Issue

Vol. 10 No. 2 (2018)

One-Pot Synthesis of Co-Based Coordination Polymer Nanowire for Li-Ion Batteries with Great Capacity and Stable Cycling Stability

https://doi.org/10.1007/s40820-017-0177-x
Peng Wang
State Key Laboratory of Precision Spectroscopy, Shanghai Key Laboratory of Magnetic Resonance, School of Physics and Materials Science, East China Normal University, Shanghai 200062, People’s Republic of China
Xiaobing Lou
State Key Laboratory of Precision Spectroscopy, Shanghai Key Laboratory of Magnetic Resonance, School of Physics and Materials Science, East China Normal University, Shanghai 200062, People’s Republic of China
Chao Li
State Key Laboratory of Precision Spectroscopy, Shanghai Key Laboratory of Magnetic Resonance, School of Physics and Materials Science, East China Normal University, Shanghai 200062, People’s Republic of China
Xiaoshi Hu
State Key Laboratory of Precision Spectroscopy, Shanghai Key Laboratory of Magnetic Resonance, School of Physics and Materials Science, East China Normal University, Shanghai 200062, People’s Republic of China
Qi Yang
State Key Laboratory of Precision Spectroscopy, Shanghai Key Laboratory of Magnetic Resonance, School of Physics and Materials Science, East China Normal University, Shanghai 200062, People’s Republic of China
Bingwen Hu
State Key Laboratory of Precision Spectroscopy, Shanghai Key Laboratory of Magnetic Resonance, School of Physics and Materials Science, East China Normal University, Shanghai 200062, People’s Republic of China

Corresponding Author: Qi Yang

qyang@lps.ecnu.edu.cn

Nano-Micro Letters, Vol. 10 No. 2 (2018), Article Number: 19

Abstract

Nanowire coordination polymer cobalt–terephthalonitrile (Co-BDCN) was successfully synthesized using a simple solvothermal method and applied as anode material for lithium-ion batteries (LIBs). A reversible capacity of 1132 mAh g−1 was retained after 100 cycles at a rate of 100 mA g−1, which should be one of the best LIBs performances among metal organic frameworks and coordination polymers-based anode materials at such a rate. On the basis of the comprehensive structural and morphology characterizations including fourier transform infrared spectroscopy, 1H NMR, 13C NMR, and scanning electron microscopy, we demonstrated that the great electrochemical performance of the as-synthesized Co-BDCN coordination polymer can be attributed to the synergistic effect of metal centers and organic ligands, as well as the stability of the nanowire morphology during cycling.


Highlights:


1 Amide-group-coordinated cobalt–terephthalonitrile (Co-BDCN) coordination polymers, with a diameter distribution of 45–55 nm, were synthesized by a one-pot solvothermal method.
2 Reversible capacity of 1132 mAh g−1 was achieved at a current density of 100 mA g−1.

