Issue

Vol. 16 (2024)

Dual-Defect Engineering Strategy Enables High-Durability Rechargeable Magnesium-Metal Batteries

https://doi.org/10.1007/s40820-024-01410-8
Fuyu Chen
National Innovation Center for Lndustry‑Education Integration of Energy Storage Technology, School of Materials Science and Engineering, Chongqing University, Chongqing 400044, People’s Republic of China
Bai‑Qing Zhao
Materials and Energy Division, Beijing Computational Science Research Center, Beijing 100193, People’s Republic of China
Kaifeng Huang
National Innovation Center for Lndustry‑Education Integration of Energy Storage Technology, School of Materials Science and Engineering, Chongqing University, Chongqing 400044, People’s Republic of China
Xiu‑Fen Ma
National Innovation Center for Lndustry‑Education Integration of Energy Storage Technology, School of Materials Science and Engineering, Chongqing University, Chongqing 400044, People’s Republic of China
Hong‑Yi Li
National Innovation Center for Lndustry‑Education Integration of Energy Storage Technology, School of Materials Science and Engineering, Chongqing University, Chongqing 400044, People’s Republic of China
Xie Zhang
School of Materials Science and Engineering, Northwestern Polytechnical University, Xi’an 710072, People’s Republic of China
Jiang Diao
National Innovation Center for Lndustry‑Education Integration of Energy Storage Technology, School of Materials Science and Engineering, Chongqing University, Chongqing 400044, People’s Republic of China
Jili Yue
National Innovation Center for Lndustry‑Education Integration of Energy Storage Technology, School of Materials Science and Engineering, Chongqing University, Chongqing 400044, People’s Republic of China
Guangsheng Huang
National Innovation Center for Lndustry‑Education Integration of Energy Storage Technology, School of Materials Science and Engineering, Chongqing University, Chongqing 400044, People’s Republic of China
Jingfeng Wang
National Innovation Center for Lndustry‑Education Integration of Energy Storage Technology, School of Materials Science and Engineering, Chongqing University, Chongqing 400044, People’s Republic of China
Fusheng Pan
National Innovation Center for Lndustry‑Education Integration of Energy Storage Technology, School of Materials Science and Engineering, Chongqing University, Chongqing 400044, People’s Republic of China

Corresponding Author: Fusheng Pan

fspan@cqu.edu.cn

Nano-Micro Letters, Vol. 16 (2024), Article Number: 184

Abstract

Rechargeable magnesium-metal batteries (RMMBs) are promising next-generation secondary batteries; however, their development is inhibited by the low capacity and short cycle lifespan of cathodes. Although various strategies have been devised to enhance the Mg2+ migration kinetics and structural stability of cathodes, they fail to improve electronic conductivity, rendering the cathodes incompatible with magnesium-metal anodes. Herein, we propose a dual-defect engineering strategy, namely, the incorporation of Mg2+ pre-intercalation defect (P-Mgd) and oxygen defect (Od), to simultaneously improve the Mg2+ migration kinetics, structural stability, and electronic conductivity of the cathodes of RMMBs. Using lamellar V2O5·nH2O as a demo cathode material, we prepare a cathode comprising Mg0.07V2O5·1.4H2O nanobelts composited with reduced graphene oxide (MVOH/rGO) with P-Mgd and Od. The Od enlarges interlayer spacing, accelerates Mg2+ migration kinetics, and prevents structural collapse, while the P-Mgd stabilizes the lamellar structure and increases electronic conductivity. Consequently, the MVOH/rGO cathode exhibits a high capacity of 197 mAh g−1, and the developed Mg foil//MVOH/rGO full cell demonstrates an incredible lifespan of 850 cycles at 0.1 A g−1, capable of powering a light-emitting diode. The proposed dual-defect engineering strategy provides new insights into developing high-durability, high-capacity cathodes, advancing the practical application of RMMBs, and other new secondary batteries.


Highlights:
1 MVOH/rGO cathode with dual defect of Mg2+ pre-intercalation defect (P-Mgd) and surface oxygen defect (Od) is prepared.
2 The dual defect of Od and P-Mgd in MVOH/rGO lamellar structure effectively enhances Mg2+ migration kinetics, structural stability, and electronic conductivity.
3 The Mg foil//MVOH/rGO full cell achieves an ultralong lifespan of 850 cycles at 0.1 A g−1 and powers an orange light-emitting diode.

Keywords

Rechargeable magnesium-metal batteries Dual-defect engineering Vanadium-based cathode High durability Lamellar structure
Chen, Fuyu, Bai‑Qing Zhao, Kaifeng Huang, Xiu‑Fen Ma, Hong‑Yi Li, Xie Zhang, Jiang Diao, Jili Yue, Guangsheng Huang, Jingfeng Wang, and Fusheng Pan. 2024. “Dual-Defect Engineering Strategy Enables High-Durability Rechargeable Magnesium-Metal Batteries”. Nano-Micro Letters 16 (April):184. https://doi.org/10.1007/s40820-024-01410-8.
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