Issue

Vol. 13 (2021)

Design Engineering, Synthesis Protocols, and Energy Applications of MOF-Derived Electrocatalysts

https://doi.org/10.1007/s40820-021-00656-w
Amr Radwan
School of Science, Wuhan University of Technology, Wuhan 430070, People’s Republic of China
Huihui Jin
School of Science, Wuhan University of Technology, Wuhan 430070, People’s Republic of China
Daping He
School of Science, Wuhan University of Technology, Wuhan 430070, People’s Republic of China
Shichun Mu
Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory, Xianhu Hydrogen Valley, Foshan 528200, People’s Republic of China

Corresponding Author: Shichun Mu

msc@whut.edu.cn

Nano-Micro Letters, Vol. 13 (2021), Article Number: 132

Abstract

The core reactions for fuel cells, rechargeable metal–air batteries, and hydrogen fuel production are the oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER), which are heavily dependent on the efficiency of electrocatalysts. Enormous attempts have previously been devoted in non-noble electrocatalysts born out of metal–organic frameworks (MOFs) for ORR, OER, and HER applications, due to the following advantageous reasons: (i) The significant porosity eases the electrolyte diffusion; (ii) the supreme catalyst–electrolyte contact area enhances the diffusion efficiency; and (iii) the electronic conductivity can be extensively increased owing to the unique construction block subunits for MOFs-derived electrocatalysis. Herein, the recent progress of MOFs-derived electrocatalysts including synthesis protocols, design engineering, DFT calculations roles, and energy applications is discussed and reviewed. It can be concluded that the elevated ORR, OER, and HER performances are attributed to an advantageously well-designed high-porosity structure, significant surface area, and plentiful active centers. Furthermore, the perspectives of MOF-derived electrocatalysts for the ORR, OER, and HER are presented.


Highlights:


1 Synthesis protocols, design engineering, theoretical calculations, and energy applications for metal–organic frameworks (MOFs)-derived electrocatalysts are systematically analyzed.
2 Synthesizing methods of MOF-derived catalysts and their oxygen reduction reaction, oxygen evolution reaction, and hydrogen evolution reaction electrocatalysis are discussed.
3 The current status, ongoing challenges, and potential future outlooks of MOFs-derived electrocatalysts are highlighted.

Keywords

MOF-derived electrocatalysis Oxygen reduction reaction Oxygen evolution reaction Hydrogen evolution reaction
Radwan, Amr, Huihui Jin, Daping He, and Shichun Mu. 2021. “Design Engineering, Synthesis Protocols, and Energy Applications of MOF-Derived Electrocatalysts”. Nano-Micro Letters 13 (June):132. https://doi.org/10.1007/s40820-021-00656-w.
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References
  1. O. Inderwildi, C. Zhang, X. Wang, M. Kraft, The impact of intelligent cyber-physical systems on the decarbonization of energy. Energy Environ. Sci. 13(3), 744–771 (2020). https://doi.org/10.1039/c9ee01919g
  2. Z. Qian, Y. Pei, H. Zareipour, N. Chen, A review and discussion of decomposition-based hybrid models for wind energy forecasting applications. Appl. Energy 235, 939–953 (2019). https://doi.org/10.1016/j.apenergy.2018.10.080
  3. D. Farinotti, V. Round, M. Huss, L. Compagno, H. Zekollari, Large hydropower and water-storage potential in future glacier-free basins. Nature 575(7782), 341–344 (2019). https://doi.org/10.1038/s41586-019-1740-z
  4. S.G. Yalew, M.T. van Vliet, D.E. Gernaat, F. Ludwig, A. Miara et al., Impacts of climate change on energy systems in global and regional scenarios. Nat. Energy 5(10), 794–802 (2020). https://doi.org/10.1038/s41560-020-0664-z
  5. J. Chang, Q. Huang, Y. Gao, Z. Zheng, Pathways of developing high-energy-density flexible lithium batteries. Adv. Mater. (2021). https://doi.org/10.1002/adma.202004419
  6. A. Radwan, Y. Liu, Y. Qi, W. Jin, V. Nguyen et al., Cycling stability of carbon coated Na5V12O32 ultralong nanowires as a cathode material for sodium-ion batteries. Mater. Res. Bull. 97, 24–29 (2018). https://doi.org/10.1016/j.materresbull.2017.08.047
  7. Y.-T. Liu, S. Liu, G.-R. Li, X.-P. Gao, Strategy of enhancing the volumetric energy density for lithium–sulfur batteries. Adv. Mater. 33(8), 2003955 (2021). https://doi.org/10.1002/adma.202003955
  8. A.R. Radwan, Y. Liu, V. Nguyen, W. Chen, Sodium vanadate nanoflowers/rGO composite as a high-rate cathode material for sodium-ion batteries. J. Mater. Sci. Mater. Electron. 29(8), 7032–7039 (2018). https://doi.org/10.1007/s10854-018-8690-3
  9. G. Qian, J. Chen, T. Yu, L. Luo, S. Yin, N-doped graphene-decorated NiCo alloy coupled with mesoporous NiCoMoO nano-sheet heterojunction for enhanced water electrolysis activity at high current density. Nano-Micro Lett. 13(1), 77 (2021). https://doi.org/10.1007/s40820-021-00607-5
  10. M. Hirscher, T. Autrey, S.-I. Orimo, Hydrogen energy. ChemPhysChem 20(10), 1157–1157 (2019). https://doi.org/10.1002/cphc.201900429
  11. H. Jin, X. Wang, C. Tang, A. Vasileff, L. Li et al., Stable and highly efficient hydrogen evolution from seawater enabled by an unsaturated nickel surface nitride. Adv. Mater. 33(13), 2007508 (2021). https://doi.org/10.1002/adma.202007508
  12. T. Kirchartz, U. Rau, What makes a good solar cell? Adv. Energy Mater. 8(28), 1703385 (2018). https://doi.org/10.1002/aenm.201703385
  13. A.Q. Gilbert, M.D. Bazilian, Can distributed nuclear power address energy resilience and energy poverty? Joule 4(9), 1839–1843 (2020). https://doi.org/10.1016/j.joule.2020.08.005
  14. S.L. Zhang, B.Y. Guan, X.F. Lu, S. Xi, Y. Du et al., Metal atom-doped Co3O4 hierarchical nanoplates for electrocatalytic oxygen evolution. Adv. Mater. 32(31), 2002235 (2020). https://doi.org/10.1002/adma.202002235
