Issue

Vol. 12 (2020)

Environment-Stable CoxNiy Encapsulation in Stacked Porous Carbon Nanosheets for Enhanced Microwave Absorption

https://doi.org/10.1007/s40820-020-00432-2
Xiaohui Liang
College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211100, People’s Republic of China
Zengming Man
College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211100, People’s Republic of China
Bin Quan
College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211100, People’s Republic of China
Jing Zheng
Department of Chemistry and Materials Science, College of Science, Nanjing Forestry University, Nanjing 210037, People’s Republic of China
Weihua Gu
College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211100, People’s Republic of China
Zhu Zhang
College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211100, People’s Republic of China
Guangbin Ji
College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211100, People’s Republic of China

Corresponding Author: Guangbin Ji

gbji@nuaa.edu.cn

Nano-Micro Letters, Vol. 12 (2020), Article Number: 102

Abstract

Magnetic/dielectric@porous carbon composites, derived from metal–organic frameworks (MOFs) with adjustable composition ratio, have attracted wide attention due to their unique magnetoelectric properties. In addition, MOFs-derived porous carbon-based materials can meet the needs of lightweight feature. This paper reports a simple process for synthesizing stacked CoxNiy@C nanosheets derived from CoxNiy-MOFs nanosheets with multiple interfaces, which is good to the microwave response. The CoxNiy@C with controllable composition can be obtained by adjusting the ratio of Co2+ and Ni2+. It is supposed that the increased Co content is benefit to the dielectric and magnetic loss. Additionally, the bandwidth of CoNi@C nanosheets can take up almost the whole Ku band. Moreover, this composite has better environmental stability in air, which characteristic provides a sustainable potential for the practical application.


Highlights:


1 The microwave absorbing performance of alloy@C composites can be controlled through regulating ratio of metal ions.
2 Carbon-based alloy@C composites exhibit the potential stability of microwave absorption with almost the whole Ku band for the practical application.

