Issue

Vol. 16 (2024)

Progress on Transition Metal Ions Dissolution Suppression Strategies in Prussian Blue Analogs for Aqueous Sodium-/Potassium-Ion Batteries

https://doi.org/10.1007/s40820-024-01355-y
Wenli Shu
Department of Physical Science and Technology, School of Science, Wuhan University of Technology, Wuhan 430070, People’s Republic of China
Junxian Li
School of Materials Science and Engineering, State Key Laboratory of Advanced Technology for Materials Synthesis, Wuhan University of Technology, Wuhan 430070, People’s Republic of China
Guangwan Zhang
School of Materials Science and Engineering, State Key Laboratory of Advanced Technology for Materials Synthesis, Wuhan University of Technology, Wuhan 430070, People’s Republic of China
Jiashen Meng
School of Materials Science and Engineering, State Key Laboratory of Advanced Technology for Materials Synthesis, Wuhan University of Technology, Wuhan 430070, People’s Republic of China
Xuanpeng Wang
Department of Physical Science and Technology, School of Science, Wuhan University of Technology, Wuhan 430070, People’s Republic of China
Liqiang Mai
School of Materials Science and Engineering, State Key Laboratory of Advanced Technology for Materials Synthesis, Wuhan University of Technology, Wuhan 430070, People’s Republic of China

Corresponding Author: Xuanpeng Wang

wxp122525691@whut.edu.cn

Nano-Micro Letters, Vol. 16 (2024), Article Number: 128

Abstract

Aqueous sodium-ion batteries (ASIBs) and aqueous potassium-ion batteries (APIBs) present significant potential for large-scale energy storage due to their cost-effectiveness, safety, and environmental compatibility. Nonetheless, the intricate energy storage mechanisms in aqueous electrolytes place stringent requirements on the host materials. Prussian blue analogs (PBAs), with their open three-dimensional framework and facile synthesis, stand out as leading candidates for aqueous energy storage. However, PBAs possess a swift capacity fade and limited cycle longevity, for their structural integrity is compromised by the pronounced dissolution of transition metal (TM) ions in the aqueous milieu. This manuscript provides an exhaustive review of the recent advancements concerning PBAs in ASIBs and APIBs. The dissolution mechanisms of TM ions in PBAs, informed by their structural attributes and redox processes, are thoroughly examined. Moreover, this study delves into innovative design tactics to alleviate the dissolution issue of TM ions. In conclusion, the paper consolidates various strategies for suppressing the dissolution of TM ions in PBAs and posits avenues for prospective exploration of high-safety aqueous sodium-/potassium-ion batteries.


Highlights:
1 Comprehensive insights into Prussian blue analogs for aqueous sodium- and potassium-ion batteries.
2 Unveiling the dissolution mechanism of transition metal ions in Prussian blue analogs.
3 Innovative solutions to suppression transition metal ion dissolution, spanning electrolyte engineering, transition metal doping/substitution, minimize defects, and composite materials.

Keywords

Prussian blue analogs Transition metal ions dissolution Suppression strategies Aqueous sodium-ion batteries Aqueous potassium-ion batteries
Shu, Wenli, Junxian Li, Guangwan Zhang, Jiashen Meng, Xuanpeng Wang, and Liqiang Mai. 2024. “Progress on Transition Metal Ions Dissolution Suppression Strategies in Prussian Blue Analogs for Aqueous Sodium-/Potassium-Ion Batteries”. Nano-Micro Letters 16 (February):128. https://doi.org/10.1007/s40820-024-01355-y.
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References
  1. Z. Yang, J. Zhang, M.C.W. Kintner-Meyer, X. Lu, D. Choi et al., Electrochemical energy storage for green grid. Chem. Rev. 111, 3577–3613 (2011). https://doi.org/10.1021/cr100290v
  2. D. Larcher, J.-M. Tarascon, Towards greener and more sustainable batteries for electrical energy storage. Nat. Chem. 7, 19–29 (2015). https://doi.org/10.1038/nchem.2085
  3. X.-T. Wang, Z.-Y. Gu, E.H. Ang, X.-X. Zhao, X.-L. Wu et al., Prospects for managing end-of-life lithium-ion batteries: present and future. Interdiscip. Mater. 1, 417–433 (2022). https://doi.org/10.1002/idm2.12041
