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Vol. 15 (2023)

Self-Generated Buried Submicrocavities for High-Performance Near-Infrared Perovskite Light-Emitting Diode

https://doi.org/10.1007/s40820-023-01097-3
Jiong Li
School of Environment and Energy, State Key Lab of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Solid Wastes Pollution Control and Recycling, South China University of Technology, Guangzhou 510000, People’s Republic of China
Chenghao Duan
School of Environment and Energy, State Key Lab of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Solid Wastes Pollution Control and Recycling, South China University of Technology, Guangzhou 510000, People’s Republic of China
Qianpeng Zhang
Department of Electronic and Computer Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, People’s Republic of China
Chang Chen
School of Environment and Energy, State Key Lab of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Solid Wastes Pollution Control and Recycling, South China University of Technology, Guangzhou 510000, People’s Republic of China
Qiaoyun Wen
School of Environment and Energy, State Key Lab of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Solid Wastes Pollution Control and Recycling, South China University of Technology, Guangzhou 510000, People’s Republic of China
Minchao Qin
Department of Physics, The Chinese University of Hong Kong, Shatin, Hong Kong, People’s Republic of China
Christopher C. S. Chan
Department of Physics, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon 999077, Hong Kong, People’s Republic of China
Shibing Zou
School of Environment and Energy, State Key Lab of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Solid Wastes Pollution Control and Recycling, South China University of Technology, Guangzhou 510000, People’s Republic of China
Jianwu Wei
School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, People’s Republic of China
Zuo Xiao
Center for Excellence in Nanoscience (CAS), Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology, Beijing 100190, People’s Republic of China
Chuantian Zuo
Center for Excellence in Nanoscience (CAS), Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology, Beijing 100190, People’s Republic of China
Xinhui Lu
Department of Physics, The Chinese University of Hong Kong, Shatin, Hong Kong, People’s Republic of China
Kam Sing Wong
Department of Physics, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon 999077, Hong Kong, People’s Republic of China
Zhiyong Fan
Department of Electronic and Computer Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, People’s Republic of China
Keyou Yan
School of Environment and Energy, State Key Lab of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Solid Wastes Pollution Control and Recycling, South China University of Technology, Guangzhou 510000, People’s Republic of China

Corresponding Author: Zhiyong Fan

eezfan@ust.hk

Nano-Micro Letters, Vol. 15 (2023), Article Number: 125

Abstract

Embedding submicrocavities is an effective approach to improve the light out-coupling efficiency (LOCE) for planar perovskite light-emitting diodes (PeLEDs). In this work, we employ phenethylammonium iodide (PEAI) to trigger the Ostwald ripening for the downward recrystallization of perovskite, resulting in spontaneous formation of buried submicrocavities as light output coupler. The simulation suggests the buried submicrocavities can improve the LOCE from 26.8 to 36.2% for near-infrared light. Therefore, PeLED yields peak external quantum efficiency (EQE) increasing from 17.3% at current density of 114 mA cm−2 to 25.5% at current density of 109 mA cm−2 and a radiance increasing from 109 to 487 W sr−1 m−2 with low rolling-off. The turn-on voltage decreased from 1.25 to 1.15 V at 0.1 W sr−1 m−2. Besides, downward recrystallization process slightly reduces the trap density from 8.90 × 1015 to 7.27 × 1015 cm−3. This work provides a self-assembly method to integrate buried output coupler for boosting the performance of PeLEDs.


Highlights:


1 Synergistic effect triggers the Ostwald ripening for the downward recrystallization of perovskite to form buried submicrocavities as light output coupler.
2 The simulation suggests the buried submicrocavities can improve the light out-coupling efficiency from 26.8% to 36.2% for near-infrared light.
3 Light-emitting diodes yields peak external quantum efficiency increasing from 17.3% at current density of 114 mA cm−2 to 25.5% at current density of 109 mA cm−2 and a radiance increasing from 109 to 487 W sr−1 m−2 with low rolling-off.

