Issue

Vol. 14 (2022)

Elastic Buffering Layer on CuS Enabling High-Rate and Long-Life Sodium-Ion Storage

https://doi.org/10.1007/s40820-022-00924-3
Yuanhua Xiao
Key Laboratory of Surface and Interface Science and Technology, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
Feng Yue
Key Laboratory of Surface and Interface Science and Technology, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
Ziqing Wen
Key Laboratory of Surface and Interface Science and Technology, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
Ya Shen
Key Laboratory of Surface and Interface Science and Technology, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
Dangcheng Su
Key Laboratory of Surface and Interface Science and Technology, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
Huazhang Guo
Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, People’s Republic of China
Xianhong Rui
Institute School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, People’s Republic of China
Liming Zhou
Key Laboratory of Surface and Interface Science and Technology, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
Shaoming Fang
Key Laboratory of Surface and Interface Science and Technology, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
Yan Yu
Hefei National Research Center for Physical Sciences at the Microscale, Department of Materials Science and Engineering, National Synchrotron Radiation Laboratory, CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China. Hefei, Anhui 230026, People’s Republic of China

Corresponding Author: Yan Yu

yanyumse@ustc.edu.cn

Nano-Micro Letters, Vol. 14 (2022), Article Number: 193

Abstract

The latest view suggests the inactive core, surface pulverization, and polysulfide shuttling effect of metal sulfides are responsible for their low capacity and poor cycling performance in sodium-ion batteries (SIBs). Whereas overcoming the above problems based on conventional nanoengineering is not efficient enough. In this work, erythrocyte-like CuS microspheres with an elastic buffering layer of ultrathin polyaniline (PANI) were synthesized through one-step self-assembly growth, followed by in situ polymerization of aniline. When CuS@PANI is used as anode electrode in SIBs, it delivers high capacity, ultrahigh rate capability (500 mAh g−1 at 0.1 A g−1, and 214.5 mAh g−1 at 40 A g−1), and superior cycling life of over 7500 cycles at 20 A g−1. A series of in/ex situ characterization techniques were applied to investigate the structural evolution and sodium-ion storage mechanism. The PANI swollen with electrolyte can stabilize solid electrolyte interface layer, benefit the ion transport/charge transfer at the PANI/electrolyte interface, and restrain the size growth of Cu particles in confined space. Moreover, finite element analyses and density functional simulations confirm that the PANI film effectively buffers the volume expansion, suppresses the surface pulverization, and traps the polysulfide.


Highlights:


1 Erythrocyte-like CuS microspheres were encapsulated in ultrathin polyaniline (PANI) layer coating.
2 PANI swollen by electrolytes stabilizes solid electrolyte interface layer and benefits the ion transport and charge transfer at the PANI/electrolyte interface.
3 Multi-functional PANI coating ensures an outstanding comprehensive performance for sodium-ion storage.