  4. D. Chao, W. Zhou, F. Xie, C. Ye, H. Li et al., Roadmap for advanced aqueous batteries: from design of materials to applications. Sci. Adv. 6, eaba4098 (2020). https://doi.org/10.1126/sciadv.aba4098
  5. N. Nitta, F. Wu, J.T. Lee, G. Yushin, Li-ion battery materials: present and future. Mater. Today 18, 252–264 (2015). https://doi.org/10.1016/j.mattod.2014.10.040
  6. K. Liu, Y. Liu, D. Lin, A. Pei, Y. Cui, Materials for lithium-ion battery safety. Sci. Adv. 4, eaas9820 (2018). https://doi.org/10.1126/sciadv.aas9820
  7. H.-J. Liang, Z.-Y. Gu, X.-X. Zhao, J.-Z. Guo, J.-L. Yang et al., Advanced flame-retardant electrolyte for highly stabilized K-ion storage in graphite anode. Sci. Bull. 67, 1581–1588 (2022). https://doi.org/10.1016/j.scib.2022.07.002
  8. R.Y. Wang, C.D. Wessells, R.A. Huggins, Y. Cui, Highly reversible open framework nanoscale electrodes for divalent ion batteries. Nano Lett. 13, 5748–5752 (2013). https://doi.org/10.1021/nl403669a
  9. K. Wang, H. Li, Z. Xu, H. Wang, M. Ge et al., Emerging photo-integrated rechargeable aqueous zinc-ion batteries and capacitors toward direct solar energy conversion and storage. Carbon Neutr. 2, 37–53 (2023). https://doi.org/10.1002/cnl2.41
  10. M. Zhu, H. Wang, W. Lin, D. Chan, H. Li et al., Amphipathic molecules endowing highly structure robust and fast kinetic vanadium-based cathode for high-performance zinc-ion batteries. Small Struct. 3, 2200016 (2022). https://doi.org/10.1002/sstr.202200016
  11. H. Wang, H. Li, Y. Tang, Z. Xu, K. Wang et al., Stabilizing Zn anode interface by simultaneously manipulating the thermodynamics of Zn nucleation and overpotential of hydrogen evolution. Adv. Funct. Mater. 32, 2270271 (2022). https://doi.org/10.1002/adfm.202270271
  12. D. Xie, Y. Sang, D.-H. Wang, W.-Y. Diao, F.-Y. Tao et al., ZnF2-Riched inorganic/organic hybrid Sei: in situ-chemical construction and performance-improving mechanism for aqueous zinc-ion batteries. Angew. Chem. Int. Ed. 62, e202216934 (2023). https://doi.org/10.1002/anie.202216934
  13. J. Jiang, J. Liu, Iron anode-based aqueous electrochemical energy storage devices: recent advances and future perspectives. Interdiscip. Mater. 1, 116–139 (2022). https://doi.org/10.1002/idm2.12007
  14. J.-L. Yang, J.-M. Cao, X.-X. Zhao, K.-Y. Zhang, S.-H. Zheng et al., Advanced aqueous proton batteries: working mechanism, key materials, challenges and prospects. EnergyChem 4, 100092 (2022). https://doi.org/10.1016/j.enchem.2022.100092
  15. G. Yang, Y. Zhu, Q. Zhao, Z. Hao, Y. Lu et al., Advanced organic electrode materials for aqueous rechargeable batteries. Sci. China Chem. (2023). https://doi.org/10.1007/s11426-023-1654-5
  16. C. Deng, Y. Li, J. Huang, Building smarter aqueous batteries. Small. Methods (2023). https://doi.org/10.1002/smtd.202300832
  17. W. Li, J.R. Dahn, D.S. Wainwright, Rechargeable lithium batteries with aqueous electrolytes. Science 264, 1115–1118 (1994). https://doi.org/10.1126/science.264.5162.1115
  18. K. Kubota, M. Dahbi, T. Hosaka, S. Kumakura, S. Komaba, Towards K-ion and Na-ion batteries as “beyond Li-ion.” Chem. Rec. 18, 459–479 (2018). https://doi.org/10.1002/tcr.201700057
  19. T. Hosaka, K. Kubota, A.S. Hameed, S. Komaba, Research development on K-ion batteries. Chem. Rev. 120, 6358–6466 (2020). https://doi.org/10.1021/acs.chemrev.9b00463
  20. F. Wan, Z. Niu, Design strategies for vanadium-based aqueous zinc-ion batteries. Angew. Chem. Int. Ed. 58, 16358–16367 (2019). https://doi.org/10.1002/anie.201903941
  21. Y. Lu, X. Wu, Z. Li, H. Jiang, L. Liu et al., Na+/K+-codoped amorphous manganese oxide with enhanced performance for aqueous sodium-ion battery. J. Alloys Compd. 937, 168344 (2023). https://doi.org/10.1016/j.jallcom.2022.168344
  22. C. Zhao, Q. Wang, Z. Yao, J. Wang, B. Sánchez-Lengeling et al., Rational design of layered oxide materials for sodium-ion batteries. Science 370, 708–711 (2020). https://doi.org/10.1126/science.aay9972
  23. X. Zhang, X. Yang, G. Sun, S. Yao, Y. Xie et al., Hydration enables air-stable and high-performance layered cathode materials for both organic and aqueous potassium-ion batteries. Adv. Funct. Mater. 32, 2204318 (2022). https://doi.org/10.1002/adfm.202204318
