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Vol. 3 No. 1 (2011)

High-Performance Li-ion Batteries and Supercapacitors Based on Prospective 1-D Nanomaterials

https://doi.org/10.1007/BF03353653
Dandan Zhao
Key Laboratory for Thin Film and Microfabrication Technology of the Ministry of Education, Research Institute of Micro/Nanometer Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, China
Ying Wang
Key Laboratory for Thin Film and Microfabrication Technology of the Ministry of Education, Research Institute of Micro/Nanometer Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, China
Yafei Zhang
Key Laboratory for Thin Film and Microfabrication Technology of the Ministry of Education, Research Institute of Micro/Nanometer Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, China

Corresponding Author: Yafei Zhang

yfzhang@sjtu.edu.cn

Nano-Micro Letters, Vol. 3 No. 1 (2011), Article Number: 62-71

Abstract

One-dimensional (1-D) nanomaterials with superior specific capacity, higher rate capability, better cycling peroperties have demonstrated significant advantages for high-performance Li-ion batteries and supercapacitors. This review describes some recent developments on the rechargeable electrodes by using 1-D nanomaterials (such as LiMn2O4 nanowires, carbon nanofibers, NiMoO4 · nH2O nanorods, V2O5 nanoribbons, carbon nanotubes, etc.). New preparation methods and superior electrochemical properties of the 1-D nanomaterials including carbon nanotube (CNT), some oxides, transition metal compounds and polymers, and their composites are emphatically introduced. The VGCF/LiFePO4/C triaxial nanowire cathodes for Li-ion battery present a positive cycling performance without any degradation in almost theoretical capacity (160 mAh/g). The Si nanowire anodes for Li-ion battery show the highest known theoretical charge capacity (4277 mAh/g), that is about 11 times lager than that of the commercial graphite (∼372 mAh/g). The SWCNT/Ni foam electrodes for supercapacitor display small equivalent series resistance (ESR, 52 mΩ) and impressive high power density (20 kW/kg). The advantages and challenges associated with the application of these materials for energy conversion and storage devices are highlighted.

Keywords

One-dimensional nanomaterials Li-ion battery Supercapacitor Electrochemical property
Zhao, Dandan, Ying Wang, and Yafei Zhang. 2011. “High-Performance Li-Ion Batteries and Supercapacitors Based on Prospective 1-D Nanomaterials”. Nano-Micro Letters 3 (1):62-71. https://doi.org/10.1007/BF03353653.
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