Issue

Vol. 15 (2023)

Built-In Electric Field-Driven Ultrahigh-Rate K-Ion Storage via Heterostructure Engineering of Dual Tellurides Integrated with Ti3C2Tx MXene

https://doi.org/10.1007/s40820-023-01202-6
Long Pan
Key Laboratory of Advanced Metallic Materials of Jiangsu Province, School of Materials Science and Engineering, Southeast University, Nanjing 211189, People’s Republic of China
Rongxiang Hu
Key Laboratory of Advanced Metallic Materials of Jiangsu Province, School of Materials Science and Engineering, Southeast University, Nanjing 211189, People’s Republic of China
Yuan Zhang
Key Laboratory of Advanced Metallic Materials of Jiangsu Province, School of Materials Science and Engineering, Southeast University, Nanjing 211189, People’s Republic of China
Dawei Sha
Key Laboratory of Advanced Metallic Materials of Jiangsu Province, School of Materials Science and Engineering, Southeast University, Nanjing 211189, People’s Republic of China
Xin Cao
Key Laboratory of Advanced Metallic Materials of Jiangsu Province, School of Materials Science and Engineering, Southeast University, Nanjing 211189, People’s Republic of China
Zhuoran Li
Key Laboratory of Advanced Metallic Materials of Jiangsu Province, School of Materials Science and Engineering, Southeast University, Nanjing 211189, People’s Republic of China
Yonggui Zhao
Department of Chemistry, University of Zurich, Winterthurerstrasse 190, CH‑8057 Zurich, Switzerland
Jiangxiang Ding
School of Materials Science and Engineering, Anhui University of Technology, Ma’anshan 243002, Anhui, People’s Republic of China
Yaping Wang
Key Laboratory of Advanced Metallic Materials of Jiangsu Province, School of Materials Science and Engineering, Southeast University, Nanjing 211189, People’s Republic of China
ZhengMing Sun
Key Laboratory of Advanced Metallic Materials of Jiangsu Province, School of Materials Science and Engineering, Southeast University, Nanjing 211189, People’s Republic of China

Corresponding Author: ZhengMing Sun

zmsun@seu.edu.cn

Nano-Micro Letters, Vol. 15 (2023), Article Number: 225

Abstract

Exploiting high-rate anode materials with fast K+ diffusion is intriguing for the development of advanced potassium-ion batteries (KIBs) but remains unrealized. Here, heterostructure engineering is proposed to construct the dual transition metal tellurides (CoTe2/ZnTe), which are anchored onto two-dimensional (2D) Ti3C2Tx MXene nanosheets. Various theoretical modeling and experimental findings reveal that heterostructure engineering can regulate the electronic structures of CoTe2/ZnTe interfaces, improving K+ diffusion and adsorption. In addition, the different work functions between CoTe2/ZnTe induce a robust built-in electric field at the CoTe2/ZnTe interface, providing a strong driving force to facilitate charge transport. Moreover, the conductive and elastic Ti3C2Tx can effectively promote electrode conductivity and alleviate the volume change of CoTe2/ZnTe heterostructures upon cycling. Owing to these merits, the resulting CoTe2/ZnTe/Ti3C2Tx (CZT) exhibit excellent rate capability (137.0 mAh g−1 at 10 A g−1) and cycling stability (175.3 mAh g−1 after 4000 cycles at 3.0 A g−1, with a high capacity retention of 89.4%). More impressively, the CZT-based full cells demonstrate high energy density (220.2 Wh kg−1) and power density (837.2 W kg−1). This work provides a general and effective strategy by integrating heterostructure engineering and 2D material nanocompositing for designing advanced high-rate anode materials for next-generation KIBs.


Highlights:
1 Heterostructure engineering is proposed to construct CoTe2/ZnTe heterostructures with built-in electric field.
2 Conductive and elastic Ti3C2Tx MXene is introduced to improve the conductivity and alleviate the volume change of CoTe2/ZnTe upon cycling.
3 The resulting CoTe2/ZnTe/Ti3C2Tx (CZT) demonstrates outstanding rate capability (137.0 mAh g−1 at 10 A g−1) and cycling stability (175.3 mAh g−1 after 4000 cycles at 3.0 A g−1). Moreover, the CZT-based full cells demonstrate excellent energy density (220.2 Wh kg−1) and power density (837.2 W kg−1).

