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Vol. 14 (2022)

Freestanding and Flexible Interfacial Layer Enables Bottom-Up Zn Deposition Toward Dendrite-Free Aqueous Zn-Ion Batteries

https://doi.org/10.1007/s40820-022-00921-6
Hangjun Ying
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Pengfei Huang
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Zhao Zhang
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Shunlong Zhang
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Qizhen Han
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Zhihao Zhang
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Jianli Wang
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China
Wei‑Qiang Han
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People’s Republic of China

Corresponding Author: Wei‑Qiang Han

hanwq@zju.edu.cn

Nano-Micro Letters, Vol. 14 (2022), Article Number: 180

Abstract

Aqueous rechargeable zinc ion batteries are regarded as a competitive alternative to lithium-ion batteries because of their distinct advantages of high security, high energy density, low cost, and environmental friendliness. However, deep-seated problems including Zn dendrite and adverse side reactions severely impede the practical application. In this work, we proposed a freestanding Zn-electrolyte interfacial layer composed of multicapsular carbon fibers (MCFs) to regulate the plating/stripping behavior of Zn anodes. The versatile MCFs protective layer can uniformize the electric field and Zn2+ flux, meanwhile, reduce the deposition overpotentials, leading to high-quality and rapid Zn deposition kinetics. Furthermore, the bottom-up and uniform deposition of Zn on the Zn-MCFs interface endows long-term and high-capacity plating. Accordingly, the Zn@MCFs symmetric batteries can keep working up to 1500 h with 5 mAh cm−2. The feasibility of the MCFs interfacial layer is also convinced in Zn@MCFs||MnO2 batteries. Remarkably, the Zn@MCFs||α-MnO2 batteries deliver a high specific capacity of 236.1 mAh g−1 at 1 A g−1 with excellent stability, and maintain an exhilarating energy density of 154.3 Wh kg−1 at 33% depth of discharge in pouch batteries.


Highlights:


1 Freestanding multicapsular carbon fibers (MCFs) cloth was synthesized by electrospinning and applied as interfacial layer to regulate the plating/stripping behavior of Zn anodes.
2 MCFs layer is supposed to uniformize the electric field and Zn2+ flux, and the moderate zincophilicity enables the bottom-up deposition of Zn on Zn@MCFs anode, thereby leading to high-quality and rapid Zn deposition kinetics.
3 Superior electrochemical performance of Zn@MCFs is achieved in symmetrical, asymmetrical and Zn||MnO2 batteries, including long cycling life, high coulombic efficiency and excellent rate performance.

