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Vol. 14 (2022)

Quasi-Solid-State Ion-Conducting Arrays Composite Electrolytes with Fast Ion Transport Vertical-Aligned Interfaces for All-Weather Practical Lithium-Metal Batteries

https://doi.org/10.1007/s40820-022-00952-z
Xinyang Li
School of Chemistry, Xi’an Key Laboratory of Sustainable Energy Materials Chemistry, State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an 710049, People’s Republic of China
Yong Wang
School of Chemistry, Xi’an Key Laboratory of Sustainable Energy Materials Chemistry, State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an 710049, People’s Republic of China
Kai Xi
School of Chemistry, Xi’an Key Laboratory of Sustainable Energy Materials Chemistry, State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an 710049, People’s Republic of China
Wei Yu
School of Chemistry, Xi’an Key Laboratory of Sustainable Energy Materials Chemistry, State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an 710049, People’s Republic of China
Jie Feng
School of Chemistry, Xi’an Key Laboratory of Sustainable Energy Materials Chemistry, State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an 710049, People’s Republic of China
Guoxin Gao
School of Chemistry, Xi’an Key Laboratory of Sustainable Energy Materials Chemistry, State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an 710049, People’s Republic of China
Hu Wu
School of Chemistry, Xi’an Key Laboratory of Sustainable Energy Materials Chemistry, State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an 710049, People’s Republic of China
Qiu Jiang
Yangtze Delta Region Institute (Huzhou), University of Electronic Science and Technology of China, Huzhou, Zhejiang 313001, People’s Republic of China
Amr Abdelkader
Faculty of Science and Technology, Bournemouth University, Talbot Campus, Fern Barrow, Poole BH12 5BB, UK
Weibo Hua
Institute for Applied Materials-Energy Storage Systems (IAM-ESS), Karlsruhe Institute of Technology (KIT), 76344 Eggenstein‑Leopoldshafen, Germany
Guiming Zhong
Laboratory of Advanced Spectroelectrochemsitry and Li‑ion Batteries, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, People’s Republic of China
Shujiang Ding
School of Chemistry, Xi’an Key Laboratory of Sustainable Energy Materials Chemistry, State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an 710049, People’s Republic of China

Corresponding Author: Shujiang Ding

dingsj@mail.xjtu.edu.cn

Nano-Micro Letters, Vol. 14 (2022), Article Number: 210

Abstract

The rapid improvement in the gel polymer electrolytes (GPEs) with high ionic conductivity brought it closer to practical applications in solid-state Li-metal batteries. The combination of solvent and polymer enables quasi-liquid fast ion transport in the GPEs. However, different ion transport capacity between solvent and polymer will cause local nonuniform Li+ distribution, leading to severe dendrite growth. In addition, the poor thermal stability of the solvent also limits the operating-temperature window of the electrolytes. Optimizing the ion transport environment and enhancing the thermal stability are two major challenges that hinder the application of GPEs. Here, a strategy by introducing ion-conducting arrays (ICA) is created by vertical-aligned montmorillonite into GPE. Rapid ion transport on the ICA was demonstrated by 6Li solid-state nuclear magnetic resonance and synchrotron X-ray diffraction, combined with computer simulations to visualize the transport process. Compared with conventional randomly dispersed fillers, ICA provides continuous interfaces to regulate the ion transport environment and enhances the tolerance of GPEs to extreme temperatures. Therefore, GPE/ICA exhibits high room-temperature ionic conductivity (1.08 mS cm−1) and long-term stable Li deposition/stripping cycles (> 1000 h). As a final proof, Li||GPE/ICA||LiFePO4 cells exhibit excellent cycle performance at wide temperature range (from 0 to 60 °C), which shows a promising path toward all-weather practical solid-state batteries.


Highlights:


1 The composite gel electrolyte with low tortuosity ion-conducting arrays (GPE/ICAs) exhibiting high room-temperature ionic conductivity (1.08 mS cm−1) was successfully prepared by directionally growing ice crystals and in-situ polymerization.
2 The stable and rapid Li+ migration through ICAs in the GPE is proved by 6Li solid-state nuclear magnetic resonance and synchrotron radiation X-ray diffraction combined with computer simulations.
3 Li/LiFePO4 full cells using GPE/ICAs exhibit excellent cycle performance and high-capacity retention at wide temperature (0–60 °C), which has the potential towards all-weather practical solid-state batteries.

