Issue

Vol. 17 (2025)

Optimization Strategies of Na3V2(PO4)3 Cathode Materials for Sodium-Ion Batteries

https://doi.org/10.1007/s40820-024-01526-x
Jiawen Hu
School of Materials Science and Engineering, Shanghai University, Shanghai 200444, People’s Republic of China
Xinwei Li
School of Materials Science and Engineering, Shanghai University, Shanghai 200444, People’s Republic of China
Qianqian Liang
School of Materials Science and Engineering, Shanghai University, Shanghai 200444, People’s Republic of China
Li Xu
School of Materials Science and Engineering, Shanghai University, Shanghai 200444, People’s Republic of China
Changsheng Ding
School of Materials Science and Engineering, Shanghai University, Shanghai 200444, People’s Republic of China
Yu Liu
Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, People’s Republic of China
Yanfeng Gao
School of Materials Science and Engineering, Shanghai University, Shanghai 200444, People’s Republic of China

Corresponding Author: Yanfeng Gao

yfgao@shu.edu.cn

Nano-Micro Letters, Vol. 17 (2025), Article Number: 33

Abstract

Na3V2(PO4)3 (NVP) has garnered great attentions as a prospective cathode material for sodium-ion batteries (SIBs) by virtue of its decent theoretical capacity, superior ion conductivity and high structural stability. However, the inherently poor electronic conductivity and sluggish sodium-ion diffusion kinetics of NVP material give rise to inferior rate performance and unsatisfactory energy density, which strictly confine its further application in SIBs. Thus, it is of significance to boost the sodium storage performance of NVP cathode material. Up to now, many methods have been developed to optimize the electrochemical performance of NVP cathode material. In this review, the latest advances in optimization strategies for improving the electrochemical performance of NVP cathode material are well summarized and discussed, including carbon coating or modification, foreign-ion doping or substitution and nanostructure and morphology design. The foreign-ion doping or substitution is highlighted, involving Na, V, and PO43− sites, which include single-site doping, multiple-site doping, single-ion doping, multiple-ion doping and so on. Furthermore, the challenges and prospects of high-performance NVP cathode material are also put forward. It is believed that this review can provide a useful reference for designing and developing high-performance NVP cathode material toward the large-scale application in SIBs.


Highlights:
1 Optimization strategies for high-performance Na3V2(PO4)3 (NVP) cathode material are well summarized and discussed, including carbon coating or modification, foreign-ion doping or substitution and nanostructure and morphology design.
2 The foreign-ion doping or substitution is highlighted, involving the Na, V, and PO43− sites, which include single-site doping, multiple-site doping, single-ion doping and multiple-ion doping.
3 Challenges and future perspectives for high-performance NVP cathode material are presented.

Keywords

Sodium-ion batteries Na3V2(PO4)3 Cathode materials Electrochemical performance Optimization strategies
Hu, Jiawen, Xinwei Li, Qianqian Liang, Li Xu, Changsheng Ding, Yu Liu, and Yanfeng Gao. 2024. “Optimization Strategies of Na3V2(PO4)3 Cathode Materials for Sodium-Ion Batteries”. Nano-Micro Letters 17 (October):33. https://doi.org/10.1007/s40820-024-01526-x.
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