Issue

Vol. 12 (2020)

A High-Capacity Ammonium Vanadate Cathode for Zinc-Ion Battery

https://doi.org/10.1007/s40820-020-0401-y
Qifei Li
Guangzhou Key Laboratory of Low‑Dimensional Materials and Energy Storage Devices, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, People’s Republic of China
Xianhong Rui
Guangzhou Key Laboratory of Low‑Dimensional Materials and Energy Storage Devices, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, People’s Republic of China
Dong Chen
Guangzhou Key Laboratory of Low‑Dimensional Materials and Energy Storage Devices, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, People’s Republic of China
Yuezhan Feng
Key Laboratory of Materials Processing and Mold (Zhengzhou University), Ministry of Education, Zhengzhou University, Zhengzhou 450002, People’s Republic of China
Ni Xiao
Aviation Fuel Research and Development Center, China National Aviation Fuel Group Limited, Beijing 102603, People’s Republic of China
Liyong Gan
Department Institute for Structure and Function and of Physics, Chongqing University, Chongqing 400030, People’s Republic of China
Qi Zhang
Guangzhou Key Laboratory of Low‑Dimensional Materials and Energy Storage Devices, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, People’s Republic of China
Yan Yu
Hefei National Laboratory for Physical Sciences at the Microscale, Department of Materials Science and Engineering, CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei 230026, People’s Republic of China
Shaoming Huang
Guangzhou Key Laboratory of Low‑Dimensional Materials and Energy Storage Devices, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, People’s Republic of China

Corresponding Author: Shaoming Huang

smhuang@gdut.edu.cn

Nano-Micro Letters, Vol. 12 (2020), Article Number: 67

Abstract

Given the advantages of being abundant in resources, environmental benign and highly safe, rechargeable zinc-ion batteries (ZIBs) enter the global spotlight for their potential utilization in large-scale energy storage. Despite their preliminary success, zinc-ion storage that is able to deliver capacity > 400 mAh g−1 remains a great challenge. Here, we demonstrate the viability of NH4V4O10 (NVO) as high-capacity cathode that breaks through the bottleneck of ZIBs in limited capacity. The first-principles calculations reveal that layered NVO is a good host to provide fast Zn2+ ions diffusion channel along its [010] direction in the interlayer space. On the other hand, to further enhance Zn2+ ion intercalation kinetics and long-term cycling stability, a three-dimensional (3D) flower-like architecture that is self-assembled by NVO nanobelts (3D-NVO) is rationally designed and fabricated through a microwave-assisted hydrothermal method. As a result, such 3D-NVO cathode possesses high capacity (485 mAh g−1) and superior long-term cycling performance (3000 times) at 10 A g−1 (~ 50 s to full discharge/charge). Additionally, based on the excellent 3D-NVO cathode, a quasi-solid-state ZIB with capacity of 378 mAh g−1 is developed.


Highlights:


1 3D flower-like architecture assembled by NH4V4O10 nanobelts (3D-NVO) was fabricated.
2 The Zn2+ ion was intercalated into NVO cathode within the interlayer region (NH4V4O10 ↔ ZnxNH4V4O10).
3 The 3D-NVO cathode could deliver a large reversible capacity of 485 mAh g−1 at a current density of 100 mA g−1 for zinc-ion battery.