Keywords

Nanowire Coordination polymer Lithium-ion battery Anode Ultra-high capacity
Wang, Peng, Xiaobing Lou, Chao Li, Xiaoshi Hu, Qi Yang, and Bingwen Hu. 2017. “One-Pot Synthesis of Co-Based Coordination Polymer Nanowire for Li-Ion Batteries With Great Capacity and Stable Cycling Stability”. Nano-Micro Letters 10 (2):19. https://doi.org/10.1007/s40820-017-0177-x.
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. M. Armand, J.M. Tarascon, Building better batteries. Nature 451(7179), 652–657 (2008). https://doi.org/10.1038/451652a
  2. A. Banerjee, V. Aravindan, S. Bhatnagar, D. Mhamane, S. Madhavi, S. Ogale, Superior lithium storage properties of α-Fe2O3 nano-assembled spindles. Nano Energy 2(5), 890–896 (2013). https://doi.org/10.1016/j.nanoen.2013.03.006
  3. W. Yin, Y. Shen, F. Zou, X. Hu, B. Chi, Y. Huang, Metal-organic framework derived ZnO/ZnFe2O4/C nanocages as stable cathode material for reversible lithium-oxygen batteries. ACS Appl. Mater. Interfaces 7(8), 4947–4954 (2015). https://doi.org/10.1021/am509143t
  4. F. Zheng, D. Zhu, X. Shi, Q. Chen, Metal-organic framework-derived porous Mn1.8Fe1.2O4 nanocubes with an interconnected channel structure as high-performance anodes for lithium ion batteries. J. Mater. Chem. A 3(6), 2815–2824 (2015). https://doi.org/10.1039/C4TA06150K
  5. C. Li, T. Chen, W. Xu, X. Lou, L. Pan, Q. Chen, B. Hu, Mesoporous nanostructured Co3O4 derived from MOF template: a high-performance anode material for lithium-ion batteries. J. Mater. Chem. A 3(10), 5585–5591 (2015). https://doi.org/10.1039/C4TA06914E
  6. X. Hu, C. Li, X. Lou, X. Yan, Y. Ning, Q. Chen, B. Hu, Controlled synthesis of CoxMn3-xO4 nanoparticles with a tunable composition and size for high performance lithium-ion batteries. RSC Adv. 6(59), 54270–54276 (2016). https://doi.org/10.1039/C6RA08700K
  7. X. Hu, C. Li, X. Lou, Q. Yang, B. Hu, Hierarchical CuO octahedra inherited from copper metal-organic frameworks: high-rate and high-capacity lithium-ion storage materials stimulated by pseudocapacitance. J. Mater. Chem. A 5(25), 12828–12837 (2017). https://doi.org/10.1039/C7TA02953E
  8. J. Guo, B. Jiang, X. Zhang, H. Liu, Monodisperse SnO2 anchored reduced graphene oxide nanocomposites as negative electrode with high rate capability and long cyclability for lithium-ion batteries. J. Power Sources 262, 15–22 (2014). https://doi.org/10.1016/j.jpowsour.2014.03.085
  9. X. Zhang, H. Chen, Y. Xie, J. Guo, Ultralong life lithium-ion battery anode with superior high-rate capability and excellent cyclic stability from mesoporous Fe2O3@TiO2 core-shell nanorods. J. Mater. Chem. A 2(11), 3912–3918 (2014). https://doi.org/10.1039/c3ta14317a
  10. J. Guo, H. Zhu, Y. Sun, L. Tang, X. Zhang, Pie-like free-standing paper of graphene paper@Fe3O4 nanorod array@carbon as integrated anode for robust lithium storage. Chem. Eng. J. 309, 272–277 (2017). https://doi.org/10.1016/j.cej.2016.10.041
  11. C. Guan, X. Wang, Q. Zhang, Z. Fan, H. Zhang, H.J. Fan, Highly stable and reversible lithium storage in SnO2 nanowires surface coated with a uniform hollow shell by atomic layer deposition. Nano Lett. 14(8), 4852–4858 (2014). https://doi.org/10.1021/nl502192p
  12. C. Wu, J. Maier, Y. Yu, Sn-based nanoparticles encapsulated in a porous 3D graphene network: advanced anodes for high-rate and long life Li-ion batteries. Adv. Funct. Mater. 25(23), 3488–3496 (2015). https://doi.org/10.1002/adfm.201500514
  13. H. Jia, P. Gao, J. Yang, J. Wang, Y. Nuli, Z. Yang, Novel three-dimensional mesoporous silicon for high power lithium-ion battery anode material. Adv. Energy Mater. 1, 1036–1039 (2011). https://doi.org/10.1002/aenm.201100485
  14. D. Ma, Z. Cao, A. Hu, Si-based anode materials for Li-ion batteries: a mini review. Nano Micro Lett. 6(4), 347–358 (2014). https://doi.org/10.1007/s40820-014-0008-2