Keywords

Solid-state batteries Composite electrolytes Vertical-aligned ion-conducting arrays Interfacial ion-conduction mechanism All-weather practical electrolyte design
Li, Xinyang, Yong Wang, Kai Xi, Wei Yu, Jie Feng, Guoxin Gao, Hu Wu, Qiu Jiang, Amr Abdelkader, Weibo Hua, Guiming Zhong, and Shujiang Ding. 2022. “Quasi-Solid-State Ion-Conducting Arrays Composite Electrolytes With Fast Ion Transport Vertical-Aligned Interfaces for All-Weather Practical Lithium-Metal Batteries”. Nano-Micro Letters 14 (October):210. https://doi.org/10.1007/s40820-022-00952-z.
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References
  1. B. Dunn, H. Kamath, J.M. Tarascon, Electrical energy storage for the grid: a battery of choices. Science 334(6058), 928–935 (2011). https://doi.org/10.1126/science.1212741
  2. S. Chu, Y. Cui, N. Liu, The path towards sustainable energy. Nat. Mater. 16(1), 16–22 (2016). https://doi.org/10.1038/nmat4834
  3. S. Randau, D.A. Weber, O. Kötz, R. Koerver, P. Braun et al., Benchmarking the performance of all-solid-state lithium batteries. Nat. Energy 5(3), 259–270 (2020). https://doi.org/10.1038/s41560-020-0565-1
  4. L. Zhou, T.T. Zuo, C.Y. Kwok, S.Y. Kim, A. Assoud et al., High areal capacity, long cycle life 4 V ceramic all-solid-state Li-ion batteries enabled by chloride solid electrolytes. Nat. Energy 7, 83–93 (2022). https://doi.org/10.1038/s41560-021-00952-0
  5. R.S. Chen, Q.H. Li, X.Q. Yu, L.Q. Chen, H. Li, Approaching practically accessible solid-state batteries: stability issues related to solid electrolytes and interfaces. Chem. Rev. 120(14), 6820–6877 (2020). https://doi.org/10.1021/acs.chemrev.9b00268
  6. L. Zeng, L. Jia, X. Liu, C. Zhang, A novel silicon/phosphorus co-flame retardant polymer electrolyte for high-safety all-solid-state lithium ion batteries. Polymers 12(12), 2937–2946 (2020). https://doi.org/10.3390/polym12122937
  7. Y. Wang, C.J. Zanelotti, X. Wang, R. Kerr, L. Jin et al., Solid-state rigid-rod polymer composite electrolytes with nanocrystalline lithium ion pathways. Nat. Mater. 20(9), 1255–1263 (2021). https://doi.org/10.1038/s41563-021-00995-4
  8. J. Wang, B. Ge, H. Li, M. Yang, J. Wang et al., Challenges and progresses of lithium-metal batteries. Chem. Eng. J. 420, 129739 (2021). https://doi.org/10.1016/j.cej.2021.129739
  9. N. Meng, F. Lian, G. Cui, Macromolecular design of lithium conductive polymer as electrolyte for solid-state lithium batteries. Small 17(3), 205762 (2021). https://doi.org/10.1002/smll.202005762
  10. X.Z. Chen, W.J. He, L.X. Ding, S.Q. Wang, H.H. Wang, Enhancing interfacial contact in all solid state batteries with a cathode-supported solid electrolyte membrane framework. Energy Environ. Sci. 12(3), 938–944 (2019). https://doi.org/10.1039/c8ee02617c
  11. K.E. Madsen, K.L. Bassett, K. Ta, B.A. Sforzo, K.E. Matusik et al., Direct observation of interfacial mechanical failure in thiophosphate solid electrolytes with operando X-ray tomography. Adv. Mater. Interfaces 7(19), 2000751 (2020). https://doi.org/10.1002/admi.202000751
  12. X.L. Cheng, J. Pan, Y. Zhao, M. Liao, H.S. Peng, Gel polymer electrolytes for electrochemical energy storage. Adv. Energy Mater. 8(7), 1702184 (2018). https://doi.org/10.1002/aenm.201702184
  13. M.J. Lee, J. Han, K. Lee, Y.J. Lee, B.G. Kim et al., Elastomeric electrolytes for high-energy solid-state lithium batteries. Nature 601(7892), 217–222 (2022). https://doi.org/10.1038/s41586-021-04209-4
  14. M. Zhu, J.X. Wu, Y. Wang, M.M. Song, L. Long et al., Recent advances in gel polymer electrolyte for high-performance lithium batteries. J. Energy Chem. 37, 126–142 (2019). https://doi.org/10.1016/j.jechem.2018.12.013