Keywords

CuS Elastic buffering layer Polyaniline Long life Sodium-ion batteries
Xiao, Yuanhua, Feng Yue, Ziqing Wen, Ya Shen, Dangcheng Su, Huazhang Guo, Xianhong Rui, Liming Zhou, Shaoming Fang, and Yan Yu. 2022. “Elastic Buffering Layer on CuS Enabling High-Rate and Long-Life Sodium-Ion Storage”. Nano-Micro Letters 14 (September):193. https://doi.org/10.1007/s40820-022-00924-3.
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. Y. Ding, Z.P. Cano, A. Yu, J. Lu, Z. Chen, Automotive Li-ion batteries: current status and future perspectives. Electrochem. Energy Rev. 2, 1–28 (2019). https://doi.org/10.1007/s41918-018-0022-z
  2. J. Yang, Z. Ju, Y. Jiang, Z. Xing, B. Xi et al., Enhanced capacity and rate capability of nitrogen/oxygen dual-doped hard carbon in capacitive potassium-ion storage. Adv. Mater. 30(4), 1700104 (2018). https://doi.org/10.1002/adma.201700104
  3. Q. Wei, Q. Li, Y. Jiang, Y. Zhao, S. Tan et al., High-energy and high-power pseudocapacitor–battery hybrid sodium-ion capacitor with Na+ intercalation pseudocapacitance anode. Nano-Micro Lett. 13, 55 (2021). https://doi.org/10.1007/s40820-020-00567-2
  4. Q. Wei, R.H. DeBlock, D.M. Butts, C. Choi, B. Dunn, Pseudocapacitive vanadium-based materials toward high-rate sodium-ion storage. Energy Environ. Mater. 3(3), 221–234 (2020). https://doi.org/10.1002/eem2.12131
  5. F. Xie, Z. Xu, Z. Guo, M.M. Titirici, Hard carbons for sodium-ion batteries and beyond. Prog. Energy 2(4), 042002 (2020). https://doi.org/10.1088/2516-1083/aba5f5
  6. Y. Lan, W. Yao, X. He, T. Song, Y. Tang, Mixed polyanionic compounds as positive electrodes for low-cost electrochemical energy storage. Angew. Chem. Int. Ed. 59(24), 9255–9262 (2020). https://doi.org/10.1002/anie.201915666
  7. J. Yang, S. Xiao, X. Cui, W. Dai, X. Lian et al., Inorganic-anion-modulated synthesis of 2D nonlayered aluminum-based metal-organic frameworks as carbon precursor for capacitive sodium ion storage. Energy Storage Mater. 26, 391–399 (2020). https://doi.org/10.1016/j.ensm.2019.11.010
  8. J. Yang, X. Wang, W. Dai, X. Lian, X. Cui et al., From micropores to ultra-micropores inside hard carbon: toward enhanced capacity in room-/low-temperature sodium-ion storage. Nano-Micro Lett. 13, 98 (2021). https://doi.org/10.1007/s40820-020-00587-y
  9. Y. Xiao, S.H. Lee, Y.K. Sun, The application of metal sulfides in sodium ion batteries. Adv. Energy Mater. 7(3), 1601329 (2017). https://doi.org/10.1002/aenm.201601329
  10. Y. Xiao, X. Zhao, X. Wang, D. Su, S. Bai et al., A nanosheet array of Cu2Se intercalation compound with expanded interlayer space for sodium ion storage. Adv. Energy Mater. 10(25), 2000666 (2020). https://doi.org/10.1002/aenm.202000666
  11. Z. Li, Y. Zhang, X. Li, F. Gu, L. Zhang et al., Reacquainting the electrochemical conversion mechanism of FeS2 sodium-ion batteries by operando magnetometry. J. Am. Chem. Soc. 143(32), 12800–12808 (2021). https://doi.org/10.1021/jacs.1c06115
  12. H. Geng, Y. Peng, L. Qu, H. Zhang, M. Wu, Structure design and composition engineering of carbon-based nanomaterials for lithium energy storage. Adv. Energy Mater. 10(10), 1903030 (2020). https://doi.org/10.1002/aenm.201903030