Keywords

Zinc-ion battery Ammonium vanadate NH4V4O10
Li, Qifei, Xianhong Rui, Dong Chen, Yuezhan Feng, Ni Xiao, Liyong Gan, Qi Zhang, Yan Yu, and Shaoming Huang. 2020. “A High-Capacity Ammonium Vanadate Cathode for Zinc-Ion Battery”. Nano-Micro Letters 12 (March):67. https://doi.org/10.1007/s40820-020-0401-y.
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. M. Li, J. Lu, Z. Chen, K. Amine, 30 years of lithium-ion batteries. Adv. Mater. 30, 1800561 (2018). https://doi.org/10.1002/adma.201800561
  2. H. Tan, L. Xu, H. Geng, X. Rui, C. Li, S. Huang, Nanostructured Li3V2(PO4)3 cathodes. Small 14, 1800567 (2018). https://doi.org/10.1002/smll.201800567
  3. L. Wang, J.-L. Shi, H. Su, G. Li, M. Zubair, Y.-G. Guo, H. Yu, Composite-structure material design for high-energy lithium storage. Small 14, 1800887 (2018). https://doi.org/10.1002/smll.201800887
  4. Y. Tang, Y. Zhang, W. Li, B. Ma, X. Chen, Rational material design for ultrafast rechargeable lithium-ion batteries. Chem. Soc. Rev. 44, 5926–5940 (2015). https://doi.org/10.1039/C4CS00442F
  5. X. Xie, S. Liang, J. Gao, S. Guo, J. Guo et al., Manipulating the ion-transference kinetics and interface stability for high-performance zinc metal anode. Energy Environ. Sci. (2019). https://doi.org/10.1039/C9EE03545A
  6. C. Xu, B. Li, H. Du, F. Kang, Energetic zinc ion chemistry: the rechargeable zinc ion battery. Angew. Chem. Int. Ed. 124, 957–959 (2012). https://doi.org/10.1002/ange.201106307
  7. L. Zhang, L. Chen, X. Zhou, Z. Liu, Towards high-voltage aqueous metal-ion batteries beyond 1.5 V: The zinc/zinc hexacyanoferrate system. Adv. Energy Mater. 5, 1400930 (2015). https://doi.org/10.1002/aenm.201400930
  8. H. Pan, Y. Shao, P. Yan, Y. Cheng, K.S. Han et al., Reversible aqueous zinc/manganese oxide energy storage from conversion reactions. Nat. Energy 1, 16039 (2016). https://doi.org/10.1038/nenergy.2016.39
  9. B. Tang, L. Shan, S. Liang, J. Zhou, Issues and opportunities facing aqueous zinc-ion batteries. Energy Environ. Sci. 12, 3288–3304 (2019). https://doi.org/10.1039/C9EE02526J
  10. B. Lee, H.R. Lee, H. Kim, K.Y. Chung, B.W. Cho, S.H. Oh, Elucidating the intercalation mechanism of zinc ions into α-MnO2 for rechargeable zinc batteries. Chem. Commun. 51, 9265–9268 (2015). https://doi.org/10.1039/C5CC02585K
  11. R. Trocoli, F. La Mantia, An aqueous zinc-ion battery based on copper hexacyanoferrate. Chemsuschem 8, 481–485 (2015). https://doi.org/10.1002/cssc.201403143
  12. G. Li, Z. Yang, Y. Jiang, C. Jin, W. Huang, X. Ding, Y. Huang, Towards polyvalent ion batteries: a zinc-ion battery based on NASICON Structured Na3V2(PO4)3. Nano Energy 25, 211–217 (2016). https://doi.org/10.1016/j.nanoen.2016.04.051
  13. S. Guo, S. Liang, B. Zhang, G. Fang, D. Ma, J. Zhou, Cathode interfacial layer formation via in situ electrochemically charging in aqueous zinc-ion battery. ACS Nano 13, 13456–13464 (2019). https://doi.org/10.1021/acsnano.9b07042
  14. B. Wu, G. Zhang, M. Yan, T. Xiong, P. He, L. He, X. Xu, L. Mai, Graphene scroll-coated alpha-MnO2 nanowires as high-performance cathode materials for aqueous Zn-ion battery. Small 14, 1703850 (2018). https://doi.org/10.1002/smll.201703850