Keywords

Perovskite light-emitting diodes Downward recrystallization Buried submicrocavities Light out-coupling efficiency Radiative recombination
Li, Jiong, Chenghao Duan, Qianpeng Zhang, Chang Chen, Qiaoyun Wen, Minchao Qin, Christopher C. S. Chan, Shibing Zou, Jianwu Wei, Zuo Xiao, Chuantian Zuo, Xinhui Lu, Kam Sing Wong, Zhiyong Fan, and Keyou Yan. 2023. “Self-Generated Buried Submicrocavities for High-Performance Near-Infrared Perovskite Light-Emitting Diode”. Nano-Micro Letters 15 (May):125. https://doi.org/10.1007/s40820-023-01097-3.
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References
  1. B.R. Sutherland, E.H. Sargent, Perovskite photonic sources. Nat. Photonics 10(5), 295–302 (2016). https://doi.org/10.1038/nphoton.2016.62
  2. L. Quan, B. Rand, R. Friend, S. Mhaisalkar, T.W. Lee et al., Perovskites for next-generation optical sources. Chem. Rev. 119, 7444–7477 (2019). https://doi.org/10.1021/acs.chemrev.9b00107
  3. Z. Liu, W. Qiu, X. Peng, G. Sun, X. Liu et al., Perovskite light-emitting diodes with EQE exceeding 28% through a synergetic dual-additive strategy for defect passivation and nanostructure regulation. Adv. Mater. 33, e2103268 (2021). https://doi.org/10.1002/adma.202103268
  4. L. Zhu, H. Cao, C. Xue, H. Zhang, M. Qin et al., Unveiling the additive-assisted oriented growth of perovskite crystallite for high performance light-emitting diodes. Nat. Commun. 12(1), 5081 (2021). https://doi.org/10.1038/s41467-021-25407-8
  5. M. Ren, S. Cao, J. Zhao, B. Zou, R. Zeng, Advances and challenges in two-dimensional organic-inorganic hybrid perovskites toward high-performance light-emitting diodes. Nano-Micro Lett. 13(1), 163 (2021). https://doi.org/10.1007/s40820-021-00685-5
  6. L. Tang, J. Qiu, Q. Wei, H. Gu, B. Du et al., Enhanced performance of perovskite light-emitting diodes via diamine interface modification. ACS Appl. Mater. Interfaces 11(32), 29132–29138 (2019). https://doi.org/10.1021/acsami.9b11866
  7. C. Liu, Y.B. Cheng, Z. Ge, Understanding of perovskite crystal growth and film formation in scalable deposition processes. Chem. Soc. Rev. 49(6), 1653–1687 (2020). https://doi.org/10.1039/c9cs00711c
  8. Z. Chen, Z. Li, Z. Chen, R. Xia, G. Zou et al., Utilization of trapped optical modes for white perovskite light-emitting diodes with efficiency over 12%. Joule 5(2), 456–466 (2021). https://doi.org/10.1016/j.joule.2020.12.008
  9. D.H. Jung, J.H. Park, H.E. Lee, J. Byun, T.H. Im et al., Flash-induced ultrafast recrystallization of perovskite for flexible light-emitting diodes. Nano Energy 61, 236–244 (2019). https://doi.org/10.1016/j.nanoen.2019.04.061
  10. F. Zhang, H. Min, Y. Zhang, Z. Kuang, J. Wang et al., Vapor-assisted in situ recrystallization for efficient tin-based perovskite light-emitting diodes. Adv. Mater. 34, e2203180 (2022). https://doi.org/10.1002/adma.202203180
  11. M.T. Hoang, A.S. Pannu, Y. Yang, S. Madani, P. Shaw et al., Surface treatment of inorganic CsPbI3 nanocrystals with guanidinium iodide for efficient perovskite light-emitting diodes with high brightness. Nano-Micro Lett. 14(1), 69 (2022). https://doi.org/10.1007/s40820-022-00813-9
  12. D. Zhang, Q. Zhang, B. Ren, Y. Zhu, M. Abdellah et al., Large-scale planar and spherical light-emitting diodes based on arrays of perovskite quantum wires. Nat. Photonics 16(4), 284–290 (2022). https://doi.org/10.1038/s41566-022-00978-0