  15. W. Cheng, X.F. Lu, D. Luan, X.W. Lou, NiMn-based bimetal–organic framework nanosheets supported on multi-channel carbon fibers for efficient oxygen electrocatalysis. Angew. Chem. Int. Ed. 59(41), 18234–18239 (2020). https://doi.org/10.1002/anie.202008129
  16. S.Y. Lim, S. Martin, G. Gao, Y. Dou, S.B. Simonsen et al., Self-standing nanofiber electrodes with Pt–Co derived from electrospun zeolitic imidazolate framework for high temperature PEM fuel cells. Adv. Funct. Mater. (2020). https://doi.org/10.1002/adfm.202006771
  17. Z. Wang, H. Jin, T. Meng, K. Liao, W. Meng et al., Fe, Cu-coordinated ZIF-derived carbon framework for efficient oxygen reduction reaction and Zinc–air batteries. Adv. Funct. Mater. 28(39), 1802596 (2018). https://doi.org/10.1002/adfm.201802596
  18. I.S. Amiinu, Z. Pu, X. Liu, K.A. Owusu, H.G.R. Monestel et al., Multifunctional Mo–N/C@ MoS2 electrocatalysts for HER, OER, ORR, and Zn–air batteries. Adv. Funct. Mater. 27(44), 1702300 (2017). https://doi.org/10.1002/adfm.201702300
  19. H. Zhou, D. He, A.I. Saana, J. Yang, Z. Wang et al., Mesoporous-silica induced doped carbon nanotube growth from metal–organic frameworks. Nanoscale 10(13), 6147–6154 (2018). https://doi.org/10.1039/C8NR00137E
  20. I.S. Amiinu, X. Liu, Z. Pu, W. Li, Q. Li et al., From 3D ZIF nanocrystals to Co–Nx/C nanorod array electrocatalysts for ORR, OER, and Zn–Air batteries. Adv. Funct. Mater. 28(5), 1704638 (2018). https://doi.org/10.1002/adfm.201704638
  21. X.F. Lu, Y. Chen, S. Wang, S. Gao, X.W. Lou, Interfacing manganese oxide and cobalt in porous graphitic carbon polyhedrons boosts oxygen electrocatalysis for Zn–Air batteries. Adv. Mater. 31(39), 1902339 (2019). https://doi.org/10.1002/adma.201902339
  22. Q. Sun, N. Wang, Q. Xu, J. Yu, Nanopore-supported metal nanocatalysts for efficient hydrogen generation from liquid-phase chemical hydrogen storage materials. Adv. Mater. 32(44), e2001818 (2020). https://doi.org/10.1002/adma.202001818
  23. H. Yuan, J. Nai, H. Tian, Z. Ju, W. Zhang et al., An ultrastable lithium metal anode enabled by designed metal fluoride spansules. Sci. Adv. 6(10), 3112 (2020). https://doi.org/10.1126/sciadv.aaz3112
  24. H. Yuan, J. Nai, Y. Fang, G. Lu, X. Tao et al., Double-shelled C@MoS2 structures preloaded with sulfur: an additive reservoir for stable lithium metal anodes. Angew. Chem. Int. Ed. 59(37), 15839–15843 (2020). https://doi.org/10.1002/ange.202001989
  25. X. Zhu, C. Hu, R. Amal, L. Dai, X. Lu, Heteroatom-doped carbon catalysts for zinc–air batteries: progress, mechanism, and opportunities. Energy Environ. Sci. 13(12), 4536–4563 (2020). https://doi.org/10.1039/D0EE02800B
  26. C.Y. Su, H. Cheng, W. Li, Z.Q. Liu, N. Li et al., Atomic modulation of FeCo–nitrogen–carbon bifunctional oxygen electrodes for rechargeable and flexible all-solid-state zinc–air battery. Adv. Energy Mater. 7(13), 1602420 (2017). https://doi.org/10.1002/aenm.201602420
  27. Y. Qiao, P. Yuan, Y. Hu, J. Zhang, S. Mu et al., Sulfuration of an Fe–N–C catalyst containing FexC/Fe species to enhance the catalysis of oxygen reduction in acidic media and for use in flexible Zn–air batteries. Adv. Mater. 30(46), 1804504 (2018). https://doi.org/10.1002/adma.201804504
  28. Z. Lu, B. Wang, Y. Hu, W. Liu, Y. Zhao et al., An isolated zinc–cobalt atomic pair for highly active and durable oxygen reduction. Angew. Chem. Int. Ed. 58, 2622–2626 (2019). https://doi.org/10.1002/anie.201810175
  29. T. Wang, Z. Kou, S. Mu, J. Liu, D. He et al., 2D dual-metal zeolitic-imidazolate-framework-(ZIF)-derived bifunctional air electrodes with ultrahigh electrochemical properties for rechargeable zinc–air batteries. Adv. Funct. Mater. 28(5), 1705048 (2018). https://doi.org/10.1002/adfm.201705048
  30. L. Yan, Y. Xu, P. Chen, S. Zhang, H. Jiang et al., A freestanding 3D Heterostructure film stitched by MOF-derived carbon nanotube microsphere superstructure and reduced graphene oxide sheets: a Superior multifunctional electrode for overall water splitting and Zn–air batteries. Adv. Mater. 32(48), 2003313 (2020). https://doi.org/10.1002/adma.202003313
  31. J. Zhang, Y. Sun, J. Zhu, Z. Kou, P. Hu et al., Defect and pyridinic nitrogen engineering of carbon-based metal-free nanomaterial toward oxygen reduction. Nano Energy 52, 307–314 (2018). https://doi.org/10.1016/j.nanoen.2018.08.003
  32. H. Wang, F.X. Yin, N. Liu, R.H. Kou, X.B. He et al., Engineering Fe–Fe3C@ Fe–N–C active sites and hybrid structures from dual metal–organic frameworks for oxygen reduction reaction in H2–O2 fuel cell and Li–O2 battery. Adv. Funct. Mater. 29(23), 1901531 (2019). https://doi.org/10.1002/adfm.201901531
  33. S.L. Zhang, B.Y. Guan, X.W. Lou, Co–Fe alloy/N-doped carbon hollow spheres derived from dual metal–organic frameworks for enhanced electrocatalytic oxygen reduction. Small 15(13), 1805324 (2019). https://doi.org/10.1002/smll.201805324
  34. B.Y. Guan, Y. Lu, Y. Wang, M. Wu, X.W. Lou, Porous iron–cobalt alloy/nitrogen-doped carbon cages synthesized via pyrolysis of complex metal–organic framework hybrids for oxygen reduction. Adv. Funct. Mater. 28(10), 1706738 (2018). https://doi.org/10.1002/adfm.201706738
  35. H. Liu, J. Guan, S. Yang, Y. Yu, R. Shao et al., Metal–organic-framework-derived Co2P nanoparticle/multi-doped porous carbon as a trifunctional electrocatalyst. Adv. Mater. 32(36), 2003649 (2020). https://doi.org/10.1002/adma.202003649
  36. A.I. Douka, Y. Xu, H. Yang, S. Zaman, Y. Yan et al., A zeolitic-imidazole frameworks-derived interconnected macroporous carbon matrix for efficient oxygen electrocatalysis in rechargeable zinc–air batteries. Adv. Mater. 32(28), 2002170 (2020). https://doi.org/10.1002/adma.202002170
  37. Y. Wang, L. Yan, K. Dastafkan, C. Zhao, X. Zhao et al., Lattice matching growth of conductive hierarchical porous MOF/LDH heteronanotube arrays for highly efficient water oxidation. Adv. Mater. (2021). https://doi.org/10.1002/adma.202006351