  24. L. Sharma, A. Manthiram, Polyanionic insertion hosts for aqueous rechargeable batteries. J. Mater. Chem. A 10, 6376–6396 (2022). https://doi.org/10.1039/D1TA11080B
  25. H. Zhang, X. Tan, H. Li, S. Passerini, W. Huang, Assessment and progress of polyanionic cathodes in aqueous sodium batteries. Energy Environ. Sci. 14, 5788–5800 (2021). https://doi.org/10.1039/D1EE01392K
  26. K.-Y. Zhang, Z.-Y. Gu, E.H. Ang, J.-Z. Guo, X.-T. Wang et al., Advanced polyanionic electrode materials for potassium-ion batteries: progresses, challenges and application prospects. Mater. Today 54, 189–201 (2022). https://doi.org/10.1016/j.mattod.2022.02.013
  27. K. Holguin, M. Mohammadiroudbari, K. Qin, C. Luo, Organic electrode materials for non-aqueous, aqueous, and all-solid-state Na-ion batteries. J. Mater. Chem. A 9, 19083–19115 (2021). https://doi.org/10.1039/D1TA00528F
  28. S. Zhang, C. Zhao, K. Zhu, J. Zhao, Y. Gao et al., An environment-friendly high-performance aqueous Mg-Na hybrid-ion battery using an organic polymer anode. Energy Environ. Mater. 6, 12388 (2023). https://doi.org/10.1002/eem2.12388
  29. R. Wang, M. Shi, L. Li, Y. Zhao, L. Zhao et al., In-situ investigation and application of cyano-substituted organic electrode for rechargeable aqueous Na-ion batteries. Chem. Eng. J. 451, 138652 (2023). https://doi.org/10.1016/j.cej.2022.138652
  30. K. Nakamoto, R. Sakamoto, Y. Sawada, M. Ito, S. Okada, Over 2 V aqueous sodium-ion battery with Prussian blue-type electrodes. Small Meth. 3, 1800220 (2019). https://doi.org/10.1002/smtd.201800220
  31. L. Jiang, Y. Lu, C. Zhao, L. Liu, J. Zhang et al., Building aqueous K-ion batteries for energy storage. Nat. Energy 4, 495–503 (2019). https://doi.org/10.1038/s41560-019-0388-0
  32. J. Ge, L. Fan, A.M. Rao, J. Zhou, B. Lu, Surface-substituted Prussian blue analogue cathode for sustainable potassium-ion batteries. Nat. Sustain. 5, 225–234 (2022). https://doi.org/10.1038/s41893-021-00810-7
  33. C. Xu, Z. Yang, X. Zhang, M. Xia, H. Yan et al., Prussian blue analogues in aqueous batteries and desalination batteries. Nano-Micro Lett. 13, 166 (2021). https://doi.org/10.1007/s40820-021-00700-9
  34. A. Simonov, T. De Baerdemaeker, H.L.B. Boström, M.L. Ríos Gómez, H.J. Gray et al., Hidden diversity of vacancy networks in Prussian blue analogues. Nature 578, 256–260 (2020). https://doi.org/10.1038/s41586-020-1980-y
  35. J. Peng, W. Zhang, Q. Liu, J. Wang, S. Chou et al., Prussian blue analogues for sodium-ion batteries: past, present, and future. Adv. Mater. 34, e2108384 (2022). https://doi.org/10.1002/adma.202108384
  36. P.N. Le Pham, R. Wernert, M. Cahu, M.T. Sougrati, G. Aquilanti et al., Prussian blue analogues for potassium-ion batteries: insights into the electrochemical mechanisms. J. Mater. Chem. A 11, 3091–3104 (2023). https://doi.org/10.1039/d2ta08439b
  37. Z. Wang, W. Zhuo, J. Li, L. Ma, S. Tan et al., Regulation of ferric iron vacancy for Prussian blue analogue cathode to realize high-performance potassium ion storage. Nano Energy 98, 107243 (2022). https://doi.org/10.1016/j.nanoen.2022.107243
  38. C. Ding, Z. Chen, C. Cao, Y. Liu, Y. Gao, Advances in Mn-based electrode materials for aqueous sodium-ion batteries. Nano-Micro Lett. 15, 192 (2023). https://doi.org/10.1007/s40820-023-01162-x
  39. W. Zhuo, J. Li, X. Li, L. Ma, G. Yan et al., Improving rechargeability of Prussian blue cathode by graphene as conductive agent for sodium ion batteries. Surf. Interfaces 23, 100911 (2021). https://doi.org/10.1016/j.surfin.2020.100911
  40. W. Shu, C. Han, X. Wang, Prussian blue analogues cathodes for nonaqueous potassium-ion batteries: past, present, and future. Adv. Funct. Mater. (2023). https://doi.org/10.1002/adfm.202309636
  41. V.D. Neff, Electrochemical oxidation and reduction of thin films of Prussian blue. J. Electrochem. Soc. 125, 886–887 (1978). https://doi.org/10.1149/1.2131575
  42. D. Ellis, M. Eckhoff, V.D. Neff, Electrochromism in the mixed-valence hexacyanides. 1. Voltammetric and spectral studies of the oxidation and reduction of thin films of Prussian blue. J. Phys. Chem. 85, 1225–1231 (1981). https://doi.org/10.1021/j150609a026