  13. Q. Zhang, M.M. Tavakoli, L. Gu, D. Zhang, L. Tang et al., Efficient metal halide perovskite light-emitting diodes with significantly improved light extraction on nanophotonic substrates. Nat. Commun. 10(1), 727 (2019). https://doi.org/10.1038/s41467-019-08561-y
  14. L. Zhao, K.M. Lee, K. Roh, S.U.Z. Khan, B.P. Rand, Improved outcoupling efficiency and stability of perovskite light-emitting diodes using thin emitting layers. Adv. Mater. 31(2), 1805836 (2019). https://doi.org/10.1002/adma.201805836
  15. X.-B. Shi, Y. Liu, Z. Yuan, X.-K. Liu, Y. Miao et al., Optical energy losses in organic-inorganic hybrid perovskite light-emitting diodes. Adv. Opt. Mater. 6(17), 1800667 (2018). https://doi.org/10.1002/adom.201800667
  16. B. Zhao, S. Bai, V. Kim, R. Lamboll, R. Shivanna et al., High-efficiency perovskite-polymer bulk heterostructure light-emitting diodes. Nat. Photonics 12(12), 783–789 (2018). https://doi.org/10.1038/s41566-018-0283-4
  17. P. Fassl, V. Lami, F.J. Berger, L.M. Falk, J. Zaumseil et al., Revealing the internal luminescence quantum efficiency of perovskite films via accurate quantification of photon recycling. Matter 4(4), 1391–1412 (2021). https://doi.org/10.1016/j.matt.2021.01.019
  18. L. Yang, Y. Zhang, J. Ma, P. Chen, Y. Yu et al., Pure red light-emitting diodes based on quantum confined quasi-two-dimensional perovskites with cospacer cations. ACS Energy Lett. 6, 2386–2394 (2021). https://doi.org/10.1021/acsenergylett.1c00752
  19. M. Jiang, Z. Hu, Z. Liu, Z. Wu, L.K. Ono et al., Engineering green-to-blue emitting CsPbBr3 quantum-dot films with efficient ligand passivation. ACS Energy Lett. 4(11), 2731–2738 (2019). https://doi.org/10.1021/acsenergylett.9b02032
  20. T. Jiang, H. Min, R. Zou, M. Wang, K. Wen et al., Molecularly controlled quantum well width distribution and optoelectronic properties in quasi-2D perovskite light-emitting diodes. J. Phys. Chem. Lett. 13(18), 4098–4103 (2022). https://doi.org/10.1021/acs.jpclett.2c00360
  21. Y. Cao, N. Wang, H. Tian, J. Guo, Y. Wei et al., Perovskite light-emitting diodes based on spontaneously formed submicrometre-scale structures. Nature 562(7726), 249–253 (2018). https://doi.org/10.1038/s41586-018-0576-2
  22. J.S. Kim, J.M. Heo, G.S. Park, S.J. Woo, C. Cho et al., Ultra-bright, efficient and stable perovskite light-emitting diodes. Nature 611(7937), 688–694 (2022). https://doi.org/10.1038/s41586-022-05304-w
  23. W. Xu, Q. Hu, S. Bai, C. Bao, Y. Miao et al., Rational molecular passivation for high-performance perovskite light-emitting diodes. Nat. Photonics 13(6), 418–424 (2019). https://doi.org/10.1038/s41566-019-0390-x
  24. H. Yuan, Z. Zhang, T. Guo, L. Yu, Z. Deng et al., Steric effect of amino-acids as additives for perovskite solar cells. J. Alloys Compd. 876, 160140 (2021). https://doi.org/10.1016/j.jallcom.2021.160140
  25. S. Pang, H. Hu, J. Zhang, S. Lv, Y. Yu et al., NH2CH═NH2PbI3: An alternative organolead iodide perovskite sensitizer for mesoscopic solar cells. Chem. Mater. 26(3), 1485–1491 (2014). https://doi.org/10.1021/cm404006p
  26. M. Ren, J. Shi, Y. Chen, Y. Miao, Y. Zhao, Cs-content-dependent organic cation exchange in FA1−xCsxPbI3 perovskite. J. Energy Chem. 72, 539–544 (2022). https://doi.org/10.1016/j.jechem.2022.05.042
  27. L. Protesescu, S. Yakunin, S. Kumar, J. Bar, F. Bertolotti et al., Dismantling the “red wall” of colloidal perovskites: highly luminescent formamidinium and formamidinium-cesium lead iodide nanocrystals. ACS Nano 11(3), 3119–3134 (2017). https://doi.org/10.1021/acsnano.7b00116
  28. W.L. Tan, C.R. McNeill, X-ray diffraction of photovoltaic perovskites: principles and applications. Appl. Phys. Rev. 9(2), 021310 (2022). https://doi.org/10.1063/5.0076665