  38. T. Liu, P. Li, N. Yao, T. Kong, G. Cheng et al., Self-sacrificial template-directed vapor-phase growth of MOF assemblies and surface vulcanization for efficient water splitting. Adv. Mater. 31(21), 1806672 (2019). https://doi.org/10.1002/adma.201806672
  39. C.C. Hou, L. Zou, Y. Wang, Q. Xu, MOF-mediated fabrication of a porous 3D superstructure of carbon nanosheets decorated with ultrafine cobalt phosphide nanoparticles for efficient electrocatalysis and zinc–air batteries. Angew. Chem. Int. Ed. 132(48), 21544–21550 (2020). https://doi.org/10.1002/ange.202011347
  40. M. Zhang, Q. Dai, H. Zheng, M. Chen, L. Dai, Novel MOF-derived Co@ N-C bifunctional catalysts for highly efficient Zn–air batteries and water splitting. Adv. Mater. 30(10), 1705431 (2018). https://doi.org/10.1002/adma.201705431
  41. H. Xia, J. Zhang, Z. Yang, S. Guo, S. Guo et al., 2D MOF Nanoflake-assembled spherical microstructures for enhanced supercapacitor and electrocatalysis performances. Nano-Micro Lett. 9(4), 43 (2017). https://doi.org/10.1007/s40820-017-0144-6
  42. Y. Arafat, M.R. Azhar, Y. Zhong, X. Xu, M.O. Tadé et al., A Porous Nano-micro-composite as a high-performance bi-functional air electrode with remarkable stability for rechargeable zinc–air batteries. Nano-Micro Lett. 12(1), 130 (2020). https://doi.org/10.1007/s40820-020-00468-4
  43. Q. Niu, B. Chen, J. Guo, J. Nie, X. Guo et al., Flexible, porous, and metal–heteroatom-doped carbon nanofibers as efficient ORR electrocatalysts for Zn–air battery. Nano-Micro Lett. 11(1), 8 (2019). https://doi.org/10.1007/s40820-019-0238-4
  44. K. Chen, S. Kim, M. Je, H. Choi, Z. Shi et al., Ultrasonic plasma engineering toward facile synthesis of single-atom M-N4/N-doped carbon (M = Fe, Co) as superior oxygen electrocatalyst in rechargeable zinc–air batteries. Nano-Micro Lett. 13(1), 60 (2021). https://doi.org/10.1007/s40820-020-00581-4
  45. Z. Zhao, C. Chen, Z. Liu, J. Huang, M. Wu et al., Pt-based nanocrystal for electrocatalytic oxygen reduction. Adv. Mater. 31(31), 1808115 (2019). https://doi.org/10.1002/adma.201808115
  46. X. Zhao, Y. Hamamura, Y. Yoshida, T. Kaneko, T. Gunji et al., Plasma-devised Pt/C model electrodes for understanding doubly beneficial roles of nanoneedle-carbon morphology and strong Pt-carbon interface in oxygen reduction reaction. ACS Appl. Energy Mater. 3(6), 5542–5551 (2020). https://doi.org/10.1021/acsaem.0c00528
  47. P. Mardle, X. Ji, J. Wu, S. Guan, H. Dong et al., Thin film electrodes from Pt nanorods supported on aligned N-CNTs for proton exchange membrane fuel cells. Appl. Catal. B-Environ. 260, 118031 (2020). https://doi.org/10.1016/j.apcatb.2019.118031
  48. A.M. Jauhar, Z. Ma, M. Xiao, G. Jiang, S. Sy et al., Space-confined catalyst design toward ultrafine Pt nanoparticles with enhanced oxygen reduction activity and durability. J. Power Sources 473, 228607 (2020). https://doi.org/10.1016/j.jpowsour.2020.228607
  49. S. Anantharaj, S. Kundu, S. Noda, “The Fe Effect”: A review unveiling the critical roles of Fe in enhancing OER activity of Ni and Co based catalysts. Nano Energy 80, 105514 (2021). https://doi.org/10.1016/j.nanoen.2020.105514
  50. L. Wang, Q. Zhou, Z. Pu, Q. Zhang, X. Mu et al., Surface reconstruction engineering of cobalt phosphides by Ru inducement to form hollow Ru-RuPx-CoxP pre-electrocatalysts with accelerated oxygen evolution reaction. Nano Energy 53, 270–276 (2018). https://doi.org/10.1016/j.nanoen.2018.08.061
  51. P. Wang, Z. Pu, Y. Li, L. Wu, Z. Tu et al., Iron-doped nickel phosphide nanosheet arrays: an efficient bifunctional electrocatalyst for water splitting. ACS Appl. Mater. Interfaces 9(31), 26001–26007 (2017). https://doi.org/10.1021/acsami.7b06305
  52. M. Wang, C. Zhang, T. Meng, Z. Pu, H. Jin et al., Iron oxide and phosphide encapsulated within N, P-doped microporous carbon nanofibers as advanced tri-functional electrocatalyst toward oxygen reduction/evolution and hydrogen evolution reactions and zinc-air batteries. J. Power Sources 413, 367–375 (2019). https://doi.org/10.1016/j.jpowsour.2018.12.056
  53. X.F. Lu, L. Yu, X.W. Lou, Highly crystalline Ni-doped FeP/carbon hollow nanorods as all-pH efficient and durable hydrogen evolving electrocatalysts. Sci. Adv. 5(2), eaav6009 (2019). https://doi.org/10.1126/sciadv.aav6009
  54. H.-F. Wang, L. Chen, H. Pang, S. Kaskel, Q. Xu, MOF-derived electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions. Chem. Soc. Rev. 49(5), 1414–1448 (2020). https://doi.org/10.1126/sciadv.aav6009
  55. Z. Liang, T. Qiu, S. Gao, R. Zhong, R. Zou, Multi-scale design of metal–organic framework-derived materials for energy electrocatalysis. Adv. Energy Mater. (2021). https://doi.org/10.1002/aenm.202003410
  56. C.C. Hou, Q. Xu, Metal–organic frameworks for energy. Adv. Energy Mater. 9(23), 1801307 (2019). https://doi.org/10.1002/aenm.201801307
  57. H. Dou, M. Xu, B. Wang, Z. Zhang, G. Wen et al., Microporous framework membranes for precise molecule/ion separations. Chem. Soc. Rev. 50(2), 986–1029 (2021). https://doi.org/10.1039/d0cs00552e
  58. R.-B. Lin, S. Xiang, H. Xing, W. Zhou, B. Chen, Exploration of porous metal–organic frameworks for gas separation and purification. Coord. Chem. Rev. 378, 87–103 (2019). https://doi.org/10.1016/j.ccr.2017.09.027
  59. Q. Qian, P.A. Asinger, M.J. Lee, G. Han, K. Mizrahi Rodriguez et al., MOF-based membranes for gas separations. Chem. Rev. 120(16), 8161–8266 (2020). https://doi.org/10.1021/acs.chemrev.0c00119
  60. Q. Liang, H. Jin, Z. Wang, Y. Xiong, S. Yuan et al., Metal-organic frameworks derived reverse-encapsulation Co-NC@Mo2C complex for efficient overall water splitting. Nano Energy 57, 746–752 (2019). https://doi.org/10.1016/j.nanoen.2018.12.060
  61. J. Chen, H. Li, C. Fan, Q. Meng, Y. Tang et al., Dual single-atomic Ni-N4 and Fe-N4 sites constructing janus hollow graphene for selective oxygen electrocatalysis. Adv. Mater. 32(30), 2003134 (2020). https://doi.org/10.1002/adma.202003134
