Issue

Vol. 12 (2020)

Enhanced Pseudo-Capacitive Contributions to High-Performance Sodium Storage in TiO2/C Nanofibers via Double Effects of Sulfur Modification

https://doi.org/10.1007/s40820-020-00506-1
Yan Zhang
Max Planck Institute for Solid State Research, Stuttgart 70569, Germany
Yuanye Huang
Max Planck Institute for Solid State Research, Stuttgart 70569, Germany
Vesna Srot
Max Planck Institute for Solid State Research, Stuttgart 70569, Germany
Peter A. van Aken
Max Planck Institute for Solid State Research, Stuttgart 70569, Germany
Joachim Maier
Max Planck Institute for Solid State Research, Stuttgart 70569, Germany
Yan Yu
Hefei National Laboratory for Physical Sciences at the Microscale, Department of Materials Science and Engineering, Key Laboratory of Materials for Energy Conversion, Chinese Academy of Sciences (CAS), University of Science and Technology of China, Hefei 230026, Anhui, People’s Republic of China

Corresponding Author: Yan Yu

yanyumse@ustc.edu.cn

Nano-Micro Letters, Vol. 12 (2020), Article Number: 165

Abstract

Pseudo-capacitive mechanisms can provide higher energy densities than electrical double-layer capacitors while being faster than bulk storage mechanisms. Usually, they suffer from low intrinsic electronic and ion conductivities of the active materials. Here, taking advantage of the combination of TiS2 decoration, sulfur doping, and a nanometer-sized structure, as-spun TiO2/C nanofiber composites are developed that enable rapid transport of sodium ions and electrons, and exhibit enhanced pseudo-capacitively dominated capacities. At a scan rate of 0.5 mV s−1, a high pseudo-capacitive contribution (76% of the total storage) is obtained for the S-doped TiS2/TiO2/C electrode (termed as TiS2/S-TiO2/C). Such enhanced pseudo-capacitive activity allows rapid chemical kinetics and significantly improves the high-rate sodium storage performance of TiO2. The TiS2/S-TiO2/C composite electrode delivers a high capacity of 114 mAh g−1 at a current density of 5000 mA g−1. The capacity maintains at high level (161 mAh g−1) even after 1500 cycles and is still characterized by 58 mAh g−1 at the extreme condition of 10,000 mA g−1 after 10,000 cycles.


Highlights:


1 One-dimensional elongated TiS2-modified and S-doped TiO2/C nanofibers electrode was synthesized through electrospinning, which exhibited a high specific capacity, excellent cyclic stability, and rate capability in sodium-ion battery.
2 An enhanced pseudo-capacitive capacity because of S doping and TiS2 decoration contributes to noticeable sodium storage performance. High capacity of 161 mAh g−1 (at 3000 mA g−1) after 1500 cycles and 58 mAh g−1 (at 10,000 mA g−1) after 10,000 cycles is delivered outstandingly.