Keywords

MOFs CoxNiy@C nanosheets Multiple interfaces Microwave absorption Environmental stability
Liang, Xiaohui, Zengming Man, Bin Quan, Jing Zheng, Weihua Gu, Zhu Zhang, and Guangbin Ji. 2020. “Environment-Stable CoxNiy Encapsulation in Stacked Porous Carbon Nanosheets for Enhanced Microwave Absorption”. Nano-Micro Letters 12 (April):102. https://doi.org/10.1007/s40820-020-00432-2.
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References
  1. J.H. Luo, K. Zhang, M.L. Cheng, M.M. Gu, X.K. Sun, MoS2 spheres decorated on hollow porous ZnO microspheres with strong wideband microwave absorption. Chem. Eng. J. 380, 122625 (2020). https://doi.org/10.1016/j.cej.2019.122625
  2. M. Jahan, R.O. Inakpenu, K. Li, G.L. Zhao, Enhancing the mechanical strength for a microwave absorption composite based on graphene nanoplatelet/epoxy with carbon fibers. Sci. Res. 9, 230 (2019). https://doi.org/10.4236/ojcm.2019.92013
  3. X.H. Liang, B. Quan, Z.M. Man, B.C. Cao, N. Li, C.H. Wang, G.B. Ji, T. Yu, Self-assembly three-dimensional porous carbon networks for efficient dielectric attenuation. ACS Appl. Mater. Interfaces 11, 30228–30233 (2019). https://doi.org/10.1021/acsami.9b08365
  4. L.X. Huang, Y.P. Duan, X.H. Dai, Y.S. Zeng, G.J. Ma, Y. Liu, S.H. Gao, W.P. Zhang, Bioinspired metamaterials: multibands electromagnetic wave adaptability and hydrophobic characteristics. Small 15, 1902730 (2019). https://doi.org/10.1002/smll.201902730
  5. O. Balci, E.O. Polat, N. Kakenov, C. Kocabas, Graphene-enabled electrically switchable radar-absorbing surfaces. Nat. Commun. 6, 1–10 (2015). https://doi.org/10.1038/ncomms7628
  6. X.L. Li, X.W. Yin, C.Q. Song, M.K. Han, H.L. Xu, W.Y. Duan, L.F. Cheng, L.T. Zhang, Self-assembly core-shell graphene-bridged hollow Mxenes spheres 3D foam with ultrahigh specific EM absorption performance. Adv. Funct. Mater. 28, 1803938 (2018). https://doi.org/10.1002/adfm.201803938
  7. M.S. Cao, X.X. Wang, W.Q. Cao, X.Y. Fang, B. Wen, J. Yuan, Thermally driven transport and relaxation switching self-powered electromagnetic energy conversion. Small 14, 1800987 (2018). https://doi.org/10.1002/smll.201800987
  8. J.C. Shu, X.Y. Yang, X.R. Zhang, X.Y. Huang, M.S. Cao, L. Li, H.J. Yang, W.Q. Cao, Tailoring MOF-based materials to tune electromagnetic property for great microwave absorbers and devices. Carbon 162, 157–171 (2020). https://doi.org/10.1016/j.carbon.2020.02.047
  9. W. Liu, L. Liu, G.B. Ji, D.R. Li, Y.N. Zhang, J.N. Ma, Y.W. Du, Composition design and structural characterization of MOF-derived composites with controllable electromagnetic properties. ACS Sustain. Chem. Eng. 5, 7961–7971 (2017). https://doi.org/10.1021/acssuschemeng.7b01514
  10. X. Bai, Y.H. Zhai, Y. Zhang, Green approach to prepare graphene-based composites with high microwave absorption capacity. J. Phys. Chem. C 115, 11673–11677 (2011). https://doi.org/10.1021/jp202475m
  11. H.T. Guan, H.Y. Wang, Y.L. Zhang, C.J. Dong, G. Chen, Y.D. Wang, J.B. Xie, Microwave absorption performance of Ni(OH)2 decorating biomass carbon composites from jackfruit peel. Appl. Surf. Sci. 447, 261–268 (2018). https://doi.org/10.1016/j.apsusc.2018.03.225
  12. C.H. Zhou, C. Wu, M.A. Yan, Versatile strategy towards magnetic/dielectric porous heterostructure with confinement effect for lightweight and broadband electromagnetic wave absorption. Chem. Eng. J. 370, 988–996 (2019). https://doi.org/10.1016/j.cej.2019.03.295
  13. B. Quan, X.H. Liang, G.B. Ji, Y.N. Zhang, G.Y. Xu, Y.W. Du, Cross-linking-derived synthesis of porous CoxNiy/C nanocomposites for excellent electromagnetic behaviors. ACS Appl. Mater. Interfaces 9, 38814–38823 (2017). https://doi.org/10.1021/acsami.7b13411
  14. Q.H. Liu, Q. Cao, H. Bi, C.Y. Liang, K.P. Yuan, W. She, Y.J. Yang, R.C. Che, CoNi@SiO2@TiO2 and CoNi@Air@TiO2 microspheres with strong wideband microwave absorption. Adv. Mater. 28, 486–490 (2016). https://doi.org/10.1002/adma.201503149