  62. L.J. Small, S.E. Henkelis, D.X. Rademacher, M.E. Schindelholz, J.L. Krumhansl et al., Near-zero power MOF-based sensors for NO2 detection. Funct. Mater. Adv. (2020). https://doi.org/10.1002/adfm.202006598
  63. C. Chen, D. Xiong, M. Gu, C. Lu, F.-Y. Yi et al., MOF-derived bimetallic CoFe-PBA composites as highly selective and sensitive electrochemical sensors for hydrogen peroxide and nonenzymatic glucose in human serum. ACS Appl. Mater. Interfaces 12(31), 35365–35374 (2020). https://doi.org/10.1021/acsami.0c09689
  64. X.S. Xing, Z.H. Fu, N.N. Zhang, X.Q. Yu, M.S. Wang et al., High proton conduction in an excellent water-stable gadolinium metal-organic framework. Chem. Commun. 55(9), 1241–1244 (2019). https://doi.org/10.1039/c8cc08700h
  65. Y. Ye, L. Gong, S. Xiang, Z. Zhang, B. Chen, Metal–organic frameworks as a versatile platform for proton conductors. Adv. Mater. 32(21), 1907090 (2020). https://doi.org/10.1002/adma.201907090
  66. Y. Feng, H. Wang, S. Zhang, Y. Zhao, J. Gao et al., Antibodies@ MOFs: an in vitro protective coating for preparation and storage of biopharmaceuticals. Adv. Mater. 31(2), 1805148 (2019). https://doi.org/10.1002/adma.201805148
  67. I.A. Lázaro, R.S. Forgan, Application of zirconium MOFs in drug delivery and biomedicine. Coord. Chem. Rev. 380, 230–259 (2019). https://doi.org/10.1016/j.ccr.2018.09.009
  68. H.-C. Zhou, J.R. Long, O.M. Yaghi, Introduction to metal–organic frameworks. Chem. Rev. 112(2), 673–674 (2012). https://doi.org/10.1021/cr300014x
  69. S. Kitagawa, Metal–organic frameworks (MOFs). Chem. Soc. Rev. 43(16), 5415–5418 (2014). https://doi.org/10.1039/C4CS90059F
  70. C.A. Downes, S.C. Marinescu, Electrocatalytic metal-organic frameworks for energy applications. Chemsuschem 10(22), 1701420 (2017). https://doi.org/10.1002/cssc.201701420
  71. S. Yuan, L. Feng, K. Wang, J. Pang, M. Bosch, Stable metal–organic frameworks: design, synthesis, and applications. Adv. Mater. 30(37), 1704303 (2018). https://doi.org/10.1002/adma.201704303
  72. X. Long, P. Yin, T. Lei, K. Wang, Z. Zhan, Methanol electro-oxidation on Cu@Pt/C core-shell catalyst derived from Cu-MOF. Appl. Catal. B-Environ. 260, 118187 (2020). https://doi.org/10.1016/j.apcatb.2019.118187
  73. H. Zhang, Z. Ma, J. Duan, H. Liu, G. Liu, Active sites implanted carbon cages in core–shell architecture: highly active and durable electrocatalyst for hydrogen evolution reaction. ACS Nano 10(1), 684–694 (2016). https://doi.org/10.1021/acsnano.5b05728
  74. V. Briega-Martos, E. Herrero, J.M. Feliu, Hydrogen peroxide and oxygen reduction studies on Pt stepped surfaces: surface charge effects and mechanistic consequences. Electrochim. Acta 334, 135452 (2020). https://doi.org/10.1016/j.electacta.2019.135452
  75. M.J. Farias, A.L. Silva, A.A. Tanaka, E. Herrero, J.M. Feliu, Surface defects as ingredients that can improve or inhibit the pathways for CO oxidation at low overpotentials using Pt (111)-type catalysts. J. Phys. Chem. C 124(49), 26583–26595 (2020). https://doi.org/10.1021/acs.jpcc.0c07104
  76. X. Wan, X. Liu, Y. Li, R. Yu, L. Zheng, Fe–N–C electrocatalyst with dense active sites and efficient mass transport for high-performance proton exchange membrane fuel cells. Nat. Catal. 2(3), 259–268 (2019). https://doi.org/10.1038/s41929-019-0237-3
  77. Y. Qian, Z. Hu, X. Ge, S. Yang, Y. Peng, A metal-free ORR/OER bifunctional electrocatalyst derived from metal-organic frameworks for rechargeable Zn-Air batteries. Carbon 111, 641–650 (2017). https://doi.org/10.1016/j.carbon.2016.10.046
  78. X. Wei, Y. Li, H. Peng, D. Gao, Y. Ou, A novel functional material of Co3O4/Fe2O3 nanocubes derived from a MOF precursor for high-performance electrochemical energy storage and conversion application. Chem. Eng. J. 355, 336–340 (2019). https://doi.org/10.1016/j.cej.2018.08.009
  79. Y. Deng, B. Chi, X. Tian, Z. Cui, E. Liu et al., g-C3N4 promoted MOF derived hollow carbon nanopolyhedra doped with high density/fraction of single Fe atoms as an ultra-high performance non-precious catalyst towards acidic ORR and PEM fuel cells. J. Mater. Chem. A 7(9), 5020–5030 (2019). https://doi.org/10.1039/C8TA11785C
  80. M. Kuang, W. Huang, C. Hegde, W. Fang, X. Tan et al., Interface engineering in transition metal carbides for electrocatalytic hydrogen generation and nitrogen fixation. Mater. Horiz. 7(1), 32–53 (2020). https://doi.org/10.1039/C9MH01094G
  81. A. Mahmood, W. Guo, H. Tabassum, R. Zou, Metal-organic framework-based nanomaterials for electrocatalysis. Adv. Energy Mater. 6(17), 1600423 (2016). https://doi.org/10.1002/aenm.201600423
  82. B.Y. Guan, X.Y. Yu, H.B. Wu, X.W. Lou, Complex nanostructures from materials based on metal–organic frameworks for electrochemical energy storage and conversion. Adv. Mater. 29(47), 1703614 (2017). https://doi.org/10.1002/adma.201703614
  83. C. Wang, J. Kim, J. Tang, M. Kim, H. Lim et al., New strategies for novel MOF-derived carbon materials based on nanoarchitectures. Chem 6(1), 19–40 (2020). https://doi.org/10.1016/j.chempr.2019.09.005
  84. X.F. Lu, Y. Fang, D. Luan, X.W.D. Lou, Metal–organic frameworks derived functional materials for electrochemical energy storage and conversion: a mini review. Nano Lett. 21(4), 1555–1565 (2021). https://doi.org/10.1021/acs.nanolett.0c04898
  85. S. Pandiaraj, H.B. Aiyappa, R. Banerjee, S. Kurungot, Post modification of MOF derived carbon via g-C3N4 entrapment for an efficient metal-free oxygen reduction reaction. Chem. Commun. 50(25), 3363–3366 (2014). https://doi.org/10.1039/c3cc47620k
  86. B. Liu, H. Shioyama, T. Akita, Q. Xu, Metal-organic framework as a template for porous carbon synthesis. J. Am. Chem. Soc. 130(16), 5390–5391 (2008). https://doi.org/10.1021/ja7106146
  87. P. Zhang, F. Sun, Z. Xiang, Z. Shen, J. Yun et al., ZIF-derived in situ nitrogen-doped porous carbons as efficient metal-free electrocatalysts for oxygen reduction reaction. Energy Environ. Sci. 7(1), 442–450 (2014). https://doi.org/10.1039/c3ee42799d