  15. G. Zhou, X. Lin, J. Liu, J. Yu, J. Wu et al., In situ formation of poly(butyl acrylate)-based non-flammable elastic quasi-solid electrolyte for dendrite-free flexible lithium metal batteries with long cycle life for wearable devices. Energy Storage Mater. 34, 629–639 (2021). https://doi.org/10.1016/j.ensm.2020.10.012
  16. F. Fu, W. Lu, Y. Zheng, K. Chen, C. Sun et al., Regulating lithium deposition via bifunctional regular-random cross-linking network solid polymer electrolyte for Li metal batteries. J. Power Sources 484, 229186 (2021). https://doi.org/10.1016/j.jpowsour.2020.229186
  17. S.J. Xu, Z.H. Sun, C.G. Sun, F. Li, K. Chen et al., Homogeneous and fast ion conduction of PEO-based solid-state electrolyte at low temperature. Adv. Funct. Mater. 30(51), 2007172 (2020). https://doi.org/10.1002/adfm.202007172
  18. X. He, Y.X. Ni, Y.P. Hou, Y. Lu, S. Jin et al., Insights into the ionic conduction mechanism of quasi-solid polymer electrolytes through multispectral characterization. Angew. Chem. Int. Ed. 60(42), 22672–22677 (2021). https://doi.org/10.1002/anie.202107648
  19. J. Yu, J. Liu, X. Lin, H.M. Law, G. Zhou et al., A solid-like dual-salt polymer electrolyte for Li-metal batteries capable of stable operation over an extended temperature range. Energy Storage Mater. 37, 609–618 (2021). https://doi.org/10.1016/j.ensm.2021.02.045
  20. C.H. Krause, A.J. Butzelaar, D. Diddens, D. Dong, P. Theato et al., Quasi-solid single ion conducting polymer electrolyte membrane containing novel fluorinated poly(arylene ether sulfonimide) for lithium metal batteries. J. Power Sources 484, 229267 (2021). https://doi.org/10.1016/j.jpowsour.2020.229267
  21. L. Dong, X. Zeng, J. Fu, L. Chen, J. Zhou et al., Cross-linked ionic copolymer solid electrolytes with loose coordination-assisted lithium transport for lithium batteries. Chem. Eng. J. 423, 130209 (2021). https://doi.org/10.1016/j.cej.2021.130209
  22. L. Yu, S. Guo, Y. Lu, Y. Li, X. Lan et al., Highly tough, Li-metal compatible organic–inorganic double-network solvate ionogel. Adv. Energy Mater. 9(22), 1900257 (2019). https://doi.org/10.1002/aenm.201900257
  23. N. Chen, Y. Xing, L. Wang, F. Liu, L. Li et al., “Tai chi” philosophy driven rigid-flexible hybrid ionogel electrolyte for high-performance lithium battery. Nano Energy 47, 35–42 (2018). https://doi.org/10.1016/j.nanoen.2018.02.036
  24. S.H. Kim, J.H. Kim, S.J. Cho, S.Y. Lee, All-solid-state printed bipolar Li-S batteries. Adv. Energy Mater. 9(40), 1901841 (2019). https://doi.org/10.1002/aenm.201901841
  25. B. Chen, Z. Huang, X.T. Chen, Y.R. Zhao, Q. Xu et al., A new composite solid electrolyte PEO/Li10GeP2S12/Sn for all-solid-state lithium battery. Electrochim. Acta 210, 905–914 (2016). https://doi.org/10.1016/j.electacta.2016.06.025
  26. D. Xu, J. Su, J. Jin, C. Sun, Y. Ruan et al., In situ generated fireproof gel polymer electrolyte with Li6.4Ga0.2La3Zr2O12 as initiator and ion-conductive filler. Adv. Energy Mater. 9(25), 1900611 (2019). https://doi.org/10.1002/aenm.201900611
  27. Q.P. Guo, Y. Han, H. Wang, S.Z. Xiong, W.W. Sun et al., Flame retardant and stable Li1.5Al0.5Ge1.5(PO4)3-supported ionic liquid gel polymer electrolytes for high safety rechargeable solid-state lithium metal batteries. J. Phys. Chem. C 122(19), 10334–10342 (2018). https://doi.org/10.1021/acs.jpcc.8b02693
  28. W.J. Hyun, C.M. Thomas, N.S. Luu, M.C. Hersam, Layered heterostructure ionogel electrolytes for high-performance solid-state lithium-ion batteries. Adv. Mater. 33(13), 2007864 (2021). https://doi.org/10.1002/adma.202007864