Keywords

Transition metal tellurides Heterostructures Built-in electric field Potassium-ion batteries Anode material
Pan, Long, Rongxiang Hu, Yuan Zhang, Dawei Sha, Xin Cao, Zhuoran Li, Yonggui Zhao, Jiangxiang Ding, Yaping Wang, and ZhengMing Sun. 2023. “Built-In Electric Field-Driven Ultrahigh-Rate K-Ion Storage via Heterostructure Engineering of Dual Tellurides Integrated With Ti3C2Tx MXene”. Nano-Micro Letters 15 (October):225. https://doi.org/10.1007/s40820-023-01202-6.
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. J. Lin, X. Zhang, E. Fan, R. Chen, F. Wu et al., Carbon neutrality strategies for sustainable batteries: from structure, recycling, and properties to applications. Energy Environ. Sci. 16(3), 745–791 (2023). https://doi.org/10.1039/d2ee03257k
  2. S. Imtiaz, I.S. Amiinu, Y. Xu, T. Kennedy, Progress and perspectives on alloying-type anode materials for advanced potassium-ion batteries. Mater. Today 48, 241–269 (2021). https://doi.org/10.1016/j.mattod.2021.02.008
  3. S. Koohi-Fayegh, M.A. Rosen, A review of energy storage types, applications and recent developments. J. Energy Storage 27, 101047 (2020). https://doi.org/10.1016/j.est.2019.101047
  4. J. Zheng, Y. Wu, Y. Sun, J. Rong, H. Li et al., Advanced anode materials of potassium ion batteries: from zero dimension to three dimensions. Nano-Micro Lett. 13(1), 12 (2020). https://doi.org/10.1007/s40820-020-00541-y
  5. W. Zhang, J. Yin, W. Wang, Z. Bayhan, H.N. Alshareef, Status of rechargeable potassium batteries. Nano Energy 83(83), 105792 (2021). https://doi.org/10.1016/j.nanoen.2021.105792
  6. X. Min, J. Xiao, M. Fang, W. Wang, Y. Zhao et al., Potassium-ion batteries: outlook on present and future technologies. Energy Environ. Sci. 14(4), 2186–2243 (2021). https://doi.org/10.1039/d0ee02917c
  7. D. Su, Y. Pei, L. Liu, Z. Liu, J. Liu et al., Wire-in-wire TiO2/C nanofibers free-standing anodes for Li-ion and K-ion batteries with long cycling stability and high capacity. Nano-Micro Lett. 13(1), 107 (2021). https://doi.org/10.1007/s40820-021-00632-4
  8. S. Zhang, L. Qiu, Y. Zheng, Q. Shi, T. Zhou et al., Rational design of core-shell ZnTe@N-doped carbon nanowires for high gravimetric and volumetric alkali metal ion storage. Adv. Funct. Mater. 31(3), 2006425 (2021). https://doi.org/10.1002/adfm.202006425
  9. H. Fan, P. Mao, H. Sun, Y. Wang, S.S. Mofarah et al., Recent advances of metal telluride anodes for high-performance lithium/sodium-ion batteries. Mater. Horiz. 9, 524–546 (2021). https://doi.org/10.1039/d1mh01587g
  10. X. Wei, B. Liu, Z. Chen, K. Wu, Y. Liu et al., Recent advances in modulation engineering-enabled metal compounds for potassium-ion storage. Energy Storage Mater. 51, 815–839 (2022). https://doi.org/10.1016/j.ensm.2022.07.022
  11. D. Sha, Y. You, R. Hu, X. Cao, Y. Wei et al., Comprehensively understanding the role of anion vacancies on K-ion storage: a case study of Se-vacancy-engineered VSe2. Adv. Mater. 35, 2211311 (2023). https://doi.org/10.1002/adma.202211311
  12. X. Xu, Y. Zhang, H. Sun, J. Zhou, Z. Liu et al., Orthorhombic cobalt ditelluride with Te vacancy defects anchoring on elastic MXene enables efficient potassium-ion storage. Adv. Mater. 33(31), 2100272 (2021). https://doi.org/10.1002/adma.202100272