  15. X. Yu, J.B. Bates, G.E. Jellison, F.X. Hart, A stable thin-film lithium electrolyte: lithium phosphorus oxynitride. J. Electrochem. Soc. 144(2), 524–532 (1997). https://doi.org/10.1149/1.1837443
  16. L. Wang, X. He, J. Li, W. Sun, J. Gao, J. Guo, C. Jiang, Nano-structured phosphorus composite as high-capacity anode materials for lithium batteries. Angew. Chem. Int. Ed. 51(36), 9034–9037 (2012). https://doi.org/10.1002/anie.201204591
  17. L. Sun, M. Li, K. Sun, S. Yu, R. Wang, H. Xie, Electrochemical activity of black phosphorus as an anode material for lithium-ion batteries. J. Phy. Chem. C 116(28), 14772–14779 (2012). https://doi.org/10.1021/jp302265n
  18. Y. Kim, Y. Park, A. Choi, N.S. Choi, J. Kim, J. Lee, J.H. Ryu, S.M. Oh, K.T. Lee, An amorphous red phosphorus/carbon composite as a promising anode material for sodium ion batteries. Adv. Mater. 25(22), 3045–3049 (2013). https://doi.org/10.1002/adma.201204877
  19. P. Poizot, S. Laruelle, S. Grugeon, L. Dupont, J.M. Tarascon, Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature 407(6803), 496–499 (2000). https://doi.org/10.1038/35035045
  20. D. Deng, J.Y. Lee, Reversible storage of lithium in a rambutan-like tin–carbon electrode. Angew. Chem. Int. Ed. 48(9), 1660–1663 (2009). https://doi.org/10.1002/anie.200803420
  21. W. Zhang, J. Hu, Y. Guo, S. Zheng, L. Zhong, W. Song, L. Wan, Tin-nanoparticles encapsulated in elastic hollow carbon spheres for high-performance anode material in lithium-ion batteries. Adv. Mater. 20(6), 1160–1165 (2008). https://doi.org/10.1002/adma.200701364
  22. S. Yang, X. Feng, S. Ivanovici, K. Müllen, Fabrication of graphene-encapsulated oxide nanoparticles: towards high-performance anode materials for lithium storage. Angew. Chem. Int. Ed. 49(45), 8408–8411 (2010). https://doi.org/10.1002/anie.201003485
  23. H. Li, M. Eddaoudi, M. O’Keeffe, O.M. Yaghi, Design and synthesis of an exceptionally stable and highly porous metal-organic framework. Nature 402(6759), 276–279 (1999). https://doi.org/10.1038/46248
  24. M. Zhao, K. Yuan, Y. Wang, G. Li, J. Guo, L. Gu, W. Hu, H. Zhao, Z. Tang, Metal-organic frameworks as selectivity regulators for hydrogenation reactions. Nature 539(7627), 76–80 (2016). https://doi.org/10.1038/nature19763
  25. H. Xia, J. Zhang, Z. Yang, S. Guo, S. Guo, Q. Xu, 2D MOF nanoflake-assembled spherical microstructures for enhanced supercapacitor and electrocatalysis performances. Nano Micro Lett. 9(4), 43 (2017). https://doi.org/10.1007/s40820-017-0144-6
  26. P. Falcaro, R. Ricco, C.M. Doherty, K. Liang, A.J. Hill, M.J. Styles, MOF positioning technology and device fabrication. Chem. Soc. Rev. 43(16), 5513–5560 (2014). https://doi.org/10.1039/C4CS00089G
  27. Q. Zhu, X. Qiang, Metal-organic framework composites. Chem. Soc. Rev. 43(16), 5468–5512 (2014). https://doi.org/10.1039/C3CS60472A
  28. A. Fateeva, P. Horcajada, T. Devic, C. Serre, J. Marrot et al., Synthesis, structure, characterization, and redox properties of the porous MIL-68(Fe) solid. Eur. J. Inorg. Chem. 24, 3789–3794 (2010). https://doi.org/10.1002/ejic.201000486
  29. J. Shin, M. Kim, J. Cirera, S. Chen, G.J. Halder, T.A. Yersak, F. Paesani, S.M. Cohen, Y.S. Meng, MIL-101(Fe) as a lithium-ion battery electrode material: a relaxation and intercalation mechanism during lithium insertion. J. Mater. Chem. A 3(8), 4738–4744 (2015). https://doi.org/10.1039/C4TA06694D
  30. Z. Zhang, H. Yoshikawa, K. Awaga, Monitoring the solid-state electrochemistry of Cu(2,7-AQDC) (AQDC = Anthraquinone Dicarboxylate) in a lithium battery: coexistence of metal and ligand redox activities in a metal-organic framework. J. Am. Chem. Soc. 136(46), 16112–16115 (2014). https://doi.org/10.1021/ja508197w
  31. L. Hu, X. Lin, J. Mo, J. Lin, H. Gan, X. Yang, Y. Cai, Lead-based metal-organic framework with stable lithium anodic performance. Inorg. Chem. 56(8), 4289–4295 (2017). https://doi.org/10.1021/acs.inorgchem.6b02663