  88. X.F. Lu, B.Y. Xia, S.Q. Zang, X.W. Lou, Metal–organic frameworks based electrocatalysts for the oxygen reduction reaction. Angew. Chem. Int. Ed. 59(12), 4634–4650 (2020). https://doi.org/10.1002/anie.201910309
  89. A. Radwan, H. Jin, B. Liu, Z. Chen, Q. Wu et al., 3D-ZIF scaffold derived carbon encapsulated iron nitride as a synergistic catalyst for ORR and zinc-air battery cathodes. Carbon 171, 368–375 (2021). https://doi.org/10.1016/j.carbon.2020.09.024
  90. Z. Lyu, G.J.H. Lim, R. Guo, Z. Kou, T. Wang et al., 3D-printed MOF-derived hierarchically porous frameworks for practical high-energy density Li-O2 batteries. Adv. Funct. Mater. 29(1), 1806658 (2019). https://doi.org/10.1002/adfm.201806658
  91. K. Rui, G. Zhao, Y. Chen, Y. Lin, Q. Zhou et al., Hybrid 2D dual-metal-organic frameworks for enhanced water oxidation catalysis. Adv. Funct. Mater. 28(26), 1801554 (2018). https://doi.org/10.1002/adfm.201801554
  92. K. Gong, F. Du, Z. Xia, M. Durstock, L. Dai, Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction. Science 323(5915), 760–764 (2009). https://doi.org/10.1126/science.1168049
  93. C.H. Choi, S.H. Park, S.I. Woo, Binary and ternary doping of nitrogen, boron, and phosphorus into carbon for enhancing electrochemical oxygen reduction activity. ACS Nano 6(8), 7084–7091 (2012). https://doi.org/10.1021/nn3021234
  94. Z. Yang, Z. Yao, G. Li, G. Fang, H. Nie et al., Sulfur-doped graphene as an efficient metal-free cathode catalyst for oxygen reduction. ACS Nano 6(1), 205–211 (2012). https://doi.org/10.1021/nn203393d
  95. Z.H. Huang, N.H. Xie, M. Zhang, B.Q. Xu, Nonpyrolyzed Fe-N coordination-based iron triazolate framework: an efficient and stable electrocatalyst for oxygen reduction reaction. Chemsuschem 12(1), 200–207 (2019). https://doi.org/10.1002/cssc.201801886
  96. A. Bavykina, N. Kolobov, I.S. Khan, J.A. Bau, A. Ramirez et al., Metal–organic frameworks in heterogeneous catalysis: recent progress, new trends, and future perspectives. Chem. Rev. 120(16), 8468–8535 (2020). https://doi.org/10.1021/acs.chemrev.9b00685
  97. R. Wang, X.Y. Dong, J. Du, J.Y. Zhao, S.Q. Zang, MOF-derived bifunctional Cu3P nanoparticles coated by a N, P-codoped carbon shell for hydrogen evolution and oxygen reduction. Adv. Mater. 30(6), 1703711 (2018). https://doi.org/10.1002/adma.201703711
  98. L. Yang, X. Zeng, W. Wang, D. Cao, Recent progress in MOF-derived, heteroatom-doped porous carbons as highly efficient electrocatalysts for oxygen reduction reaction in fuel cells. Adv. Funct. Mater. 28(7), 1704537 (2018). https://doi.org/10.1002/adfm.201704537
  99. C.R. Raj, A. Samanta, S.H. Noh, S. Mondal, T. Okajima et al., Emerging new generation electrocatalysts for the oxygen reduction reaction. J. Mater. Chem. A 4(29), 11156–11178 (2016). https://doi.org/10.1039/C6TA03300H
  100. W. Zhou, J. Zhou, Y. Zhou, J. Lu, K. Zhou et al., N-doped carbon-wrapped cobalt nanoparticles on N-doped graphene nanosheets for high-efficiency hydrogen production. Chem. Mater. 27(6), 2026–2032 (2015). https://doi.org/10.1021/acs.chemmater.5b00331
  101. Q. Fu, J. Han, X. Wang, P. Xu, T. Yao et al., 2D transition metal dichalcogenides: Design, modulation, and challenges in electrocatalysis. Adv. Mater. 33(6), 1907818 (2021). https://doi.org/10.1002/adma.201907818
  102. Y. Li, Z. Wang, J. Hu, S. Li, Y. Du et al., Metal–organic frameworks derived interconnected bimetallic metaphosphate nanoarrays for efficient electrocatalytic oxygen evolution. Adv. Funct. Mater. 30(25), 1910498 (2020). https://doi.org/10.1002/adfm.201910498
  103. H. Huang, Y. Zhao, Y. Bai, F. Li, Y. Zhang et al., Conductive metal–organic frameworks with extra metallic sites as an efficient electrocatalyst for the hydrogen evolution reaction. Adv. Sci. 7(9), 2000012 (2020). https://doi.org/10.1002/advs.202000012
  104. Z.W. Chen, L.X. Chen, Z. Wen, Q. Jiang, Understanding electro-catalysis by using density functional theory. Phys. Chem. Chem. Phys. 21(43), 23782–23802 (2019). https://doi.org/10.1039/c9cp04430b
  105. S. Hammes-Schiffer, A conundrum for density functional theory. Science 355(6320), 28–29 (2017). https://doi.org/10.1126/science.aal3442
  106. S.S. Shinde, C.H. Lee, J.-Y. Jung, N.K. Wagh, S.-H. Kim et al., Unveiling dual-linkage 3D hexaiminobenzene metal–organic frameworks towards long-lasting advanced reversible Zn–air batteries. Energy Environ. Sci. 12(2), 727–738 (2019). https://doi.org/10.1039/C8EE02679C
  107. W. Cheng, X. Zhao, H. Su, F. Tang, W. Che et al., Lattice-strained metal–organic-framework arrays for bifunctional oxygen electrocatalysis. Nat. Energy 4(2), 115–122 (2019). https://doi.org/10.1038/s41560-018-0308-8
  108. Y. Zhu, Z. Zhang, Z. Lei, Y. Tan, W. Wu et al., Defect-enriched hollow porous Co–N-doped carbon for oxygen reduction reaction and Zn-Air batteries. Carbon 167, 188–195 (2020). https://doi.org/10.1016/j.carbon.2020.06.006
  109. Y. Lin, H. Wan, D. Wu, G. Chen, N. Zhang et al., Metal–organic framework hexagonal nanoplates: bottom-up synthesis, topotactic transformation, and efficient oxygen evolution reaction. J. Am. Chem. Soc. 142(16), 7317–7321 (2020). https://doi.org/10.1021/jacs.0c01916
  110. W. Li, S. Xue, S. Watzele, S. Hou, J. Fichtner et al., Advanced bifunctional oxygen reduction and evolution electrocatalyst derived from surface-mounted metal-organic frameworks. Angew. Chem. Int. Ed. 59(14), 5837–5843 (2020). https://doi.org/10.1002/anie.201916507
  111. B. Yan, D. Liu, X. Feng, M. Shao, Y. Zhang, Ru species supported on MOF-derived N-doped TiO2/C hybrids as efficient electrocatalytic/photocatalytic hydrogen evolution reaction catalysts. Adv. Funct. Mater. 30(31), 2003007 (2020). https://doi.org/10.1002/adfm.202003007
  112. H. Huang, S. Zhou, C. Yu, H. Huang, J. Zhao et al., Rapid and energy-efficient microwave pyrolysis for high-yield production of highly-active bifunctional electrocatalysts for water splitting. Energy Environ. Sci. 13(2), 545–553 (2020). https://doi.org/10.1039/C9EE03273H