Keywords

Sodium-ion battery Pseudo-capacitive Anodes TiO2/C nanofibers Sulfur doped
Zhang, Yan, Yuanye Huang, Vesna Srot, Peter A. van Aken, Joachim Maier, and Yan Yu. 2020. “Enhanced Pseudo-Capacitive Contributions to High-Performance Sodium Storage in TiO2/C Nanofibers via Double Effects of Sulfur Modification”. Nano-Micro Letters 12 (August):165. https://doi.org/10.1007/s40820-020-00506-1.
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. B. Dunn, H. Kamath, J. Tarascon, Electrical energy storage for the grid: a battery of choices. Science 334(6058), 928–935 (2011). https://doi.org/10.1126/science.1212741
  2. M.S. Islam, C.A.J. Fisher, Lithium and sodium battery cathode materials: computational insights into voltage, diffusion and nanostructural properties. Chem. Soc. Rev. 43(1), 185–204 (2014). https://doi.org/10.1039/C3CS60199D
  3. J. Deng, W. Luo, S. Chou, H. Liu, S. Dou, Sodium-ion batteries: from academic research to practical commercialization. Adv. Energy Mater. 8(4), 1701428 (2017). https://doi.org/10.1002/aenm.201701428
  4. W. Luo, F. Shen, C. Bommier, H. Zhu, X. Ji, L. Hu, Na-ion battery anodes: materials and electrochemistry. Acc. Chem. Res. 49(2), 231–240 (2016). https://doi.org/10.1021/acs.accounts.5b00482
  5. M. Doeff, Y. Ma, S. Visco, L. De Jonghe, Electrochemical insertion of sodium into carbon. J. Electrochem. Soc. 140(12), L169–L170 (1993). https://doi.org/10.1149/1.2221153
  6. H. Tao, L. Xiong, S. Du, Y. Zhang, X. Yang, L. Zhang, Interwoven N and P dual-doped hollow carbon fibers/graphitic carbon nitride: an ultrahigh capacity and rate anode for Li and Na ion batteries. Carbon 122, 54–63 (2017). https://doi.org/10.1016/j.carbon.2017.06.040
  7. W. Luo, Y. Wang, L. Wang, W. Jiang, S. Chou et al., Silicon/mesoporous carbon/crystalline TiO2 nanoparticles for highly stable lithium storage. ACS Nano 10(11), 10524–10532 (2016). https://doi.org/10.1002/acsnano.6b06517
  8. Y. Cao, L. Xiao, M. Sushko, W. Wang, B. Schwenzer et al., Sodium ion insertion in hollow carbon nanowires for battery applications. Nano Lett. 12(7), 3783–3787 (2012). https://doi.org/10.1021/nl3016957
  9. H. Hou, L. Shao, Y. Zhang, G. Zou, J. Chen, X. Ji, Large-area carbon nanosheets doped with phosphorus: a high-performance anode material for sodium-ion batteries. Adv. Sci. 4(1), 1600243 (2016). https://doi.org/10.1002/advs.201600243
  10. W. Hong, Y. Zhang, L. Yang, Y. Tian, P. Ge et al., Carbon quantum dot micelles tailored hollow carbon anode for fast potassium and sodium storage. Nano Energy 65, 104038 (2019). https://doi.org/10.1016/j.nanoen.2019.104038
  11. H. Hou, C. Banks, M. Jing, Y. Zhang, X. Ji, Carbon quantum dots and their derivative 3D porous carbon frameworks for sodium-ion batteries with ultralong cycle life. Adv. Mater. 27(47), 7861–7866 (2015). https://doi.org/10.1002/adma.201503816
  12. T. Wu, C. Zhang, G. Zou, J. Hu, L. Zhu et al., The bond evolution mechanism of covalent sulfurized carbon during electrochemical sodium storage process. Sci. China Mater. 62(8), 1127–1138 (2019). https://doi.org/10.1007/s40843-019-9418-8
  13. W. Wang, Y. Liu, X. Wu, J. Wang, L. Fu et al., Advances of TiO2 as negative electrode materials for sodium-ion batteries. Adv. Mater. Technol. 3(9), 1800004 (2018). https://doi.org/10.1002/admt.201800004
  14. Y. Zhang, Z. Ding, W. Christopher, C. Banks, X. Qiu, X. Ji, Oxygen vacancies evoked blue TiO2(B) nanobelts with efficiency enhancement in sodium storage behaviors. Adv. Funct. Mater. 27(27), 1700856 (2017). https://doi.org/10.1002/adfm.201700856
  15. B. Wang, F. Zhao, G. Du, S. Porter, Y. Liu et al., Boron-doped anatase TiO2 as a high-performance anode material for sodium-ion batteries. ACS Appl. Mater. Interfaces 8(25), 16009–16015 (2016). https://doi.org/10.1021/acsami.6b03270
  16. Y. Zhang, C. Wang, H. Hou, G. Zou, X. Ji, Nitrogen doped/carbon tuning yolk-like TiO2 and its remarkable impact on sodium storage performances. Adv. Energy Mater. 7(4), 1600173 (2016). https://doi.org/10.1002/aenm.201600173