Keywords

Aqueous zinc-ion battery Flexible interfacial layer Dendrite inhibition Bottom-up deposition Moderate zincophilicity
Ying, Hangjun, Pengfei Huang, Zhao Zhang, Shunlong Zhang, Qizhen Han, Zhihao Zhang, Jianli Wang, and Wei‑Qiang Han. 2022. “Freestanding and Flexible Interfacial Layer Enables Bottom-Up Zn Deposition Toward Dendrite-Free Aqueous Zn-Ion Batteries”. Nano-Micro Letters 14 (September):180. https://doi.org/10.1007/s40820-022-00921-6.
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References
  1. X. Feng, D. Ren, X. He, M. Ouyang, Mitigating thermal runaway of lithium-ion batteries. Joule 4(4), 743–770 (2020). https://doi.org/10.1016/j.joule.2020.02.010
  2. Y. Zhang, P. Chen, T. Wang, D. Su, C. Wang, Development of small-scale monitoring and modeling strategies for safe lithium-ion batteries. Batter. Supercaps 5(2), e202100292 (2022). https://doi.org/10.1002/batt.202100292
  3. L. Suo, O. Borodin, T. Gao, M. Olguin, J. Ho et al., “Water-in-salt” electrolyte enables high-voltage aqueous lithium-ion chemistries. Science 350(6263), 938–943 (2015). https://doi.org/10.1126/science.aab1595
  4. D. Bin, F. Wang, A.G. Tamirat, L. Suo, Y. Wang et al., Progress in aqueous rechargeable sodium-ion batteries. Adv. Energy Mater. 8(17), 1703008 (2018). https://doi.org/10.1002/aenm.201703008
  5. Q. Zhang, J. Luan, Y. Tang, X. Ji, H. Wang, Interfacial design of dendrite-free zinc anodes for aqueous zinc-ion batteries. Angew. Chem. Int. Ed. 59(32), 13180–13191 (2020). https://doi.org/10.1002/anie.202000162
  6. M. Song, H. Tan, D. Chao, H.J. Fan, Recent advances in Zn-ion batteries. Adv. Funct. Mater. 28(41), 1802564 (2018). https://doi.org/10.1002/adfm.201802564
  7. H. Tian, Z. Li, G. Feng, Z. Yang, D. Fox et al., Stable, high-performance, dendrite-free, seawater-based aqueous batteries. Nat. Commun. 12, 237 (2021). https://doi.org/10.1038/s41467-020-20334-6
  8. Y. Yang, C. Liu, Z. Lv, H. Yang, Y. Zhang et al., Synergistic manipulation of Zn2+ ion flux and desolvation effect enabled by anodic growth of a 3D ZnF2 matrix for long-lifespan and dendrite-free Zn metal anodes. Adv. Mater. 33(11), 2007388 (2021). https://doi.org/10.1002/adma.202007388
  9. B. Zhang, L. Qin, Y. Fang, Y. Chai, X. Xie et al., Tuning Zn2+ coordination tunnel by hierarchical gel electrolyte for dendrite-free zinc anode. Sci. Bull. 67(9), 955–962 (2022). https://doi.org/10.1016/j.scib.2022.01.027
  10. P. Ruan, S. Liang, B. Lu, H.J. Fan, J. Zhou, Design strategies for high-energy-density aqueous zinc batteries. Angew. Chem. Int. Ed. 61(17), e202200598 (2022). https://doi.org/10.1002/anie.202200598
  11. Z. Liu, L. Qin, B. Lu, X. Wu, S. Liang et al., Issues and opportunities facing aqueous Mn2+/MnO2-based batteries. Chemsuschem 15(10), e202200348 (2022). https://doi.org/10.1002/cssc.202200348
  12. D. Li, L. Cao, T. Deng, S. Liu, C. Wang, Design of a solid electrolyte interphase for aqueous Zn batteries. Angew. Chem. Int. Ed. 60(23), 13035–13041 (2021). https://doi.org/10.1002/anie.202103390
  13. Z. Cao, X. Zhu, D. Xu, P. Dong, M.O.L. Chee et al., Eliminating Zn dendrites by commercial cyanoacrylate adhesive for zinc ion battery. Energy Storage Mater. 36, 132–138 (2021). https://doi.org/10.1016/j.ensm.2020.12.022