  15. M.H. Alfaruqi, J. Gim, S. Kim, J. Song, J. Jo, S. Kim, V. Mathew, J. Kim, Enhanced reversible divalent zinc storage in a structurally stable alpha-MnO2 nanorod electrode. J. Power Sources 288, 320–327 (2015). https://doi.org/10.1016/j.jpowsour.2015.04.140
  16. C. Li, X. Shi, S. Liang, X. Ma, M. Han, X. Wu, J. Zhou, Spatially homogeneous copper foam as surface dendrite-free host for zinc metal anode. Chem. Eng. J. 379, 122248 (2020). https://doi.org/10.1016/j.cej.2019.122248
  17. M.H. Alfaruqi, V. Mathew, J. Gim, S. Kim, J. Song, J.P. Baboo, S.H. Choi, J. Kim, Electrochemically induced structural transformation in a gamma-MnO2 cathode of a high capacity zinc-ion battery system. Chem. Mater. 27, 3609–3620 (2015). https://doi.org/10.1021/cm504717p
  18. B. Jiang, C. Xu, C. Wu, L. Dong, J. Li, F. Kang, Manganese sesquioxide as cathode material for multivalent zinc ion battery with high capacity and long cycle life. Electrochim. Acta 229, 422–428 (2017). https://doi.org/10.1016/j.electacta.2017.01.163
  19. J. Hao, J. Mou, J. Zhang, L. Dong, W. Liu, C. Xu, F. Kang, Electrochemically induced spinel-layered phase transition of Mn3O4 in high performance neutral aqueous rechargeable zinc battery. Electrochim. Acta 259, 170–178 (2018). https://doi.org/10.1016/j.electacta.2017.10.166
  20. X. Wu, Y. Xiang, Q. Peng, X. Wu, Y. Li et al., Green-low-cost rechargeable aqueous zinc-ion batteries using hollow porous spinel ZnMn2O4 as the cathode material. J. Mater. Chem. A 5, 17990–17997 (2017). https://doi.org/10.1039/C7TA00100B
  21. N. Zhang, F. Cheng, Y. Liu, Q. Zhao, K. Lei, C. Chen, X. Liu, J. Chen, Cation-deficient spinel ZnMn2O4 cathode in Zn(CF3SO3)2 electrolyte for rechargeable aqueous Zn-ion battery. J. Am. Chem. Soc. 138, 12894–12901 (2016). https://doi.org/10.1021/jacs.6b05958
  22. J. Ding, Z. Du, L. Gu, B. Li, L. Wang, S. Wang, Y. Gong, S. Yang, Ultrafast Zn2+ intercalation and deintercalation in vanadium dioxide. Adv. Mater. 30, 1800762 (2018). https://doi.org/10.1002/adma.201800762
  23. T. Wei, Q. Li, G. Yang, C. Wang, An electrochemically induced bilayered structure facilitates long-life zinc storage of vanadium dioxide. J. Mater. Chem. A 6, 8006–8012 (2018). https://doi.org/10.1039/C8TA02090F
  24. P. Senguttuvan, S.-D. Han, S. Kim, A.L. Lipson, S. Tepavcevic et al., A high power rechargeable nonaqueous multivalent Zn/V2O5 battery. Adv. Energy Mater. 6, 1600826 (2016). https://doi.org/10.1002/aenm.201600826
  25. P. Hu, M. Yan, T. Zhu, X. Wang, X. Wei et al., Zn/V2O5 aqueous hybrid-ion battery with high voltage platform and long cycle life. ACS Appl. Mater. Interfaces 9, 42717–42722 (2017). https://doi.org/10.1021/acsami.7b13110
  26. F. Liu, Z. Chen, G. Fang, Z. Wang, Y. Cai, B. Tang, J. Zhou, S. Liang, V2O5 nanospheres with mixed vanadium valences as high electrochemically active aqueous zinc-ion battery cathode. Nano-Micro Letters 11, 25 (2019). https://doi.org/10.1007/s40820-019-0256-2
  27. M. Yan, P. He, Y. Chen, S. Wang, Q. Wei et al., Water-lubricated intercalation in V2O5·nH2O for high-capacity and high-rate aqueous rechargeable zinc batteries. Adv. Mater. 30, 1703725 (2018). https://doi.org/10.1002/adma.201703725