  17. M. Lukatskaya, S. Kota, Z. Lin, M. Zhao, N. Shpigel et al., Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides. Nat. Energy 2, 17105 (2017). https://doi.org/10.1038/nenergy.2017.105
  18. H. Xiong, M. Slater, M. Balasubramanian, C. Johnson, T. Rajh, Amorphous TiO2 nanotube anode for rechargeable sodium ion batteries. J. Phys. Chem. Lett. 2(20), 2560–2565 (2011). https://doi.org/10.1021/jz2012066
  19. C. Chen, Y. Wen, X. Hu, X. Ji, M. Yan et al., Na+ intercalation pseudocapacitance in graphene-coupled titanium oxide enabling ultra-fast sodium storage and long-term cycling. Nat. Commun. 6, 6929 (2015). https://doi.org/10.1038/ncomms7929
  20. H. Zhang, Y. Jiang, Z. Qi, X. Zhong, Y. Yu, Sulfur doped ultra-thin anatase TiO2 nanosheets/graphene nanocomposite for high-performance pseudocapacitive sodium storage. Energy Storage Mater. 12, 37–43 (2018). https://doi.org/10.1016/j.ensm.2017.11.008
  21. Z. Le, F. Liu, P. Nie, X. Li, X. Liu et al., Pseudocapacitive sodium storage in mesoporous single-crystal-like TiO2-graphene nanocomposite enables high-performance sodium-ion capacitors. ACS Nano 11(3), 2952–2960 (2017). https://doi.org/10.1021/acsnano.6b08332
  22. J. Kang, S. Zhang, Z. Zhang, Three-dimensional binder-free nanoarchitectures for advanced pseudocapacitors. Adv. Mater. 29(48), 1700515 (2017). https://doi.org/10.1002/adma.201700515
  23. Y. Zhang, H. Tao, S. Du, X. Yang, Conversion of MoS2 to a ternary MoS2–xSex alloy for high-performance sodium-ion batteries. ACS Appl. Mater. Interfaces. 11(12), 11327–11337 (2019). https://doi.org/10.1021/acsami.8b19701
  24. D. Winn, J. Shemilt, B. Steele, Titanium disulphide: a solid solution electrode for sodium and lithium. Mater. Res. Bull. 11(5), 559–566 (1976). https://doi.org/10.1016/0025-5408(76)90239-7
  25. G. Newman, L. Klemann, Ambient-temperature cycling of an Na-TiS2 cell. J. Electrochem. Soc. 127(10), 2097–2099 (1980). https://doi.org/10.1149/1.2129353
  26. L. Conroy, K. Park, Electrical properties of group IV disulfides TiS2, ZrS2, HfS2, and SnS2. Inorg. Chem. 7(3), 459–463 (1968). https://doi.org/10.1021/ic50061a015
  27. M. Dresselhaus, I. Thomas, Alternative energy technologies. Nature 414, 332–337 (2001). https://doi.org/10.1038/35104599
  28. J. Trevey, C. Stoldt, S. Lee, High power nanocomposite TiS2 cathodes for all-solid-state lithium batteries. J. Electrochem. Soc. 158(12), A1282–A1289 (2011). https://doi.org/10.1149/2.017112jes
  29. A. Let, D. Mainwaring, C. Rix, P. Murugaraj, Thio sol–gel synthesis of titanium disulfide thin films and powders using titanium alkoxide precursors. J. Non-Cryst. Solids 354(15), 1801–1807 (2008). https://doi.org/10.1016/j.jnoncrysol.2007.09.005
  30. A. Huckaba, S. Gharibzadeh, M. Ralaiarisoa, C. Roldán-Carmona, N. Mohammadian et al., Low-cost TiS2 as hole-transport material for perovskite solar cells. Small Methods 1(10), 1700250 (2017). https://doi.org/10.1002/smtd.201700250
  31. A. Huckaba, M. Ralaiarisoa, K. Cho, E. Oveisi, N. Koch, M. Nazeeruddin, Intercalation makes the difference with TiS2: boosting electrocatalytic water oxidation activity through co intercalation. J. Mater. Res. 33(5), 528–537 (2017). https://doi.org/10.1557/jmr.2017.431
  32. J. Ni, S. Fu, C. Wu, J. Maier, Y. Yu, L. Li, Self-supported nanotube arrays of sulfur-doped TiO2 enabling ultrastable and robust sodium storage. Adv. Mater. 28(11), 2259–2265 (2016). https://doi.org/10.1002/adma.201504412
  33. C. McManamon, J. O’Connell, P. Delaney, S. Rasappa, J.D. Holmes, M.A. Morris, A facile route to synthesis of S-doped TiO2 nanoparticles for photocatalytic activity. J. Mol. Catal. A: Chem. 406, 51–57 (2015). https://doi.org/10.1016/j.molcata.2015.05.002
  34. L.G. Devi, R. Kavitha, Enhanced photocatalytic activity of sulfur doped TiO2 for the decomposition of phenol: a new insight into the bulk and surface modification. Mater. Chem. Phys. 143(3), 1300–1308 (2014). https://doi.org/10.1016/j.matchemphys.2013.11.038