  43. K. Itaya, T. Ataka, S. Toshima, Spectroelectrochemistry and electrochemical preparation method of Prussian blue modified electrodes. J. Am. Chem. Soc. 104(18), 4767–4772 (1982). https://doi.org/10.1021/ja00382a006
  44. A.A. Karyakin, Prussian blue and its analogues: electrochemistry and analytical applications. Electroanalysis 13, 813–819 (2001). https://doi.org/10.1002/1521-4109
  45. M. Pasta, C.D. Wessells, R.A. Huggins, Y. Cui, A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage. Nat. Commun. 3, 1149 (2012). https://doi.org/10.1038/ncomms2139
  46. C.D. Wessells, R.A. Huggins, Y. Cui, Copper hexacyanoferrate battery electrodes with long cycle life and high power. Nat. Commun. 2, 550 (2011). https://doi.org/10.1038/ncomms1563
  47. G. Fang, Q. Wang, J. Zhou, Y. Lei, Z. Chen et al., Metal organic framework-templated synthesis of bimetallic selenides with rich phase boundaries for sodium-ion storage and oxygen evolution reaction. ACS Nano 13, 5635–5645 (2019). https://doi.org/10.1021/acsnano.9b00816
  48. J. Li, P. Ruan, X. Chen, S. Lei, B. Lu et al., Aqueous batteries for human body electronic devices. ACS Energy Lett. 8, 2904–2918 (2023). https://doi.org/10.1021/acsenergylett.3c00678
  49. S. Qiu, Y. Xu, X. Wu, X. Ji, Prussian blue analogues as electrodes for aqueous monovalent ion batteries. Electrochem. Energy Rev. 5, 242–262 (2022). https://doi.org/10.1007/s41918-020-00088-x
  50. A. Zhou, W. Cheng, W. Wang, Q. Zhao, J. Xie et al., Hexacyanoferrate-type Prussian blue analogs: principles and advances toward high-performance sodium and potassium ion batteries. Adv. Energy Mater. 11, 2000943 (2021). https://doi.org/10.1002/aenm.202000943
  51. D. Kim, T. Hwang, J.-M. Lim, M.-S. Park, M. Cho et al., Hexacyanometallates for sodium-ion batteries: insights into higher redox potentials using d electronic spin configurations. Phys. Chem. Chem. Phys. 19, 10443–10452 (2017). https://doi.org/10.1039/c7cp00378a
  52. A. Kumar, S.M. Yusuf, L. Keller, Structural and magnetic properties of Fe[Fe(CN)6]·4H2O. Phys. Rev. B 71, 054414 (2005). https://doi.org/10.1103/PhysRevB.71.054414
  53. N. Shimamoto, S.-I. Ohkoshi, O. Sato, K. Hashimoto, Control of charge-transfer-induced spin transition temperature on cobalt-iron Prussian blue analogues. Inorg. Chem. 41, 678–684 (2002). https://doi.org/10.1021/ic010915u
  54. A. Paolella, C. Faure, V. Timoshevskii, S. Marras, G. Bertoni et al., A review on hexacyanoferrate-based materials for energy storage and smart windows: challenges and perspectives. J. Mater. Chem. A 5, 18919–18932 (2017). https://doi.org/10.1039/C7TA05121B
  55. H.J. Buser, D. Schwarzenbach, W. Petter, A. Ludi, The crystal structure of Prussian Blue: Fe4[Fe(CN)6]3.xH2O. Inorg. Chem. 16, 2704–2710 (1977). https://doi.org/10.1021/ic50177a008
  56. J. Sun, H. Ye, J.A.S. Oh, A. Plewa, Y. Sun et al., Elevating the discharge plateau of Prussian blue analogs through low-spin fe redox induced intercalation pseudocapacitance. Energy Storage Mater. 43, 182–189 (2021). https://doi.org/10.1016/j.ensm.2021.09.004
  57. M. Jiang, Z. Hou, L. Ren, Y. Zhang, J.-G. Wang, Prussian blue and its analogues for aqueous energy storage: from fundamentals to advanced devices. Energy Storage Mater. 50, 618–640 (2022). https://doi.org/10.1016/j.ensm.2022.06.006
  58. L.-P. Wang, P.-F. Wang, T.-S. Wang, Y.-X. Yin, Y.-G. Guo et al., Prussian blue nanocubes as cathode materials for aqueous Na-Zn hybrid batteries. J. Power. Sources 355, 18–22 (2017). https://doi.org/10.1016/j.jpowsour.2017.04.049
  59. Z. Wang, Y. Huang, D. Chu, C. Li, Y. Zhang et al., Continuous conductive networks built by Prussian blue cubes and mesoporous carbon lead to enhanced sodium-ion storage performances. ACS Appl. Mater. Interfaces 13, 38202–38212 (2021). https://doi.org/10.1021/acsami.1c06634
  60. T. Shao, C. Li, C. Liu, W. Deng, W. Wang et al., Electrolyte regulation enhances the stability of Prussian blue analogues in aqueous Na-ion storage. J. Mater. Chem. A 7, 1749–1755 (2019). https://doi.org/10.1039/C8TA10860A
  61. X. Wu, M. Sun, S. Guo, J. Qian, Y. Liu et al., Vacancy-free Prussian blue nanocrystals with high capacity and superior cyclability for aqueous sodium-ion batteries. ChemNanoMat 1, 188–193 (2015). https://doi.org/10.1002/cnma.201500021