  29. M. Qin, P.F. Chan, X. Lu, A systematic review of metal halide perovskite crystallization and film formation mechanism unveiled by in situ giwaxs. Adv. Mater. 33(51), e2105290 (2021). https://doi.org/10.1002/adma.202105290
  30. F. Xie, C.-C. Chen, Y. Wu, X. Li, M. Cai et al., Vertical recrystallization for highly efficient and stable formamidinium-based inverted-structure perovskite solar cells. Energy Environ. Sci. 10(9), 1942–1949 (2017). https://doi.org/10.1039/c7ee01675a
  31. Y. Shen, L.P. Cheng, Y.Q. Li, W. Li, J.D. Chen et al., High-efficiency perovskite light-emitting diodes with synergetic outcoupling enhancement. Adv. Mater. 31, 1901517 (2019). https://doi.org/10.1002/adma.201901517
  32. L. Spanhel, Colloidal ZnO nanostructures and functional coatings: A survey. J. Sol-Gel Sci. Technol. 39(1), 7–24 (2006). https://doi.org/10.1007/s10971-006-7302-5
  33. Q. Jiang, Y. Zhao, X. Zhang, X. Yang, Y. Chen et al., Surface passivation of perovskite film for efficient solar cells. Nat. Photonics 13(7), 460–466 (2019). https://doi.org/10.1038/s41566-019-0398-2
  34. J. Guo, J. Sun, L. Hu, S. Fang, X. Ling et al., Indigo: a natural molecular passivator for efficient perovskite solar cells. Adv. Energy Mater. 12(22), 2200537 (2022). https://doi.org/10.1002/aenm.202200537
  35. C. Shi, Q. Song, H. Wang, S. Ma, C. Wang et al., Molecular hinges stabilize formamidinium-based perovskite solar cells with compressive strain. Adv. Funct. Mater. 32, 2201193 (2022). https://doi.org/10.1002/adfm.202201193
  36. H. Li, H. Lin, D. Ouyang, C. Yao, C. Li et al., Efficient and stable red perovskite light-emitting diodes with operational stability > 300 h. Adv. Mater. 33(15), e2008820 (2021). https://doi.org/10.1002/adma.202008820
  37. F. Wang, W. Geng, Y. Zhou, H.H. Fang, C.J. Tong et al., Phenylalkylamine passivation of organolead halide perovskites enabling high-efficiency and air-stable photovoltaic cells. Adv. Mater. 28(45), 9986–9992 (2016). https://doi.org/10.1002/adma.201603062
  38. M. Filipič, P. Löper, B. Niesen, S. De Wolf, J. Krč et al., CH3NH3PbI3 perovskite/silicon tandem solar cells: characterization based optical simulations. Opt. Express 23(7), A263–A278 (2015). https://doi.org/10.1364/OE.23.00A263
  39. Z. Xie, S. Sun, Y. Yan, L. Zhang, R. Hou et al., Refractive index and extinction coefficient of NH2CH=NH2PbI3 perovskite photovoltaic material. J. Phys. Condens. Matter 29(24), 245702 (2017). https://doi.org/10.1088/1361-648x/aa6e6c
  40. L. Lin, R. Proietti Zaccaria, D. Garoli, R. Krahne, Photonic cavity effects for enhanced efficiency in layered perovskite-based light-emitting diodes. Nanomater (Basel) 11(11), 2947 (2021). https://doi.org/10.3390/nano11112947
  41. D.-K. Lee, Y. Shin, H.J. Jang, J.-H. Lee, K. Park et al., Nanocrystalline polymorphic energy funnels for efficient and stable perovskite light-emitting diodes. ACS Energy Lett. 6(5), 1821–1830 (2021). https://doi.org/10.1021/acsenergylett.1c00565
  42. X.Q. Dong Shi, Y. Li, Y. He, C. Zhong, J. Pan et al., Spiro-OMeTAD single crystals: remarkably enhanced charge-carrier transport via mesoscale ordering. Sci. Adv. 2, e1501491 (2016). https://doi.org/10.1126/sciadv.1501491
  43. O.A. Jaramillo-Quintero, R.S. Sanchez, M. Rincon, I. Mora-Sero, Bright visible-infrared light emitting diodes based on hybrid halide perovskite with Spiro-OMeTAD as a hole-injecting layer. J. Phys. Chem. Lett. 6(10), 1883–1890 (2015). https://doi.org/10.1021/acs.jpclett.5b00732