  15. J. Feng, F.Z. Pu, Z.X. Li, X.H. Li, X.Y. Hu, J.T. Bai, Interfacial interactions and synergistic effect of CoNi nanocrystals and nitrogen-doped graphene in a composite microwave absorber. Carbon 104, 214–225 (2016). https://doi.org/10.1016/j.carbon.2016.04.006
  16. B. Quan, W.H. Shi, S.J.H. Ong, X.C. Lu, P.L.Y. Wang et al., Defect engineering in two common types of dielectric materials for electromagnetic absorption applications. Adv. Funct. Mater. 29, 1901236 (2019). https://doi.org/10.1002/adfm.201901236
  17. H.Q. Zhao, Y. Cheng, W. Liu, L.J. Yang, B.S. Zhang, L.Y.P. Wang, G.B. Ji, Z.C.J. Xu, Biomass-derived porous carbon-based nanostructures for microwave absorption. Nano-Micro Lett. 11, 24 (2019). https://doi.org/10.1007/s40820-019-0255-3
  18. G. Li, T. Xie, S. Yang, J.H. Jin, J.M. Jiang, Microwave absorption enhancement of porous carbon fibers compared with carbon nanofibers. J. Phys. Chem. C 116, 9196–9201 (2012). https://doi.org/10.1021/jp300050u
  19. X. Qiu, L. Wang, H. Zhu, Y.K. Guan, Q.T. Zhang, Lightweight and efficient microwave absorbing materials based on walnut shell-derived nano-porous carbon. Nanoscale 9, 7408–7418 (2017). https://doi.org/10.1039/C7NR02628E
  20. Y. Liang, R. Fu, D. Wu, Reactive template-induced self-assembly to ordered mesoporous polymeric and carbonaceous materials. ACS Nano 7, 1748–1754 (2013). https://doi.org/10.1021/nn305841e
  21. Z. Wu, Q. Li, D. Feng, P. Webley, D. Zhao, Ordered mesoporous crystalline γ-Al2O3 with variable architecture porosity from a single hard template. J. Am. Chem. Soc. 132, 12042–12050 (2010). https://doi.org/10.1021/ja104379a
  22. C.W. Abney, K.M.L. Taylor-Pashow, S.R. Russell, Y. Chen, R. Samantaray, J.V. Lockard, W.B. Lin, Topotactic transformations of metal-organic frameworks to highly porous and stable inorganic sorbents for efficient radionuclide sequestration. Chem. Mater. 26, 5231–5243 (2014). https://doi.org/10.1021/cm501894h
  23. P. Falcaro, R. Ricco, C.M. Doherty, K. Liang, A.J. Hillb, M.J. Styles, MOF positioning technology and device fabrication. Chem. Soc. Rev. 43, 5513–5560 (2014). https://doi.org/10.1039/C4CS00089G
  24. X.M. Zhang, G.B. Ji, W. Liu, B. Quan, X.H. Liang, C.M. Shang, Y. Cheng, Y.W. Du, Thermal conversion of an Fe3O4@metal-organic framework: a new method for an efficient Fe-Co/nanoporous carbon microwave absorbing material. Nanoscale 7, 12932–12942 (2015). https://doi.org/10.1039/C5NR03176A
  25. J.C. Shu, M.S. Cao, M. Zhang, X.X. Wang, W.Q. Cao, X.Y. Fang, M.Q. Cao, Molecular patching engineering to drive energy conversion as efficient and environment-friendly cell toward wireless power transmission. Adv. Funct. Mater. (2020). https://doi.org/10.1002/adfm.201908299
  26. M.S. Cao, X.X. Wang, M. Zhang, W.Q. Cao, X.Y. Fang, J. Yuan, Variable-temperature electron transport and dipole polarization turning flexible multifunctional microsensor beyond electrical and optical energy. Adv. Mater. (2020). https://doi.org/10.1002/adma.201907156
  27. Y.F. Wang, D.L. Chen, X. Yin, P. Xu, F. Wu, M. He, Hybrid of MoS2 and reduced graphene oxide: a lightweight and broadband electromagnetic wave absorber. ACS Appl. Mater. Interfaces 7, 26226–26234 (2015). https://doi.org/10.1021/acsami.5b08410
  28. J.P. Xie, Y.Q. Zhu, N. Zhuang, H. Lei, W.L. Zhu et al., Rational design of metal organic framework derived FeS2 hollow nanocages@reduced graphene oxide for K-ion storage. Nanoscale 10, 17092–17098 (2018). https://doi.org/10.1039/c8nr05239e
  29. Z.M. Man, P. Li, D. Zhou, R. Zang, S.J. Wang et al., High-performance lithium-organic batteries by achieving 16 lithium storage in poly (imine-anthraquinone). J. Mater. Chem. A 7, 2368–2375 (2019). https://doi.org/10.1039/C8TA11230D
  30. R. Kuchi, H.M. Nguyen, V. Dongquoc, P.C. Van, S. Surabhi, S.G. Yoon, D. Kim, J.R. Jeong, In-situ Co-arc discharge synthesis of Fe3O4/SWCNT composites for highly effective microwave absorption. Phys. Status Solidi A 215, 1700989 (2018). https://doi.org/10.1002/pssa.201700989