  13. X.Y. Yu, L. Yu, X.W. Lou, Metal sulfide hollow nanostructures for electrochemical energy storage. Adv. Energy Mater. 6(3), 1501333 (2016). https://doi.org/10.1002/aenm.201501333
  14. Y. Xiao, Z. Xu, Y. Liu, L. Peng, J. Xi et al., Sheet collapsing approach for rubber-like graphene papers. ACS Nano 11(8), 8092–8102 (2017). https://doi.org/10.1021/acsnano.7b02915
  15. S. Güryel, B. Hajgató, Y. Dauphin, J.M. Blairon, H.E. Miltner et al., Effect of structural defects and chemical functionalisation on the intrinsic mechanical properties of graphene. Phys. Chem. Chem. Phys. 15(2), 659–665 (2013). https://doi.org/10.1039/C2CP43033A
  16. Z. Zhang, X. Zhang, Y. Wang, Y. Wang, Y. Zhang et al., Crack propagation and fracture toughness of graphene probed by Raman spectroscopy. ACS Nano 13(9), 10327–10332 (2019). https://doi.org/10.1021/acsnano.9b03999
  17. P. Li, K. Sun, J. Ouyang, Stretchable and conductive polymer films prepared by solution blending. ACS Appl. Mater. Interfaces 7(33), 18415–18423 (2015). https://doi.org/10.1021/acsami.5b04492
  18. G. Kalimuldina, A. Nurpeissova, A. Adylkhanova, D. Adair, I. Taniguchi et al., Morphology and dimension variations of copper sulfide for high-performance electrode in rechargeable batteries: a review. ACS Appl. Energy Mater. 3(12), 11480–11499 (2020). https://doi.org/10.1021/acsaem.0c01686
  19. N. Yamakawa, M. Jiang, C.P. Grey, Investigation of the conversion reaction mechanisms for binary copper(II) compounds by solid-state NMR spectroscopy and X-ray diffraction. Chem. Mater. 21(14), 3162–3176 (2009). https://doi.org/10.1021/cm900581b
  20. A. Kitani, M. Kaya, S.I. Tsujioka, K. Sasaki, Flexible polyaniline. J. Polym. Sci. A Polym. Chem. 26(6), 1531–1539 (1988). https://doi.org/10.1002/pola.1988.080260604
  21. P. Kumar, M. Gusain, R. Nagarajan, Synthesis of Cu1.8S and CuS from copper-thiourea containing precursors; anionic (Cl−, NO3−, SO42−) influence on the product stoichiometry. Inorg. Chem. 50(7), 3065–3070 (2011). https://doi.org/10.1021/ic102593h
  22. C. Wu, S.H. Yu, M. Antonietti, Complex concaved cuboctahedrons of copper sulfide crystals with highly geometrical symmetry created by a solution process. Chem. Mater. 18(16), 3599–3601 (2006). https://doi.org/10.1021/cm060956u
  23. S. Wang, S. Jiao, J. Wang, H.S. Chen, D. Tian et al., High-performance aluminum-ion battery with CuS@C microsphere composite cathode. ACS Nano 11(1), 469–477 (2017). https://doi.org/10.1021/acsnano.6b06446
  24. M. Ye, X. Wen, N. Zhang, W. Guo, X.Y. Liu et al., In situ growth of CuS and Cu1.8S nanosheet arrays as efficient counter electrodes for quantum dot-sensitized solar cells. J. Mater. Chem. A 3(18), 9595–9600 (2015). https://doi.org/10.1039/C5TA00390C
  25. L. An, P. Zhou, J. Yin, H. Liu, F. Chen et al., Phase transformation fabrication of a Cu2S nanoplate as an efficient catalyst for water oxidation with glycine. Inorg. Chem. 54(7), 3281–3289 (2015). https://doi.org/10.1021/ic502920r
  26. Y. Situ, W. Ji, C. Liu, J. Xu, H. Huang, Synergistic effect of homogeneously dispersed PANI-TiN nanocomposites towards long-term anticorrosive performance of epoxy coatings. Prog. Org. Coat. 130, 158–167 (2019). https://doi.org/10.1016/j.porgcoat.2019.01.034