  35. S. Laruelle, S. Grugeon, P. Poizot, M. Dolle, L. Dupont, J.M. Tarascon, On the origin of the extra electrochemical capacity displayed by mo/li cells at low potential. J. Electrochem. Soc. 149(5), A627–A634 (2002). https://doi.org/10.1149/1.1467947
  36. Y. Liu, H. Wang, L. Cheng, N. Han, F. Zhao et al., TiS2 nanoplates: a high-rate and stable electrode material for sodium ion batteries. Nano Energy 20, 168–175 (2016). https://doi.org/10.1016/j.nanoen.2015.12.028
  37. L. Wu, D. Bresser, D. Buchholz, A.G. Guinevere, R.C. Claudia, A. Ochel, S. Passerini, Unfolding the mechanism of sodium insertion in anatase TiO2 nanoparticles. Adv. Energy Mater. 5(2), 1401142 (2014). https://doi.org/10.1002/aenm.201401142
  38. K. Lan, Y. Liu, W. Zhang, Y. Liu, A. Elzatahry et al., Uniform ordered two-dimensional mesoporous TiO2 nanosheets from hydrothermal-induced solvent-confined monomicelle assembly. J. Am. Chem. Soc. 140(11), 4135–4143 (2018). https://doi.org/10.1021/jacs.8b00909
  39. M. Tahir, B. Oschmann, D. Buchholz, X. Dou, I. Lieberwirth et al., Extraordinary performance of carbon-coated anatase TiO2 as sodium-ion anode. Adv. Energy Mater. 6(4), 1501489 (2015). https://doi.org/10.1002/aenm.201501489
  40. H. Lindström, S. Södergren, A. Solbrand, H. Rensmo, J. Hjelm, A. Hagfeldt, S.-E. Lindquist, Li+ ion insertion in TiO2 (anatase). 2. Voltammetry on nanoporous films. J. Phys. Chem. B 101(39), 7717–7722 (1997). https://doi.org/10.1021/jp970490q
  41. V. Augustyn, J. Come, M.A. Lowe, J.W. Kim, P.-L. Taberna et al., High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance. Nat. Mater. 12, 518–522 (2013). https://doi.org/10.1038/nmat3601
  42. K. Brezesinski, J. Wang, J. Haetge, C. Reitz, S.O. Steinmueller et al., Pseudocapacitive contributions to charge storage in highly ordered mesoporous group V transition metal oxides with iso-oriented layered nanocrystalline domains. J. Am. Chem. Soc. 132(20), 6982–6990 (2010). https://doi.org/10.1021/ja9106385
  43. C. Zhao, C. Yu, M. Zhang, H. Huang, S. Li et al., Ultrafine MoO2-carbon microstructures enable ultralong-life power-type sodium ion storage by enhanced pseudocapacitance. Adv. Energy Mater. 7(15), 1602880 (2017). https://doi.org/10.1002/aenm.201602880
  44. L. Que, F. Yu, Z. Wang, D. Gu, Pseudocapacitance of TiO2−x/CNT anodes for high-performance quasi-solid-state li-ion and na-ion capacitors. Small 14(17), 1704508 (2018). https://doi.org/10.1002/smll.201704508
  45. T. Brezesinski, J. Wang, J. Polleux, B. Dunn, S.H. Tolbert, Templated nanocrystal-based porous TiO2 films for next-generation electrochemical capacitors. J. Am. Chem. Soc. 131(5), 1802–1809 (2009). https://doi.org/10.1021/ja8057309
  46. Y. Xiong, J. Ian, Y. Cao, X. Ai, H. Yang, Electrospun TiO2/C nanofibers as a high-capacity and cycle-stable anode for sodium-ion batteries. ACS Appl. Mater. Interfaces 8(26), 16684–16689 (2016). https://doi.org/10.1021/acsami.6b03757
  47. Y. Wu, X. Liu, Z. Yang, L. Gu, Y. Yu, Nitrogen-doped ordered mesoporous anatase TiO2 nanofibers as anode materials for high performance sodium-ion batteries. Small 12(26), 3522–3529 (2016). https://doi.org/10.1002/smll.201600606
  48. Q. Zhao, R. Bi, J. Cui, X. Yang, L. Zhang, TiO2–x nanocages anchored in N-doped carbon fiber films as a flexible anode for high-energy sodium-ion batteries. ACS Appl. Energy Mater. 1(9), 4459–4466 (2018). https://doi.org/10.1021/acsaem.8b00985
  49. N. Lee, J. Jung, J. Lee, H. Jang, I.D. Kim, W.H. Ryu, Facile and fast na-ion intercalation employing amorphous black TiO2-x/C composite nanofiber anodes. Electrochim. Acta 263, 417–425 (2018). https://doi.org/10.1016/j.electacta.2018.01.085
Read More
Author biographies are not available.
Download this PDF file
PDF SUPPLEMENTARY MATERIAL
Statistic
Read Counter : 7144 Download : 5399

Most read articles by the same author(s)

1 2 > >>