Issue

Vol. 9 No. 2 (2017)

BiVO4/TiO2(N2) Nanotubes Heterojunction Photoanode for Highly Efficient Photoelectrocatalytic Applications

https://doi.org/10.1007/s40820-016-0115-3
Rui Wang
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China
Jing Bai
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China
Yunpo Li
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China
Qingyi Zeng
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China
Jinhua Li
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China
Baoxue Zhou
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China

Corresponding Author: Baoxue Zhou

zhoubaoxue@sjtu.edu.cn

Nano-Micro Letters, Vol. 9 No. 2 (2017), Article Number: 14

Abstract

We report the development of a novel visible response BiVO4/TiO2(N2) nanotubes photoanode for photoelectrocatalytic applications. The nitrogen-treated TiO2 nanotube shows a high carrier concentration rate, thus resulting in a high efficient charge transportation and low electron–hole recombination in the TiO2–BiVO4. Therefore, the BiVO4/TiO2(N2) NTs photoanode enabled with a significantly enhanced photocurrent of 2.73 mA cm−2 (at 1 V vs. Ag/AgCl) and a degradation efficiency in the oxidation of dyes under visible light. Field emission scanning electron microscopy, X-ray diffractometry, energy-dispersive X-ray spectrometer, and UV–Vis absorption spectrum were conducted to characterize the photoanode and demonstrated the presence of both metal oxides as a junction composite.

