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Vol. 15 (2023)

Crystallization and Orientation Modulation Enable Highly Efficient Doctor-Bladed Perovskite Solar Cells

https://doi.org/10.1007/s40820-023-01138-x
Jianhui Chang
Hunan Key Laboratory of Nanophotonics and Devices, School of Physics and Electronics, Central South University, Changsha 410083, Hunan, People’s Republic of China
Erming Feng
Hunan Key Laboratory of Nanophotonics and Devices, School of Physics and Electronics, Central South University, Changsha 410083, Hunan, People’s Republic of China
Hengyue Li
Hunan Key Laboratory of Nanophotonics and Devices, School of Physics and Electronics, Central South University, Changsha 410083, Hunan, People’s Republic of China
Yang Ding
Hunan Key Laboratory of Nanophotonics and Devices, School of Physics and Electronics, Central South University, Changsha 410083, Hunan, People’s Republic of China
Caoyu Long
Hunan Key Laboratory of Nanophotonics and Devices, School of Physics and Electronics, Central South University, Changsha 410083, Hunan, People’s Republic of China
Yuanji Gao
Hunan Key Laboratory of Nanophotonics and Devices, School of Physics and Electronics, Central South University, Changsha 410083, Hunan, People’s Republic of China
Yingguo Yang
Shanghai Synchrotron Radiation Facility (SSRF), Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201204, People’s Republic of China
Chenyi Yi
Department of Electrical Engineering, Tsinghua University, Beijing 100084, People’s Republic of China
Zijian Zheng
Department of Applied Biology and Chemical Technology, Faculty of Science, The Hong Kong Polytechnic University, Hong Kong 999077, People’s Republic of China
Junliang Yang
Hunan Key Laboratory of Nanophotonics and Devices, School of Physics and Electronics, Central South University, Changsha 410083, Hunan, People’s Republic of China

Corresponding Author: Junliang Yang

junliang.yang@csu.edu.cn

Nano-Micro Letters, Vol. 15 (2023), Article Number: 164

Abstract

With the rapid rise in perovskite solar cells (PSCs) performance, it is imperative to develop scalable fabrication techniques to accelerate potential commercialization. However, the power conversion efficiencies (PCEs) of PSCs fabricated via scalable two-step sequential deposition lag far behind the state-of-the-art spin-coated ones. Herein, the additive methylammonium chloride (MACl) is introduced to modulate the crystallization and orientation of a two-step sequential doctor-bladed perovskite film in ambient conditions. MACl can significantly improve perovskite film quality and increase grain size and crystallinity, thus decreasing trap density and suppressing nonradiative recombination. Meanwhile, MACl also promotes the preferred face-up orientation of the (100) plane of perovskite film, which is more conducive to the transport and collection of carriers, thereby significantly improving the fill factor. As a result, a champion PCE of 23.14% and excellent long-term stability are achieved for PSCs based on the structure of ITO/SnO2/FA1-xMAxPb(I1-yBry)3/Spiro-OMeTAD/Ag. The superior PCEs of 21.20% and 17.54% are achieved for 1.03 cm2 PSC and 10.93 cm2 mini-module, respectively. These results represent substantial progress in large-scale two-step sequential deposition of high-performance PSCs for practical applications.


Highlights:


1 High quality and strongly oriented perovskite films are prepared by two step doctor blading in air.
2 Methylammonium chloride induced low dimensional intermediate phase regulates the crystallization and orientation of the perovskite.
3 Two step doctor bladed perovskite solar cells achieve a power conversion efficiency (PCE) of 23.14%, while 1.03 cm2 PSCs and 10.93 cm2 mini modules achieve PCEs of 21.20% and 17.54%, respectively.