  28. Y. Yang, Y. Tang, G. Fang, L. Shan, J. Guo et al., Li+ intercalated V2O5·nH2O with enlarged layer spacing and fast ion diffusion as an aqueous zinc-ion battery cathode. Energy Environ. Sci. 11, 3157–3162 (2018). https://doi.org/10.1039/C8EE01651H
  29. D. Kundu, B.D. Adams, V.D. Ort, S.H. Vajargah, L.F. Nazar, A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode. Nat. Energy 1, 16119 (2016). https://doi.org/10.1038/nenergy.2016.119
  30. W. Zhang, S. Liang, G. Fang, Y. Yang, J. Zhou, Ultra-high mass-loading cathode for aqueous zinc-ion battery based on graphene-wrapped aluminum vanadate nanobelts. Nano-Micro Lett. 11, 69 (2019). https://doi.org/10.1007/s40820-019-0300-2
  31. C. Xia, J. Guo, P. Li, X. Zhang, H.N. Alshareef, Highly stable aqueous zinc-ion storage using a layered calcium vanadium oxide bronze cathode. Angew. Chem. Int. Ed. 57, 3943–3948 (2018). https://doi.org/10.1002/anie.201713291
  32. M.H. Alfaruqi, V. Mathew, J. Song, S. Kim, S. Islam et al., Electrochemical zinc intercalation in lithium vanadium oxide: a high-capacity zinc-ion battery cathode. Chem. Mater. 29, 1684–1694 (2017). https://doi.org/10.1021/acs.chemmater.6b05092
  33. Q. Zheng, H. Yi, X. Li, H. Zhang, Progress and prospect for NASICON-type Na3V2(PO4)3 for electrochemical energy storage. J. Energy Chem. 27, 1597–1617 (2018). https://doi.org/10.1016/j.jechem.2018.05.001
  34. V. Soundharrajan, B. Sambandam, S. Kim, M.H. Alfaruqi, D.Y. Putro et al., Na2V6O16·3H2O barnesite nanorod: an open door to display a stable and high energy for aqueous rechargeable Zn-ion batteries as cathodes. Nano Lett. 18, 2402–2410 (2018). https://doi.org/10.1021/acs.nanolett.7b05403
  35. H. Geng, M. Cheng, B. Wang, Y. Yang, Y. Zhang, C. Li, Electronic structure regulation of layered vanadium oxide via interlayer doping strategy toward superior high-rate and low-temperature zinc-ion batteries. Adv. Funct. Mater. (2019). https://doi.org/10.1002/adfm.201907684
  36. B. Tang, G. Fang, J. Zhou, L. Wang, Y. Lei et al., Potassium vanadates with stable structure and fast ion diffusion channel as cathode for rechargeable aqueous zinc-ion batteries. Nano Energy 51, 579–587 (2018). https://doi.org/10.1016/j.nanoen.2018.07.014
  37. P. He, M. Yan, G. Zhang, R. Sun, L. Chen, Q. An, L. Mai, Layered VS2 nanosheet-based aqueous Zn ion battery cathode. Adv. Energy Mater. 7, 1601920 (2017). https://doi.org/10.1002/aenm.201601920
  38. N.A. Chernova, M. Roppolo, A.C. Dillon, M.S. Whittingham, Layered vanadium and molybdenum oxides: batteries and electrochromics. J. Mater. Chem. 19, 2526–2552 (2009). https://doi.org/10.1039/b819629j
  39. S. Sarkar, P.S. Veluri, S. Mitra, Morphology controlled synthesis of layered NH4V4O10 and the impact of binder on stable high rate electrochemical performance. Electrochim. Acta 132, 448–456 (2014). https://doi.org/10.1016/j.electacta.2014.03.144
  40. D. Fang, Y. Cao, R. Liu, W. Xu, S. Liu et al., Novel hierarchical three-dimensional ammonium vanadate nanowires electrodes for lithium ion battery. Appl. Surf. Sci. 360, 658–665 (2016). https://doi.org/10.1016/j.apsusc.2015.11.038
  41. K.-F. Zhang, G.-Q. Zhang, X. Liu, Z.-X. Su, H.-L. Li, Large scale hydrothermal synthesis and electrochemistry of ammonium vanadium bronze nanobelts. J. Power Sources 157, 528–532 (2006). https://doi.org/10.1016/j.jpowsour.2005.07.043