  13. D. Sha, Y. You, R. Hu, X. Cao, Y. Wei et al., Revealing the evolution of doping anions and their impact on K-ion storage: a case study of Se-doped In2S3. Energy Storage Mater. 58, 165–175 (2023). https://doi.org/10.1016/j.ensm.2023.03.021
  14. Y. Zhang, L. Tao, C. Xie, D. Wang, Y. Zou et al., Defect engineering on electrode materials for rechargeable batteries. Adv. Mater. 32(7), 1905923 (2020). https://doi.org/10.1002/adma.201905923
  15. G.D. Park, J.-S. Park, J.K. Kim, Y.C. Kang, Recent advances in heterostructured anode materials with multiple anions for advanced alkali-ion batteries. Adv. Energy Mater. 11(27), 2003058 (2021). https://doi.org/10.1002/aenm.202003058
  16. C. Ke, R. Shao, Y. Zhang, Z. Sun, S. Qi et al., Synergistic engineering of heterointerface and architecture in new-type ZnS/Sn heterostructures in situ encapsulated in nitrogen-doped carbon toward high-efficient lithium-ion storage. Adv. Funct. Mater. 32(38), 2205635 (2022). https://doi.org/10.1002/adfm.202205635
  17. Q. Pan, Z. Tong, Y. Su, Y. Zheng, L. Shang et al., Flat-zigzag interface design of chalcogenide heterostructure toward ultralow volume expansion for high-performance potassium storage. Adv. Mater. 34(39), 2203485 (2022). https://doi.org/10.1002/adma.202203485
  18. Z. Xia, X. Chen, H. Ci, Z. Fan, Y. Yi et al., Designing N-doped graphene/ReSe2/Ti3C2 MXene heterostructure frameworks as promising anodes for high-rate potassium-ion batteries. J. Energy Chem. 53, 155–162 (2021). https://doi.org/10.1016/j.jechem.2020.04.071
  19. P. Zhang, F. Wang, M. Yu, X. Zhuang, X. Feng, Two-dimensional materials for miniaturized energy storage devices: from individual devices to smart integrated systems. Chem. Soc. Rev. 47(19), 7426–7451 (2018). https://doi.org/10.1039/c8cs00561c
  20. A. Khan, J. Azadmanjiri, B. Wu, L. Liping, J. Min, Atomically thin nanosheets confined in 2D heterostructures: metal-ion batteries prospective. Adv. Energy Mater. 11(20), 2100451 (2021). https://doi.org/10.1002/aenm.202100451
  21. M.K. Aslam, M. Xu, A mini-review: MXene composites for sodium/potassium-ion batteries. Nanoscale 12(30), 15993–16007 (2020). https://doi.org/10.1039/d0nr04111d
  22. H. Wang, Z. Cui, S.A. He, J.Q. Zhu, W. Luo et al., Construction of ultrathin layered MXene-TiN heterostructure enabling favorable catalytic ability for high-areal-capacity lithium–sulfur batteries. Nano-Micro Lett. 14(1), 189 (2022). https://doi.org/10.1007/s40820-022-00935-0
  23. M. Lu, H. Li, W. Han, J. Chen, W. Shi et al., 2D titanium carbide (MXene) electrodes with lower-F surface for high performance lithium-ion batteries. J. Energy Chem. 31, 148–153 (2019). https://doi.org/10.1016/j.jechem.2018.05.017
  24. C. Zhang, Y. Ma, X. Zhang, S. Abdolhosseinzadeh, H. Sheng et al., Two-dimensional transition metal carbides and nitrides (MXenes): synthesis, properties, and electrochemical energy storage applications. Energy Environ. Mater. 3(1), 29–55 (2020). https://doi.org/10.1002/eem2.12058