  62. L. Wang, J. Song, R. Qiao, L.A. Wray, M.A. Hossain et al., Rhombohedral Prussian white as cathode for rechargeable sodium-ion batteries. J. Am. Chem. Soc. 137, 2548–2554 (2015). https://doi.org/10.1021/ja510347s
  63. M. Qin, W. Ren, J. Meng, X. Wang, X. Yao et al., Realizing superior Prussian blue positive electrode for potassium storage via ultrathin nanosheet assembly. ACS Sustain. Chem. Eng. 7, 11564–11570 (2019). https://doi.org/10.1021/acssuschemeng.9b01454
  64. A. Zhou, Z. Xu, H. Gao, L. Xue, J. Li et al., Size-, water-, and defect-regulated potassium manganese hexacyanoferrate with superior cycling stability and rate capability for low-cost sodium-ion batteries. Small 15, e1902420 (2019). https://doi.org/10.1002/smll.201902420
  65. L. Deng, J. Qu, X. Niu, J. Liu, J. Zhang et al., Defect-free potassium manganese hexacyanoferrate cathode material for high-performance potassium-ion batteries. Nat. Commun. 12, 2167 (2021). https://doi.org/10.1038/s41467-021-22499-0
  66. Y. Shang, X. Li, J. Song, S. Huang, Z. Yang et al., Unconventional Mn vacancies in Mn-Fe Prussian blue analogs: suppressing jahn-teller distortion for ultrastable sodium storage. Chem 6, 1804–1818 (2020). https://doi.org/10.1016/j.chempr.2020.05.004
  67. F. Gebert, D.L. Cortie, J.C. Bouwer, W. Wang, Z. Yan et al., Epitaxial nickel ferrocyanide stabilizes jahn-teller distortions of manganese ferrocyanide for sodium-ion batteries. Angew. Chem. Int. Ed. 60, 18519–18526 (2021). https://doi.org/10.1002/anie.202106240
  68. L. Shen, Y. Jiang, Y. Liu, J. Ma, T. Sun et al., High-stability monoclinic nickel hexacyanoferrate cathode materials for ultrafast aqueous sodium ion battery. Chem. Eng. J. 388, 124228 (2020). https://doi.org/10.1016/j.cej.2020.124228
  69. W. Ren, X. Chen, C. Zhao, Ultrafast aqueous potassium-ion batteries cathode for stable intermittent grid-scale energy storage. Adv. Energy Mater. 8, 1801413 (2018). https://doi.org/10.1002/aenm.201801413
  70. S.-B. Son, Z. Zhang, J. Gim, C.S. Johnson, Y. Tsai et al., Transition metal dissolution in lithium-ion cells: a piece of the puzzle. J. Phys. Chem. C 127, 1767–1775 (2023). https://doi.org/10.1021/acs.jpcc.2c08234
  71. Y. Zhang, A. Hu, D. Xia, S. Hwang, S. Sainio et al., Operando characterization and regulation of metal dissolution and redeposition dynamics near battery electrode surface. Nat. Nanotechnol. 18, 790–797 (2023). https://doi.org/10.1038/s41565-023-01367-6
  72. D.H. Jang, Y.J. Shin, S.M. Oh, Dissolution of spinel oxides and capacity losses in 4 V Li / Li x Mn2 O 4 cells. J. Electrochem. Soc. 143, 2204–2211 (1996). https://doi.org/10.1149/1.1836981
  73. X. Gao, Y.H. Ikuhara, C.A.J. Fisher, R. Huang, A. Kuwabara et al., Oxygen loss and surface degradation during electrochemical cycling of lithium-ion battery cathode material LiMn2O4. J. Mater. Chem. A 7, 8845–8854 (2019). https://doi.org/10.1039/C8TA08083F
  74. T. Liu, A. Dai, J. Lu, Y. Yuan, Y. Xiao et al., Correlation between manganese dissolution and dynamic phase stability in spinel-based lithium-ion battery. Nat. Commun. 10, 4721 (2019). https://doi.org/10.1038/s41467-019-12626-3
  75. H. Yaghoobnejad Asl, A. Manthiram, Proton-induced disproportionation of jahn–teller-active transition-metal ions in oxides due to electronically driven lattice instability. J. Am. Chem. Soc. 142, 21122–21130 (2020). https://doi.org/10.1021/jacs.0c10044
  76. W. Li, Review—an unpredictable hazard in lithium-ion batteries from transition metal ions: dissolution from cathodes, deposition on anodes and elimination strategies. J. Electrochem. Soc. 167, 090514 (2020). https://doi.org/10.1149/1945-7111/ab847f
  77. Z. Zhao, W. Zhang, M. Liu, S.J. Yoo, N. Yue et al., Ultrafast nucleation reverses dissolution of transition metal ions for robust aqueous batteries. Nano Lett. 23(11), 5307–5316 (2023). https://doi.org/10.1021/acs.nanolett.3c01435
  78. C. Zhan, T. Wu, J. Lu, K. Amine, Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes–a critical review. Energy Environ. Sci. 11, 243–257 (2018). https://doi.org/10.1039/C7EE03122J