Keywords

Crystallization regulation Orientation modulation Perovskite solar cells Doctor-blading Ambient condition
Chang, Jianhui, Erming Feng, Hengyue Li, Yang Ding, Caoyu Long, Yuanji Gao, Yingguo Yang, Chenyi Yi, Zijian Zheng, and Junliang Yang. 2023. “Crystallization and Orientation Modulation Enable Highly Efficient Doctor-Bladed Perovskite Solar Cells”. Nano-Micro Letters 15 (June):164. https://doi.org/10.1007/s40820-023-01138-x.
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References
  1. J.J. Yoo, G. Seo, M.R. Chua, T.G. Park, Y. Lu et al., Efficient perovskite solar cells via improved carrier management. Nature 590, 587–593 (2021). https://doi.org/10.1038/s41586-021-03285-w
  2. J. Jeong, M. Kim, J. Seo, H. Lu, P. Ahlawat et al., Pseudo-halide anion engineering for α-FAPbI3 perovskite solar cells. Nature 592, 381–385 (2021). https://doi.org/10.1038/s41586-021-03406-5
  3. Z. Li, B. Li, X. Wu, S.A. Sheppard, S. Zhang et al., Organometallic-functionalized interfaces for highly efficient inverted perovskite solar cells. Science 376(6591), 416–420 (2022). https://doi.org/10.1126/science.abm8566
  4. J. Park, J. Kim, H.-S. Yun, M.J. Paik, E. Noh et al., Controlled growth of perovskite layers with volatile alkylammonium chlorides. Nature 616, 724–730 (2023). https://doi.org/10.1038/s41586-023-05825-y
  5. Y. Xiao, C. Zuo, J.-X. Zhong, W.-Q. Wu, L. Shen et al., Large-area blade-coated solar cells: advances and perspectives. Adv. Energy Mater. 11(21), 2100378 (2021). https://doi.org/10.1002/aenm.202100378
  6. J. Chang, K. Liu, S. Lin, Y. Yuan, C. Zhou et al., Solution-processed perovskite solar cells. J. Cent. South Univ. 27, 1104–1133 (2020). https://doi.org/10.1007/s11771-020-4353-7
  7. N.-G. Park, K. Zhu, Scalable fabrication and coating methods for perovskite solar cells and solar modules. Nat. Rev. Mater. 5, 333–350 (2020). https://doi.org/10.1038/s41578-019-0176-2
  8. Y. Zhu, M. Hu, M. Xu, B. Zhang, F. Huang et al., Bilayer metal halide perovskite for efficient and stable solar cells and modules. Mater. Futur. 1(4), 042102 (2022). https://doi.org/10.1088/2752-5724/ac9248
  9. D.-K. Lee, D.-N. Jeong, T.K. Ahn, N.-G. Park, Precursor engineering for a large-area perovskite solar cell with >19% efficiency. ACS Energy Lett. 4(10), 2393–2401 (2019). https://doi.org/10.1021/acsenergylett.9b01735
  10. Y. Deng, C.H.V. Brackle, X. Dai, J. Zhao, B. Chen et al., Tailoring solvent coordination for high-speed, room-temperature blading of perovskite photovoltaic films. Sci. Adv. 5(12), eaax7537 (2019). https://doi.org/10.1126/sciadv.aax7537
  11. Y. Deng, X. Zheng, Y. Bai, Q. Wang, J. Zhao et al., Surfactant-controlled ink drying enables high-speed deposition of perovskite films for efficient photovoltaic modules. Nat. Energy 3, 560–566 (2018). https://doi.org/10.1038/s41560-018-0153-9
  12. T. Bu, L.K. Ono, J. Li, J. Su, G. Tong et al., Modulating crystal growth of formamidinium–caesium perovskites for over 200 cm2 photovoltaic sub-modules. Nat. Energy 7, 528–536 (2022). https://doi.org/10.1038/s41560-022-01039-0
  13. Z. Wu, E. Bi, C. Li, L. Chen, Z. Song et al., Scalable two-step production of high-efficiency perovskite solar cells and modules. Solar RRL 7(1), 2200571 (2023). https://doi.org/10.1002/solr.202200571
  14. Z. Li, T.R. Klein, D.H. Kim, M. Yang, J.J. Berry et al., Scalable fabrication of perovskite solar cells. Nat. Rev. Mater. 3, 18017 (2018). https://doi.org/10.1038/natrevmats.2018.17
  15. Y. Zhao, F. Ma, Z. Qu, S. Yu, T. Shen et al., Inactive (PbI2)2RbCl stabilizes perovskite films for efficient solar cells. Science 377(6605), 531–534 (2022). https://doi.org/10.1126/science.abp8873
  16. F. Guo, W. He, S. Qiu, C. Wang, X. Liu et al., Sequential deposition of high-quality photovoltaic perovskite layers via scalable printing methods. Adv. Funct. Mater. 29(24), 1900964 (2019). https://doi.org/10.1002/adfm.201900964
  17. Z. Huang, X. Hu, Z. Xing, X. Meng, X. Duan et al., Stabilized and operational PbI2 precursor ink for large-scale perovskite solar cells via two-step blade-coating. J. Phys. Chem. C 124(15), 8129–8139 (2020). https://doi.org/10.1021/acs.jpcc.0c00908