  25. X. Xu, L. Yang, W. Zheng, H. Zhang, F. Wu et al., MXenes with applications in supercapacitors and secondary batteries: a comprehensive review. Mater. Rep. Energy 2(1), 100080 (2022). https://doi.org/10.1016/j.matre.2022.100080
  26. M. Lu, W. Han, H. Li, W. Shi, J. Wang et al., Tent-pitching-inspired high-valence period 3-cation pre-intercalation excels for anode of 2D titanium carbide (MXene) with high Li storage capacity. Energy Storage Mater. 16, 163–168 (2019). https://doi.org/10.1016/j.ensm.2018.04.029
  27. Y. Wen, M. Wu, M. Zhang, C. Li, G. Shi, Topological design of ultrastrong and highly conductive graphene films. Adv. Mater. 29(41), 1702831 (2017). https://doi.org/10.1002/adma.201702831
  28. J. Zhang, N. Kong, S. Uzun, A. Levitt, S. Seyedin et al., Scalable manufacturing of free-standing, strong Ti3C2Tx MXene films with outstanding conductivity. Adv. Mater. 32(23), 2001093 (2020). https://doi.org/10.1002/adma.202001093
  29. R. Hu, D. Sha, X. Cao, C. Lu, Y. Wei et al., Anchoring metal-organic framework-derived ZnTe@C onto elastic Ti3C2Tx MXene with 0D/2D dual confinement for ultrastable potassium-ion storage. Adv. Energy Mater. 12(47), 2203118 (2022). https://doi.org/10.1002/aenm.202203118
  30. C. Zhang, H. Li, X. Zeng, S. Xi, R. Wang et al., Accelerated diffusion kinetics in ZnTe/CoTe2 heterojunctions for high rate potassium storage. Adv. Energy Mater. 12(41), 2202577 (2022). https://doi.org/10.1002/aenm.202202577
  31. W. Feng, X. Wen, Y. Wang, L. Song, X. Li et al., Interfacial coupling SnSe2/SnSe heterostructures as long cyclic anodes of lithium-ion battery. Adv. Sci. 10(2), 2204671 (2023). https://doi.org/10.1002/advs.202204671
  32. D. Sha, C. Lu, W. He, J. Ding, H. Zhang et al., Surface selenization strategy for V2CTx MXene toward superior Zn-ion storage. ACS Nano 16(2), 2711–2720 (2022). https://doi.org/10.1021/acsnano.1c09639
  33. X. Zhao, H. Xu, Z. Hui, Y. Sun, C. Yu et al., Electrostatically assembling 2D nanosheets of MXene and MOF-derivatives into 3D hollow frameworks for enhanced lithium storage. Small 15(47), 1904255 (2019). https://doi.org/10.1002/smll.201904255
  34. S.D. Negedu, R. Tromer, C.C. Gowda, C.F. Woellner, F.E. Olu et al., Two-dimensional cobalt telluride as a piezo-tribogenerator. Nanoscale 14(21), 7788–7797 (2022). https://doi.org/10.1039/d2nr00132b
  35. L. Pan, X.-D. Zhu, X.-M. Xie, Y.-T. Liu, Smart Hybridization of TiO2 nanorods and Fe3O4 nanops with pristine graphene nanosheets: hierarchically nanoengineered ternary heterostructures for high-rate lithium storage. Adv. Funct. Mater. 25(22), 3341–3350 (2015). https://doi.org/10.1002/adfm.201404348
  36. H. Jiang, L. Huang, Y. Wei, B. Wang, H. Wu et al., Bio-derived hierarchical multicore-shell Fe2N-nanop-impregnated N-doped carbon nanofiber bundles: a host material for lithium-/potassium-ion storage. Nano-Micro Lett. 11(1), 56 (2019). https://doi.org/10.1007/s40820-019-0290-0
  37. Y. Li, Q. Zhang, Y. Yuan, H. Liu, C. Yang et al., Surface amorphization of vanadium dioxide (B) for K-ion battery. Adv. Energy Mater. 10(23), 2000717 (2020). https://doi.org/10.1002/aenm.202000717
  38. J. Cao, Z. Sun, J. Li, Y. Zhu, Z. Yuan et al., Microbe-Assisted assembly of Ti3C2Tx MXene on fungi-derived nanoribbon heterostructures for ultrastable sodium and potassium ion storage. ACS Nano 15(2), 3423–3433 (2021). https://doi.org/10.1021/acsnano.0c10491