  79. L. Chen, W. Sun, K. Xu, Q. Dong, L. Zheng et al., How Prussian blue analogues can be stable in concentrated aqueous electrolytes. ACS Energy Lett. 7, 1672–1678 (2022). https://doi.org/10.1021/acsenergylett.2c00292
  80. J. Agrisuelas, J.J. García-Jareño, D. Gimenez-Romero, F. Vicente, Insights on the mechanism of insoluble-to-soluble Prussian blue transformation. J. Electrochem. Soc. 156, P149 (2009). https://doi.org/10.1149/1.3177258
  81. Y. Huang, S. Ren, Multifunctional Prussian blue analogue magnets: emerging opportunities. Appl. Mater. Today 22, 100886 (2021). https://doi.org/10.1016/j.apmt.2020.100886
  82. C. Liu, X. Xie, B. Lu, J. Zhou, S. Liang, Electrolyte strategies toward better zinc-ion batteries. ACS Energy Lett. 6, 1015–1033 (2021). https://doi.org/10.1021/acsenergylett.0c02684
  83. F. Wang, W. Sun, Z. Shadike, E. Hu, X. Ji et al., How water accelerates bivalent ion diffusion at the electrolyte/electrode interface. Angew. Chem. Int. Ed. 57, 11978–11981 (2018). https://doi.org/10.1002/anie.201806748
  84. J. Yue, L. Lin, L. Jiang, Q. Zhang, Y. Tong et al., Interface concentrated-confinement suppressing cathode dissolution in water-in-salt electrolyte. Adv. Energy Mater. 10, 2000665 (2020). https://doi.org/10.1002/aenm.202000665
  85. X. Dong, Y.-G. Wang, Y. Xia, Promoting rechargeable batteries operated at low temperature. Acc. Chem. Res. 54, 3883–3894 (2021). https://doi.org/10.1021/acs.accounts.1c00420
  86. H.Y. Asl, A. Manthiram, Reining in dissolved transition-metal ions. Science 369, 140–141 (2020). https://doi.org/10.1126/science.abc5454
  87. J. Cattermull, M. Pasta, A.L. Goodwin, Structural complexity in Prussian blue analogues. Mater. Horiz. 8, 3178–3186 (2021). https://doi.org/10.1039/d1mh01124c
  88. Z. Caixiang, J. Hao, J. Zhou, X. Yu, B. Lu, Interlayer-engineering and surface-substituting manganese-based self-evolution for high-performance potassium cathode. Adv. Energy Mater. 13, 2203126 (2023). https://doi.org/10.1002/aenm.202203126
  89. B. Liu, Q. Zhang, U. Ali, Y. Li, Y. Hao et al., Solid-solution reaction suppresses the Jahn-Teller effect of potassium manganese hexacyanoferrate in potassium-ion batteries. Chem. Sci. 13, 10846–10855 (2022). https://doi.org/10.1039/d2sc03824b
  90. F.D. Speck, A. Zagalskaya, V. Alexandrov, S. Cherevko, Periodicity in the electrochemical dissolution of transition metals. Angew. Chem. Int. Ed. 60, 13343–13349 (2021). https://doi.org/10.1002/anie.202100337
  91. T. Zhang, Y. Tang, S. Guo, X. Cao, A. Pan et al., Fundamentals and perspectives in developing zinc-ion battery electrolytes: a comprehensive review. Energy Environ. Sci. 13, 4625–4665 (2020). https://doi.org/10.1039/D0EE02620D
  92. Z. Xing, G. Xu, J. Han, G. Chen, B. Lu et al., Facing the capacity fading of vanadium-based zinc-ion batteries. Trends Chem. 5, 380–392 (2023). https://doi.org/10.1016/j.trechm.2023.02.008
  93. K. Nakamoto, R. Sakamoto, M. Ito, A. Kitajou, S. Okada, Effect of concentrated electrolyte on aqueous sodium-ion battery with sodium manganese hexacyanoferrate cathode. Electrochemistry 85, 179–185 (2017). https://doi.org/10.5796/electrochemistry.85.179
  94. D.P. Leonard, Z. Wei, G. Chen, F. Du, X. Ji, Water-in-salt electrolyte for potassium-ion batteries. ACS Energy Lett. 3, 373–374 (2018). https://doi.org/10.1021/acsenergylett.8b00009
  95. J. Han, H. Zhang, A. Varzi, S. Passerini, Fluorine-free water-in-salt electrolyte for green and low-cost aqueous sodium-ion batteries. ChemSusChem 11, 3704–3707 (2018). https://doi.org/10.1002/cssc.201801930
  96. L. Jiang, L. Liu, J. Yue, Q. Zhang, A. Zhou et al., High-voltage aqueous Na-ion battery enabled by inert-cation-assisted water-in-salt electrolyte. Adv. Mater. 32, e1904427 (2020). https://doi.org/10.1002/adma.201904427
  97. Z. Hou, X. Zhang, X. Li, Y. Zhu, J. Liang et al., Surfactant widens the electrochemical window of an aqueous electrolyte for better rechargeable aqueous sodium/zinc battery. J. Mater. Chem. A 5, 730–738 (2017). https://doi.org/10.1039/C6TA08736A
  98. Z. Liang, F. Tian, G. Yang, C. Wang, Enabling long-cycling aqueous sodium-ion batteries via Mn dissolution inhibition using sodium ferrocyanide electrolyte additive. Nat. Commun. 14, 3591 (2023). https://doi.org/10.1038/s41467-023-39385-6