  18. Q. Liu, Z. Ma, Y. Li, G. Yan, D. Huang et al., Heterogeneous lead iodide obtains perovskite solar cells with efficiency of 24.27%. Chem. Eng. J. 448(15), 137676 (2022). https://doi.org/10.1016/j.cej.2022.137676
  19. H. Li, C. Zuo, D. Angmo, H. Weerasinghe, M. Gao et al., Fully roll-to-roll processed efficient perovskite solar cells via precise control on the morphology of PbI2:CsI layer. Nano-micro Lett. 14, 79 (2022). https://doi.org/10.1007/s40820-022-00815-7
  20. C. Liu, L. Zuo, Ding, Self-spreading produces highly efficient perovskite solar cells. Nano Energy 90, 106509 (2021). https://doi.org/10.1016/j.nanoen.2021.106509
  21. C. Zuo, L. Ding, Drop-casting to make efficient perovskite solar cells under high humidity. Angew. Chem. Int. Ed. 60(20), 11242–11246 (2021). https://doi.org/10.1002/anie.202101868
  22. F. Matteocci, L. Vesce, F.U. Kosasih, L.A. Castriotta, S. Cacovich et al., Fabrication and morphological characterization of high-efficiency blade-coated perovskite solar modules. ACS Appl. Mater. Interfaces 11(28), 25195–25204 (2019). https://doi.org/10.1021/acsami.9b05730
  23. N.Y. Nia, M. Zendehdel, L. Cinà, F. Matteocci, A.D. Carlo, A crystal engineering approach for scalable perovskite solar cells and module fabrication: a full out of glove box procedure. J. Mater. Chem. A 6(2), 659–671 (2018). https://doi.org/10.1039/C7TA08038G
  24. X. Duan, X. Li, L. Tan, Z. Huang, J. Yang et al., Controlling crystal growth via an autonomously longitudinal scaffold for planar perovskite solar cells. Adv. Mater. 32(26), 2000617 (2020). https://doi.org/10.1002/adma.202000617
  25. Y. Peng, F. Zeng, Y. Cheng, C. Wang, K. Huang et al., Fully Doctor-bladed efficient perovskite solar cells in ambient condition via composition engineering. Org. Electron. 83, 105736 (2020). https://doi.org/10.1016/j.orgel.2020.105736
  26. J. Zhang, T. Bu, J. Li, H. Li, Y. Mo et al., Two-step sequential blade-coating of high quality perovskite layers for efficient solar cells and modules. J. Mater. Chem. A 8(17), 8447–8454 (2020). https://doi.org/10.1039/D0TA02043E
  27. W. Yu, J. Li, X. Gao, C. Tian, H. Zhu et al., Two-Step sequential blade-coating large-area FA-based perovskite thin film via a controlled PbI2 microstructure. Acta Phys. Chim. Sin. 39(2), 2203048 (2023). https://doi.org/10.3866/PKU.WHXB202203048
  28. F. Ye, J. Ma, C. Chen, H. Wang, Y. Xu et al., Roles of MACl in sequentially deposited bromine-free perovskite absorbers for efficient solar cells. Adv. Mater. 33(3), 2007126 (2021). https://doi.org/10.1002/adma.202007126
  29. M. Kim, G.-H. Kim, T.K. Lee, I.W. Choi, H.W. Choi et al., Methylammonium chloride induces intermediate phase stabilization for efficient perovskite solar cells. Joule 3(9), 2179–2192 (2019). https://doi.org/10.1016/j.joule.2019.06.014
  30. X. Zhu, H. Dong, J. Chen, J. Xu, Z. Li et al., Photoinduced cross linkable polymerization of flexible perovskite solar cells and modules by incorporating benzyl acrylate. Adv. Funct. Mater. 32(30), 2202408 (2022). https://doi.org/10.1002/adfm.202202408
  31. Q. Sun, B. Tuo, Z. Ren, T. Xue, Y. Zhang et al., A thiourea competitive crystallization strategy for fa-based perovskite solar cells. Adv. Funct. Mater. 32(51), 2208885 (2022). https://doi.org/10.1002/adfm.202208885
  32. C. Long, K. Huang, J. Chang, C. Zuo, Y. Gao et al., Creating a dual-functional 2D perovskite layer at the interface to enhance the performance of flexible perovskite solar cells. Small 17(32), 2102368 (2021). https://doi.org/10.1002/smll.202102368
  33. J. Huang, GIWAXS-Tools, Version [2.1.7], https://gitee.com/swordshinehjy/giwaxs-script
  34. D.P. McMeekin, P. Holzhey, S.O. Fürer, S.P. Harvey, L.T. Schelhas et al., Intermediate-phase engineering via dimethylammonium cation additive for stable perovskite solar cells. Nat. Mater. 22, 73–83 (2023). https://doi.org/10.1038/s41563-022-01399-8
  35. Q. Liang, K. Liu, M. Sun, Z. Ren, P.W.K. Fong et al., Manipulating crystallization kinetics in high-performance blade-coated perovskite solar cells via cosolvent-assisted phase transition. Adv. Mater. 34(16), 2200276 (2022). https://doi.org/10.1002/adma.202200276