  27. K. Chen, G. Zhang, L. Xiao, P. Li, W. Li et al., Polyaniline encapsulated amorphous V2O5 nanowire-modified multi-functional separators for lithium–sulfur batteries. Small Methods 5(3), 2001056 (2021). https://doi.org/10.1002/smtd.202001056
  28. M.S. Dopico-García, A. Ares, A. Lasagabáster-Latorre, X. García, L. Arboleda et al., Extruded polyaniline/EVA blends: enhancing electrical conductivity using gallate compatibilizers. Synth. Met. 189, 193–202 (2014). https://doi.org/10.1016/j.synthmet.2014.01.009
  29. J. Kang, H. Sahin, F.M. Peeters, Mechanical properties of monolayer sulphides: a comparative study between MoS2, HfS2 and TiS3. Phys. Chem. Chem. Phys. 17(41), 27742–27749 (2015). https://doi.org/10.1039/C5CP04576B
  30. S.U. Rehman, F.K. Butt, B.U. Haq, S. AlFaify, W.S. Khan et al., Exploring novel phase of tin sulfide for photon/energy harvesting materials. Sol. Energy 169, 648–657 (2018). https://doi.org/10.1016/j.solener.2018.05.006
  31. A. Roldan, D. Santos-Carballal, N.H. Leeuw, A comparative DFT study of the mechanical and electronic properties of greigite Fe3S4 and magnetite Fe3O4. J. Chem. Phys. 138(20), 204712 (2013). https://doi.org/10.1063/1.4807614
  32. R. Garcia-Mendez, J.G. Smith, J.C. Neuefeind, D.J. Siegel, J. Sakamoto, Correlating macro and atomic structure with elastic properties and ionic transport of glassy Li2S-P2S5 (LPS) solid electrolyte for solid-state Li metal batteries. Adv. Energy Mater. 10(19), 2000335 (2020). https://doi.org/10.1002/aenm.202000335
  33. M.F. Yu, O. Lourie, M.J. Dyer, K. Moloni, T.F. Kelly et al., Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load. Science 287(5453), 637–640 (2000). https://doi.org/10.1126/science.287.5453.637
  34. J.M. Sansiñena, J. Gao, H.L. Wang, High-performance, monolithic polyaniline electrochemical actuators. Adv. Funct. Mater. 13(9), 703–709 (2003). https://doi.org/10.1002/adfm.200304347
  35. A. Makradi, S. Ahzi, R.V. Gregory, Modeling of the mechanical response and evolution of optical anisotropy in deformed polyaniline. Polym. Eng. Sci. 40(7), 1716–1723 (2000). https://doi.org/10.1002/pen.11303
  36. J.N. Pereira, P. Vieira, A. Ferreira, A.J. Paleo, J.G. Rocha et al., Piezoresistive effect in spin-coated polyaniline thin films. J. Polym. Res. 19(2), 9815 (2012). https://doi.org/10.1007/s10965-011-9815-z
  37. H. Valentová, J. Stejskal, Mechanical properties of polyaniline. Synth. Met. 160(7), 832–834 (2010). https://doi.org/10.1016/j.synthmet.2010.01.007
  38. W. Li, K. Cao, H. Wang, J. Liu, L. Zhou et al., Carbon coating may expedite the fracture of carbon-coated silicon core–shell nanops during lithiation. Nanoscale 8(9), 5254–5259 (2016). https://doi.org/10.1039/C5NR08498A
  39. Z.F. Li, E.T. Kang, K.G. Neoh, K.L. Tan, Effect of thermal processing conditions on the intrinsic oxidation states and mechanical properties of polyaniline films. Synth. Met. 87(1), 45–52 (1997). https://doi.org/10.1016/S0379-6779(97)80096-3
  40. H.M. Xiao, W.D. Zhang, C. Lv, S.Y. Fu, M.X. Wan et al., Large enhancement in conductivity of polyaniline films by cold stretching. Macromol. Chem. Phys. 211(10), 1109–1116 (2010). https://doi.org/10.1002/macp.200900711
  41. W. Tan, J.C. Stallard, C. Jo, M.F.L.D. Volder, N.A. Fleck, The mechanical and electrochemical properties of polyaniline-coated carbon nanotube mat. J. Energy Storage 41, 102757 (2021). https://doi.org/10.1016/j.est.2021.102757