  99. J. Chen, S. Lei, S. Zhang, C. Zhu, Q. Liu et al., Dilute aqueous hybrid electrolyte with regulated core-shell-solvation structure endows safe and low-cost potassium-ion energy storage devices. Adv. Funct. Mater. 33, 2215027 (2023). https://doi.org/10.1002/adfm.202215027
  100. D. Zhang, L. Sun, C. Wang, Q. Xue, J. Feng et al., An open-framework structured material: [Ni(en)2]3[Fe(CN)6]2 as a cathode material for aqueous sodium- and potassium-ion batteries. ACS Appl. Mater. Interfaces 14, 16197–16203 (2022). https://doi.org/10.1021/acsami.2c00143
  101. J. Chen, C. Liu, Z. Yu, J. Qu, C. Wang et al., High-energy-density aqueous sodium-ion batteries enabled by chromium hexacycnochromate anodes. Chem. Eng. J. 415, 129003 (2021). https://doi.org/10.1016/j.cej.2021.129003
  102. J.-H. Lee, G. Ali, D.H. Kim, K.Y. Chung, Metal-organic framework cathodes based on a vanadium hexacyanoferrate Prussian blue analogue for high-performance aqueous rechargeable batteries. Adv. Energy Mater. 7, 1601491 (2017). https://doi.org/10.1002/aenm.201601491
  103. J. Xie, L. Ma, J. Li, X. Yin, Z. Wen et al., Self-healing of Prussian blue analogues with electrochemically driven morphological rejuvenation. Adv. Mater. 34, e2205625 (2022). https://doi.org/10.1002/adma.202205625
  104. U. Ali, B. Liu, H. Jia, Y. Li, Y. Li et al., In situ Fe-substituted hexacyanoferrate for high-performance aqueous potassium ion batteries. Small (2023). https://doi.org/10.1002/smll.202305866
  105. M.A. Oliver-Tolentino, J. Vázquez-Samperio, S.N. Arellano-Ahumada, A. Guzmán-Vargas, D. Ramírez-Rosales et al., Enhancement of stability by positive disruptive effect on Mn-Fe charge transfer in vacancy-free Mn-co hexacyanoferrate through a charge/discharge process in aqueous Na-ion batteries. J. Phys. Chem. C 122, 20602–20610 (2018). https://doi.org/10.1021/acs.jpcc.8b05506
  106. Y. Ma, Y. Ma, S.L. Dreyer, Q. Wang, K. Wang et al., High-entropy metal–organic frameworks for highly reversible sodium storage. Adv. Mater. 33, 2101342 (2021). https://doi.org/10.1002/adma.202101342
  107. M. Du, P. Geng, C. Pei, X. Jiang, Y. Shan et al., High-entropy Prussian blue analogues and their oxide family as sulfur hosts for lithium-sulfur batteries. Angew. Chem. Int. Ed. 61, e202209350 (2022). https://doi.org/10.1002/anie.202209350
  108. J. Xing, Y. Zhang, Y. Jin, Q. Jin, Active cation-integration high-entropy Prussian blue analogues cathodes for efficient Zn storage. Nano Res. 16, 2486–2494 (2023). https://doi.org/10.1007/s12274-022-5020-0
  109. X. Zhao, Z. Xing, C. Huang, Investigation of high-entropy Prussian blue analog as cathode material for aqueous sodium-ion batteries. J. Mater. Chem. A 11, 22835–22844 (2023). https://doi.org/10.1039/D3TA04349E
  110. B. Wenger, P.K. Nayak, X. Wen, S.V. Kesava, N.K. Noel et al., Consolidation of the optoelectronic properties of CH3NH3PbBr3 perovskite single crystals. Nat. Commun. 8, 590 (2017). https://doi.org/10.1038/s41467-017-00567-8
  111. M. Xue, Y. Wang, X. Wang, X. Huang, J. Ji, Single-crystal-conjugated polymers with extremely high electron sensitivity through template-assisted in situ polymerization. Adv. Mater. 27, 5923–5929 (2015). https://doi.org/10.1002/adma.201502511
  112. H. Liang, X. Ma, Z. Yang, P. Wang, X. Zhang et al., Emergence of superconductivity in doped glassy-carbon. Carbon 99, 585–590 (2016). https://doi.org/10.1016/j.carbon.2015.12.046
  113. D. Su, A. McDonagh, S.-Z. Qiao, G. Wang, High-capacity aqueous potassium-ion batteries for large-scale energy storage. Adv. Mater. 29, 1604007 (2017). https://doi.org/10.1002/adma.201604007
  114. X. Wu, C. Wu, C. Wei, L. Hu, J. Qian et al., Highly crystallized Na2CoFe(CN)6 with suppressed lattice defects as superior cathode material for sodium-ion batteries. ACS Appl. Mater. Interfaces 8, 5393–5399 (2016). https://doi.org/10.1021/acsami.5b12620
  115. D. Cai, X. Yang, B. Qu, T. Wang, Comparison of the electrochemical performance of iron hexacyanoferrate with high and low quality as cathode materials for aqueous sodium-ion batteries. Chem. Commun. 53, 6780–6783 (2017). https://doi.org/10.1039/C7CC02516E