  42. E.A. Esparcia Jr., M.S. Chae, J.D. Ocon, S.-T. Hong, Ammonium vanadium bronze (NH4V4O10) as a high-capacity cathode material for nonaqueous magnesium-ion batteries. Chem. Mater. 30, 3690–3696 (2018). https://doi.org/10.1021/acs.chemmater.8b00462
  43. H. Fei, X. Liu, Y. Lin, M. Wei, Facile synthesis of ammonium vanadium oxide nanorods for Na-ion battery cathodes. J. Colloid Interface Sci. 428, 73–77 (2014). https://doi.org/10.1016/j.jcis.2014.04.029
  44. T. Sarkar, P. Kumar, M.D. Bharadwaj, U. Waghmare, Structural transformation during Li/Na insertion and theoretical cyclic voltammetry of the delta-NH4V4O10 electrode: a first-principles study. Phys. Chem. Chem. Phys. 18, 9344–9348 (2016). https://doi.org/10.1039/C5CP07782F
  45. V. Thuan Ngoc, H. Kim, J. Hur, W. Choi, I.T. Kim, Surfactant-assisted ammonium vanadium oxide as a superior cathode for calcium-ion batteries. J. Mater. Chem. A 6, 22645–22654 (2018). https://doi.org/10.1039/C8TA07831A
  46. A. Sarkar, S. Sarkar, T. Sarkar, P. Kumar, M.D. Bharadwaj, S. Mitra, Rechargeable sodium-ion battery: high-capacity ammonium vanadate cathode with enhanced stability at high rate. ACS Appl. Mater. Interfaces 7, 17044–17053 (2015). https://doi.org/10.1021/acsami.5b03210
  47. D. Chen, Q. Zhang, X. Rui, H. Geng, L. Gan et al., Persistent zinc-ion storage in mass-produced V2O5 architectures. Nano Energy 60, 171–178 (2019). https://doi.org/10.1016/j.nanoen.2019.03.034
  48. X. Zhao, X. Zhang, D. Wu, H. Zhang, F. Ding, Z. Zhou, Ab initio investigations on bulk and monolayer V2O5 as cathode materials for Li-, Na-, K- and Mg-ion batteries. J. Mater. Chem. A 4, 16606–16611 (2016). https://doi.org/10.1039/C6TA04986A
  49. N. Wang, W. Chen, L. Mai, Y. Dai, Selected-control hydrothermal synthesis and formation mechanism of 1D ammonium vanadate. J. Solid State Chem. 181, 652–657 (2008). https://doi.org/10.1016/j.jssc.2007.12.036
  50. G. Yang, T. Wei, C. Wang, Self-healing lamellar structure boosts highly stable zinc-storage property of bilayered vanadium oxides. ACS Appl. Mater. Interfaces 10, 35079–35089 (2018). https://doi.org/10.1021/acsami.8b10849
  51. J.P. Perdew, K. Burke, M. Ernzerhof, Generalized gradient approximation made simple. Phys. Rev. Lett. 77, 3865–3868 (1996). https://doi.org/10.1103/PhysRevLett.77.3865
  52. P.E. Blöchl, Projector augmented-wave method. Phys. Rev. B 50, 17953–17979 (1994). https://doi.org/10.1103/PhysRevB.50.17953
  53. G. Kresse, D. Joubert, From ultrasoft pseudopotentials to the projector augmented-wave method. Phys. Rev. B 59, 1758–1775 (1999). https://doi.org/10.1103/PhysRevB.59.1758
  54. C. Persson, A.F. da Silva, Strong polaronic effects on rutile TiO2 electronic band edges. Appl. Phys. Lett. 86, 231912 (2005). https://doi.org/10.1063/1.1940739
  55. G. Henkelman, B.P. Uberuaga, H. Jonsson, A climbing image nudged elastic band method for finding saddle points and minimum energy paths. J. Chem. Phys. 113, 9901–9904 (2000). https://doi.org/10.1063/1.1329672
  56. J.S. Braithwaite, C.R.A. Catlow, J.D. Gale, J.H. Harding, Lithium intercalation into vanadium pentoxide: a theoretical study. Chem. Mater. 11, 1990–1998 (1999). https://doi.org/10.1021/cm980735r