  14. Z. Zhao, J. Zhao, Z. Hu, J. Li, J. Li et al., Long-life and deeply rechargeable aqueous Zn anodes enabled by a multifunctional brightener-inspired interphase. Energy Environ. Sci. 12(6), 1938–1949 (2019). https://doi.org/10.1039/C9EE00596J
  15. C. Deng, X. Xie, J. Han, Y. Tang, J. Gao et al., A sieve-functional and uniform-porous kaolin layer toward stable zinc metal anode. Adv. Funct. Mater. 30(21), 2000599 (2020). https://doi.org/10.1002/adfm.202000599
  16. L. Kang, M. Cui, F. Jiang, Y. Gao, H. Luo et al., Nanoporous CaCO3 coatings enabled uniform Zn stripping/plating for long-life zinc rechargeable aqueous batteries. Adv. Energy Mater. 8(25), 1801090 (2018). https://doi.org/10.1002/aenm.201801090
  17. C. Shen, X. Li, N. Li, K. Xie, J. Wang et al., Graphene-boosted, high-performance aqueous Zn-ion battery. ACS Appl. Mater. Interfaces 10(30), 25446–25453 (2018). https://doi.org/10.1021/acsami.8b07781
  18. M. Li, Q. He, Z. Li, Q. Li, Y. Zhang et al., A novel dendrite-free Mn2+/Zn2+ hybrid battery with 2.3 V voltage window and 11000-cycle lifespan. Adv. Energy Mater. 9(29), 1901469 (2019). https://doi.org/10.1002/aenm.201901469
  19. H. Yang, Z. Chang, Y. Qiao, H. Deng, X. Mu et al., Constructing a super-saturated electrolyte front surface for stable rechargeable aqueous zinc batteries. Angew. Chem. Int. Ed. 59(24), 9377–9381 (2020). https://doi.org/10.1002/anie.202001844
  20. Q. Zhang, J. Luan, L. Fu, S. Wu, Y. Tang et al., The three-dimensional dendrite-free zinc anode on a copper mesh with a zinc-oriented polyacrylamide electrolyte additive. Angew. Chem. Int. Ed. 58(44), 15841–15847 (2019). https://doi.org/10.1002/anie.201907830
  21. Y. Cui, Q. Zhao, X. Wu, X. Chen, J. Yang et al., An interface-bridged organic–inorganic layer that suppresses dendrite formation and side reactions for ultra-long-life aqueous zinc metal anodes. Angew. Chem. Int. Ed. 132(38), 16737–16744 (2020). https://doi.org/10.1002/ange.202005472
  22. N. Zhang, S. Huang, Z. Yuan, J. Zhu, Z. Zhao et al., Direct self-assembly of MXene on Zn anodes for dendrite-free aqueous zinc-ion batteries. Angew. Chem. Int. Ed. 60(6), 2861–2865 (2021). https://doi.org/10.1002/anie.202012322
  23. X. Zeng, J. Mao, J. Hao, J. Liu, S. Liu et al., Electrolyte design for in situ construction of highly Zn2+-conductive solid electrolyte interphase to enable high-performance aqueous Zn-ion batteries under practical conditions. Adv. Mater. 33(11), 2007416 (2021). https://doi.org/10.1002/adma.202007416
  24. Y. Liang, Y. Wang, H. Mi, L. Sun, D. Ma et al., Functionalized carbon nanofiber interlayer towards dendrite-free Zn-ion batteries. Chem. Eng. J. 425, 131862 (2021). https://doi.org/10.1016/j.cej.2021.131862
  25. P. Xue, C. Guo, N. Wang, K. Zhu, S. Jing et al., Synergistic manipulation of Zn2+ ion flux and nucleation induction effect enabled by 3D hollow SiO2/TiO2/carbon fiber for long-lifespan and dendrite-free Zn–metal composite anodes. Adv. Funct. Mater. 31(50), 2106417 (2021). https://doi.org/10.1002/adfm.202106417