  113. W. Zhang, Y. Wang, H. Zheng, R. Li, Y. Tang et al., Embedding ultrafine metal oxide nanoparticles in monolayered metal–organic framework nanosheets enables efficient electrocatalytic oxygen evolution. ACS Nano 14(2), 1971–1981 (2020). https://doi.org/10.1021/acsnano.9b08458
  114. L. Huang, G. Gao, H. Zhang, J. Chen, Y. Fang et al., Self-dissociation-assembly of ultrathin metal-organic framework nanosheet arrays for efficient oxygen evolution. Nano Energy 68, 104296 (2020). https://doi.org/10.1016/j.nanoen.2019.104296
  115. W. Cheng, X.F. Lu, D. Luan, X.W. Lou, NiMn-based bimetal–organic framework nanosheets supported on multi-channel carbon fibers for efficient oxygen electrocatalysis. Angew. Chem. Int. Ed. 59(41), 18234–18239 (2020). https://doi.org/10.1002/anie.202008129
  116. G. Yilmaz, K.M. Yam, C. Zhang, H.J. Fan, G.W. Ho, In situ transformation of MOFs into layered double hydroxide embedded metal sulfides for improved electrocatalytic and supercapacitive performance. Adv. Mater. 29(26), 1606814 (2017). https://doi.org/10.1002/adma.201606814
  117. D.Y. Chung, K.J. Lee, S.-H. Yu, M. Kim, S.Y. Lee et al., Alveoli-inspired facile transport structure of N-doped porous carbon for electrochemical energy applications. Adv. Energy Mater. 5(3), 1401309 (2015). https://doi.org/10.1002/aenm.201401309
  118. Y. Hou, T. Huang, Z. Wen, S. Mao, S. Cui et al., Metal−Organic framework-derived nitrogen-doped core-shell-structured porous Fe/Fe3C@C nanoboxes supported on graphene sheets for efficient oxygen reduction reactions. Adv. Energy Mater. 4(11), 1400337 (2014). https://doi.org/10.1002/aenm.201400337
  119. S.S.A. Shah, T. Najam, M.K. Aslam, M. Ashfaq, M.M. Rahman et al., Recent advances on oxygen reduction electrocatalysis: correlating the characteristic properties of metal organic frameworks and the derived nanomaterials. Appl. Catal. B-Environ. 268, 118570 (2020). https://doi.org/10.1016/j.apcatb.2019.118570
  120. L. Ge, Y. Yang, L. Wang, W. Zhou, R. De Marco et al., High activity electrocatalysts from metal–organic framework-carbon nanotube templates for the oxygen reduction reaction. Carbon 82, 417–424 (2015). https://doi.org/10.1016/j.carbon.2014.10.085
  121. C. Xu, Z. Lin, D. Zhao, Y. Sun, Y. Zhong et al., Facile in situ fabrication of Co nanoparticles embedded in 3D N-enriched mesoporous carbon foam electrocatalyst with enhanced activity and stability toward oxygen reduction reaction. J. Mater. Sci. 54(7), 5412–5423 (2019). https://doi.org/10.1007/s10853-018-03255-0
  122. L. Yang, G. Xu, J. Ban, L. Zhang, G. Xu et al., Metal-organic framework-derived metal-free highly graphitized nitrogen-doped porous carbon with a hierarchical porous structure as an efficient and stable electrocatalyst for oxygen reduction reaction. J. Colloid Interface Sci. 535, 415–424 (2019). https://doi.org/10.1016/j.jcis.2018.10.007
  123. X. Zhao, H. Zhao, T. Zhang, X. Yan, Y. Yuan et al., One-step synthesis of nitrogen-doped microporous carbon materials as metal-free electrocatalysts for oxygen reduction reaction. J. Mater. Chem. A 2(30), 11666–11671 (2014). https://doi.org/10.1039/c4ta00846d
  124. F. Zheng, Y. Yang, Q. Chen, High lithium anodic performance of highly nitrogen-doped porous carbon prepared from a metal-organic framework. Nat. Commun. 5(1), 1–10 (2014). https://doi.org/10.1038/ncomms6261
  125. L. Chai, L. Zhang, X. Wang, L. Xu, C. Han et al., Bottom-up synthesis of MOF-derived hollow N-doped carbon materials for enhanced ORR performance. Carbon 146, 248–256 (2019). https://doi.org/10.1016/j.carbon.2019.02.006
  126. J. Li, Y. Chen, Y. Tang, S. Li, H. Dong et al., Metal–organic framework templated nitrogen and sulfur co-doped porous carbons as highly efficient metal-free electrocatalysts for oxygen reduction reactions. J. Mater. Chem. A 2(18), 6316–6319 (2014). https://doi.org/10.1039/C3TA15335E
  127. J.-S. Li, S.-L. Li, Y.-J. Tang, K. Li, L. Zhou et al., Heteroatoms ternary-doped porous carbons derived from MOFs as metal-free electrocatalysts for oxygen reduction reaction. Sci. Rep. 4, 5130 (2014). https://doi.org/10.1038/srep05130
  128. J. Yan, X. Zheng, C. Wei, Z. Sun, K. Zeng et al., Nitrogen-doped hollow carbon polyhedron derived from salt-encapsulated ZIF-8 for efficient oxygen reduction reaction. Carbon 171, 320–328 (2021). https://doi.org/10.1016/j.carbon.2020.09.005
  129. J. Wei, Y. Hu, Y. Liang, B. Kong, J. Zhang et al., Nitrogen-doped nanoporous carbon/graphene nano-sandwiches: synthesis and application for efficient oxygen reduction. Adv. Funct. Mater. 25(36), 5768–5777 (2015). https://doi.org/10.1002/adfm.201502311
  130. Q. Ren, H. Wang, X.F. Lu, Y.X. Tong, G.R. Li, Recent progress on MOF-derived heteroatom-doped carbon-based electrocatalysts for oxygen reduction reaction. Adv. Sci. 5(3), 1700515 (2018). https://doi.org/10.1002/advs.201700515
  131. L. Du, L. Xing, G. Zhang, S. Sun, Metal-organic framework derived carbon materials for electrocatalytic oxygen reactions: recent progress and future perspectives. Carbon 156, 77–92 (2020). https://doi.org/10.1016/j.carbon.2019.09.029
  132. F. Guo, H. Yang, L. Liu, Y. Han, A.M. Al-Enizi et al., Hollow capsules of doped carbon incorporating metal@ metal sulfide and metal@ metal oxide core–shell nanoparticles derived from metal-organic framework composites for efficient oxygen electrocatalysis. J. Mater. Chem. A 7, 3624–3631 (2019). https://doi.org/10.1039/C8TA11213D
  133. X. Wen, X. Yang, M. Li, L. Bai, J. Guan, Co/CoOx nanoparticles inlaid onto nitrogen-doped carbon-graphene as a trifunctional electrocatalyst. Electrochim. Acta 296, 830–841 (2019). https://doi.org/10.1016/j.electacta.2018.11.129
  134. J. Zhu, W. Tu, Z. Bai, H. Pan, P. Ji et al., Zeolitic-imidazolate-framework-derived Co@Co3O4 embedded into iron, nitrogen, sulfur Co-doped reduced graphene oxide as efficient electrocatalysts for overall water splitting and zinc-air batteries. Electrochim. Acta 323, 134821 (2019). https://doi.org/10.1016/j.electacta.2019.134821
