Issue

Vol. 16 (2024)

PDOL-Based Solid Electrolyte Toward Practical Application: Opportunities and Challenges

https://doi.org/10.1007/s40820-024-01354-z
Hua Yang
Institute for Advanced Materials, School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, People’s Republic of China
Maoxiang Jing
Institute for Advanced Materials, School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, People’s Republic of China
Li Wang
Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, People’s Republic of China
Hong Xu
Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, People’s Republic of China
Xiaohong Yan
Institute for Advanced Materials, School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, People’s Republic of China
Xiangming He
Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, People’s Republic of China

Corresponding Author: Xiangming He

hexm@tsinghua.edu.cn

Nano-Micro Letters, Vol. 16 (2024), Article Number: 127

Abstract

Polymer solid-state lithium batteries (SSLB) are regarded as a promising energy storage technology to meet growing demand due to their high energy density and safety. Ion conductivity, interface stability and battery assembly process are still the main challenges to hurdle the commercialization of SSLB. As the main component of SSLB, poly(1,3-dioxolane) (PDOL)-based solid polymer electrolytes polymerized in-situ are becoming a promising candidate solid electrolyte, for their high ion conductivity at room temperature, good battery electrochemical performances, and simple assembly process. This review analyzes opportunities and challenges of PDOL electrolytes toward practical application for polymer SSLB. The focuses include exploring the polymerization mechanism of DOL, the performance of PDOL composite electrolytes, and the application of PDOL. Furthermore, we provide a perspective on future research directions that need to be emphasized for commercialization of PDOL-based electrolytes in SSLB. The exploration of these schemes facilitates a comprehensive and profound understanding of PDOL-based polymer electrolyte and provides new research ideas to boost them toward practical application in solid-state batteries.


Highlights:
1 The poly(1,3-dioxolane) (PDOL) electrolyte demonstrates promising potential for practical application due to its advantages in in-situ polymerization process, high ionic conductivity, and long cycle life.
2 This review focuses on the polymerization mechanism, composite innovation, and application of PDOL electrolytes.
3 This review provides a comprehensive summary of the challenges associated with the PDOL electrolyte and makes forward-looking recommendations.

Keywords

Poly(1,3-dioxolane) Solid electrolyte Polymerization mechanism Composite electrolyte Practical application
Yang, Hua, Maoxiang Jing, Li Wang, Hong Xu, Xiaohong Yan, and Xiangming He. 2024. “PDOL-Based Solid Electrolyte Toward Practical Application: Opportunities and Challenges”. Nano-Micro Letters 16 (February):127. https://doi.org/10.1007/s40820-024-01354-z.
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