  26. D. Saliba, M. Ammar, M. Rammal, M. Al-Ghoul, M. Hmadeh, Crystal growth of ZIF-8, ZIF-67, and their mixed-metal derivatives. J. Am. Chem. Soc. 140(5), 1812–1823 (2018). https://doi.org/10.1021/jacs.7b11589
  27. Z. Wang, J. Huang, Z. Guo, X. Dong, Y. Liu et al., A metal-organic framework host for highly reversible dendrite-free zinc metal anodes. Joule 3(5), 1289–1300 (2019). https://doi.org/10.1016/j.joule.2019.02.012
  28. H. Pan, Y. Shao, P. Yan, Y. Cheng, K.S. Han et al., Reversible aqueous zinc/manganese oxide energy storage from conversion reactions. Nat. Energy 1(5), 171 (2016). https://doi.org/10.1038/NENERGY.2016.39
  29. P. Giannozzi, S. Baroni, N. Bonini, M. Calandra, R. Car et al., Quantum espresso: a modular and open-source software project for quantum simulations of materials. J. Phys. Condens. Matter 21(39), 395502 (2009). https://doi.org/10.1088/0953-8984/21/39/395502
  30. P. Giannozzi, O. Andreussi, T. Brumme, O. Bunau, M.B. Nardelli et al., Advanced capabilities for materials modelling with quantum espresso. J. Phys. Condens. Matter 29(46), 465901 (2017). https://doi.org/10.1088/1361-648X/aa8f79
  31. J.P. Perdew, K. Burke, M. Ernzerhof, Generalized gradient approximation made simple. Phys. Rev. Lett. 77(18), 3865 (1996). https://doi.org/10.1103/PhysRevLett.77.3865
  32. P.E. Blöchl, O. Jepsen, O.K. Andersen, Improved tetrahedron method for brillouin-zone integrations. Phys. Rev. B 49(23), 16223 (1994). https://doi.org/10.1103/PhysRevB.49.16223
  33. G. Kresse, D. Joubert, From ultrasoft pseudopotentials to the projector augmented-wave method. Phys. Rev. B 59(3), 1758 (1999). https://doi.org/10.1103/PhysRevB.59.1758
  34. H.J. Monkhorst, J.D. Pack, Special points for brillouin-zone integrations. Phys. Rev. B 13(12), 5188 (1976). https://doi.org/10.1103/PhysRevB.13.5188
  35. C. Wang, J. Kim, M. Kim, H. Lim, M. Zhang et al., Nanoarchitectured metal–organic framework-derived hollow carbon nanofiber filters for advanced oxidation processes. J. Mater. Chem. A 7(22), 13743–13750 (2019). https://doi.org/10.1039/C9TA03128F
  36. Z. Sun, S. Vijay, H.H. Heenen, A.Y.S. Eng, W. Tu et al., Catalytic polysulfide conversion and physiochemical confinement for lithium–sulfur batteries. Adv. Energy Mater. 10(22), 1904010 (2020). https://doi.org/10.1002/aenm.201904010
  37. Y. Fang, Y. Zeng, Q. Jin, X.F. Lu, D. Luan et al., Nitrogen-doped amorphous Zn–carbon multichannel fibers for stable lithium metal anodes. Angew. Chem. Int. Ed. 133(15), 8596–8601 (2021). https://doi.org/10.1002/anie.202100471
  38. K. Yan, S. Zhao, J. Zhang, J. Safaei, X. Yu et al., Dendrite-free sodium metal batteries enabled by the release of contact strain on flexible and sodiophilic matrix. Nano Lett. 20(8), 6112–6119 (2020). https://doi.org/10.1021/acs.nanolett.0c02215
  39. H. Liu, J. Li, X. Zhang, X. Liu, Y. Yan et al., Ultrathin and ultralight Zn micromesh-induced spatial-selection deposition for flexible high-specific-energy Zn-ion batteries. Adv. Funct. Mater. 31(48), 2106550 (2021). https://doi.org/10.1002/adfm.202106550
  40. P. Chen, X. Yuan, Y. Xia, Y. Zhang, L. Fu et al., An artificial polyacrylonitrile coating layer confining zinc dendrite growth for highly reversible aqueous zinc-based batteries. Adv. Sci. 8(11), 2100309 (2021). https://doi.org/10.1002/advs.202100309