  135. X. Yi, X. He, F. Yin, B. Chen, G. Li et al., Co-CoO-Co3O4/N-doped carbon derived from metal-organic framework: The addition of carbon black for boosting oxygen electrocatalysis and Zn-Air battery. Electrochim. Acta 295, 966–977 (2019). https://doi.org/10.1016/j.electacta.2018.11.142
  136. H. Jin, Z. Kou, W. Cai, H. Zhou, P. Ji et al., P-Fe bond oxygen reduction catalysts toward high-efficiency metal–air batteries and fuel cells. J. Mater. Chem. A 8(18), 9121–9127 (2020). https://doi.org/10.1039/D0TA02334E
  137. Y. Deng, B. Chi, X. Tian, Z. Cui, E. Liu et al., gC3N4 promoted MOF derived hollow carbon nanopolyhedra doped with high density/fraction of single Fe atoms as an ultra-high performance non-precious catalyst towards acidic ORR and PEM fuel cells. J. Mater. Chem. A 7(9), 5020–5030 (2019). https://doi.org/10.1039/C8TA11785C
  138. Q. Lin, X. Bu, A. Kong, C. Mao, X. Zhao et al., New heterometallic zirconium metalloporphyrin frameworks and their heteroatom-activated high-surface-area carbon derivatives. J. Am. Chem. Soc. 137(6), 2235–2238 (2015). https://doi.org/10.1021/jacs.5b00076
  139. H.S. Kim, M.S. Kang, W.C. Yoo, Boost-up electrochemical performance of MOFs via confined synthesis within nanoporous carbon matrices for supercapacitor and oxygen reduction reaction applications. J. Mater. Chem. A 7(10), 5561–5574 (2019). https://doi.org/10.1039/C8TA12200H
  140. Y. Li, W.-J. Zhang, J. Li, H. Ma, H. Du et al., Fe-MOF derived efficient ORR/OER bifunctional electrocatalyst for rechargeable Zinc-Air battery. ACS Appl. Mater. Interfaces 12(40), 44710–44719 (2020). https://doi.org/10.1021/acsami.0c11945
  141. C. Castillo-Blas, N. Lopez-Salas, M.C. Gutierrez, I. Puente-Orench, E. Gutierrez-Puebla et al., Encoding metal-cation arrangements in metal-organic frameworks for programming the composition of electrocatalytically active multimetal oxides. J. Am. Chem. Soc. 141(4), 1766–1774 (2019). https://doi.org/10.1021/jacs.8b12860
  142. X. Duan, S. Ren, N. Pan, M. Zhang, H. Zheng, MOF-derived Fe, Co@ N-C bifunctional oxygen electrocatalysts for Zn–air batteries. J. Mater. Chem. A 8(18), 9355–9363 (2020). https://doi.org/10.1039/D0TA02825H
  143. H. Wang, F. Yin, G. Li, B. Chen, Z. Wang, Preparation, characterization and bifunctional catalytic properties of MOF (Fe/Co) catalyst for oxygen reduction/evolution reactions in alkaline electrolyte. Int. J. Hydrog. Energy 39(28), 16179–16186 (2014). https://doi.org/10.1016/j.ijhydene.2013.12.120
  144. L. Li, W. Xie, J. Chen, J. Yang, ZIF-67 derived P/Ni/Co/NC nanoparticles as highly efficient electrocatalyst for oxygen reduction reaction (ORR). J. Solid State Chem. 264, 1–5 (2018). https://doi.org/10.1016/j.jssc.2018.04.035
  145. M. Kuang, Q. Wang, P. Han, G. Zheng, Cu, Co-embedded N-enriched mesoporous carbon for efficient oxygen reduction and hydrogen evolution reactions. Adv. Energy Mater. 7(17), 1700193 (2017). https://doi.org/10.1002/aenm.201700193
  146. X.-F. Lu, L.-F. Gu, J.-W. Wang, J.-X. Wu, P.-Q. Liao et al., Bimetal-organic framework derived CoFe2O4/C Porous hybrid nanorod arrays as high-performance electrocatalysts for oxygen evolution reaction. Adv. Mater. 29(3), 1604437 (2017). https://doi.org/10.1002/adma.201604437
  147. H.B. Wu, X.W.D. Lou, Metal-organic frameworks and their derived materials for electrochemical energy storage and conversion: promises and challenges. Sci Adv (2017). https://doi.org/10.1126/sciadv.aap9252
  148. Y. Yan, T. He, B. Zhao, K. Qi, H. Liu et al., Metal/covalent–organic frameworks-based electrocatalysts for water splitting. J. Mater. Chem. A 6(33), 15905–15926 (2018). https://doi.org/10.1039/C8TA05985C
  149. W. Chen, Y. Zhang, G. Chen, R. Huang, Y. Zhou et al., Mesoporous cobalt–iron–organic frameworks: a plasma-enhanced oxygen evolution electrocatalyst. J. Mater. Chem. A 7(7), 3090–3100 (2019). https://doi.org/10.1039/C8TA10952D
  150. Y.V. Kaneti, J. Tang, R.R. Salunkhe, X. Jiang, A. Yu et al., Nanoarchitectured design of porous materials and nanocomposites from metal-organic frameworks. Adv. Mater. 29(12), 1604898 (2017). https://doi.org/10.1002/adma.201604898
  151. H. Wang, F. Yin, B. Chen, G. Li, Synthesis of an ε-MnO2/metal–organic-framework composite and its electrocatalysis towards oxygen reduction reaction in an alkaline electrolyte. J. Mater. Chem. A 3(31), 16168–16176 (2015). https://doi.org/10.1039/C5TA02244D
  152. E.M. Miner, T. Fukushima, D. Sheberla, L. Sun, Y. Surendranath et al., Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2. Nat. Commun. 7(1), 1–7 (2016). https://doi.org/10.1038/ncomms10942
  153. R.K. Tripathy, A.K. Samantara, J. Behera, A cobalt metal–organic framework (Co-MOF): a bi-functional electro active material for the oxygen evolution and reduction reaction. Dalton Trans. 48(28), 10557–10564 (2019). https://doi.org/10.1039/C9DT01730E
  154. X. Wang, L. Yu, B.Y. Guan, S. Song, X.W. Lou, Metal–organic framework hybrid-assisted formation of Co3O4/Co-Fe oxide double-shelled nanoboxes for enhanced oxygen evolution. Adv. Mater. 30(29), 1801211 (2018). https://doi.org/10.1002/adma.201801211
  155. J. Zhou, Y. Dou, A. Zhou, L. Shu, Y. Chen et al., Layered metal–organic framework-derived metal oxide/carbon nanosheet arrays for catalyzing the oxygen evolution reaction. ACS Energy Lett. 3(7), 1655–1661 (2018). https://doi.org/10.1021/acsenergylett.8b00809
  156. J. Yang, F. Zhang, X. Wang, D. He, G. Wu et al., Porous molybdenum phosphide nano-octahedrons derived from confined phosphorization in UIO-66 for efficient hydrogen evolution. Angew. Chem. Int. Ed. 55(41), 12854–12858 (2016). https://doi.org/10.1002/anie.201604315
  157. X. Liang, D. Zhang, Z. Wu, D. Wang, The Fe-promoted MoP catalyst with high activity for water splitting. Appl. Catal. A 524, 134–138 (2016). https://doi.org/10.1016/j.apcata.2016.06.029