Keywords

BiVO4 TiO2(N2) nanotube Heterojunction Photoelectrocatalytic Degradation of dyes
Wang, Rui, Jing Bai, Yunpo Li, Qingyi Zeng, Jinhua Li, and Baoxue Zhou. 2016. “BiVO4/TiO2(N2) Nanotubes Heterojunction Photoanode for Highly Efficient Photoelectrocatalytic Applications”. Nano-Micro Letters 9 (2):14. https://doi.org/10.1007/s40820-016-0115-3.
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. M.G. Walter, E.L. Warren, J.R. McKone, S.W. Boettcher, Q.X. Mi, E.A. Santori, N.S. Lewis, Solar water splitting cells. Chem. Rev. 110(11), 6446–6473 (2010). doi:10.1021/cr1002326
  2. J. Bai, J.H. Li, Y.B. Liu, B.X. Zhou, W.M. Cai, A new glass substrate photoelectrocatalytic electrode for efficient visible-light hydrogen production: CdS sensitized TiO2 nanotube arrays. Appl. Catal. B 95(3–4), 408–413 (2010). doi:10.1016/j.apcatb.2010.01.020
  3. Z. Liu, X. Zhang, S. Nishimoto, M. Jin, D.A. Tryk, T. Murakami, A. Fujishima, Highly ordered TiO2 nanotube arrays with controllable length for photoelectrocatalytic degradation of phenol. J. Phys. Chem. C 112(1), 253–259 (2008). doi:10.1021/jp0772732
  4. J. Bai, Y.B. Liu, J.H. Li, B.X. Zhou, Q. Zheng, W.M. Cal, A novel thin-layer photoelectrocatalytic (PEC) reactor with double-faced titania nanotube arrays electrode for effective degradation of tetracycline. Appl. Catal. B 98(3–4), 154–160 (2010). doi:10.1016/j.apcatb.2010.05.024
  5. J.W. Tang, Z.G. Zou, J.H. Ye, Efficient photocatalytic decomposition of organic contaminants over CaBi2O4 under visible-light irradiation. Angew. Chem. Int. Ed. 43(34), 4463–4466 (2004). doi:10.1002/anie.200353594
  6. Z.G. Zou, H. Arakawa, Direct water splitting into H2 and O2 under visible light irradiation with a new series of mixed oxide semiconductor photocatalysts. J. Photochem. Photobiol. A 158(2–3), 145–162 (2003). doi:10.1016/S1010-6030(03)00029-7
  7. A. Kudo, Photocatalyst materials for water splitting. Catal. Surv. Asia 7(1), 31–38 (2003). doi:10.1023/A:1023480507710
  8. Y. Park, K.J. McDonald, K.S. Choi, Progress in bismuth vanadate photoanodes for use in solar water oxidation. Chem. Soc. Rev. 42(6), 2321–2337 (2013). doi:10.1039/C2CS35260E
  9. Y.B. Kuang, Q.X. Jia, H. Nishiyama, T. Yamada, A. Kudo, K. Domen, A front-illuminated nanostructured transparent BiVO4 photoanode for >2% efficient water splitting. Adv. Energy Mater. 6(2), 1501645 (2016). doi:10.1002/aenm.201501645
  10. S.M. Thalluri, S. Hernandez, S. Bensaid, G. Saracco, N. Russo, Green-synthesized W- and Mo-doped BiVO4 oriented along the 040 facet with enhanced activity for the sun-driven water oxidation. Appl. Catal. B 180, 630–636 (2016). doi:10.1016/j.apcatb.2015.07.029
  11. T.W. Kim, K.S. Choi, Nanoporous BiVO4 photoanodes with dual-layer oxygen evolution catalysts for solar water splitting. Science 343(6174), 990–994 (2014). doi:10.1126/science.1246913
  12. L. Zhang, D.R. Chen, X.L. Jiao, Monoclinic structured BiVO4 nanosheets: hydrothermal preparation, formation mechanism, and coloristic and photocatalytic properties. J. Phys. Chem. B 110(6), 2668–2673 (2006). doi:10.1021/jp056367d
  13. Y. Hu, D.Z. Li, Y. Zheng, W. Chen, Y.H. He, Y. Shao, X.Z. Fu, G.C. Xiao, BiVO4/TiO2 nanocrystalline heterostructure: a wide spectrum responsive photocatalyst towards the highly efficient decomposition of gaseous benzene. Appl. Catal. B 104(1–2), 30–36 (2011). doi:10.1016/j.apcatb.2011.02.031
  14. J. Bai, B.X. Zhou, Titanium dioxide nanomaterials for sensor applications. Chem. Rev. 114(19), 10131–10176 (2014). doi:10.1021/cr400625j
  15. X.Z. Lan, J. Bai, S. Masala, S.M. Thon, Y. Ren et al., Self-Assembled, nanowire network electrodes for depleted bulk heterojunction solar cells. Adv. Mater. 25(12), 1769–1773 (2013). doi:10.1002/adma.201203759
  16. B. Gao, Y.J. Kim, A.K. Chakraborty, W.I. Lee, Efficient decomposition of organic compounds with FeTiO3/TiO2 heterojunction under visible light irradiation. Appl. Catal. B 83(3–4), 202–207 (2008). doi:10.1016/j.apcatb.2008.02.017
  17. K. Sridharan, E. Jang, T.J. Park, Novel visible light active graphitic C3N4–TiO2 composite photocatalyst: synergistic synthesis, growth and photocatalytic treatment of hazardous pollutants. Appl. Catal. B 142, 718–728 (2013). doi:10.1016/j.apcatb.2013.05.077