  116. C. Li, X. Wang, W. Deng, C. Liu, J. Chen et al., Size engineering and crystallinity control enable high-capacity aqueous potassium-ion storage of Prussian white analogues. ChemElectroChem 5, 3887–3892 (2018). https://doi.org/10.1002/celc.201801277
  117. W. Zhang, L. Xia, C. Shi, R. Qi, M. Hu, ting and recycling of insoluble, labile single-crystal coordination polymer through reversible solid-liquid-solid transition. Matter 6, 3394–3412 (2023). https://doi.org/10.1016/j.matt.2023.05.024
  118. X. Liu, Y. Cao, J. Sun, Defect engineering in Prussian blue analogs for high-performance sodium-ion batteries. Adv. Energy Mater. 12, 2202532 (2022). https://doi.org/10.1002/aenm.202202532
  119. M. Wan, R. Zeng, J. Meng, Z. Cheng, W. Chen et al., Post-synthetic and in situ vacancy repairing of iron hexacyanoferrate toward highly stable cathodes for sodium-ion batteries. Nano-Micro Lett. 14, 9 (2021). https://doi.org/10.1007/s40820-021-00742-z
  120. F. Peng, L. Yu, S. Yuan, X.-Z. Liao, J. Wen et al., Enhanced electrochemical performance of sodium manganese ferrocyanide by Na3(VOPO4)2F coating for sodium-ion batteries. ACS Appl. Mater. Interfaces 11, 37685–37692 (2019). https://doi.org/10.1021/acsami.9b12041
  121. F. Feng, S. Chen, S. Zhao, W. Zhang, Y. Miao et al., Enhanced electrochemical performance of MnFe@NiFe Prussian blue analogue benefited from the inhibition of Mn ions dissolution for sodium-ion batteries. Chem. Eng. J. 411, 128518 (2021). https://doi.org/10.1016/j.cej.2021.128518
  122. C. Xu, Y. Ma, J. Zhao, P. Zhang, Z. Chen et al., Surface engineering stabilizes rhombohedral sodium manganese hexacyanoferrates for high-energy Na-ion batteries. Angew. Chem. Int. Ed. 62, e202217761 (2023). https://doi.org/10.1002/anie.202217761
  123. M. Lucero, D.B. Armitage, X. Yang, S.K. Sandstrom, M. Lyons et al., Ball milling-enabled Fe2.4+ to Fe3+ redox reaction in Prussian blue materials for long-life aqueous sodium-ion batteries. ACS Appl. Mater. Interfaces 15, 36366–36372 (2023). https://doi.org/10.1021/acsami.3c07304
  124. E. Nossol, V.H.R. Souza, A.J.G. Zarbin, Carbon nanotube/Prussian blue thin films as cathodes for flexible, transparent and ITO-free potassium secondary battery. J. Colloid Interface Sci. 478, 107–116 (2016). https://doi.org/10.1016/j.jcis.2016.05.056
  125. M. Morant-Giner, R. Sanchis-Gual, J. Romero, A. Alberola, L. García-Cruz et al., Prussian Blue@MoS2 layer composites as highly efficient cathodes for sodium-and potassium-ion batteries. Adv. Funct. Mater. 28, 1706125 (2018). https://doi.org/10.1002/adfm.201706125
  126. M. Zhang, T. Dong, D. Li, K. Wang, X. Wei et al., High-performance aqueous sodium-ion battery based on graphene-doped Na2MnFe(CN)6–zinc with a highly stable discharge platform and wide electrochemical stability. Energy Fuels 35, 10860–10868 (2021). https://doi.org/10.1021/acs.energyfuels.1c01095
  127. C.D. Wessells, S.V. Peddada, R.A. Huggins, Y. Cui, Nickel hexacyanoferrate nanop electrodes for aqueous sodium and potassium ion batteries. Nano Lett. 11, 5421–5425 (2011). https://doi.org/10.1021/nl203193q
  128. Y. Zhang, J. Xu, Z. Li, Y. Wang, S. Wang et al., All-climate aqueous Na-ion batteries using “water-in-salt” electrolyte. Sci. Bull. 67, 161–170 (2022). https://doi.org/10.1016/j.scib.2021.08.010
  129. T.Y. Pan, C.Y. Ruqia, C.S. Wu, S.G. Ni et al., Improvement in cycling stability of Prussian blue analog-based aqueous sodium-ion batteries by ligand substitution and electrolyte optimization. Electrochim. Acta 427, 140778 (2022). https://doi.org/10.1016/j.electacta.2022.140778
  130. J. Liu, C. Yang, B. Wen, B. Li, Y. Liu, Ultra-long cycle of Prussian blue analogs achieved by equilibrium electrolyte for aqueous sodium-ion batteries. Small 19, e2303896 (2023). https://doi.org/10.1002/smll.202303896
  131. S. Husmann, A.J.G. Zarbin, R.A.W. Dryfe, High-performance aqueous rechargeable potassium batteries prepared via interfacial synthesis of a Prussian blue-carbon nanotube composite. Electrochim. Acta 349, 136243 (2020). https://doi.org/10.1016/j.electacta.2020.136243
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