  32. S. Li, Q. Xu, Metal-organic frameworks as platforms for clean energy. Energy Environ. Sci. 6(6), 1656–1683 (2013). https://doi.org/10.1039/c3ee40507a
  33. T. Gong, X. Lou, E. Gao, B. Hu, Pillared-layer metal-organic frameworks for improved lithium-ion storage performance. ACS Appl. Mater. Interfaces 9(26), 21839–21847 (2017). https://doi.org/10.1021/acsami.7b05889
  34. D. Ji, H. Zhou, Y. Tong, J. Wang, M. Zhu, T. Chen, A. Yuan, Facile fabrication of MOF-derived octahedral CuO wrapped 3D graphene network as binder-free anode for high performance lithium-ion batteries. Chem. Eng. J. 313, 1623–1632 (2017). https://doi.org/10.1016/j.cej.2016.11.063
  35. D. Ji, H. Zhou, J. Zhang, Y. Dan, H. Yang, A. Yuan, Facile synthesis of a metal-organic framework-derived Mn2O3 nanowire coated three-dimensional graphene network for high-performance free-standing supercapacitor electrodes. J. Mater. Chem. A 4(21), 8283–8290 (2016). https://doi.org/10.1039/C6TA01377E
  36. X. Li, F. Cheng, S. Zhang, J. Chen, Shape-controlled synthesis and lithium-storage study of metal-organic frameworks Zn4O(1,3,5-benzenetribenzoate)2. J. Power Sources 160(1), 542–547 (2006). https://doi.org/10.1016/j.jpowsour.2006.01.015
  37. K. Saravanan, M. Nagarathinam, P. Balaya, J.J. Vittal, Lithium storage in a metal organic framework with diamondoid topology—a case study on metal formats. J. Mater. Chem. 20(38), 8329–8335 (2010). https://doi.org/10.1039/c0jm01671c
  38. Q. Liu, L. Yu, Y. Wang, Y. Ji, J. Horvat, M. Cheng, X. Jia, G. Wang, Manganese-based layered coordination polymer: synthesis, structural characterization, magnetic property, and electrochemical performance in lithium-ion batteries. Inorg. Chem. 52(6), 2817–2822 (2013). https://doi.org/10.1021/ic301579g
  39. S. Maiti, A. Pramanik, U. Manju, S. Mahanty, Reversible lithium storage in manganese 1,3,5-benzenetricarboxylate metal-organic framework with high capacity and rate performance. ACS Appl. Mater. Interfaces 7(30), 16357–16363 (2015). https://doi.org/10.1021/acsami.5b03414
  40. L. Gou, L. Hao, Y.X. Shi, S. Ma, X. Fan, L. Xu, D. Li, K. Wang, One-pot synthesis of a metal-organic framework as an anode for Li-ion batteries with improved capacity and cycling stability. J. Solid State Chem. 210(1), 121–124 (2014). https://doi.org/10.1016/j.jssc.2013.11.014
  41. C. Li, X. Hu, X. Lou, Q. Chen, B. Hu, Bimetallic coordination polymer as a promising anode material for lithium-ion batteries. Chem. Commun. 52(10), 2035–2038 (2016). https://doi.org/10.1039/C5CC07151H
  42. C. Li, X. Lou, M. Shen, X. Hu, Z. Guo, Y. Wang, B. Hu, Q. Chen, High anodic performance of Co 1,3,5-benzenetricarboxylate coordination polymers for Li-ion battery. ACS Appl. Mater. Interfaces 8(24), 15352–15360 (2016). https://doi.org/10.1021/acsami.6b03648
  43. M. Armand, S. Grugeon, H. Vezin, S. Laruelle, P. Ribière, P. Poizot, J.M. Tarascon, Conjugated dicarboxylate anodes for Li-ion batteries. Nat. Mater. 8(2), 120–125 (2009). https://doi.org/10.1038/nmat2372
  44. X. Ma, Y. He, Y. Hu, M. Lu, Copper(II)-catalyzed hydration of nitriles with the aid of acetaldoxime. Tetrahedron Lett. 53(4), 449–452 (2012). https://doi.org/10.1016/j.tetlet.2011.11.075
  45. R.J. Abraham, L. Griffiths, M. Perez, 1H NMR spectra. Part 30:1H chemical shifts in amides and the magnetic anisotropy, electric field and steric effects of the amide group. Magn. Reson. Chem. 51(3), 143–155 (2013). https://doi.org/10.1002/mrc.3920
  46. W. Xia, A. Mahmood, R. Zou, Q. Xu, Metal-organic frameworks and their derived nanostructures for electrochemical energy storage and conversion. Energy Environ. Sci. 8(7), 1837–1866 (2015). https://doi.org/10.1039/C5EE00762C
Read More
Author biographies are not available.
Download this PDF file
PDF SUPPLEMENTARY MATERIAL
Statistic
Read Counter : 3219 Download : 2447

Most read articles by the same author(s)