  42. H. Li, Y. Wang, J. Jiang, Y. Zhang, Y. Peng et al., CuS microspheres as high-performance anode material for Na-ion batteries. Electrochim. Acta 247, 851–859 (2017). https://doi.org/10.1016/j.electacta.2017.07.018
  43. R. Liu, Y. Zhang, D. Wang, L. Xu, S. Luo et al., Microwave-assisted synthesis of self-assembled camellia-like CuS superstructure of ultra-thin nanosheets and exploration of its sodium ion storage properties. J. Electroanal. Chem. 898, 115607 (2021). https://doi.org/10.1016/j.jelechem.2021.115607
  44. Z. Hu, Q. Liu, S. Chou, S. Dou, Advances and challenges in metal sulfides/selenides for next-generation rechargeable sodium-ion batteries. Adv. Mater. 29(48), 1700606 (2017). https://doi.org/10.1002/adma.201700606
  45. Y. Fang, B.Y. Guan, D. Luan, X.W.D. Lou, Synthesis of CuS@CoS2 double-shelled nanoboxes with enhanced sodium storage properties. Angew. Chem. Int. Ed. 58(23), 7739–7743 (2019). https://doi.org/10.1002/anie.201902583
  46. D. Zhao, M. Yin, C. Feng, K. Zhan, Q. Jiao et al., Rational design of N-doped CuS@C nanowires toward high-performance half/full sodium-ion batteries. ACS Sustain. Chem. Eng. 8(30), 11317–11327 (2020). https://doi.org/10.1021/acssuschemeng.0c03273
  47. Z. Yang, Z. Wu, J. Liu, Y. Liu, S. Gao et al., Platelet-like CuS impregnated with twin crystal structures for high performance sodium-ion storage. J. Mater. Chem. A 8(16), 8049–8057 (2020). https://doi.org/10.1039/d0ta00763c
  48. L. Zhang, Y. Hu, Y. Liu, J. Bai, H. Ruan et al., Tunable CuS nanocables with hierarchical nanosheet-assembly for ultrafast and long-cycle life sodium-ion storage. Ceram Int. 47(10), 14138–14145 (2021). https://doi.org/10.1016/j.ceramint.2021.01.284
  49. Z.G. Yang, Z.G. Wu, W.B. Hua, Y. Xiao, G.K. Wang et al., Hydrangea-like CuS with irreversible amorphization transition for high-performance sodium-ion storage. Adv. Sci. 7(11), 1903279 (2020). https://doi.org/10.1002/advs.201903279
  50. Y. Xiao, D. Su, X. Wang, S. Wu, L. Zhou et al., CuS microspheres with tunable interlayer space and micropore as a high-rate and long-life anode for sodium-ion batteries. Adv. Energy Mater. 8(22), 1800930 (2018). https://doi.org/10.1002/aenm.201800930
  51. Y. Hu, L. Zhang, J. Bai, F. Liu, Z. Wang et al., Boosting high-rate sodium storage of CuS via a hollow spherical nanostructure and surface pseudocapacitive behavior. ACS Appl. Energy Mater. 4(9), 8901–8909 (2021). https://doi.org/10.1021/acsaem.1c01103
  52. C. An, Y. Ni, Z. Wang, X. Li, X. Liu, Facile fabrication of CuS microflower as a highly durable sodium-ion battery anode. Inorg. Chem. Front. 5(5), 1045–1052 (2018). https://doi.org/10.1039/c8qi00117k
  53. W. Zhao, L. Gao, L. Yue, X. Wang, Q. Liu et al., Constructing a hollow microflower-like ZnS/CuS@C heterojunction as an effective ion-transport booster for an ultrastable and high-rate sodium storage anode. J. Mater. Chem. A 9(10), 6402–6412 (2021). https://doi.org/10.1039/d1ta00497b
  54. W. Zhao, X. Wang, X. Ma, L. Yue, Q. Liu et al., In situ tailoring bimetallic–organic framework-derived yolk–shell NiS2/CuS hollow microspheres: an extraordinary kinetically pseudocapacitive nanoreactor for an effective sodium-ion storage anode. J. Mater. Chem. A 9(28), 15807–15819 (2021). https://doi.org/10.1039/d1ta04386b
