54.11169
  60. J.P. Perdew, M. Ernzerhof, K. Burke, Rationale for mixing exact exchange with density functional approximations. J. Chem. Phys. 105(22), 9982–9985 (1996). https://doi.org/10.1063/1.472933
  61. P.E. Blöchl, Projector augmented-wave method. Phys. Rev. B 50(24), 17953–17979 (1994). https://doi.org/10.1103/PhysRevB.50.17953
  62. S.L. Dudarev, G.A. Botton, S.Y. Savrasov, C.J. Humphreys, A.P. Sutton, Electron-energy-loss spectra and the structural stability of nickel oxide: an LSDA+U study. Phys. Rev. B 57(3), 1505–1509 (1998). https://doi.org/10.1103/PhysRevB.57.1505
  63. L. Wang, T. Maxisch, G. Ceder, Oxidation energies of transition metal oxides within the GGA+U framework. Phys. Rev. B 73(19), 195107 (2006). https://doi.org/10.1103/PhysRevB.73.195107
  64. M.K. Aydinol, A.F. Kohan, G. Ceder, K. Cho, J. Joannopoulos, Ab initio study of lithium intercalation in metal oxides and metal dichalcogenides. Phys. Rev. B 56(3), 1354–1365 (1997). https://doi.org/10.1103/PhysRevB.56.1354
  65. S. Kandambeth, A. Mallick, B. Lukose, M.V. Mane, T. Heine et al., Construction of crystalline 2D covalent organic frameworks with remarkable chemical (acid/base) stability via a combined reversible and irreversible route. J. Am. Chem. Soc. 134, 19524–19527 (2012). https://doi.org/10.1021/ja308278w
  66. Q. Liu, C. Chen, M. Du, Y. Wu, C. Ren et al., Porous hexagonal boron nitride sheets: effect of hydroxyl and secondary amino groups on photocatalytic hydrogen evolution. ACS Appl. Nano Mater. 1, 4566–4575 (2018). https://doi.org/10.1021/acsanm.8b00867
  67. Y. Wang, Q. Yang, F. Yi, R. Lu, Y. Chen et al., NH2-UiO-66 coated with two-dimensional covalent organic frameworks: high stability and photocatalytic activity. ACS Appl. Mater. Interfaces 13, 29916–29925 (2021). https://doi.org/10.1021/acsami.1c06008
  68. A. Ishikawa, T. Takata, J.N. Kondo, M. Hara, H. Kobayashi et al., Oxysulfide Sm2Ti2S2O5 as a stable photocatalyst for water oxidation and reduction under visible light irradiation (λ ≤ 650 nm). J. Am. Chem. Soc. 124, 13547–13553 (2002). https://doi.org/10.1021/ja0269643
  69. Z. Wang, P.K. Nayak, J.A. Caraveo-Frescas, H.N. Alshareef, Recent developments in p-type oxide semiconductor materials and devices. Adv. Mater. 28, 3831–3892 (2016). https://doi.org/10.1002/adma.201503080
  70. S. Cao, L. Piao, Considerations for a more accurate evaluation method for photocatalytic water splitting. Angew. Chem. Int. Ed. 59, 18312–18320 (2020). https://doi.org/10.1002/anie.202009633
  71. Z. Wang, T. Hisatomi, R. Li, K. Sayama, G. Liu et al., Efficiency accreditation and testing protocols for particulate photocatalysts toward solar fuel production. Joule 5, 344–359 (2021). https://doi.org/10.1016/j.joule.2021.01.001
  72. J.M. Buriak, Preface to the special issue on methods and protocols in materials chemistry. Chem. Mater. 29, 1–2 (2017). https://doi.org/10.1021/acs.chemmater.6b05235
  73. S.M.H. Hejazi, M. Shahrezaei, P. Błoński, M. Allieta, P.M. Sheverdyaeva et al., Defect engineering over anisotropic brookite toward substrate-specific photo-oxidation of alcohols. Chem. Catal. 2, 1177–1190 (2022). https://doi.org/10.1016/j.checat.2022.03.015
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