Issue

Vol. 10 No. 4 (2018)

Metal–Organic Framework-Based Sensors for Environmental Contaminant Sensing

https://doi.org/10.1007/s40820-018-0218-0
Xian Fang
Biomedical Multidisciplinary Innovation Research Institute, Shanghai East Hospital, State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092, People’s Republic of China
Boyang Zong
Biomedical Multidisciplinary Innovation Research Institute, Shanghai East Hospital, State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092, People’s Republic of China
Shun Mao
Biomedical Multidisciplinary Innovation Research Institute, Shanghai East Hospital, State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092, People’s Republic of China

Corresponding Author: Shun Mao

shunmao@tongji.edu.cn

Nano-Micro Letters, Vol. 10 No. 4 (2018), Article Number: 64

Abstract

Increasing demand for timely and accurate environmental pollution monitoring and control requires new sensing techniques with outstanding performance, i.e., high sensitivity, high selectivity, and reliability. Metal–organic frameworks (MOFs), also known as porous coordination polymers, are a fascinating class of highly ordered crystalline coordination polymers formed by the coordination of metal ions/clusters and organic bridging linkers/ligands. Owing to their unique structures and properties, i.e., high surface area, tailorable pore size, high density of active sites, and high catalytic activity, various MOF-based sensing platforms have been reported for environmental contaminant detection including anions, heavy metal ions, organic compounds, and gases. In this review, recent progress in MOF-based environmental sensors is introduced with a focus on optical, electrochemical, and field-effect transistor sensors. The sensors have shown unique and promising performance in water and gas contaminant sensing. Moreover, by incorporation with other functional materials, MOF-based composites can greatly improve the sensor performance. The current limitations and future directions of MOF-based sensors are also discussed.


Highlights:


1 Representative metal–organic framework (MOF)-based sensing platforms in environmental contaminant detection are introduced.
2 The unique structures and properties of MOFs lead to high sensing capabilities in environmental contaminant detection.
3 By combining with functional materials, MOF-based composites can improve sensor performance.

Keywords

Metal–organic frameworks Environmental contaminant Optical sensor Electrochemical sensor Field-effect transistor sensor Micro- and nanostructure
Fang, Xian, Boyang Zong, and Shun Mao. 2018. “Metal–Organic Framework-Based Sensors for Environmental Contaminant Sensing”. Nano-Micro Letters 10 (4):64. https://doi.org/10.1007/s40820-018-0218-0.
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