  41. X. Yang, C. Li, Z. Sun, S. Yang, Z. Shi et al., Interfacial manipulation via in-situ grown ZnSe overlayer toward highly reversible Zn metal anodes. Adv. Mater. 33(52), 2105951 (2021). https://doi.org/10.1002/adma.202105951
  42. X. Xie, S. Liang, J. Gao, S. Guo, J. Guo et al., Manipulating the ion-transfer kinetics and interface stability for high-performance zinc metal anodes. Energy Environ. Sci. 13(2), 503–510 (2020). https://doi.org/10.1039/C9EE03545A
  43. S. Li, J. Fu, G. Miao, S. Wang, W. Zhao et al., Toward planar and dendrite-free Zn electrodepositions by regulating Sn-crystal textured surface. Adv. Mater. 33(21), 2008424 (2021). https://doi.org/10.1002/adma.202008424
  44. J. Cao, D. Zhang, C. Gu, X. Wang, S. Wang et al., Manipulating crystallographic orientation of zinc deposition for dendrite-free zinc ion batteries. Adv. Energy Mater. 11(29), 2101299 (2021). https://doi.org/10.1002/aenm.202101299
  45. L.P. Wang, N.W. Li, T.S. Wang, Y.X. Yin, Y.G. Guo et al., Conductive graphite fiber as a stable host for zinc metal anodes. Electrochim. Acta 244, 172–177 (2017). https://doi.org/10.1016/j.electacta.2017.05.072
  46. A. Pei, G. Zheng, F. Shi, Y. Li, Y. Cui, Nanoscale nucleation and growth of electrodeposited lithium metal. Nano Lett. 17(2), 1132–1139 (2017). https://doi.org/10.1021/acs.nanolett.6b04755
  47. T. Wang, Y. Li, J. Zhang, K. Yan, P. Jaumaux et al., Immunizing lithium metal anodes against dendrite growth using protein molecules to achieve high energy batteries. Nat. Commun. 11, 5429 (2020). https://doi.org/10.1038/s41467-020-19246-2
  48. M. Li, J. Meng, Q. Li, M. Huang, X. Liu et al., Finely crafted 3D electrodes for dendrite-free and high-performance flexible fiber-shaped Zn–Co batteries. Adv. Funct. Mater. 28(32), 1802016 (2018). https://doi.org/10.1002/adfm.201802016
  49. X. Pu, B. Jiang, X. Wang, W. Liu, L. Dong et al., High-performance aqueous zinc-ion batteries realized by MOF materials. Nano Micro Lett. 12, 152 (2020). https://doi.org/10.1007/s40820-020-00487-1
  50. K. Hu, X. Guan, R. Lv, G. Li, Z. Hu et al., Stabilizing zinc metal anodes by artificial solid electrolyte interphase through a surface ion-exchanging strategy. Chem. Eng. J. 396, 125363 (2020). https://doi.org/10.1016/j.cej.2020.125363
  51. K. Zhao, C. Wang, Y. Yu, M. Yan, Q. Wei et al., Ultrathin surface coating enables stabilized zinc metal anode. Adv. Mater. Interfaces 5(16), 1800848 (2018). https://doi.org/10.1002/admi.201800848
  52. J. Hao, B. Li, X. Li, X. Zeng, S. Zhang et al., An in-depth study of Zn metal surface chemistry for advanced aqueous Zn-ion batteries. Adv. Mater. 32(34), 2003021 (2020). https://doi.org/10.1002/adma.202003021
  53. P. Zou, R. Zhang, L. Yao, J. Qin, K. Kisslinger et al., Ultrahigh-rate and long-life zinc–metal anodes enabled by self-accelerated cation migration. Adv. Energy Mater. 11(31), 2100982 (2021). https://doi.org/10.1002/aenm.202100982
  54. Q. Lu, C. Liu, Y. Du, X. Wang, L. Ding et al., Uniform Zn deposition achieved by Ag coating for improved aqueous zinc-ion batteries. ACS Appl. Mater. Interfaces 13(14), 16869–16875 (2021). https://doi.org/10.1021/acsami.0c22911