  158. L.-A. Stern, L. Feng, F. Song, X. Hu, Ni2P as a Janus catalyst for water splitting: the oxygen evolution activity of Ni2P nanoparticles. Energy Environ. Sci. 8(8), 2347–2351 (2015). https://doi.org/10.1039/C5EE01155H
  159. E. Hu, Y. Feng, J. Nai, D. Zhao, Y. Hu et al., Construction of hierarchical Ni–Co–P hollow nanobricks with oriented nanosheets for efficient overall water splitting. Energy Environ. Sci. 11(4), 872–880 (2018). https://doi.org/10.1039/C8EE00076J
  160. T. Liu, P. Li, N. Yao, G. Cheng, S. Chen et al., CoP-doped MOF-based electrocatalyst for pH-universal hydrogen evolution reaction. Angew. Chem. Int. Ed. 58(14), 4679–4684 (2019). https://doi.org/10.1002/ange.201901409
  161. Z. Wang, H. Jin, T. Meng, K. Liao, W. Meng et al., Fe, Cu-coordinated ZIF-derived carbon framework for efficient oxygen reduction reaction and zinc-air batteries. Adv. Funct. Mater. 28(39), 1802596 (2018). https://doi.org/10.1002/adfm.201802596
  162. S. Ren, X. Duan, F. Ge, M. Zhang, H. Zheng, Trimetal-based N-doped carbon nanotubes arrays on Ni foams as self-supported electrodes for hydrogen/oxygen evolution reactions and water splitting. J. Power Sources 480, 228866 (2020). https://doi.org/10.1016/j.jpowsour.2020.228866
  163. L. Liao, S. Wang, J. Xiao, X. Bian, Y. Zhang et al., A nanoporous molybdenum carbide nanowire as an electrocatalyst for hydrogen evolution reaction. Energy Environ. Sci. 7(1), 387–392 (2014). https://doi.org/10.1039/C3EE42441C
  164. Y. Du, M. Zhang, Z. Wang, Y. Liu, Y. Liu et al., A self-templating method for metal–organic frameworks to construct multi-shelled bimetallic phosphide hollow microspheres as highly efficient electrocatalysts for hydrogen evolution reaction. J. Mater. Chem. A 7(14), 8602–8608 (2019). https://doi.org/10.1039/C9TA00557A
  165. H.B. Wu, B.Y. Xia, L. Yu, X.Y. Yu, X.W. Lou, Porous molybdenum carbide nano-octahedrons synthesized via confined carburization in metal-organic frameworks for efficient hydrogen production. Nat. Commun. 6(1), 6512 (2015). https://doi.org/10.1038/ncomms7512
  166. T. Wang, Q. Zhou, X. Wang, J. Zheng, X. Li, MOF-derived surface modified Ni nanoparticles as an efficient catalyst for the hydrogen evolution reaction. J. Mater. Chem. A 3(32), 16435–16439 (2015). https://doi.org/10.1039/C5TA04001A
  167. Y. Jiao, Y. Zheng, M. Jaroniec, S.Z. Qiao, Design of electrocatalysts for oxygen-and hydrogen-involving energy conversion reactions. Chem. Soc. Rev. 44(8), 2060–2086 (2015). https://doi.org/10.1039/C4CS00470A
  168. B.Y. Xia, Y. Yan, N. Li, H.B. Wu, X.W.D. Lou et al., A metal–organic framework-derived bifunctional oxygen electrocatalyst. Nat. Energy 1(1), 1–8 (2016). https://doi.org/10.1038/nenergy.2015.6
  169. L. Zhang, X. Wang, R. Wang, M. Hong, Structural evolution from metal–organic framework to hybrids of nitrogen-doped porous carbon and carbon nanotubes for enhanced oxygen reduction activity. Chem. Mater. 27(22), 7610–7618 (2015). https://doi.org/10.1021/acs.chemmater.5b02708
  170. L. Ye, G. Chai, Z. Wen, Zn-MOF-74 derived N-doped mesoporous carbon as pH-universal electrocatalyst for oxygen reduction reaction. Adv. Funct. Mater. 27(14), 1606190 (2017). https://doi.org/10.1002/adfm.201606190
  171. Q. Lai, Y. Zhao, Y. Liang, J. He, J. Chen, In situ confinement pyrolysis transformation of ZIF-8 to nitrogen-enriched meso-microporous carbon frameworks for oxygen reduction. Adv. Funct. Mater. 26(45), 8334–8344 (2016). https://doi.org/10.1002/adfm.201603607
  172. P.-C. Shi, J.-D. Yi, T.-T. Liu, L. Li, L.-J. Zhang et al., Hierarchically porous nitrogen-doped carbon nanotubes derived from core–shell ZnO@ zeolitic imidazolate framework nanorods for highly efficient oxygen reduction reactions. J. Mater. Chem. A 5(24), 12322–12329 (2017). https://doi.org/10.1039/C7TA02999C
  173. L. Zhang, Z. Su, F. Jiang, L. Yang, J. Qian et al., Highly graphitized nitrogen-doped porous carbon nanopolyhedra derived from ZIF-8 nanocrystals as efficient electrocatalysts for oxygen reduction reactions. Nanoscale 6(12), 6590–6602 (2014). https://doi.org/10.1039/C4NR00348A
  174. H. Park, S. Oh, S. Lee, S. Choi, M. Oh, Cobalt-and nitrogen-codoped porous carbon catalyst made from core–shell type hybrid metal–organic framework (ZIF-L@ ZIF-67) and its efficient oxygen reduction reaction (ORR) activity. Appl. Catal. B-Environ. 246, 322–329 (2019). https://doi.org/10.1016/j.apcatb.2019.01.083
  175. L. Zheng, Y. Dong, B. Chi, Z. Cui, Y. Deng et al., UIO-66-NH2-derived mesoporous carbon catalyst Co-doped with Fe/N/S as highly efficient cathode catalyst for PEMFCs. Small 15(4), 1803520 (2019). https://doi.org/10.1002/smll.201803520
  176. S. Li, Z. Jiang, X. Xiao, W. Chen, X. Tian et al., MOF-derived Co nanoparticles embedded in N, S-codoped carbon layer/MWCNTs for efficient oxygen reduction in alkaline media. Ionics 25(2), 785–796 (2019). https://doi.org/10.1007/s11581-018-2775-0
  177. L. Fan, X. Du, Y. Zhang, M. Li, M. Wen et al., N, P-Doped carbon with encapsulated Co nanoparticles as efficient electrocatalysts for oxygen reduction reactions. Dalton Trans. 48(7), 2352–2358 (2019). https://doi.org/10.1039/C8DT04650F
  178. Z. Meng, S. Cai, R. Wang, H. Tang, S. Song et al., Bimetallic− organic framework-derived hierarchically porous Co-Zn-NC as efficient catalyst for acidic oxygen reduction reaction. Appl. Catal. B 244, 120–127 (2019). https://doi.org/10.1016/j.apcatb.2018.11.037
  179. M. Lu, Y. Li, P. He, J. Cong, D. Chen et al., Bimetallic metal-organic framework nanosheets as efficient electrocatalysts for oxygen evolution reaction. J. Solid State Chem. 272, 32–37 (2019). https://doi.org/10.1016/j.jssc.2019.01.023
  180. M. Ding, J. Chen, M. Jiang, X. Zhang, G. Wang, Ultrathin trimetallic metal–organic framework nanosheets for highly efficient oxygen evolution reaction. J. Mater. Chem. A 7(23), 14163–14168 (2019). https://doi.org/10.1039/c9ta00708cr
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