  29. T.K. Lee, R. Andersson, N.A. Dzulkurnain, G. Hernandez, J. Mindemark et al., Polyester-ZrO2 nanocomposite electrolytes with high Li transference numbers for ambient temperature all-solid-state lithium batteries. Batteries Supercaps 4(4), 653–662 (2020). https://doi.org/10.1002/batt.202000254
  30. L. Chen, W. Li, L.Z. Fan, C.W. Nan, Q. Zhang, Intercalated electrolyte with high transference number for dendrite-free solid-state lithium batteries. Adv. Funct. Mater. 29(28), 1901047 (2019). https://doi.org/10.1002/adfm.201901047
  31. Y. Wang, X. Li, Y. Qin, D. Zhang, Z. Song et al., Local electric field effect of montmorillonite in solid polymer electrolytes for lithium metal batteries. Nano Energy 90, 106490 (2021). https://doi.org/10.1016/j.nanoen.2021.106490
  32. Y.M. Jeon, S. Kim, M. Lee, W.B. Lee, J.H. Park, Polymer-clay nanocomposite solid-state electrolyte with selective cation transport boosting and retarded lithium dendrite formation. Adv. Energy Mater. 10(47), 2003114 (2020). https://doi.org/10.1002/aenm.202003114
  33. W. Zha, W. Li, Y. Ruan, J. Wang, Z. Wen, In situ fabricated ceramic/polymer hybrid electrolyte with vertically aligned structure for solid-state lithium batteries. Energy Storage Mater. 36, 171–178 (2021). https://doi.org/10.1016/j.ensm.2020.12.028
  34. H. Zhai, P. Xu, M. Ning, Q. Cheng, J. Mandal et al., A flexible solid composite electrolyte with vertically aligned and connected ion-conducting nanops for lithium batteries. Nano Lett. 17(5), 3182–3187 (2017). https://doi.org/10.1021/acs.nanolett.7b00715
  35. X. Wang, H.W. Zhai, B.Y. Qie, Q. Cheng, A.J. Li et al., Rechargeable solid-state lithium metal batteries with vertically aligned ceramic nanop/polymer composite electrolyte. Nano Energy 60, 205–212 (2019). https://doi.org/10.1016/j.nanoen.2019.03.051
  36. J. Wan, J. Xie, X. Kong, Z. Liu, K. Liu et al., Ultrathin, flexible, solid polymer composite electrolyte enabled with aligned nanoporous host for lithium batteries. Nat. Nanotechnol. 14(7), 705–711 (2019). https://doi.org/10.1038/s41565-019-0465-3
  37. J. Dai, K. Fu, Y. Gong, J. Song, C. Chen et al., Flexible solid-state electrolyte with aligned nanostructures derived from wood. ACS Mater. Lett. 1(3), 354–361 (2019). https://doi.org/10.1021/acsmaterialslett.9b00189
  38. M.K. Wang, S.J. Dong, Enhanced electrochemical properties of nanocomposite polymer electrolyte based on copolymer with exfoliated clays. J. Power Sources 170(2), 425–432 (2007). https://doi.org/10.1016/j.jpowsour.2007.04.031
  39. W. Liu, S.W. Lee, D. Lin, F. Shi, S. Wang et al., Enhancing ionic conductivity in composite polymer electrolytes with well-aligned ceramic nanowires. Nat. Energy 2(5), 17035 (2017). https://doi.org/10.1038/nenergy.2017.35
  40. Y.Y. Yan, J.W. Ju, S.M. Dong, Y.T. Wang, L. Huang et al., In situ polymerization permeated three-dimensional Li+-percolated porous oxide ceramic framework boosting all solid-state lithium metal battery. Adv. Sci. 8(9), 2003887 (2021). https://doi.org/10.1002/advs.202003887
  41. T. Chen, T. Liu, T. Ding, B. Pang, L. Wang et al., Surface oxygen injection in tin disulfide nanosheets for efficient CO2 electroreduction to formate and syngas. Nano-Micro Lett. 13, 189 (2021). https://doi.org/10.1007/s40820-021-00703-6
  42. W. Hua, S. Wang, K. Wang, A. Missyul, Q. Fu et al., Li+/Na+ ion exchange in layered Na2/3(Ni0.25Mn0.75)O2: a simple and fast way to synthesize O3/O2-type layered oxides. Chem. Mater. 33(14), 5606–5617 (2021). https://doi.org/10.1021/acs.chemmater.1c00962
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