  39. K.-T. Chen, S. Chong, L. Yuan, Y.-C. Yang, H.-Y. Tuan, Conversion-alloying dual mechanism anode: nitrogen-doped carbon-coated Bi2Se3 wrapped with graphene for superior potassium-ion storage. Energy Storage Mater. 39, 239–249 (2021). https://doi.org/10.1016/j.ensm.2021.04.019
  40. X. Li, J. Li, W. Zhuo, Z. Li, L. Ma et al., In situ monitoring the potassium-ion storage enhancement in iron selenide with ether-based electrolyte. Nano-Micro Lett. 13(1), 179 (2021). https://doi.org/10.1007/s40820-021-00708-1
  41. X. Li, H. Liang, X. Liu, R. Sun, Z. Qin et al., Ion-exchange strategy of CoS2/Sb2S3 hetero-structured nanocrystals encapsulated into 3D interpenetrating dual-carbon framework for high-performance Na+/K+ batteries. Chem. Eng. J. 425, 130657 (2021). https://doi.org/10.1016/j.cej.2021.130657
  42. R. Verma, P.N. Didwal, A.-G. Nguyen, C.-J. Park, SnSe nanocomposite chemically-bonded with carbon-coating as an anode material for K-ion batteries with outstanding capacity and cyclability. Chem. Eng. J. 421(1), 129988 (2021). https://doi.org/10.1016/j.cej.2021.129988
  43. S.H. Yang, Y.J. Lee, H. Kang, S.-K. Park, Y.C. Kang, Carbon-coated three-dimensional MXene/iron selenide ball with core-shell structure for high-performance potassium-ion batteries. Nano-Micro Lett. 14(1), 17 (2022). https://doi.org/10.1007/s40820-021-00741-0
  44. W. Luo, Y. Feng, D. Shen, J. Zhou, C. Gao et al., Engineering ion diffusion by CoS@SnS heterojunction for ultrahigh-rate and stable potassium batteries. ACS Appl. Mater. Interfaces 14(14), 16379–16385 (2022). https://doi.org/10.1021/acsami.2c02679
  45. Z. Tong, R. Yang, S. Wu, D. Shen, T. Jiao et al., Surface-engineered black niobium oxide@graphene nanosheets for high-performance sodium-/potassium-ion full batteries. Small 15(28), 1901272 (2019). https://doi.org/10.1002/smll.201901272
  46. Y. Liu, Z. Sun, X. Sun, Y. Lin, K. Tan et al., Construction of hierarchical nanotubes assembled from ultrathin V3S4@C nanosheets towards alkali-ion batteries with ion-dependent electrochemical mechanisms. Angew. Chem. Int. Ed. 59(6), 2473–2482 (2020). https://doi.org/10.1002/anie.201913343
  47. C.H. Chang, K.T. Chen, Y.Y. Hsieh, C.B. Chang, H.Y. Tuan, Crystal facet and architecture engineering of metal oxide nanonetwork anodes for high-performance potassium ion batteries and hybrid capacitors. ACS Nano 16(1), 1486–1501 (2022). https://doi.org/10.1021/acsnano.1c09863
  48. N. Cheng, W. Zhou, J. Liu, Z. Liu, B. Lu, Reversible oxygen-rich functional groups grafted 3D honeycomb-like carbon anode for super-long potassium ion batteries. Nano-Micro Lett. 14(1), 146 (2022). https://doi.org/10.1007/s40820-022-00892-8
  49. L. Sun, J. Sun, S. Zhai, T. Dong, H. Yang et al., Homologous MXene-derived electrodes for potassium-ion full batteries. Adv. Energy Mater. 12(23), 2200113 (2022). https://doi.org/10.1002/aenm.202200113
Read More
Author biographies are not available.
Download this PDF file
PDF SUPPLEMENTARY FILE
Statistic
Read Counter : 2317 Download : 1721

Most read articles by the same author(s)