  36. H. Li, J. Zhou, L. Tan, M. Li, C. Jiang et al., Sequential vacuum-evaporated perovskite solar cells with more than 24% efficiency. Sci. Adv. 8(28), 7422 (2022). https://doi.org/10.1126/sciadv.abo7422
  37. D.H. Kim, J. Park, Z. Li, M. Yang, J.-S. Park et al., 300% enhancement of carrier mobility in uniaxial-oriented perovskite films formed by topotactic-oriented attachment. Adv. Mater. 29(23), 1606831 (2017). https://doi.org/10.1002/adma.201606831
  38. Y. Ding, B. Ding, H. Kanda, O.J. Usiobo, T. Gallet et al., Single-crystalline TiO2 nanops for stable and efficient perovskite modules. Nat. Nanotechnol. 17, 598–605 (2022). https://doi.org/10.1038/s41565-022-01108-1
  39. H. Zhang, J. Cheng, F. Lin, H. He, J. Mao et al., Pinhole-free and surface-nanostructured NiOx film by room-temperature solution process for high-performance flexible perovskite solar cells with good stability and reproducibility. ACS Nano 10(1), 1503–1511 (2016). https://doi.org/10.1021/acsnano.5b07043
  40. J.W. Jung, C.-C. Chueh, A.K.-Y. Jen, High-performance semitransparent perovskite solar cells with 10% power conversion efficiency and 25% average visible transmittance based on transparent CuSCN as the hole-transporting material. Adv. Energy Mater. 5(17), 1500486 (2015). https://doi.org/10.1002/aenm.201500486
  41. W. Chen, Y. Wu, J. Fan, A.B. Djurišić, F. Liu et al., Understanding the doping effect on NiO: toward high-performance inverted perovskite solar cells. Adv. Energy Mater. 8(19), 1703519 (2018). https://doi.org/10.1002/aenm.201703519
  42. Y.-W. Jang, S. Lee, K.M. Yeom, K. Jeong, K. Choi et al., Intact 2D/3D halide junction perovskite solar cells via solid-phase in-plane growth. Nat. Energy 6, 63–71 (2021). https://doi.org/10.1038/s41560-020-00749-7
  43. S. Rühle, Tabulated values of the Shockley-Queisser limit for single junction solar cells. Sol. Energy 130, 139–147 (2016). https://doi.org/10.1016/j.solener.2016.02.015
  44. Y. Zhao, H. Tan, H. Yuan, Z. Yang, J.Z. Fan et al., Perovskite seeding growth of formamidinium-lead-iodide-based perovskites for efficient and stable solar cells. Nat. Commun. 9, 1607 (2018). https://doi.org/10.1038/s41467-018-04029-7
  45. B. Zong, D. Hu, Q. Sun, J. Deng, Z. Zhang et al., 2, 3, 4, 5, 6-Pentafluorophenylammonium bromide-based double-sided interface engineering for efficient planar heterojunction perovskite solar cells. Chem. Eng. J. 452(2), 139308 (2023). https://doi.org/10.1016/j.cej.2022.139308
  46. R.H. Bube, Trap density determination by space-charge-limited currents. J. Appl. Phys. 33(5), 1733–1737 (1962). https://doi.org/10.1063/1.1728818
  47. C. Gong, C. Zhang, Q. Zhuang, H. Li, H. Yang et al., Stabilizing buried interface via synergistic effect of fluorine and sulfonyl functional groups toward efficient and stable perovskite solar cells. Nano-micro Lett. 15, 17 (2023). https://doi.org/10.1007/s40820-022-00992-5
  48. W. Peng, C. Aranda, O.M. Bakr, G. Garcia-Belmonte, J. Bisquert et al., Quantification of ionic diffusion in lead halide perovskite single crystals. ACS Energy Lett. 3(7), 1477–1481 (2018). https://doi.org/10.1021/acsenergylett.8b00641
  49. H. Kim, S.-U. Lee, D.Y. Lee, M.J. Paik, H. Na et al., Optimal interfacial engineering with different length of alkylammonium halide for efficient and stable perovskite solar cells. Adv. Energy Mater. 9(47), 1902740 (2019). https://doi.org/10.1002/aenm.201902740
  50. L.A. Castriotta, M. Zendehdel, N. Yaghoobi Nia, E. Leonardi, M. Löffler et al., Reducing losses in perovskite large area solar technology: laser design optimization for highly efficient modules and minipanels. Adv. Energy Mater. 12, 2103420 (2022). https://doi.org/10.1002/aenm.202103420
  51. J. Zhang, X. Jiang, X. Liu, X. Guo, C. Li, Maximizing merits of undesirable δ-FAPbI3 by constructing yellow/black heterophase bilayer for efficient and stable perovskite photovoltaics. Adv. Funct. Mater. 32(44), 2204642 (2022). https://doi.org/10.1002/adfm.202204642
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