  18. Y. Liu, H. Zhou, J. Li, H. Chen, D. Li, B. Zhou, W. Cai, Enhanced photoelectrochemical properties of Cu2O-loaded short TiO2 nanotube array electrode prepared by sonoelectrochemical deposition. Nano-Micro Lett. 2(4), 277–284 (2010). doi:10.3786/nml.v2i4.p277-284
  19. M.Z. Xie, X.D. Fu, L.Q. Jing, P. Luan, Y.J. Feng, H.G. Fu, Long-lived, visible-light-excited charge carriers of TiO2/BiVO4 nanocomposites and their unexpected photoactivity for water splitting. Adv. Energy Mater. 4(5), 1300995 (2014). doi:10.1002/aenm.201300995
  20. H.F. Li, H.T. Yu, X. Quan, S. Chen, H.M. Zhao, Improved photocatalytic performance of heterojunction by controlling the contact facet: high electron transfer capacity between TiO2 and the 110 facet of BiVO4 caused by suitable energy band alignment. Adv. Funct. Mater. 25(20), 3074–3080 (2015). doi:10.1002/adfm.201500521
  21. J. Bai, R. Wang, Y.P. Li, Y.Y. Tang, Q.Y. Zeng et al., A solar light driven dual photoelectrode photocatalytic fuel cell (PFC) for simultaneous wastewater treatment and electricity generation. J. Hazard. Mater. 311, 51–62 (2016). doi:10.1016/j.jhazmat.2016.02.052
  22. L.E. Greene, M. Law, J. Goldberger, F. Kim, J.C. Johnson, Y.F. Zhang, R.J. Saykally, P.D. Yang, Low-temperature wafer-scale production of ZnO nanowire arrays. Angew. Chem. Int. Ed. 42(26), 3031–3034 (2003). doi:10.1002/anie.200351461
  23. J.H. Lee, I.C. Leu, M.C. Hsu, Y.W. Chung, M.H. Hon, Fabrication of aligned TiO2 nanostructured arrays using a one-step templating solution approach. J. Phys. Chem. B 109(27), 13056–13059 (2005). doi:10.1021/jp052203l
  24. Q.X. Jia, K. Iwashina, A. Kudo, Facile fabrication of an efficient BiVO4 thin film electrode for water splitting under visible light irradiation. Proc. Natl. Acad. Sci. 109(29), 11564–11569 (2012). doi:10.1073/pnas.1204623109
  25. V.K. Mahajan, M. Misra, K.S. Raja, S.K. Mohapatra, Self-organized TiO2 nanotubular arrays for photoelectrochemical hydrogen generation: effect of crystallization and defect structures. J. Phys. D 41(12), 125307 (2008). doi:10.1088/0022-3727/41/12/125307
  26. C. Jin, W.G. Zhang, S.W. Yao, H.Z. Wang, Effect of heat-treatment process on the structure and photoelectric performance of TiO2 nanotube arrays. J. Inorg. Mater. 27(1), 54–58 (2012). doi:10.3724/SP.J.1077.2012.00054
  27. R.P. Vitiello, J.M. Macak, A. Ghicov, H. Tsuchiya, L.F.P. Dick, N-doping of anodic TiO2 nanotubes using heat treatment in ammonia. Electrochem. Commun. 8(4), 544–548 (2006). doi:10.1016/j.elecom.2006.01.023
  28. A. Iwase, A. Kudo, Photoelectrochemical water splitting using visible-light-responsive BiVO4 fine particles prepared in an aqueous acetic acid solution. J. Mater. Chem. 20(35), 7536–7542 (2010). doi:10.1039/c0jm00961j
  29. C. Liu, Y. Ding, W. Wu, Y. Teng, A simple and effective strategy to fast remove chromium (VI) and organic pollutant in photoelectrocatalytic process at low voltage. Chem. Eng. J. 306, 22–30 (2016). doi:10.1016/j.cej.2016.07.043
  30. X. Zhao, J.J. Zhang, M. Qiao, H.J. Liu, J.H. Qu, Enhanced photoelectrocatalytic decomposition of copper cyanide complexes and simultaneous recovery of copper with a Bi2MoO6 electrode under visible light by EDTA/K4P2O7. Environ. Sci. Technol. 49(7), 4567–4574 (2015). doi:10.1021/es5062374
  31. L. Liu, R. Li, Y. Liu, J. Zhang, Simultaneous degradation of loxacin and recovery of Cu(II) by photoelectrocatalysis with highly ordered TiO2 nanotubes. J. Hazard. Mater. 308, 264–275 (2016). doi:10.1016/j.jhazmat.2016.01.046
  32. A.G. Munoz, Semiconducting properties of self-organized TiO2 nanotubes. Electrochim. Acta 52(12), 4167–4176 (2007). doi:10.1016/j.electacta.2006.11.035
  33. J. Kruger, R. Plass, M. Gratzel, P.J. Cameron, L.M. Peter, Charge transport and back reaction in solid-state dye-sensitized solar cells: a study using intensity-modulated photovoltage and photocurrent spectroscopy. J. Phys. Chem. B 107(31), 7536–7539 (2003). doi:10.1021/jp0348777
Read More
Author biographies are not available.
Download this PDF file
PDF SUPPLEMENTARY MATERIAL
Statistic
Read Counter : 3261 Download : 2475

Most read articles by the same author(s)