  57. H.A. Abbood, H. Peng, X. Gao, B. Tan, K. Huang, Fabrication of cross-like NH4V4O10 nanobelt array controlled by CMC as soft template and photocatalytic activity of its calcinated product. Chem. Eng. J. 209, 245–254 (2012). https://doi.org/10.1016/j.cej.2012.08.027
  58. D. Chen, H. Tan, X. Rui, Q. Zhang, Y. Feng et al., Oxyvanite V3O5: a new intercalation-type anode for lithium-ion battery. InfoMat 1, 251–259 (2019). https://doi.org/10.1002/inf2.12011
  59. M. Bhattacharya, T. Basak, A review on the susceptor assisted microwave processing of materials. Energy 97, 306–338 (2016). https://doi.org/10.1016/j.energy.2015.11.034
  60. P. He, G. Zhang, X. Liao, M. Yan, X. Xu, Q. An, J. Liu, L. Mai, Sodium ion stabilized vanadium oxide nanowire cathode for high-performance zinc-ion batteries. Adv. Energy Mater. 8, 1702463 (2018). https://doi.org/10.1002/aenm.201702463
  61. B. Sambandam, V. Soundharrajan, S. Kim, M.H. Alfaruqi, J. Jo et al., Aqueous rechargeable Zn-ion batteries: an imperishable and high-energy Zn2V2O7 nanowire cathode through intercalation regulation. J. Mater. Chem. A 6, 3850–3856 (2018). https://doi.org/10.1039/C7TA11237H
  62. C. Xia, J. Guo, Y. Lei, H. Liang, C. Zhao, H.N. Alshareef, Rechargeable aqueous zinc-ion battery based on porous framework zinc pyrovanadate intercalation cathode. Adv. Mater. 30, 1705580 (2018). https://doi.org/10.1002/adma.201705580
  63. P. Hu, T. Zhu, X. Wang, X. Wei, M. Yan et al., Highly durable Na2V6O16·1.63H2O nanowire cathode for aqueous zinc-ion battery. Nano Lett. 18, 1758–1763 (2018). https://doi.org/10.1021/acs.nanolett.7b04889
  64. A. Manthiram, X. Yu, S. Wang, Lithium battery chemistries enabled by solid-state electrolytes. Nat. Rev. Mater. 2, 16103 (2017). https://doi.org/10.1038/natrevmats.2016.103
  65. X. Chen, W. He, L. Ding, S. Wang, H. Wang, Enhancing interfacial contact in all solid state batteries with a cathode-supported solid electrolyte membrane framework. Energy Environ. Sci. 12, 938–944 (2019). https://doi.org/10.1039/C8EE02617C
  66. Z. Jiang, H. Xie, S. Wang, X. Song, X. Yao, H.H. Wang, Perovskite membranes with vertically aligned microchannels for all-solid-state lithium batteries. Adv. Energy Mater. 8, 1801433 (2018). https://doi.org/10.1002/aenm.201801433
  67. H. Xiang, J. Chen, Z. Li, H. Wang, An inorganic membrane as a separator for lithium-ion battery. J. Power Sources 196, 8651–8655 (2011). https://doi.org/10.1016/j.jpowsour.2011.06.055
  68. D. Chao, C. Zhu, M. Song, P. Liang, X. Zhang et al., A high-rate and stable quasi-solid-state zinc-ion battery with novel 2D layered zinc orthovanadate array. Adv. Mater. 30, 1803181 (2018). https://doi.org/10.1002/adma.201803181
  69. N. Zhang, M. Jia, Y. Dong, Y. Wang, J. Xu, Y. Liu, L. Jiao, F. Cheng, Hydrated layered vanadium oxide as a highly reversible cathode for rechargeable aqueous zinc batteries. Adv. Funct. Mater. 29, 1807331 (2019). https://doi.org/10.1002/adfm.201807331
Read More
Author biographies are not available.
Download this PDF file
PDF SUPPLEMENTARY MATERIAL
Statistic
Read Counter : 7133 Download : 5393

Most read articles by the same author(s)