  44. J.S. Manser, P.V. Kamat, Band filling with free charge carriers in organometal halide perovskites. Nat. Photonics 8(9), 737–743 (2014). https://doi.org/10.1038/nphoton.2014.171
  45. K.Y. Zhang, Q. Yu, H. Wei, S. Liu, Q. Zhao et al., Long-lived emissive probes for time-resolved photoluminescence bioimaging and biosensing. Chem. Rev. 118(4), 1770–1839 (2018). https://doi.org/10.1021/acs.chemrev.7b00425
  46. T. Handa, D.M. Tex, A. Shimazaki, A. Wakamiya, Y. Kanemitsu, Charge injection mechanism at heterointerfaces in CH3NH3PbI3 perovskite solar cells revealed by simultaneous time-resolved photoluminescence and photocurrent measurements. J. Phys. Chem. Lett. 8(5), 954–960 (2017). https://doi.org/10.1021/acs.jpclett.6b02847
  47. J. Dagar, K. Hirselandt, A. Merdasa, A. Czudek, R. Munir et al., Alkali salts as interface modifiers in n-i-p hybrid perovskite solar cells. Solar RRL 3(9), 1900088 (2019). https://doi.org/10.1002/solr.201900088
  48. S. Zhang, H. Si, W. Fan, M. Shi, M. Li et al., Graphdiyne: bridging SnO2 and perovskite in planar solar cells. Angew. Chem. Int. Ed. 59(28), 11573–11582 (2020). https://doi.org/10.1002/anie.202003502
  49. J. Wang, L. Yuan, H. Luo, C. Duan, B. Zhou et al., Ambient air processed highly oriented perovskite solar cells with efficiency exceeding 23% via amorphous intermediate. Chem. Eng. J. 446, 136968 (2022). https://doi.org/10.1016/j.cej.2022.136968
  50. S.D. Stranks, R.L.Z. Hoye, D. Di, R.H. Friend, F. Deschler, The physics of light emission in halide perovskite devices. Adv. Mater. 31(47), e1803336 (2019). https://doi.org/10.1002/adma.201803336
  51. M. Lu, Y. Zhang, S. Wang, J. Guo, W.W. Yu et al., Metal halide perovskite light-emitting devices: promising technology for next-generation displays. Adv. Funct. Mater. 29(30), 1902008 (2019). https://doi.org/10.1002/adfm.201902008
  52. Z. Wei, J. Xing, The rise of perovskite light-emitting diodes. J. Phys. Chem. Lett. 10(11), 3035–3042 (2019). https://doi.org/10.1021/acs.jpclett.9b00277
  53. C. Duan, Z. Liu, L. Yuan, H. Zhu, H. Luo et al., PEDOT:PSS-metal oxide composite electrode with regulated wettability and work function for high-performance inverted perovskite solar cells. Adv. Opt. Mater. 8(17), 2000216 (2020). https://doi.org/10.1002/adom.202000216
  54. H. Zhu, C. Duan, M. Qin, Z. Liu, J. Li et al., Trifluoromethylphenylacetic acid as in situ accelerant of ostwald ripening for stable and efficient perovskite solar cells. Solar RRL 5, 2100040 (2021). https://doi.org/10.1002/solr.202100040
  55. U. Rau, Reciprocity relation between photovoltaic quantum efficiency and electroluminescent emission of solar cells. Phys. Rev. B 76(8), 085303 (2007). https://doi.org/10.1103/PhysRevB.76.085303
  56. J. Li, C. Duan, Q. Wen, L. Yuan, S. Zou et al., Reciprocally photovoltaic light-emitting diode based on dispersive perovskite nanocrystal. Small 18(18), e2107145 (2022). https://doi.org/10.1002/smll.202107145
  57. M. Kim, J.M. Figueroa-Tapia, M. Prato, A. Petrozza, Engineering multiphase metal halide perovskites thin films for stable and efficient solar cells. Adv. Energy Mater. 10(8), 1903221 (2020). https://doi.org/10.1002/aenm.201903221
  58. C. Duan, J. Li, Z. Liu, Q. Wen, H. Tang et al., Highly electroluminescent and stable inorganic CsPbI2Br perovskite solar cell enabled by balanced charge transfer. Chem. Eng. J. 417, 128053 (2021). https://doi.org/10.1016/j.cej.2020.128053
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