  55. D. Han, S. Wu, S. Zhang, Y. Deng, C. Cui et al., A corrosion-resistant and dendrite-free zinc metal anode in aqueous systems. Small 16(29), 2001736 (2020). https://doi.org/10.1002/smll.202001736
  56. X. Liu, J. Zhang, S. Guo, N. Pinna, Graphene/N-doped carbon sandwiched nanosheets with ultrahigh nitrogen doping for boosting lithium-ion batteries. J. Mater. Chem. A 4(4), 1423–1431 (2016). https://doi.org/10.1039/C5TA09066K
  57. Y. Borodko, S.E. Habas, M. Koebel, P. Yang, H. Frei et al., Probing the interaction of poly (vinylpyrrolidone) with platinum nanocrystals by UV-Raman and FTIR. J. Phys. Chem. B 110(46), 23052–23059 (2006). https://doi.org/10.1021/jp063338+
  58. Y. Wang, W. Zhao, Z. Qi, L. Zhang, Y. Zhang et al., Designing ZIF-8/hydroxylated MWCNT nanocomposites for phosphate adsorption from water: capability and mechanism. Chem. Eng. J. 394, 124992 (2020). https://doi.org/10.1016/j.cej.2020.124992
  59. Z. Sun, X. Wang, H. Zhao, S.W. Koh, J. Ge et al., Rambutan-like hollow carbon spheres decorated with vacancy-rich nickel oxide for energy conversion and storage. Carbon Energy 2(1), 122–130 (2020). https://doi.org/10.1002/cey2.16
  60. T. Wang, D. Su, Y. Chen, K. Yan, L. Yu et al., Biomimetic 3D Fe/CeO2 decorated N-doped carbon nanotubes architectures for high-performance lithium-sulfur batteries. Chem. Eng. J. 401, 126079 (2020). https://doi.org/10.1016/j.cej.2020.126079
  61. Y. Liu, N. Zhang, L. Jiao, J. Chen, Tin nanodots encapsulated in porous nitrogen-doped carbon nanofibers as a free-standing anode for advanced sodium-ion batteries. Adv. Mater. 27(42), 6702–6707 (2015). https://doi.org/10.1002/adma.201503015
  62. H. Ying, S. Zhang, Z. Meng, Z. Sun, W.Q. Han, Ultrasmall Sn nanodots embedded inside N-doped carbon microcages as high-performance lithium and sodium ion battery anodes. J. Mater. Chem. A 5(18), 8334–8342 (2017). https://doi.org/10.1039/C7TA01480E
  63. H. Ying, T. Yang, S. Zhang, R. Guo, J. Wang et al., Dual immobilization of SnOx nanops by N-doped carbon and TiO2 for high-performance lithium-ion battery anodes. ACS Appl. Mater. Interfaces 12(50), 55820–55829 (2020). https://doi.org/10.1021/acsami.0c15670
  64. Q. Cao, H. Gao, Y. Gao, J. Yang, C. Li et al., Regulating dendrite-free zinc deposition by 3D zincopilic nitrogen-doped vertical graphene for high-performance flexible Zn-ion batteries. Adv. Funct. Mater. 31(37), 2103922 (2021). https://doi.org/10.1002/adfm.202103922
  65. F. Xie, H. Li, X. Wang, X. Zhi, D. Chao et al., Mechanism for zincophilic sites on zinc-metal anode hosts in aqueous batteries. Adv. Energy Mater. 11(9), 2003419 (2021). https://doi.org/10.1002/aenm.202003419
  66. J. Zhou, M. Xie, F. Wu, Y. Mei, Y. Hao et al., Ultrathin surface coating of nitrogen-doped graphene enables stable zinc anodes for aqueous zinc-ion batteries. Adv. Mater. 33(33), 2101649 (2021). https://doi.org/10.1002/adma.202101649
  67. W. Sun, F. Wang, S. Hou, C. Yang, X. Fan et al., Zn/MnO2 battery chemistry with H+ and Zn2+ coinsertion. J. Am. Chem. Soc. 139(29), 9775–9778 (2017). https://doi.org/10.1021/jacs.7b04471
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