  55. J.S. Chung, H.J. Sohn, Electrochemical behaviors of CuS as a cathode material for lithium secondary batteries. J. Power Sources 108(1–2), 226–231 (2002). https://doi.org/10.1016/S0378-7753(02)00024-1
  56. Y. Zhang, P. Zhu, L. Huang, J. Xie, S. Zhang et al., Few-layered SnS2 on few-layered reduced graphene oxide as na-ion battery anode with ultralong cycle life and superior rate capability. Adv. Funct. Mater. 25(3), 481–489 (2015). https://doi.org/10.1002/adfm.201402833
  57. M.M. Sung, K. Sung, C.G. Kim, S.S. Lee, Y. Kim, Self-assembled monolayers of alkanethiols on oxidized copper surfaces. J. Phys. Chem. B 104(10), 2273–2277 (2000). https://doi.org/10.1021/jp992995h
  58. X. Liang, C. Hart, Q. Pang, A. Garsuch, T. Weiss et al., A highly efficient polysulfide mediator for lithium–sulfur batteries. Nat. Commun. 6, 5682 (2015). https://doi.org/10.1038/ncomms6682
  59. C.D. Wagner, Handbook of X-ray Photoelectron Spectroscopy. (Perkin-Elmer Corporation, 1979).
  60. S. Deng, Y. Shen, D. Xie, Y. Lu, X. Yu et al., Directional construction of Cu2S branch arrays for advanced oxygen evolution reaction. J. Energy Chem. 39, 61–67 (2019). https://doi.org/10.1016/j.jechem.2019.01.014
  61. M. Fantauzzi, B. Elsener, D. Atzei, A. Rigoldi, A. Rossi, Exploiting XPS for the identification of sulfides and polysulfides. RSC Adv. 5(93), 75953–75963 (2015). https://doi.org/10.1039/C5RA14915K
  62. X. Yu, A. Manthiram, Room-temperature sodium–sulfur batteries with liquid-phase sodium polysulfide catholytes and binder-free multiwall carbon nanotube fabric electrodes. J. Phys. Chem. C 118(40), 22952–22959 (2014). https://doi.org/10.1021/jp507655u
  63. M. Hu, Z. Ju, Z. Bai, K. Yu, Z. Fang et al., Revealing the critical factor in metal sulfide anode performance in sodium-ion batteries: an investigation of polysulfide shuttling issues. Small Methods 4(1), 1900673 (2020). https://doi.org/10.1002/smtd.201900673
  64. H. Jin, S. Xin, C. Chuang, W. Li, H. Wang et al., Black phosphorus composites with engineered interfaces for high-rate high-capacity lithium storage. Science 370(6513), 192–197 (2020). https://doi.org/10.1126/science.aav5842
  65. F. Song, J. Hu, G. Li, J. Wang, S. Chen et al., Room-temperature assembled MXene-based aerogels for high mass-loading sodium-ion storage. Nano-Micro Lett. 14, 37 (2021). https://doi.org/10.1007/s40820-021-00781-6
  66. N. Kurra, M. Alhabeb, K. Maleski, C.H. Wang, H.N. Alshareef et al., Bistacked titanium carbide (MXene) anodes for hybrid sodium-ion capacitors. ACS Energy Lett. 3(9), 2094–2100 (2018). https://doi.org/10.1021/acsenergylett.8b01062
  67. R. Ding, L. Qi, H. Wang, An investigation of spinel NiCo2O4 as anode for Na-ion capacitors. Electrochim. Acta 114, 726–735 (2013). https://doi.org/10.1016/j.electacta.2013.10.113
  68. J. Yin, L. Qi, H. Wang, Sodium titanate nanotubes as negative electrode materials for sodium-ion capacitors. ACS Appl. Mater. Interfaces 4(5), 2762–2768 (2012). https://doi.org/10.1021/am300385r
Read More
Author biographies are not available.
Download this PDF file
PDF SUPPLEMENTARY MATERIAL
Statistic
Read Counter : 3548 Download : 2669

Most read articles by the same author(s)