  31. W.H. Gu, B. Quan, X.H. Liang, W. Liu, G.B. Ji, Y.W. Du, Composition and structure design of Co3O4 nanowires network by nickel foam with effective electromagnetic performance in C and X Band. ACS Sustain. Chem. Eng. 7, 5543–5552 (2019). https://doi.org/10.1021/acssuschemeng.9b00017
  32. X. Yang, Y.P. Duan, Y.S. Zeng, H.F. Pang, G.J. Ma, X.H. Dai, Experimental and theoretical evidence for temperature driving an electric-magnetic complementary effect in magnetic microwave absorbing materials. J. Mater. Chem. C 8, 1583–1590 (2020). https://doi.org/10.1039/c9tc06551b
  33. L.L. Song, Y.P. Duan, J. Liu, H.F. Pang, Transformation between nanosheets and nanowires structure in MnO2 upon providing Co2+ ions and applications for microwave absorption. Nano Res. 13, 95–104 (2020). https://doi.org/10.1007/s12274-019-2578-2
  34. X.J. Zhang, J.Q. Zhu, P.G. Yin, A.P. Guo, A.P. Huang, L. Guo, G.S. Wang, Tunable high-performance microwave absorption of Co1−xS hollow spheres constructed by nanosheets within ultralow filler loading. Adv. Funct. Mater. 28, 1800761 (2018). https://doi.org/10.1002/adfm.201800761
  35. S. Yun, A. Kirakosyan, S. Surabhi, J.R. Jeong, J. Choi, Controlled morphology of MWCNTs driven by polymer-grafted nanoparticles for enhanced microwave absorption. J. Mater. Chem. C 5, 8436–8443 (2017). https://doi.org/10.1039/C7TC02892J
  36. X.F. Zhang, X.L. Dong, H. Huang, B. Lv, J.P. Lei, C.J. Choi, Microstructure and microwave absorption properties of carbon-coated iron nanocapsules. J. Phys. D: Appl. Phys. 40, 5383–5387 (2007). https://doi.org/10.1088/0022-3727/40/17/056
  37. J. Ma, J.G. Li, X. Ni, X.D. Zhang, J.J. Huang, Microwave resonance in Fe/SiO2 nanocomposite. Appl. Phys. Lett. 95, 102505 (2009). https://doi.org/10.1063/1.3224883
  38. X.Q. Cui, X.H. Liang, W. Liu, W.H. Gu, G.B. Ji, Y.W. Du, Stable microwave absorber derived from 1D customized heterogeneous structures of Fe3N@C. Chem. Eng. J. 381, 122589 (2020). https://doi.org/10.1016/j.cej.2019.122589
  39. Z.G. An, S.L. Pan, J.J. Zhang, Facile preparation and electromagnetic properties of core-shell composite spheres composed of aloe-like nickel flowers assembled on hollow glass spheres. J. Phys. Chem. C 113, 2715–2721 (2009). https://doi.org/10.1021/jp809199s
  40. B.H. An, B.C. Park, H.A. Yassi, J.S. Lee, J.R. Park, Y.K. Kim, J.E. Ryu, D.S. Choi, Fabrication of graphene-magnetite multi-granule nanocluster composites for microwave absorption application. J. Compos. Mater. 53, 28–30 (2019). https://doi.org/10.1177/0021998319853032
  41. J.S. Deng, X. Zhang, B. Zhao, Z.Y. Bai, S.M. Wen et al., Fluffy microrods to heighten the microwave absorption properties through tuning the electronic state of Co/CoO. J. Mater. Chem. C 6, 7128–7140 (2018). https://doi.org/10.1039/C8TC02520G
  42. M.S. Cao, W.L. Song, Z.L. Hou, B. Wen, J. Yuan, The effects of temperature and frequency on the dielectric properties, electromagnetic interference shielding and microwave-absorption of short carbon fiber/silica composites. Carbon 48, 788–796 (2010). https://doi.org/10.1016/j.carbon.2009.10.028
  43. B. Wen, M.S. Cao, Z.L. Hou, W.L. Song, L. Zhang et al., Temperature dependent microwave attenuation behavior for carbon-nanotube/silica composites. Carbon 65, 124–139 (2013). https://doi.org/10.1016/j.carbon.2013.07.110
  44. W.Q. Cao, X.X. Wang, J. Yuan, W.Z. Wang, M.S. Cao, Temperature dependent microwave absorption of ultrathin graphene composites. J. Mater. Chem. C 3, 10017–10022 (2015). https://doi.org/10.1039/c5tc02185e
  45. B. Wen, M.S. Cao, M.M. Lu, W.Q. Cao, H.L. Shi et al., Reduced graphene oxides: light-weight and high-efficiency electromagnetic interference shielding at elevated temperatures. Adv. Mater. 26, 3484–3489 (2014). https://doi.org/10.1002/adma.201400108
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